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NASA NTRS1981

High-resolution atmospheric spectroscopy using a diode laser heterodyne spectrometer

A tunable-diode-laser radiometer with a spectral resolution of 0.007/cm was used to obtain IR solar absorption spectra in the 9.1-11.1 micron region. Spectra exhibiting absorption by HNO3, CO2, O3, and H2O were obtained in a piecewise manner using emission modes from a single Pb-salt laser local oscillator. The measured spectra were compared to synthetic atmospheric spectra calculated using a line-by-line model. The results demonstrate that high-resolution IR solar absorption spectroscopy and atmospheric extinction measurements can be routinely performed over wide spectral regions using semiconductor lasers.

Hoell, J. M., Jr.↗

NASA NTRS1980

Solar occultation sounding of pressure and temperature using narrowband radiometers

A technique for simultaneously retrieving pressure and temperature profiles using satellite-based narrowband radiometer measurements of absorption in the CO2 4.3-micron band is described. Pressure and temperature profiles for earth's upper atmosphere on a global scale can be obtained with errors less than 3% and 3 K, respectively. The p-T information can be used not only for improving the accuracy of inverted gas concentrations in the same absorption experiment but also for investigating the upper atmosphere circulation.

Park, J. H.↗

NASA NTRS2015

Advanced Intensity-Modulation Continuous-Wave Lidar Techniques for ASCENDS O2 Column Measurements

Global atmospheric carbon dioxide (CO2) measurements for the NASA Active Sensing of CO2 Emissions over Nights, Days, and Seasons (ASCENDS) space mission are critical for improving our understanding of global CO2 sources and sinks. Advanced Intensity- Modulated Continuous-Wave (IM-CW) lidar techniques are investigated as a means of facilitating CO2 measurements from space to meet the ASCENDS measurement requirements. In recent numerical, laboratory and flight experiments we have successfully used the Binary Phase Shift Keying (BPSK) modulation technique to uniquely discriminate surface lidar returns from intermediate aerosol and cloud contamination. We demonstrate the utility of BPSK to eliminate sidelobes in the range profile as a means of making Integrated Path Differential Absorption (IPDA) column CO2 measurements in the presence of optically thin clouds, thereby eliminating the need to correct for sidelobe bias errors caused by the clouds. Furthermore, high accuracy and precision ranging to the surface as well as to the top of intermediate cloud layers, which is a requirement for the inversion of column CO2 number density measurements to column CO2 mixing ratios, has been demonstrated using new hyperfine interpolation techniques that takes advantage of the periodicity of the modulation waveforms. This approach works well for both BPSK and linear swept-frequency modulation techniques. The BPSK technique under investigation has excellent auto-correlation properties while possessing a finite bandwidth. A comparison of BPSK and linear swept-frequency is also discussed in this paper. These results are extended to include Richardson-Lucy deconvolution techniques to extend the resolution of the lidar beyond that implied by limit of the bandwidth of the modulation, where it is shown useful for making tree canopy measurements.

Campbell, Joel F.↗

NASA NTRS2000

The Abundances of Solid N2 and Gaseous CO2 in Interstellar Dense Molecular Clouds

We present 2338-2322 per centimeter (4.277-4.307 micrometer) infrared spectra of a number of N2-containing mixed molecular ices and demonstrate that the strength of the infrared "forbidden" band due to the N=N stretch near 2328 per centimeter (4.295 micrometer) is extremely sensitive to the composition of the ice. The strength of the 2328 per centimeter N2 fundamental is significantly enhanced relative to that of pure N2 ice when NH3, H2O, or CO2 are present, but is largely unaffected by the presence of CO, CH4 or O2. We use the laboratory data in coil junction with ISO data that probes several lines-of-sight through dense molecular clouds to place limits on the abundance of interstellar solid phase N2 and the composition of the ices. Deriving upper limits is complicated by the presence of overlapping absorptions due to CO2 gas in the clouds and, in some cases, to photospheric CO in the background star. These upper limits are just beginning to be low enough to constrain interstellar grain models and the composition of possible N2-bearing interstellar ices. We outline the search criteria that will need to be met if solid interstellar N2 is to be detected in the future. We also discuss some of the implications of the presence of warm CO2 gas along the lines-of-sight to embedded protostars and demonstrate that its presence may help resolve certain puzzles associated with the previously derived gas/solid CO2 ratios and the relative abundances of polar and nonpolar ices towards these objects. Finally, we briefly comment on the possible implications of these results for the interpretation of N2 detections on outer solar system bodies.

