Engineering Papers⌕ Search

SEARCH · Engineering Papers

Results for “BASIC INTERACTIONS”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 253 records · Page 14

Multibody-plasma interactions - Charging in the wake

Multibody-plasma interactions refers to two or more charged bodies simultaneously interacting with the surrounding plasma as well as each other. This paper concerns a basic type of such interactions in space: the charging of a free flyer in the wake of a large structure. The conditions for severe charging are discussed quantitatively. Computer particle simulations are carried out to obtain the charging potentials in the wake of both floating and biased plate. It is shown that a severe charging zone exists in the near wake of a floating plate within which a free flyer is charged to the KV range under the sun shadow/auroral electron condition. Whether the plate is biased or floating, a large potential difference always exists between the plate and a docking free flyer in the wake. The effects of wake charging on spacecraft docking operations are discussed.

Wang, J.↗

A perturbation calculation of the dynamical effects of cosmic rays and interstellar gas on the solar wind

The modulation of galactic cosmic rays and other energetic particles by the solar wind produces a gradient in their pressure, which in turn influences the wind dynamics. The basic equations describing this interaction are presented in the 'hydrodynamic' approximation. A perturbation solution of the equations is presented for the case in which both the galactic cosmic ray pressure, and the pressure of the anomalous cosmic ray component accelerated at the wind termination shock, are small compared with the wind ram pressure. Analytical expressions for the deceleration of the wind and the modification of the shock and its location are derived in this case. These effects are estimated to have a relative magnitude of several percent in the solar wind. The interstellar neutral gas which penetrates the heliosphere is ionized, predominantly by photoionization and charge exchange with the wind, and may also have a significant dynamical effect on the wind. The basic equations describing this interaction are also presented, A perturbation solution is presented under the assumption that the mass loading and momentum-loading of the wind by the interstellar pickup ions is small compared with the wind ram pressure. Analytical expressions for the deceleration of the wind, the contribution of the pickup ions to the wind pressure, and the modification of the termination shock location are derived. Again, with the exception of pickup ion pressure which is large compared with solar wind thermal pressure, the effects are estimated to be several percent in relative magnitude in the solar wind.

Lee, M. A.↗

Anomalous dimensions and non-gaussianity

Here, we analyze the signatures of inflationary models that are coupled to interacting field theories, a basic class of multifield models also motivated by their role in providing dynamically small scales. Near the squeezed limit of the bispectrum, we find a simple scaling behavior determined by operator dimensions, which are constrained by the appropriate unitarity bounds. Specifically, we analyze two simple and calculable classes of examples: conformal field theories (CFTs), and large-N CFTs deformed by relevant time-dependent double-trace operators. Together these two classes of examples exhibit a wide range of scalings and shapes of the bispectrum, including nearly equilateral, orthogonal and local non-Gaussianity in different regimes. Along the way, we compare and contrast the shape and amplitude with previous results on weakly coupled fields coupled to inflation. This signature provides a precision test for strongly coupled sectors coupled to inflation via irrelevant operators suppressed by a high mass scale up to ~ 10 3 times the inflationary Hubble scale.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

Inhibition of d-xylose isomerase by polyols: atomic details by joint X-ray/neutron crystallography

A joint X-ray/neutron structure of d-xylose isomerase in complex with the inhibitor sorbitol was determined at room temperature at an acidic pH of 5.9. Protonation of the O5 O atom of the sugar was directly observed in the nuclear density maps. Under acidic conditions sorbitol gains a water-mediated interaction with the enzyme active site, which may explain the increased potency of the inhibitor at low pH. d-Xylose isomerase (XI) converts the aldo-sugars xylose and glucose to their keto analogs xylulose and fructose, but is strongly inhibited by the polyols xylitol and sorbitol, especially at acidic pH. In order to understand the atomic details of polyol binding to the XI active site, a 2.0 Å resolution room-temperature joint X-ray/neutron structure of XI in complex with Ni{sup 2+} cofactors and sorbitol inhibitor at pH 5.9 and a room-temperature X-ray structure of XI containing Mg{sup 2+} ions and xylitol at the physiological pH of 7.7 were obtained. The protonation of oxygen O5 of the inhibitor, which was found to be deprotonated and negatively charged in previous structures of XI complexed with linear glucose and xylulose, was directly observed. The Ni{sup 2+} ions occupying the catalytic metal site (M2) were found at two locations, while Mg{sup 2+} in M2 is very mobile and has a high B factor. Under acidic conditions sorbitol gains a water-mediated interaction that connects its O1 hydroxyl to Asp257. This contact is not found in structures at basic pH. The new interaction that is formed may improve the binding of the inhibitor, providing an explanation for the increased affinity of the polyols for XI at low pH.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

