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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 253 records · Page 14

Hybrid Capture for Net-Negative Emissions

The Energy & Environmental Research Center, in partnership with the U.S. Department of Energy and North Dakota ethanol producer Red Trail Energy, LLC (RTE), completed an initial engineering design (IED) for a potential hybrid capture system at the RTE CCS (carbon capture and storage) site. The RTE CCS Project is currently operating a CO2 capture facility, adjacent to the RTE ethanol facility in western North Dakota, and injecting the CO2 more than a mile below RTE property for permanent storage. This novel process would add capturing CO2 produced from natural gas boilers to the existing bioprocessing capture system to achieve a net-negative CO2 emissions industrial process at commercial scale (~310,000 tonnes/yr CO2). Initial findings of the IED showed the hybrid system to be technically viable with a moderate estimated cost of $55/tonne CO2 captured for the hybrid system. A cradle-to-gate life cycle assessment (LCA) was also conducted, showing preliminary net-negative carbon emissions potential anticipated from implementing a hybrid CCS system at a commercial scale. Recommended next steps toward potential implementation include hybrid capture system demonstration testing for detailed engineering and LCA model comparisons with low-carbon fuel incentive programs for financial support.

01 COAL, LIGNITE, AND PEAT↗

Advanced Modular Sub-Atmospheric Hybrid Heat Engine (Final Report)

The Phase 1 Final Technical Report describes the results of the work completed during the “Advanced Modular Sub-Atmospheric Hybrid Heat Engine” project. A key part of the Phase 1 work was the completion of a thermodynamic cycle analysis for the MHHE at the selected module size. The hybrid heat engine has been developed as a modular unit (sized in the range of 500kW – 60MW) that can be used with modular coal or biomass gasifiers, with distributed power generation systems, with large power plants comprised of multiple generating units, and with natural gas compression stations. The MHHE will provide cleaner, more efficient, and lower cost generation with better load following capabilities than existing competing technologies with a singular generating source such as solar farm, gas turbine, or combustion engine. The drivers of the MHHE technology are: benefits of modular power generation (reduced equipment cost, construction cost and implementation time, connection ready on delivery, flexible scalability, serviceability), fuel flexibility, lowest cost power generation and reduced emissions.A logical progression of work and a clear path forward toward meeting the FOA goals and objectives have been established. Namely, a preliminary market analysis and primary fuel identification was completed first and then the modularity of the system was defined. The benefits of the proposed hybrid and modular heat engine were described when applied to modular coal gasifiers, distributed power generators, and larger power plants. Based on the market analysis, modularity, and chosen primary fuel, a conceptual design and layout of the hybrid heat engine was developed, analyzed, and characterized. The technology gaps already identified have been reviewed and expanded upon, and a test plan to address these gaps through bench scale testing in Phase 2 has been developed. Cost estimate methodology and considerations in support of a potential Phase 2 project have been described.

08 HYDROGEN↗

Integration of a Microturbine Power Conversion Unit in MAGNET

The Microreactor Agile Non-nuclear Experimental Testbed (MAGNET) facility is being constructed at Idaho National Laboratory’s (INL’s) Energy Systems Laboratory to assist with the development, demonstration, and validation of microreactor components and systems. MAGNET will accommodate various types of test articles representative of different microreactor designs. A power conversion unit (PCU) simulator loop was proposed to use the rejected heat from the test article and mimic the thermal hydraulic conditions (e.g., temperature, pressure and flow rate) that would be experienced if an actual Brayton cycle PCU was attached. However, due to the high-estimated cost of the PCU simulator and the availability of a turbogenerator used for previous testing at Sandia National Laboratories, the PCU simulator design was abandoned in favor of integrating an actual PCU into MAGNET. A commercial Capstone C30 was modified by Sandia to use external electrical heating, rather than combustion heating, to provide a power output from 1 to ~30 kWe. The C30 has a single-stage centrifugal combustor, a static radial heat exchanger, and a radial inflow turbine arranged on a single shaft with a high-speed alternator. Since the operating temperature and energy transfer per unit working fluid mass are comparable, the MAGNET PCU will provide researchers with the ability to evaluate the test article heat transfer under representative operating conditions with the transient system behavior associated with a closed Brayton cycle PCU. This report examines the integration of a modified commercial Capstone C30 turbogenerator into MAGNET, outlines a proposed set of tests, and describes future work.

