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All sourcesNASA NTRSDOE OSTI
NASA NTRS2019

Near-saturation Conditions at the Tropical Tropopause: Results from Ticosonde

Balloon-borne frostpoint measurements have shown a high frequency of supersaturation near the tropical tropopause, and this has been attributed to forced ascent associated with wavemotions as well as diabatic heating. Long-term profile statistics are typically presented on altitude, pressure or potential temperature surfaces. For example, at Costa Rica long-term mean values of CFH RH at 16.8 km, the mean annual height of the tropopause, range from less than 60 percent in July to over 90% in October. While a plot of the annual cycle vs height shows relatively high humidities in the upper troposphere and especially so as one approaches the tropopause, the overall picture is one of subsaturation. A very different picture emerges,however, if the analysis is done in height relative to the tropopause. Here the long-term average of RH at the tropopause is 94 percent or greater throughout the year. We discuss this paradoxical result in the context of dynamical and cloud processes occurring near the tropical tropopause.

Tropical↗
NASA NTRS2019

Ozonesonde Quality Assurance: JOSIE-SHADOZ (2017) and SHALLOTS (2018)

Ozonesonde data constitute a mainstay of satellite calibration and are used for climatologies and analysis of trends, especially in the lower stratosphere where satellites are most uncertain. The electrochemical-concentration cell (ECC) ozonesonde has been deployed at ~100 stations worldwide since the 1960s, with changes over time in manufacture and procedures, including details of the cell chemical solution and data processing. As a consequence, there are biases among different stations and discontinuities in profile timeseries from individual site records. Since 1996 the Jülich [Germany] Ozone Sonde Intercomparison Experiment (JOSIE) has periodically tested ozonesondes in a simulation chamber designated the World Calibration Centre for Ozonesondes by WMO. In October- November 2017 a JOSIE campaign evaluated the sondes and procedures used in SHADOZ (Southern Hemisphere Additional Ozonesondes), a 14-station tropical and subtropical network. A distinctive feature of the 2017 JOSIE was that the tests were conducted by operators from eight SHADOZ stations; Nairobi, Natal, Irene, Costa Rica, Paramaribo, Reunion, Hanoi, Kuala Lumpur. Experimental protocols and preliminary results for the SHADOZ sonde configurations, which represent most of those in use today, are described. SHADOZ stations that follow WMO-recommended protocols record total ozone within 3% of the JOSIE reference instrument. Instrument biases noted in prior JOSIE and field tests like BESOS (2004) were noted in JOSIE-2017, with maximum effect in the stratosphere. In June 2018 we organized a series of dual launches during the OWLETS II campaign in the Maryland and Chesapeake Bay area (SHALLOTS = SHADOZ-OWLETS ParaLLel Ozonesonde Test Study). Instrument and solution types were varied as in JOSIE-2017 and three radiosonde-ozonesonde variants were tested. An example of a parallel sampling in SHALLOTS, from a Greenbelt EnSCI-iMet sonde combination flown with the Wallops SPCLMS package, is illustrated in the Figure. The result was a range of biases but in general the instrument combination (EnSCI-iMet) deployed at 11 SHADOZ stations recorded ~5-10% less ozone in the stratosphere than the SPC ECC sonde flown with a Vaisala or LMS system. These 2017 and 2018 results and prior JOSIEs demonstrate that regular testing is essential to maintain best practices in ozonesonde operations and to ensure high-quality data for the ozone assessment communities.

Quality assurance↗
NASA NTRS2019

Near-Saturation Conditions at the Tropical Tropopause: Results from Ticosonde

The TTL lies between the neutral buoyancy level (NBL) at ~350 K and the tropopause. Within the the TTL radiative heating drives ascent and air parcel supersaturation. Ticosonde measurements since 2005 show that the incidence ofsupersaturation in the TTL over Costa Rica is ~60%. This is due to diabatic ascent. The frequency is highest (68%) in summer, when convection is frequent. The TSL was defined by Selkirk et al. (2010) as the upper edge of the TTL. It isIn this layer that the final saturation of air parcels rising into the stratosphere occurs and thus the water vapor minima which define the so-called "writehead" of the Atmospheric Tape Recorder.