Simulation of Particle-Material Interactions

This paper gives an overview of the particle transport theory essentials, the basics of particle-material interaction simulation, physical quantities needed to simulate particle transport and interactions in materials, Monte Carlo simulation flow, response of additive detectors, statistical weights and other techniques to minimize statistical errors. Effects in materials under irradiation, materials response related to component lifetime and performance are considered with a focus on high-energy and high-power accelerator applications. Implementation of simulation of particle-material interactions in the modern Monte Carlo codes along with the code s main features and results of recent benchmarking are described.

43 PARTICLE ACCELERATORS↗

Heat transfer measurements and CFD comparison of swept shock wave/boundary-layer interactions

An experimental research program providing basic knowledge and establishing new data on the heat transfer in swept shock wave/boundary-layer interactions is described. An equilibrium turbulent boundary-layer on a flat plate is subjected to impingement by swept planar shock waves generated by a sharp fin. Five different interactions with fin angles ranging from 10 to 20 deg at freestream Mach numbers of 3.0 and 4.0 produce a variety of interaction strengths from weak to very strong. A foil heater generates a uniform heat flux over the flat plate surface and miniature thin-film-resistance sensors mounted on it are used to measure the local surface temperature. The heat convection equation is then solved for the heat transfer distribution within an interaction, yielding a total uncertainty of about +/- 10 percent. These experimental data are compared with the results of numerical Navier-Stokes solutions which employ a kappa-epsilon turbulence model. Finally, a simplified form of the peak heat transfer correlation for fin interactions is suggested.

Lee, Y.↗

Investigating the Variation in Solvation Interactions of Choline Chloride-Based Deep Eutectic Solvents Formed Using Different Hydrogen Bond Donors

Choline chloride-based deep eutectic solvents (DESs) have gained widespread recognition as green solvents in catalysis and separation science as their designer properties permit solvation properties to be modulated by the choice of the hydrogen bond donor (HBD) as well as its molar ratio. Despite being one of the most popular classes of DESs, very little is currently understood regarding how their solvation characteristics differ among themselves as well as from other classes of DESs. Previous studies have shown that the catalytic activity, extraction efficiency, and solubilities of natural compounds can be influenced by the type of choline salt and HBD, but no study has systematically related these parameters with its solvation properties. In this study, inverse gas chromatography was employed for the first time to study the individual solvation characteristics of a diverse range of choline chloride and acetate-based DESs composed of amides, diols, organic acids, and carbohydrates. Furthermore, hydrogen bond acidity was found to be a dominant interaction for all DESs, especially those composed of organic acid HBDs. DESs composed of isomers of butane diol and hexane diol as HBDs exhibited higher hydrogen bond basicity and dispersive-type interactions compared to those composed of urea, acetamide, and organic acids with the position of the hydroxyl functional group influencing their solvation interactions. Choline acetate-based DESs exhibited lower dipolarity and stronger hydrogen bond basicity and dispersive-type interactions compared to choline chloride DESs. The solvation models developed in this study were used to interpret and explain DES behavior in previously reported studies involving catalysis, organic synthesis, and extractions demonstrating that the measured solute–solvent interactions can serve to predict the performance of choline chloride-based DESs when used in various applications.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Measurements of Ionizing Radiation Doses Induced by High Irradiance Laser on Targets in LCLS MEC Instrument - Paper 75