Sandford, Scott A.↗

NASA NTRS1976

Laser absorption phenomena in flowing gas devices

A theoretical and experimental investigation is presented of inverse Bremsstrahlung absorption of CW CO2 laser radiation in flowing gases seeded with alkali metals. In order to motivate this development, some simple models are described of several space missions which could use laser powered rocket vehicles. Design considerations are given for a test call to be used with a welding laser, using a diamond window for admission of laser radiation at power levels in excess of 10 kW. A detailed analysis of absorption conditions in the test cell is included. The experimental apparatus and test setup are described and the results of experiments presented. Injection of alkali seedant and steady state absorption of the laser radiation were successfully demonstrated, but problems with the durability of the diamond windows at higher powers prevented operation of the test cell as an effective laser powered thruster.

Chapman, P. K.↗

NASA NTRS2016

The Response of Phanerozoic Surface Temperature to Variations in Atmospheric Oxygen Concentration

Recently, Poulsen et al. (2015) suggested that O2 has played a major role in climate forcing during the Phanerozoic. Specifically, they argued that decreased O2 levels during the Cenomanian stage of the middle Cretaceous (94–100 Ma) could help explain the extremely warm climate during that time. The postulated warming mechanism involves decreased Rayleigh scattering by a thinner atmosphere, which reduces the planetary albedo and allows greater surface warming. This warming effect is then amplified by cloud feedbacks within their 3-D climate model. This increase in shortwave surface forcing, in their calculations, exceeds any decrease in the greenhouse effect caused by decreased O2. Here we use a 1-D radiative-convective climate model (with no cloud feedback) to check their results. We also include a self-consistent calculation of the change in atmospheric ozone and its effect on climate. Our results are opposite to those of Poulsen et al.: we find that the climate warms by 1.4 K at 35% O2 concentrations as a result of increased pressure broadening of CO2 and H2O absorption lines and cools by 0.8 K at 10% O2 as a result of decreased pressure broadening. The surface temperature changes are only about 1 K either way, though, for reasonable variations in Phanerozoic O2 concentrations (10%–35% by volume). Hence, it seems unlikely that changes in atmospheric O2 account for the warm climate of the Cenomanian. Other factors, such as a higher-than-expected sensitivity of climate to increased CO2 concentrations, may be required to obtain agreement with the paleoclimate data.

Atmospheric O2 levels↗

NASA NTRS1990

Spectral albedo and emissivity of CO2 in Martian polar caps - Model results

In this paper, a snow albedo model previously developed for terrestrial snow is extended to the case of CO2 snow on Mars. Pure CO2 snow is calculated to have high albedo at visible wavelengths but not as high as that of water snow. At any given wavelength, the primary variable controlling albedo and emissivity is the snow grain size, with albedo decreasing and emissivity increasing as grain size increases. Observations that red albedo is much higher than blue albedo in the Martian south polar cap indicates that the snow or the atmosphere is contaminated with red dust. The absorption coefficient of CO2 ice in the thermal infrared is two to three orders of magnitude smaller than that measured for H2O ice. CO2 snow emissivity is therefore much lower than H2O snow, varying substantially with wavelength and quite sensitive to grain size and emission angle. Factors tending to increase emissivity are large grain size, small emission angle, and large concentrations of dust or water.

Warren, Stephen G.↗

NASA NTRS1974

Is there another major constituent in the atmosphere of Mars?

In view of the possible finding of several tens percent of inert gas in the atmosphere of Mars by an instrument on the descent module of the USSR's Mars 6 spacecraft, the likelihood of the correctness of this result was examined. The basis for the well-known fact that the most likely candidate is radiogenic argon is described. It is shown that, for the two important methods of investigating the atmosphere, earth-based CO2 is infrared absorption spectroscopy and S-band occultation, within the estimated 1 standard deviation uncertainties of these methods about 20% argon can be accommodated. Within the estimated 3 standard deviation uncertainties, more than 35% is possible. It is also stated that even with 35% argon the maximum value of heat transfer rate on the Viking 75 entry vehicle does not exceed the design value.