Selkirk, Henry↗
NASA NTRS2017

NASA Experience with Large and Small UAS for Atmospheric Science

NASA's unmanned aerial systems (UAS) have been utilized in many science missions, going all the way back to 1993. Some of these missions have targeted imagery (fire, vegetation) and surface measurements, but many have been applied to atmospheric research, both physical (dynamics, weather, etc.) and chemical (e.g.,composition). NASA's largest UAS, the Global Hawk, has been used to study atmospheric composition at the tropical tropopause in the Airborne Tropical TRopopause EXperiment (ATTREX) mission, where the benefit of the UAS was long range and especially duration of up to 24 hours. Two Global Hawks were used in the Hurricane and Severe Storm Sentinal (HS3) mission to observe hurricane development. Again, long duration at altitude was the significant feature of the UAS. At the smallest scale, NASA has flown DragonEye UAS to measure volcanic gas emissions in both Costa Rica and Hawaii. The small DragonEye could sample gases in hazardous locations where manned aircraft could not fly. At mid-size, the NASA SIERRA UAS has flown imaging payloads and chemical remote sensing instruments in local and international settings. Theseexperiences provide direction for best use of UAS in atmospheric science, which will be presented.

Schoenung, Susan↗
NASA NTRS2020

Organic Matter in the Aguas Zarcas (CM2) Meteorite: High Abundance of Aliphatic Carbon in Metal-Rich Lithology

The Aguas Zarcas meteorite is a new CM2 chondrite which fell on 23 April 2019 (local time) in Costa Rica. Aguas Zarcas is brecciated and contains several different lithologies, e.g., metal-rich lithology and CI-like lithology. This fresh CM2 chondrite gives us good op-portunities for analyses of organic matter (OM) without terrestrial contamination and weathering, particularly some stones which were collected before rain fell over the fall site. We also aim to characterize local hetero-geneities and associations of organic and mineral phases using state-of-the-art microscopic techniques to con-strain the origin and evolutionally processes of OM during pre- and post-accretion.

Kebukawa, Y.↗
NASA NTRS2020

Characteristics of a New Carbonaceous Chondrite, Metal-Rich-Lithology Found in the Carbonaceous Chondrite Breccia Aguas Zarcas

The Aguas Zarcas meteorite fell in Costa Rica on 23 April 2019 at 21:07 local time, with a total mass of about 27 kg. Hundreds of fusion-crusted stones ranging from 0.1 to 1868 g were recovered (The Meteoritical Bulletin). The meteorite was classified as a CM chondrite, but some lithlogies show a different texture to that of CM. In this study, we investigated the petrography, mineral-ogy, chemistry, and isotopic composition of an unusual “Metal-rich-lithology” from this fresh fall.

Kerraouch, I.↗
NASA NTRS2018

TPSAS-NF1676L-31995-DND

The Osa Peninsula, located in the southern region of Costa Rica’s Pacific Coast, is one of the most biologically-diverse places on Earth and is a popular ecotourism destination. However, the area faces watershed degradation and loss of biodiversity due to deforestation, pollution from agriculture, and human settlement. The NASA DEVELOP National Program worked with Osa Conservation to analyze land use and land cover change in the Osa Peninsula to better understand threats to river water quality and mangrove health. This project used Landsat 5 Thematic Mapper (TM), Landsat 8 Operational Land Imager (OLI), and Terra Advanced Spaceborne Thermal Emission and Reflection Radiometer (ASTER) to create a land cover time series map from 1987 to 2017. These time series data were used to compare land use over time, as well as patterns in water quality, mangrove health, erosion, and deforestation. The time series also helped to identify the impact of the creation of protected areas and the 1996 Forest Law 7575, which aimed to support reforestation and riparian health. Osa Conservation will use and distribute results to the National System of Conservation Areas (SINAC), Ministry of Environment and Energy (MINAE), and local communities to inform land management decisions, policy enforcement, education and outreach initiatives, and watershed restoration and monitoring.