High-power laser interaction with targets in vacuum at high laser irradiance levels can generate plasma and, consequently, create ionizing radiation hazards. The theory for ionizing radiation generation from laser-plasma interaction is complicated. The basics of theory and phenomenology are available qualitatively. However, the ionizing radiation yields associated with laser-plasma interaction have not been well quantified. Based on the theoretical analysis and review of the published reports and measurement data, SLAC National Accelerator Laboratory (SLAC) developed an analytic model to estimate conservatively the electron temperature and photon radiation yield (Sv/J) of a laser pulse hitting a solid target at 1 m as a function of laser irradiance between 10{sup 15} and 10{sup 21} W/cm{sup 2}. Ionizing radiation measurements from high-intensity laser-induced plasma interactions on solid targets inside the Al-walled vacuum chamber of the LCLS MEC instrument at SLAC were conducted using passive and active detectors at irradiance between 3x10{sup 16} and 6x10{sup 17} W/cm{sup 2}. Each run of the more than 20 runs had a unique set of laser, optic and target conditions with laser pulses rastering over the target surface mainly perpendicularly at a fixed irradiance. Significant effort was made in characterizing the laser irradiance values for each configuration of laser, focusing mirror, and target; four irradiances with targets of Au foils and copper plate were found to produce good measurement results. Electron doses inside the target chamber were highly anisotropic and peaked at backward direction by several orders of magnitude. Photon doses outside the target chamber were nearly isotropic (a factor of ∼2 higher in backward direction). When considering the large uncertainties of the irradiance (a factor of 2-3) and the potential shielding effects from detectors and target chamber, the measured photon dose rates at 1 m (150 mJ and 10 Hz) outside the target chamber (when averaged over different types of detectors) were in good agreement (a factor of ∼3) with the calculated values of the SLAC model, except at 3.0x10{sup 16} W/cm{sup 2}, which has an electron temperature of only 14 keV. At 6x10{sup 17} W/cm{sup 2}, a low level of ∼0.1 mrem/h from fast neutrons was measured (at 1 m, 150 mJ and 10 Hz) with a neutron-to-photon dose ratio of 0.2%. This is equivalent to a neutron dose yield of 2.8x10{sup -8} mSv/J (to be compared to the LULI measurements of 1x10{sup -4} mSv/J at 3x10{sup 19} W/cm{sup 2}). Both active and passive types of detectors performed well and the dose results were consistent, which is the same as the dose measurements in the Titan laser facility. Active detectors were not affected by the electromagnetic pulses associated with the MEC laser system; this was different from the Titan radiation measurements, in which all active detectors failed to respond, likely due to the high EMP in the Titan's high laser intensity fields. (authors)

43 PARTICLE ACCELERATORS↗

Three-dimensional relativistic field-electron interaction in a multicavity high-power klystron. 1: Basic theory

A theoretical investigation of three dimensional relativistic klystron action is described. The relativistic axisymmetric equations of motion are derived from the time-dependent Lagrangian function for a charged particle in electromagnetic fields. An analytical expression of the fringing RF electric and magnetic fields within and in the vicinity of the interaction gap and the space-charge forces between axially and radially elastic deformable rings of charges are both included in the formulation. This makes an accurate computation of electron motion through the tunnel of the cavities and the drift tube spaces possible. Method of analysis is based on Lagrangian formulation. Bunching is computed using a disk model of electron stream in which the electron stream is divided into axisymmetric disks of equal charge and each disk is assumed to consist of a number of concentric rings of equal charges. The Individual representative groups of electrons are followed through the interaction gaps and drift tube spaces. Induced currents and voltages in interacting cavities are calculated by invoking the Shockley-Ramo theorem.

Kosmahl, H. G.↗

Diffusion Behavior of Differently Charged Molecules in Self-Assembled Organic Nanotubes Studied Using Imaging Fluorescence Correlation Spectroscopy