Wood, G. P.↗

NASA NTRS1976

Monitoring complex trace-gas mixtures by long-path laser absorption spectrometry

Laser-based spectrophotometric methods, which have been proposed for the detection of trace concentrations of gaseous contaminants, include Raman and passive radiometry. The paper discusses a simple long-path laser absorption method which is capable of resolving complex mixtures of closely related trace contaminants at ppm levels. A number of species were selected which are most likely to accumulate in closed environments, such as submarines or long-duration manned space flights. Absorption coefficients at CO2 laser wavelengths were measured, accurate to + 3 per cent or better, for each of these species. This data base was then used to determine the presence and concentration of the contaminants in prepared mixtures of 12 to 15 gases. Computer programs have been developed which will permit a real-time analysis of the monitored atmosphere. Minimum detectable concentrations for individual species are generally in the ppm range, and are not seriously degraded by interferences even in complex mixtures. Estimates of the dynamic range of this monitoring technique for various system configurations and comparison with other methods of analysis are discussed

Green, B. D.↗

NASA NTRS1979

On the possibility of analytical approximation of line forms during random disorders of the resonance frequencies in molecular vibration-rotation spectra for satellite sounding

The generalization spectral line contour concept and formulas for a two component mixture, as well as consequences of the general formula are discussed. The calculation procedure, initial information, calculation results and comparison of calculations with available experimental data, for radiation absorption in three CO2 bands are presented.

Fomin, V. V.↗

NASA NTRS1979

Stratospheric sounding by infrared heterodyne spectroscopy

Intensity profiles of infrared spectral lines of stratospheric constituents can be fully resolved with a heterodyne spectrometer of sufficiently high resolution (approximately 5 MHz = 0.000167 kaysers at 10 microns). The constituents' vertical distributions can then be evaluated accurately by analytic inversion of the measured line profiles. Estimates of the detection sensitivity of a heterodyne receiver are given in terms of minimum detectable volume mixing ratios of stratospheric constituents, indicating a large number of minor constituents which can be studied. Stratospheric spectral line shapes and the resolution required to measure them are discussed in light of calculated synthetic line profiles for some stratospheric molecules in a model atmosphere. The inversion technique for evaluation of gas concentration profiles is briefly described, and applications to synthetic lines of O3, CO2, CH4, and N2O are given. Some recent heterodyne measurements of CO2 and O3 absorption lines are analytically inverted, and the vertical distributions of the two gases are determined.

Abbas, M. M.↗

NASA NTRS1983

Signal averaging limitations in heterodyne- and direct-detection laser remote sensing measurements

The improvement in measurement uncertainty brought about by the averaging of increasing numbers of pulse return signals in both heterodyne- and direct-detection lidar systems is investigated. A theoretical analysis is presented which shows the standard deviation of the mean measurement to decrease as the inverse square root of the number of measurements, except in the presence of temporal correlation. Experimental measurements based on a dual-hybrid-TEA CO2 laser differential absorption lidar system are reported which demonstrate that the actual reduction in the standard deviation of the mean in both heterodyne- and direct-detection systems is much slower than the inverse square-root dependence predicted for uncorrelated signals, but is in agreement with predictions in the event of temporal correlation. Results thus favor the use of direct detection at relatively short range where the lower limit of the standard deviation of the mean is about 2 percent, but advantages of heterodyne detection at longer ranges are noted.

Menyuk, N.↗

NASA NTRS1983

Spectroscopic measurements of the 8- to 13-micrometer transmission of the upper atmosphere following the El Chichon eruptions

Infrared transmission spectra of the atmosphere above 11-km altitude were obtained at latitudes from 2 deg S to 50 deg N in December 1982. A circular variable-interference filter spectrometer mounted in a Convair 990 (the Galileo II) aircraft was used to obtain spectra of the sun through different air masses. Comparisons of spectra through different air masses provide atmospheric transmission measurements that show not only normal absorption features, such as those from CO2 and O3, but also additional absorption near 8.5 microns consistent with H2SO4 aerosols. The average fractional absorption from latitude 10 deg N to 41 deg N at 8.5 microns was 0.02/air mass, half of which was attributable to aerosols.