Suravi Shrestha↗
NASA NTRS2020

Extraterrestrial Organic Compounds and Cyanide in the CM2 Carbonaceous Chondrites Aguas Zarcas and Murchison

Evaluating the water-soluble organic composition of carbonaceous chondrites is key to understanding the inventory of organic matter present at the origins of the solar system and the subsequent processes that took place inside asteroid parent bodies. Here, we present a side-by-side analysis and comparison of the abundance and molecular distribution of aliphatic amines, aldehydes, ketones, mono- and dicarboxylic acids, and free and acid-releasable cyanide species in the CM2 chondrites Aguas Zarcas and Murchison. The Aguas Zarcas meteorite is a recent fall that occurred in central Costa Rica and constitutes the largest recovered mass of a CM-type meteorite after Murchison. The overall content of organic species we investigated was systematically higher in Murchison than in Aguas Zarcas. Similar to previous meteoritic organic studies, carboxylic acids were one to two orders of magnitude more abundant than other soluble organic compound classes investigated in both meteorite samples. We did not identify free cyanide in Aguas Zarcas and Murchison; however, cyanide species analyzed after acid-digestion of the water-extracted meteorite mineral matrix were detected and were quantified at slightly higher abundances in Aguas Zarcas compared to Murchison. Although there were differences in the total abundances of specific compound classes, these two carbonaceous chondrites showed similar isomeric distributions of aliphatic amines and carboxylic acids, with common traits such as a complete suite of structural isomers that decreases in concentration with increasing molecular weight. These observations agree with their petrologic CM type-2 classification, suggesting that these meteorites experienced similar organic formation processes and/or conditions during parent body aqueous alteration.

Jose Carlos Aponte Silva↗
NASA NTRSDate not supplied

The Aguas Zarcas Breccia - Similarities to Surface Features of Asteroids Ryugu and Bennu

At 21:07 local time on 23rd April 2019, a meteorite fall occurred in Aguas Zarcas, San Carlos County, Alajuela province, Costa Rica. The rapid recovery of this brecciated carbonaceous chondrite after its fall provides an opportunity to investigate a freshly-fallen, relatively uncontaminated and highly-brecciated meteorite for comparison to the samples returned from C-group asteroids by the Hayabusa2 and OSIRIS-REx spacecraft. The study includes several pre-rain fragments. Our X-ray Computed Tomography(XCT) results show many different lithologies. In this study we describe the petrography and mineralogy of five different lithologies of the Aguas Zarcas meteorite. We also present bulk oxygen isotope data of some lithologies and results concerning the organic matter. We describe all the fragments in detail and attempt a classification of each lithology in order to understand the origin and the history of formation of the Aguas Zarcas' parent body. Our results show some lithologies of Aguas Zarcas similar to those in CM chondrites, but others are unique. The different lithologies [1] represent different levels of hydration and heating as well, which are good analogues for the types of materials returned from asteroids Bennu and Ryugu. Spectroscopic observations of the Ryugu and Bennu asteroids compared to laboratory measurements of meteorites suggest that the asteroids show some similarities to heated CM, heated CI or, CI chondrites [2-5]. Both asteroids are regarded to consist of materials altered by aqueous alteration (e.g., [5]) and formed by re-accretion after impact destruction and brecciation (e.g., [6-7]). Considering the various different lithologies in Aguas Zarcas [2] and other CM chondrites [8-9] these types of carbonaceous chondrites may be regarded as good analogues for samples from the Ryugu and Bennu asteroids. The presence of unique and rare lithologies in the Aguas Zarcas, that are distinct from typical CM chondrite lithologies, indicates a complex mixing of various materials in a highly dynamic environment.

Imene Kerraouch↗
NASA NTRSDate not supplied

Building Capacity to Use Earth Observations for Ecosystem Services & Biodiversity Applications: A Summary of NASA’s DEVELOP Program and Projects in Central and South America

NASA’s DEVELOP program engages individuals and organizations in 10-week feasibility studies to apply NASA Earth observations (EO) to decision makers’ needs. Since 2018, DEVELOP conducted 21 projects in Central and South America, eight of those in collaboration with Sistema de la Integración Centroamericana (SICA) and its member state partner agencies. These projects addressed a diverse set of community needs across multiple themes, including 11 addressing issues related to biodiversity and ecosystem services that utilized a suite of EO to measure and monitor deforestation, habitat suitability, and land change impacts on watershed health in Peru, Costa Rica, Panama, Honduras, and Colombia. This poster introduces DEVELOP, its approach to capacity building, key partnerships, and project results highlighting the capabilities of EO for enhanced decision making in the area of ecosystem services and biodiversity.