22 GENERAL STUDIES OF NUCLEAR REACTORS↗

Pit Disassembly and Processing/Oxidation Capacity (PDP) for Disposition of Surplus Plutonium at Los Alamos (FY2021 Workshop 1) [Slides]

This workshop will establish NNSA/LANL consensus on the planning basis for: updating the 2017 Life Cycle Cost Estimate (LCCE) pre-conceptual estimate by identifying the specific scope elements that will be included; identifying the specific scope elements that will be included in the Line Item project; and identifying the preliminary agenda items for the next PDP workshop.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

DPC Cement Filler Development (Progress Report)

The fillers research and development (R&D) program, mostly experimental, is part of a broader R&D program that includes new process modeling and performance assessment of criticality effects and the overall importance of criticality to repository performance (consequence screening). A literature research and consultation effort with experts by Hardin and Brady (2018) identified several potentially effective and workable filler materials including cements (primarily phosphate based), moltenmetal alloys, and low-temperature glasses. Filler attributes were defined, and the preliminary lists were compared qualitatively. Further comparative analysis will be done (e.g., cost estimates) after experimental screening has narrowed the list of alternatives. The following cement filler compositions were selected for experimental development work and accelerated testing in FY20: Aluminum phosphate cements (APCs); more specifically aluminum oxide / aluminum phosphate (Al 2 O 3 / AlPO 4 ) cements in which Al 2 O 3 serves as the filler material bound by an AlPO 4 binder formed by the reaction of Al 2 O 3 with H 3 PO 4 ; Calcium phosphate cements (CPCs); more specifically composed of pure or nearly pure hydroxyapatite or HAP (Ca 5 (PO 4 ) 3 (OH)); Wollastonite phosphate cements (WPC), specifically wollastonite and aluminum or calcium aluminum phosphates in which CaSiO 3 serves as the filler material and the phosphate serves as the binder. The FY20 effort focused on the optimization of compositions and subsequent processing of these three materials to achieve dense and well-consolidated monolithic samples with 30 to 40% porosity and permeabilities of 1 millidarcy. At the close of this progress report the aluminum phosphate cements (APCs) and the wollastonite phosphate cements (WPCs) appear to show the most promise for continued development. Less progress has been made with the calcium phosphate cements (CPCs); their slurry viscosities are high (and difficult to measure) and they exhibit relatively short cure times of 2 to 3 hours with concomitant and excessive volatile (e.g. CO 2 ) generation.

36 MATERIALS SCIENCE↗

Preliminary Technoeconomic Analysis for Power Generation from Coal Water Slurry Using Modular Staged-OMB Gasifier

Trimeric performed a technoeconomic analysis for a proposed 5 MWe gross modular gasification power generation facility. The cost estimate was used to determine the economic advantages of the proposed modular, staged-OMB gasifier in comparison to other modular gasifier designs. The project, Staged OMB for Modular Gasifier/Burner, is led by The University of Kentucky Center for Applied Energy Research (UK CAER) and supported by East China University of Science and Technology (ECUST) and Trimeric Corporation. A high-level summary of the findings from this project are presented below.