Witteborn, F. C.↗

NASA NTRS1986

Heating rates in tropical anvils

An IR radiative transfer model for cirrus clouds was developed on the basis of data acquired with a U-2 aircraft. The emission and scattering of radiation was expressed with a two-stream algorithm that considered the cloud in 10 layers. Exponential sums were employed to quantify gaseous absorption by H2O, CO2 and O3 over the IR spectrum of 4.5-250 microns. Ice water content had the greatest impact on radiative heating of the high altitude anvils, although the vertical extent of the anvil and the cloudiness of the underlying atmosphere were also important.

Ackerman, T. P.↗

NASA NTRS1990

The deep atmosphere of Venus revealed by high-resolution nightside spectra

The first high-resolution spectroscopic observations of the night side of Venus obtained in two narrow spectral windows centered at 1.74 and 2.3 microns, where the nightside is anomalously bright, are reported. Absorption features from CO2, CO, H2O, HDO, HCl, HF, and COS are detected, and there are a number of unidentified features. A preliminary analysis indicates that the observed radiation is thermal emission from atmospheric layers in the eight-bar pressure region for the 2.3 micron window and even deeper at 1.7 micron. The derived CO and H2O abundances agree with in situ Pioneer measurements in the deep troposphere and are consistent with the high deuterium enrichment inferred from Pioneer data. The first measurements of HCl and HF below the clouds are reported along with the first firm detection of COS.

Bezard, Bruno↗

NASA NTRS1991

Infrared cooling rate calculations in operational general circulation models - Comparisons with benchmark computations

The performance of several parameterized models is described with respect to numerical prediction and climate research at GFDL, NCAR, and GISS. The radiation codes of the models were compared to benchmark calculations and other codes for the intercomparison of radiation codes in climate models (ICRCCM). Cooling rates and fluxes calculated from the models are examined in terms of their application to established general circulation models (GCMs) from the three research institutions. The newest radiation parameterization techniques show the most significant agreement with the benchmark line-by-line (LBL) results. The LBL cooling rates correspond to cooling rate profiles from the models, but the parameterization of the water vapor continuum demonstrates uncertain results. These uncertainties affect the understanding of some lower tropospheric cooling, and therefore more accurate parameterization of the water vapor continuum, as well as the weaker absorption bands of CO2 and O3 is recommended.

Kiehl, J. T.↗

NASA NTRS1993

Nongray gas analyses for reflecting walls utilizing a flux technique

A flux formulation for a planar slab of molecular gas radiation bounded by diffuse reflecting walls is developed. While this formulation is limited to the planar geometry, it is useful for studying approximations necessary in modeling nongray radiative heat transfer. The governing equations are derived by considering the history of multiple reflections between the walls. Accurate solutions are obtained by explicitly accounting for a finite number of reflections and approximating the spectral effects of the remaining reflections. Four approximate methods are presented and compared using a single absorption band of H2O. All four methods reduce to an identical zeroth-order formulation, which accounts for all reflections approximately but does handle nonreflected radiation correctly. A single absorption band of CO2 is also considered using the best-behaved approximation for higher orders. A zeroth-order formulation is sufficient to predict the radiative transfer accurately for many cases considered. For highly reflecting walls, higher order solutions are necessary for better accuracy. Including all the important bands of H2O, the radiative source distributions are also obtained for two different temperature and concentration profiles.

Menart, J. A.↗

NASA NTRS2001

A Thermal Infrared Radiation Parameterization for Atmospheric Studies

This technical memorandum documents the longwave radiation parameterization developed at the Climate and Radiation Branch, NASA Goddard Space Flight Center, for a wide variety of weather and climate applications. Based on the 1996-version of the Air Force Geophysical Laboratory HITRAN data, the parameterization includes the absorption due to major gaseous absorption (water vapor, CO2, O3) and most of the minor trace gases (N2O, CH4, CFCs), as well as clouds and aerosols. The thermal infrared spectrum is divided into nine bands. To achieve a high degree of accuracy and speed, various approaches of computing the transmission function are applied to different spectral bands and gases. The gaseous transmission function is computed either using the k-distribution method or the table look-up method. To include the effect of scattering due to clouds and aerosols, the optical thickness is scaled by the single-scattering albedo and asymmetry factor. The parameterization can accurately compute fluxes to within 1% of the high spectral-resolution line-by-line calculations. The cooling rate can be accurately computed in the region extending from the surface to the 0.01-hPa level.

Chou, Ming-Dah↗