Capacity Building↗
NASA NTRS2021

Central America Disasters: Using Earth Observations to Map Flooding for Disaster Monitoring, Inform Potential Risk, and Prepare for Possible Response

In November 2020, Hurricanes Eta and Iota hit Central America within weeks of each other, causing severe flooding, landslides, and widespread damage. NASA DEVELOP partnered with Comité Regional de Recursos Hidráulicos (CRRH), Centro de Coordinación para la Prevención de los Desastres en América Central y República Dominicana (CEPREDENAC), and Sistema de la Integración Centroamericana (SICA) to better understand how flooding throughout Central America has impacted and will continue to affect communities, focusing on sites in Guatemala, Honduras, El Salvador, Belize, Nicaragua, western Panama, and eastern Costa Rica from January 2015 to October 2021. The team utilized surface reflectance data from Landsat 7 Enhanced Thematic Mapper Plus (ETM+), Landsat 8 Operational Land Imager (OLI), Sentinel-2 MultiSpectral Instrument (MSI), Suomi National Polar-orbiting Partnership (NPP) Visible Infrared Imaging Radiometer Suite (VIIRS), and Terra Moderate Resolution Imaging Spectroradiometer (MODIS). This project also utilized backscatter data from Sentinel-1 C-band Synthetic Aperture Radar (C-SAR) and elevation data from the Shuttle Radar Topography Mission (SRTM). Incorporating these Earth observations in NASA SERVIR’s Hydrologic Remote Sensing Analysis for Floods (HYDRAFloods) tool run on Google Earth Engine (GEE), the team produced historical surface water maps, a case study analysis of the two hurricanes, and a code tutorial. These results indicated that surface water increased in priority sites from 2015 to 2021, optical and SAR imagery detected similar flood patterns and extent after the hurricanes, and rainfall was concentrated on the east coast of the region. These products allow partners to make informed decisions around flooding preparation and disaster mitigation.

Caroline Williams↗
NASA NTRS2021

Near-Optimum Real-Time Range Estimation Algorithms for Proximity Links

The renewed interest in space exploration and cis-lunar situational awareness demands accurate ranging algorithms to enable navigation solutions for a multitude of spacecraft, rovers, and human explorers on the Moon and even on Mars, in the near future. Current state-of-the-art in ground-based ranging accuracy is on the order of 30 cm, however complicated equipment calibration and significant post-processing is required to achieve this level of ranging accuracy. This article examines ad-hoc approaches that achieve near-optimum real-time ranging performance with reduced complexity by utilizing a DPLL (digital phase-locked loop) to track the phase of the residual carrier for both direct and subcarrier modulated PN sequences, and a DCL (digital Costas loop) to obtain independent estimates of carrier phase and optimal combinations of these implementations to achieve near-optimum real-time performance with reduced computational complexity.

Cheung, Kar-Ming↗
NASA NTRSDate not supplied

The Aguas Zarcas Breccia - Similarities to Surface Features of C-Complex Asteroids Ryugu and Bennu