10 SYNTHETIC FUELS↗

Development and Advanced Testing of DPC Cement Fillers

The fillers research and development (R&D) program, mostly experimental, is part of a broader R&D program that includes new process modeling and performance assessment of criticality effects and the overall importance of criticality to repository performance (consequence screening). A literature research and consultation effort with experts by Hardin and Brady (2018) identified several potentially effective and workable filler materials including cements (primarily phosphate based), moltenmetal alloys, and low-temperature glasses. Filler attributes were defined, and the preliminary lists were compared qualitatively. Further comparative analysis will be done (e.g., cost estimates) after experimental screening has narrowed the list of alternatives. The research presented here is focused Sandia’s efforts for the development of phosphate-based cement fillers. Molten metal filler research is an ongoing activity at Oak Ridge National Laboratories and is not discussed herein. After the completion of the FY20 research effort the following cement filler compositions were selected for further experimental development work and advanced testing in FY21: 1. Aluminum phosphate cements (APCs); more specifically aluminum oxide / aluminum phosphate (Al 2 O 3 / AlPO 4 ) cements in which Al 2 O 3 serves as the filler material bound by an AlPO 4 binder formed by the reaction of Al 2 O 3 with various phosphate sources; 2. Wollastonite phosphate cements (WPCs), specifically wollastonite and aluminum or calcium aluminum phosphates in which CaSiO 3 serves as the filler material bound by a calcium phosphate that serves as the binder; and 3. Calcium aluminate phosphate cements (CAPCs) specifically grossite (CaAl 4 O 7 ) and hibonite (CaAl 11 O 18 ) fillers bound by an aluminum phosphate that serves as the binder. This effort focused on the optimization and subsequent processing of these three cements to achieve dense and well-consolidated monolithic samples. Upon completion of the FY21 effort the aluminum phosphate cements (APCs) and the calcium aluminate phosphate cements (CAPCs) show the most promise for advanced testing and scale up. We will begin the work in FY22 focused on testing the performance of these two cements in small scale DPCs as well as advanced materials testing to evaluate cement performance under expected radiation doses and representative post-closure geochemical environments.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Composite Solid Ion Conductor with Engineered Lithium Interface

Successful widespread commercialization of electric vehicles is contingent upon development of safe high energy density batteries capable of long cycle life. Lithium metal affords the highest theoretical capacity (3,860 mAh/g) and lowest electrochemical potential (-3.04V vs SHE), which offers the highest specific energy density of anode materials today. While Li-ion batteries are capable of delivering energy densities of 400-600 Wh/kg, the development of lithium metal batteries such as Li-S and Li-air may boost this number up to 650 and 950 Wh/kg, respectively. However, significant progress towards the passivation of lithium metal must occur before the energy density benefit can be realized. Issues with lithium dendrite formation, anode volume expansion, and continuous solid electrolyte interphase (SEI) build-up often result in significant safety concerns, high cell resistance, and poor cycle life. The intrinsic high reactivity between lithium metal with conventional lithium ion electrolytes (organic carbonate-based solvents) makes it extremely difficult to overcome these problems. In this project, Wildcat performed focused, fundamental research and development on composite polymer/ceramic electrolytes and protected lithium metal anodes to develop an all solid state lithium metal battery targeting the DOE requirements to enable commercialization. Wildcat successfully leveraged its high throughput battery platform and explored a broad composite electrolyte compositional space. Additionally, Wildcat screened large numbers of inorganic and organic coatings for lithium metal protection using in situ liquid methods and translated the best results to all solid cells. The proposed composite polymer/ceramic electrolyte and a protected lithium metal anode enabled a solid-state lithium metal battery. The ultimate targets from this effort will deliver a safe all solid-state lithium metal pouch cell with over 350 Wh/kg and over 1,000 cycles (C/3) with the cost estimate below $100/kWh. During the course of the project, we demonstrated stable cycling of 10’s of cycles with the composite SSE and our protected lithium. The work has continued after the conclusion of the DOE funding, demonstrating further improvements in catholyte composition and thinner composite solid electrolytes.

25 ENERGY STORAGE↗

Providencia Island High-Level Power System Capacity Expansion Analyses [Slides]

Results of a high level cost-benefit analysis using HOMER Pro software are presented for Providencia Island, Colombia. The analysis focuses on integrating solar photovoltaics (PV) and a battery energy storage system (BESS) into an existing diesel-only remote power system. The analysis uses fuel costs and discount rates provided by the stakeholders and NREL-derived capital cost estimates.