The diffusion behavior of fluorescent molecules within bolaamphiphile-based organic nanotubes (ONTs) was systematically explored using imaging fluorescence correlation spectroscopy (imaging FCS). Anionic sulforhodamine B (SRB), zwitterionic/cationic rhodamine B (RB) or cationic rhodamine 123 (R123) was loaded into ONTs having cylindrical hollow structures (ca. 10 nm in inner diameter) with amine and glucose groups on the inner and outer surfaces, respectively. Wide-field fluorescence video microscopy was used to acquire imaging FCS data for dye-doped ONTs in aqueous solutions of different ionic strengths (1 – 500 mM) at different pH (3.4 – 8.4). The diffusion behavior of these dyes was discussed on the basis of their apparent diffusion coefficients (D) that were determined by autocorrelating the time transient of fluorescence intensity at each pixel on an ONT. Molecular diffusion in the ONTs was significantly slowed by molecule-nanotube interactions, as shown by the very small D (10-1 – 10-2 µm2/s). The pH-dependence of D revealed that dye diffusion was basically controlled by electrostatic interactions associated with the protonation of the amine groups on the ONT inner surface. The pH-dependent change in D was observed over a wide pH range, possibly due to electrostatically induced variations in the pKa of the densely packed ammonium ions on the ONT inner surface. On the other hand, the influence of ionic strength on D was relatively unclear, suggesting the involvement of non-coulombic interactions with the ONTs in molecular diffusion. Notably, individual ONTs of different lengths (1 – 5 µm) afforded similar diffusion coefficients for each type of dye at each solution condition, implying that the properties of ONTs were uniform in terms of solute loading and release. These conclusions highlight the characteristics of molecular diffusion behavior within the ONTs, and will help in the design of organic nanotubes better suited for use as drug vehicles and contaminant adsorbents.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Wall pressure fluctuations beneath swept shock wave/boundary layer interactions

An experimental research program providing basic knowledge and establishing a database on the fluctuating pressure loads produced on aerodynamic surfaces beneath 3D shock wave/boundary layer interactions is presented. A turbulent boundary layer on a flat plate is subjected to interactions with swept planar shock waves generated by sharp fins at angle of attack. Measurements are made for the first time in the aft areas of these interactions, showing fluctuating pressure levels as high as 160 dB.

Garg, S.↗

An experimental study of the sources of fluctuating pressure loads beneath swept shock/boundary-layer interactions

An experimental research program providing basic knowledge and establishing a database on the fluctuating pressure loads produced on aerodynamic surfaces beneath three dimensional shock wave/boundary layer interactions is described. Such loads constitute a fundamental problem of critical concern to future supersonic and hypersonic flight vehicles. A turbulent boundary layer on a flat plate is subjected to interactions with swept planar shock waves generated by sharp fins at angle of attack. Fin angles from 10 to 20 deg at freestream Mach numbers of 3 and 4 produce a variety of interaction strengths from weak to very strong. Miniature Kulite pressure transducers flush-mounted in the flat plate are used to measure interaction-induced wall pressure fluctuations. The distributions of properties of the pressure fluctuations, such as their ring levels, amplitude distributions, and power spectra, are also determined. Measurements were made for the first time in the aft regions of these interactions, revealing fluctuating pressure levels as high as 160 dB. These fluctuations are dominated by low frequency (0-5 kHz) signals. The maximum ring levels in the interactions show an increasing trend with increasing interaction strength. On the other hand, the maximum ring levels in the forward portion of the interactions decrease linearly with increasing interaction sweep back. These ring pressure distributions and spectra are correlated with the features of the interaction flowfield. The unsteadiness of the off-surface flowfield is studied using a new, non-intrusive technique based on the shadow graph method. The results indicate that the entire lambda-shock structure generated by the interaction undergoes relatively low-frequency oscillations. Some regions where particularly strong fluctuations are generated were identified. Fluctuating pressure measurements are also made along the line of symmetry of an axisymmetric jet impinging upon a flat plate at an angle. This flow was chosen as a simple analog to the impinging jet region found in the rear portion of the shock wave/boundary layer interactions under study. It is found that a sharp peak in ring pressure level exists at or near the mean stagnation point. It is suggested that the phenomena responsible for this peak may be active in the swept interactions as well, and may cause the extremely high fluctuating pressures observed in the impinging jet region in the present experimental program.