Knowledge of the materials originally present in the proto-solar nebula is one of the most significant constraints for models concerning the formation of our solar system. The physicochemical properties of these original materials can be determined through two distinct and complementary approaches: astronomical observations of nascent stellar systems and the dense clouds from which they originated; and laboratory studies of available astromaterials such as meteorites, interplanetary dust particles, comets, as well as returned mission samples (e.g., from Hayabusa -1 -2;OSIRIS -Rex). Laboratory study of these extraterrestrial materials provides valuable information about the first solids portion of the early solar system and their evolution. Here, we present petrographic and mineralogical characteristics of the polymic beccias Aguas Zarcas based on the research results of [1].On April 23, 2019, at 21:07 local time, a meteorite fall occurred in Aguas Zarcas, San Carlos County, Alajuela province, Costa Rica. The rapid recovery of this brecciated carbonaceous chondrite after its fall provides an opportunity to study a freshly fallen, relatively uncontaminated, and highly brecciated meteorite to compare with samples returned by theHayabusa2 and OSIRIS-REx spacecraft from C-group asteroids. The study includes several pre-rain fragments [1].The X-ray Computed Tomography (XCT) results show many different lithologies. We describe the petrography and mineralogy of five different lithologies of the Aguas Zarcas meteorite. We also present data on bulk oxygen isotopes. We describe all fragments in detail and attempt to classify each lithology in order to understand the origin and formation history of the Aguas Zarcas parent body. Our results show that some lithologies of Aguas Zarcas are similar to those in CM chondrites, but others are unique. The different lithologies [1] also represent different degrees of hydration and heating, which are good analogues for the types of materials returned by the Bennu and Ryugu asteroids. Spectroscopic observations of the Ryugu and Bennu asteroids compared to laboratory measurements of meteorites suggest that the asteroids have some similarities to heated CM, heated CI, or CI chondrites[2-5]. Both asteroids are thought to be composed of materials altered by aqueous alteration (e.g., [5]) and formed by reaccretion after destruction by impacts and brecciation (e.g., [6-7]). Considering the different lithologies in Aguas Zarcas [2] and other CM chondrites [8-9], these types of carbonaceous chondrites can be considered good analogues for samples from the Ryugu and Bennu asteroids. The presence of unique and rare lithologies in the Aguas Zarcas, different from the typical CM chondrite lithologies, suggests complex mixing of different materials in a highly dynamic environment.

Imene Kerraouch↗
NASA NTRSDate not supplied

Spectral and Mineralogical Analyses of Aguas Zarcas in Search of Its Parent Body

Aguas Zarcas is an intriguing carbonaceous chondrite that fell in Aguas Zarcas district, San Carlos, Alajulea, Costa Rica on 23 April 2019 [1]. This carbonaceous chondrite was found to be a breccia at al all scales with diverse lithologies (metal-rich, brecciated CM, and CI) [2]. Here we present spectroscopic and PSD-XRD analyses of a sample of Aguas Zarcas(donated to NASA JSC by Robert Ward) to better understand the origin and parent body for this meteorite. The spectral and mineralogical analyses are placed in the context of the published petrological and geochemical analyses of Aguas Zarcas, and its spectra are compared to a suite of spectra of asteroidal materials, including cabon-bearing asteroids, asteroid returned samples, and carbonaceous chondrites. The focus of this investigation will be on hydrated minerals and carbon-bearing materials, including organics and carbonates.

D. Takir↗
NASA NTRSDate not supplied

Detecting Volcanic Co2 Emissions Hidden in Tropical Volcanic Forests Using Fixed-Wing sUAS

CO2 emissions are among the earliest indicators of subsurface state change and reactivation of volcanic systems and these deep signals reflect in faint diffuse emissions variations on volcanic flanks. Monitoring vast areas of rainforests covering tropical volcanoes is challenging, and space-borne sensors like OCO-2 are not sensitive enough. Fortunately, trees exposed to mild enhancements of CO2 may experience fertilization and build excess CO2 into excess biomass (Cawse-Nicholson, et al. 2018, Biogeosciences). They also process excess CO2 through photosynthesis, measurable by fluorescence (Bogue et al., 2019, Biogeosciences). Furthermore, spaceborne remote sensing instruments have demonstrated increasing NDVI months to years before eruptions, unexplained by other factors (e.g., Houlie et al. 2006, EPSL; Seiler et al. 2017, PLoS One). By providing a means to map large areas of above-canopy CO2 variations over tropical rainforest on the flanks of actively degassing volcanoes, we enable to interpret the signals plants provide in response to excess CO2 with airborne and spaceborne hyperspectral remote sensing methods, including a possible future Surface Biology and Geology (SBG) NASA satellite mission.As a critical step to mature and test this concept, we deployed small unmanned aerial systems (sUAS) using a fixed-wing sUAS designed for autonomous operations and long endurance in extreme environments, without causing significant disturbance of the sampled air. We integrated an in-situ sensor to record the CO2 enhancement field above the forest canopy. Test flight results on the flanks of Turrialba volcano in Costa Rica above forest canopies covering known moderate gas seeps demonstrate the sUAS-borne detection and mapping capabilities of above-canopy elevated CO2 gradients. The strong detection capabilities and high detector signal stability resulted from key system design elements including RF shielding, mechanical stabilization, and calibration procedures. This highly robust system is readily applied for diffuse volcanic CO2 emission studies on active volcanoes covered by dense vegetation.