14 SOLAR ENERGY↗

Integration of Pumped Heat Energy Storage with Fossil-Fired Power Plant (Final Report)

The project team of Southwest Research Institute ® (SwRI ® ), Malta Inc. (Malta), and Luminant Generation Company LLC (Luminant) completed a feasibility study for the integration of a 100-MW, 10-hour (1000-MWh) Malta Pumped Heat Energy Storage (MPHES) system with multiple full-sized fossil-fired electricity generation units (EGU) in Luminant portfolio. MPHES is a long-duration, molten-salt-energy storage technology that uses turbomachinery and heat exchangers to transfer energy to a thermal storage media when charging, and removes the heat in a similar fashion when discharging. With high round trip efficiency (60-65%) and long lifespan (30+ years), MPHES provides economic benefits to the fossil-asset owners that can be scaled to integrate with assets across their portfolio. This technology uses hardware components, workforce personnel, and skillsets similar to those used by fossil EGUs, allowing for synergy when co-locating the two technologies. Luminant has approximately 39,000 megawatts of generation across 12 states, operating in six of the seven competitive markets in the U.S. and powered by a diverse portfolio of natural gas, nuclear, coal, and solar facilities. The DeCordova plant in Granbury, Texas, a simple cycle natural gas peaker power plant, was used as the fossil-fired asset in this project. The local market in Granbury, Texas has many influences, including several nearby power plants, a Luminant-owned nuclear plant (Comanche Peak), and substantial wind energy, which causes both negative pricing at night and high market volatility. Reducing false starts of the DeCordova plant and better responding to market volatility would be an economic advantage. Luminant is currently integrating battery storage plant on site to begin addressing these challenges. Integrating long-duration storage, like MPHES, would expand this capability beyond one hour of storage and have the potential to greatly reduce the total number of gas turbine starts. The MPHES charging requirement could help offset the overnight operating costs of Comanche Peak, which cannot load follow, and the nearby Luminant-owned Wise County combined cycle plant that cycles too often. Following the assessment of Luminant’s ERCOT-based portfolio for integration compatibility with Malta’s PHES system and the project tasks of conceptual study, technoeconomic analysis, technology gap assessment, and commercialization plan, the project team effort has resulted in several key outcomes: (1) Identification of market trends in a high-wind penetration market outside a major metropolitan area; (2) Creation of a dispatching model for the MPHES system and the pairing of Li-ion battery with a gas turbine in a real time market; (3) Revenue and cost estimations for operating MPHES alongside a gas peaker plant with real dispatching considerations and comparison with variations in the Malta implementation, including doubling the storage capacity and using two discharge drivetrains; (4) Potential carbon emission reductions possible by replacing gas turbine operation with Malta PHES operation; and (5) Summary of literature-based future market predictions for Texas.

20 FOSSIL-FUELED POWER PLANTS↗

Fast Modular Reactor (FMR): Overview and Conceptual Design Work

The conceptual design of the FMR including the experimental and numerical verifications will lead to: Cost estimation of the FMR based on the conceptual design results and guidelines of advanced reactor construction. Submittal of the pre-application licensing plan to the NRC for review and feedback.

22 GENERAL STUDIES OF NUCLEAR REACTORS↗

Advanced Ceramic Membranes/Modules for Ultra Efficient Hydrogen (H2) Production/Carbon Dioxide (CO2) Capture for Coal-Based Polygeneration Plants: Fabrication, Testing, and CFD Modeling