Settles, G. S.↗

Matrix isolation studies of the interactions of BF3 with water and substituted diethyl ethers. Chemical ionization mass spectrometric determination of the proton affinity of (CF3CH2)2O

BF3 was co-condensed with H2O, D2O, (C2H5)2O, (CF3CH2)2O, and (C2F5)2O in excess argon at 15 K. Infrared spectra of BF3/water isolated in solid argon provided a more complete analysis of the BF3--H2O complex than previously published. Infrared spectra of the matrices showed a definite Lewis acid-base interaction between BF3 and diethyl ether; a weak but definite interaction with bis (2,2,2-trifluorodiethyl) ether, and no observable interaction with perfluorodiethyl ether. Thus, the ether data indicate a clear trend between strength of interaction with BF3 and the degree of F substitution. To support and explain the emerging relationship between interaction strength and the basicity of the oxygen-containing molecule, the proton affinity of (CF3CH2)2O was measured using chemical ionization mass spectrometry. The implications of the results for lubricant/metal oxide surface interactions are discussed.

Ball, David W.↗

Neutrino Properties and Interactions

In this chapter, we present basic concepts of neutrino physics. We start with a brief introduction to the standard model electroweak sector, followed by calculations of some relevant neutrino interaction cross sections. Here, we obtain the oscillation formalism from the Dirac equation, alongside with a self-contained derivation of matter effects from the standard model electroweak Lagrangian. Some key features of neutrino oscillation phenomenology are discussed as well. We then review the most precise oscillation measurements and finalize with some broad discussion of the current open questions in neutrino physics.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗

Nonlinear instability of a forced baroclinic Rossby wave

The nonlinear instability of forced baroclinic Rossby waves to finite-amplitude perturbations was investigated using a simple two-layer quasi-geostrophic weakly nonlinear model and a low-order spectral model, developed for this purpose. The results were applied to a study of the interaction of planetary-scale stationary eddies with synoptic-scale transient eddies. A comparison of the energetics of the weakly nonlinear solution with that seen in observational analysis and in GCM experiments indicate three basic properties of the interaction between the two types of eddies: (1) eddy available potential energy is transferred from the planetary-scale stationary eddies to the synoptic-scale transient eddies, (2) eddy kinetic energy is transferred in the opposite direction, and (3) the eddy available potential energy transfer dominates the transfer of eddy kinetic energy. It is concluded that the simple weakly nonlinear model used in these studies does indeed capture much of the fundamental behavior of wave-wave interactions seen in the atmosphere.

Feldstein, Steven B.↗

Magnetospheric plasma - Sources, wave-particle interactions and acceleration mechanisms.

Some of the basic problems associated with magnetospheric physics are reviewed. The sources of magnetospheric plasma, with auroral particles included as a subset, are discussed. The possible ways in which the solar wind plasma can gain access to the magnetosphere are outlined. Some important consequences of wave-particle interactions are examined. Finally, the basic mechanisms which energize or accelerate particles by reconnection and convection are explained.

Speiser, T. W.↗

Structural, functional, and genetic analyses of the actinobacterial transcription factor RbpA

Gene expression is highly regulated at the step of transcription initiation, and transcription activators play a critical role in this process. RbpA, an actinobacterial transcription activator that is essential in Mycobacterium tuberculosis (Mtb), binds selectively to group 1 and certain group 2 σ-factors. To delineate the molecular mechanism of RbpA, we show that the Mtb RbpA σ-interacting domain (SID) and basic linker are sufficient for transcription activation. We also present the crystal structure of the Mtb RbpA-SID in complex with domain 2 of the housekeeping σ-factor, σ A . The structure explains the basis of σ-selectivity by RbpA, showing that RbpA interacts with conserved regions of σ A as well as the nonconserved region (NCR), which is present only in housekeeping σ-factors. Thus, the structure is the first, to our knowledge, to show a protein interacting with the NCR of a σ-factor. We confirm the basis of selectivity and the observed interactions using mutagenesis and functional studies. In addition, the structure allows for a model of the RbpA-SID in the context of a transcription initiation complex. Unexpectedly, the structural modeling suggests that RbpA contacts the promoter DNA, and we present in vivo and in vitro studies supporting this finding. As a result, our combined data lead to a better understanding of the mechanism of RbpA function as a transcription activator.

59 BASIC BIOLOGICAL SCIENCES↗