Volcanic↗
NASA NTRS2022

Mesoamerica Ecological Forecasting: Assessing Land Cover Change to Inform Management Planning for the Mesoamerican Biological Corridor

In 1992, Central America and Mexico drew up an agreement to establish the Mesoamerican Biological Corridor (MBC) which defines natural corridors to connect nearly 600 protected areas. The MBC is home to 9% of the world's terrestrial species on 0.7% of the world's landmass, yet this biodiverse area has been impacted by great levels of deforestation. The MBC supports protected areas and the important conservation efforts that are tied into the area’s economic and sustainable development. The NASA DEVELOP team partnered with NASA SERVIR, Sistema de la Integración Centroamericana (SICA), Tropical Agriculture Research and High Education Center (CATIE), and Ministries of the Environment for Costa Rica, El Salvador, and Guatemala to assess forest cover change in the MBC. While the southern states of Mexico are included in the MBC, the team excluded Mexico in this study. The team acquired data from Landsat 5 Thematic Mapper (TM), Landsat 7 Enhanced Thematic Mapper Plus (ETM+), Landsat 8 Operational Land Imager (OLI), and Landsat 9 OLI-2 to develop a forest versus non-forest classification. This classification was used to create a Land Use Land Cover Change (LULC) trend map and Deforestation Detection Time Series analysis between 1992 and 2022. The team found that minimum distance classification was the most effective classifier for the project scope. Analysis showed that 6.18% of the study area experienced forest loss and 10.99% experienced forest growth. These observations will help partners visualize the evolution and severity of deforestation and allow decision making for future land management and transboundary conservation efforts.

Hanna Jung↗
NASA NTRS2019

Forearc Carbon Sink Reduces Long-Term Volatile Recycling Into the Mantle

Carbon and other volatiles are transported from Earth’s surface into the mantle at subduction margins. The efficiency of this transfer has profound implications for the nature and scale of geochemical heterogeneities in Earth’s deep (mantle) and shallow (crustal) reservoirs, as well as Earth’s oxidation state. However, the proportion of volatiles released in the forearc and backarc are not well constrained compared to fluxes from the volcanic front. Here, we use helium and carbon isotope data from deeply sourced springs along two cross-arc transects to show that ~91% of carbon released from the slab/mantle beneath the Costa Rica forearc is sequestered within the crust by calcite deposition, and an additional ~3% is incorporated into biomass through microbial chemolithoautotrophy. We estimate that ~1.2 × 10(exp 8) to 1.3 × 10(exp 10) mol CO2/yr are released from the slab beneath the forearc, resulting in up to ~19% less carbon being transferred to Earth’s deep mantle than previously estimated.

Carbon cycle↗
DOE OSTI2025

Recent Developments in DFTB+, a Software Package for Efficient Atomistic Quantum Mechanical Simulations

DFTB+ is a flexible, open-source software package developed by its community, designed for fast and efficient atomistic quantum mechanical simulations. It employs various methods that approximate density functional theory (DFT), such as density functional-based tight binding (DFTB) and the extended tight binding (xTB) approach allowing simulations of large systems over extended time scales with reasonable accuracy, while being significantly faster than traditional ab initio methods. In recent years, several new extensions of the DFTB method have been developed and implemented in the DFTB+ program package in order to improve the accuracy and generality of the available simulation results. In this paper, we review those enhancements, show several use case examples and discuss the strengths and limitations of its features.

36 MATERIALS SCIENCE↗