Inorganic membrane-based systems are a promising technology for precombustion CO2 capture with simultaneous H2 production. State-of-the-art packages for high temperature and pressure service consist of multiple tube membrane bundles prepared in a "candle filter" configuration, in which the membrane tubes are open at one end and sealed at the other. This configuration is used for practical reasons, specifically the need to minimize problems due to thermal expansion mismatch between the ceramic tube bundle and the steel housing. However, the primary technical problem with the candle filter format for commercial-scale installations is the inability to purge the tube side (typically the permeate side), a feature that is crucial for high H2 recovery. In this study, the focus is to design and fabricate the first dual-end open full ceramic multiple tube membrane bundle that enables tube side (permeate) purge for gas separation applications. An additional key feature of this design is the simplified module layout, as the membrane bundles can be installed end-to-end with tube side (permeate) flow directly from one bundle to the next. This layout simplifies the membrane to housing seals and yields significant improvement in membrane packing density. Detailed focus areas in our studies include: (i) Materials development and preparation of the tube-to-tube sheet potting for the dual-ended bundle; (ii) the sealing and optimal module configuration design to minimize membrane stress upon module mounting; (iii) the demonstration, via the fabrication of CMS and Pd-alloy membranes supported on full-size, dual-ended ceramic support bundles, of the first example of a purgeable ceramic membrane and module; and (iv) development of a CFD model of the membrane module for calculation of feed flow distribution, and for use in scale-up, and capital cost estimating. The CFD model was validated using experimental data with the multi-tubular membrane system, employing He/N2 as a model gas mixture (surrogate for H2/CO2), and has been shown to be quite accurate. Employing the model, we are able to study the effects of operating pressure and temperature, feed and sweep gas flow rates, and the choice of membrane tube configuration on system performance.

20 FOSSIL-FUELED POWER PLANTS↗

LH CO 2 MENT Colorado Project (Final Report)

The objective of Electricore’s pre-FEED project “LH CO 2 MENT COLORADO PROJECT” is to accelerate the implementation of a 1.5 million tonnes per year (TPY), and first-of-a-kind (FOAK) at world scale, Svante VeloxoTherm™ carbon capture plant. This project represents a quantum leap to a large-scale facility that will launch Svante’s carbon capture technology into the next era of accomplishments and market acceptance. By completing the Front-End Loading (FEL) Feasibility Study Report (FEL-2) for a fit-for-purpose design at the HOLCIM cement plant, located near Florence Colorado, USA, this technology can be proven as the future of large-scale deployment for carbon capture and storage. This carbon capture plant was designed with the goal of reaching a target of near Net Zero Emissions by capturing 90% of the carbon dioxide (CO 2 ) emissions from the HOLCIM cement plant and from the boiler which produces steam required to regenerate the adsorbent. Additionally, this project will be leveraging a renewable Power Purchase Agreement (PPA) using solar energy to acquire power at the target price of 0.04 $/kWh or less. In its current configuration CO 2 emissions from the HOLCIM cement plant is around 700 – 800 kg/ton of clinker produced. The proposed new carbon capture plant will allow a reduction of CO 2 emissions to about 100 kg/ton of clinker produced. The scope of work consists of the process design and capital & operating cost estimation (Class IV) for a total plant capacity of 4,750 TPD of pipeline grade CO 2 . The Svante VeloxoTherm™ technology is comprised of a Rotary Adsorption Machine (RAM) for intensified Thermal Swing Adsorption (TSA) using Structured Adsorbent Beds (SABs) and related Balance of Plant (BOP), including CO 2 compression. A business case (financial analysis) evaluation has been undertaken for the Owner’s management review. Recommendations on how best to proceed to the next stage of the project have been conveyed and are documented within this report. This analysis has relied on a detailed and comprehensive Project Financial Model, evaluating the Total Project IRR (after tax, unlevered, and including all forecast 45Q PTCs and 100% tax efficiency) – the project financial analysis (as opposed to standard TEA analysis) only considered a 12 year plant economic lifetime as a result of 45Q being the sole driver considered at this stage. The Total Project IRR was evaluated across a large number of potential scenarios. The evaluation demonstrated that if the 45Q PTD is increased to $85/MT for sequestration, there are a large number of feasible scenarios which demonstrate economic returns.

01 COAL, LIGNITE, AND PEAT↗

Volume 10: Flow Test Facilities

Adding additional flow testing facilities has been considered as part of the High Flux Isotope Reactor (HFIR) Sustaining and Enhancing Neutron Science (SENSe) Initiative at Oak Ridge National Laboratory (ORNL) to support HFIR operations and experiments. This prospect has prompted many ideas and discussions regarding potential features, configurations, locations, and applications for the facilities. A working group of ORNL staff members was formed in fiscal year 2022 to recommend one or more configurations to best support future HFIR operations and scientific capacities and to develop order-of magnitude cost estimates and timing. The ideas discussed in this report include options ranging from upgrading existing small-scale testing facilities to building a full-scale HFIR mockup for detailed thermohydraulic testing and fuel assessment.

07 ISOTOPE AND RADIATION SOURCES↗

Volume 4: Detection Systems and Ultra-Cold Neutrons

As part of the Sustaining and Enhancing Nuclear Science (SENSe) initiative at Oak Ridge National Laboratory (ORNL), the prospect of adding new detection systems to support High Flux Isotope Reactor (HFIR) operations and to advance scientific research has prompted many ideas and discussions regarding potential features, configurations, locations, and applications. A working group of ORNL staff members was organized to further develop the concepts and recommending one or more configurations to best support future HFIR operations and scientific capacities and to provide order-of-magnitude cost estimates and timing. The areas of investigation included fast access detection systems, non-scattering beamline instruments, shielded detection instruments, and an ultracold neutron source. In each case, the focus was to develop world leading capabilities that would be unmatched by any other facility.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗

Analytics Supporting Stockpile and Enterprise Planning [Slides]

A robust and growing modeling effort supports Los Alamos weapons leadership as well as NNSA (NA18, NA12, NA19) and DoD (DASD-NM, USSTRATCOM). Current work are valuable to several key NNSA working groups supporting strategic planning: Stockpile Stewardship Management Plan (SSMP); Requirements & Planning Document (RPD) analysis; Requirements and Capacity Working Group (RCWG); Production Integration Collaboration Working Group (PICWG); Enterprise Modeling and Analysis Consortium (EMAC); Cost Estimating Analysis Group (CEAG).

45 MILITARY TECHNOLOGY, WEAPONRY, AND NATIONAL DEF↗

Volume 6: Experiment Facility Spectrum Tailoring (HFIR Futures – Enhanced Capabilities Series)

In-core irradiation experiment research, such as materials and fuels irradiation research and radioisotope production, is one of the primary missions of Oak Ridge National Laboratory’s (ORNL) versatile High Flux Isotope Reactor (HFIR). In support of the HFIR-Sustaining and Enhancing Neutron Science (SENSe) Initiative, a technically diverse group of ORNL irradiation research subject matter experts formed the Spectrum Tailoring Working Group, with the goal of developing a compendium of experiment facility concepts to enhance irradiation experiment conditions via neutron spectrum tailoring capabilities. The purpose of this report is to document the concepts developed in FY22 and the associated scientific justifications, identify potential facility sponsors, and estimate costs and schedules for each concept. This report documents the efforts performed in FY22, which may continue in FY23 or later pending the direction of the HFIR-SENSe Initiative and the interested sponsors.

21 SPECIFIC NUCLEAR REACTORS AND ASSOCIATED PLANTS↗

Prefabricated Standard Modular Hydropower Installations for Low-cost Small Hydropower

The goal of the present project was to investigate the potential savings in greenfield hydropower project costs across sites having vastly different characteristics. Littoral Power Systems, Inc. (LPS) undertook the project described herein to explore the promise of Standard Modular Hydropower (SMH) to transform the processes of site identification, conceptual design, detailed design, and construction planning to support low- cost, environmentally attractive development of small hydropower facilities at new stream- reaches. This report includes descriptions of the work to develop these processes, the resulting facility designs achieved using these processes and the projected economics. Installation cost estimates for the resulting conceptual greenfield facility design at two different locations come in at $\$3,419$/kW for Balcony Falls and $\$2,124$/kW for LPS 566. The installation time from site preparation to commissioning-ready is estimated to be 58 weeks for the conceptual facility at Balcony Falls and 42 weeks for the conceptual facility at LPS 566. A real challenge to any hydropower facility – not only the two cases studied here – is that environmental and social conditions can change, and as such, the facility may be required to change. The h-Modulor modules connect uniquely and are structurally independent, enabling site configurations to be changed on the fly, as needed. These results show that LPS's h-Modulor SMH approach delivers an attractive balance between efficiency, economics, and environmental sustainability for small hydro greenfield sites.

13 HYDRO ENERGY↗