Engineering Papers⌕ Search

SEARCH · Engineering Papers

Results for “Ar”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 253 records · Page 14

Measurement of Argon-37 Background Concentrations in the Atmosphere

Radioisotopes of noble gases, primarily xenon and argon, are important indicators of underground nuclear explosions. The Comprehensive Nuclear-Test-Ban Treaty (CTBT) includes monitoring capabilities to identify potential nuclear explosions conducted in violation of the CTBT. This monitoring currently focuses on measurement of the xenon isotopes 133 Xe, 135 Xe, 131 mXe and 133 mXe. However, it is predicted that within 100 days of an underground nuclear explosion (UNE) 37 Ar would be released to the atmosphere at higher concentrations than xenon isotopes (Haas et al. 2010). Therefore, inclusion of 37 Ar measurement capabilities at atmospheric International Monitoring System (IMS) stations could improve the capability to detect a nuclear explosion. At an IMS station, it could be difficult to determine what constitutes an elevated concentration as a result of an UNE without first understanding the expected range of background concentrations. This work describes our analysis of atmospheric samples for 37 Ar to evaluate the range of background concentrations. The range of 37 Ar concentrations measured in atmospheric air samples was relatively narrow ranging between less than 1 mBq/m 3 to greater than 2 mBq/m 3 . The average atmospheric concentration of all samples was 0.98 mBq/m 3 , with a standard deviation of 0.5 mBq/m 3 . This is consistent with previous published results. The results presented here demonstrate the capability to detect background concentrations of 37 Ar in atmospheric air.

61 RADIATION PROTECTION AND DOSIMETRY↗

Characterization of Additively Manufactured Tungsten Heavy Alloy Material (CRADA Final Report)

LLNL and Aerojet Rocketdyne, Inc. (AR), using earlier collaborative work in powder bed printing of other materials, have been collaboratively pursuing the additive manufacture of tungsten heavy alloy (WHA) material since 2014. The goal of the project was to establish the ability to produce the LLNL developed material at the AR production facility. When accomplished, AR would produce an agreed array of test samples to technically characterize the material properties via testing. AR would conduct a portion of that testing and provide those results to LLNL. The goal of this work was to perform a trial transfer of LLNL’s WHA technology to AR

36 MATERIALS SCIENCE↗

Augmented Reality Technologies for Radiation Safety Training: A Systematic Review of Sensor Integration and Visualization Approaches

This paper presents a comprehensive systematic review examining the application of augmented reality (AR) and sensor technologies for visualizing ionizing radiation in virtual training environments. The review methodology involved systematic identification and analysis of the relevant literature based on predetermined criteria including publication type, year of publication, application domain, and technological approach. The literature search encompassed publications from 2011 to 2021 across four major academic databases: Web of Science, Google Scholar, IEEE Xplore, and Scopus. Through rigorous screening following PRISMA 2020 guidelines, 23 research articles met the inclusion criteria for detailed analysis. From 404 initial database records, 360 were excluded during title/abstract screening (primarily for lacking AR components, radiation focus, or training applications) and 4 during full-text assessment (all for lacking sensor integration). The findings reveal that AR-based ionizing radiation visualization has been successfully implemented across diverse domains, including nuclear facility operations, medical procedures, CERN research activities, and educational and monitoring applications. The analysis identified multiple dimensions of impact, encompassing distinct benefits, emerging opportunities, and implementation challenges associated with AR deployment for ionizing radiation training. Each of these dimensions is comprehensively examined and documented within this review. Additionally, this study identifies critical research gaps that currently limit the full potential of AR technology in supporting ionizing radiation training programs. These gaps are systematically analyzed and discussed to establish clear directions for future research endeavors in this emerging field.

61 - RADIATION PROTECTION AND DOSIMETRY↗

Wintertime extreme warming events in the high Arctic: characteristics, drivers, trends, and the role of atmospheric rivers

Abstract. An extreme warming event near the North Pole, with 2 m temperature rising above 0 °C, was observed in late December 2015. This specific event has been attributed to cyclones and their associated moisture intrusions. However, little is known about the characteristics and drivers of similar events in the historical record. Here, using data from European Centre for Medium-Range Weather Forecasts Reanalysis, version 5 (ERA5), we study these winter extreme warming events with 2 m temperature over a grid point above 0 °C over the high Arctic (poleward of 80° N) that occurred during 1980–2021. In ERA5, such wintertime extreme warming events can only be found over the Atlantic sector. They occur rarely over many grid points, with a total absence during some winters. Furthermore, even when occurring, they tend to be short-lived, with the majority of the events lasting for less than a day. By examining their surface energy budget, we found that these events transition with increasing latitude from a regime dominated by turbulent heat flux into the one dominated by downward longwave radiation. Positive sea level pressure anomalies which resemble blocking over northern Eurasia are identified as a key ingredient in driving these events, as they can effectively deflect the eastward propagating cyclones poleward, leading to intense moisture and heat intrusions into the high Arctic. Using an atmospheric river (AR) detection algorithm, the roles of ARs in contributing to the occurrence of these extreme warming events defined at the grid-point scale are explicitly quantified. The importance of ARs in inducing these events increases with latitude. Poleward of about 83° N, 100 % of these events occurred under AR conditions, corroborating that ARs were essential in contributing to the occurrence of these events. Over the past 4 decades, both the frequency, duration, and magnitude of these events have been increasing significantly. As the Arctic continues to warm, these events are likely to increase in both frequency, duration, and magnitude, with great implications for the local sea ice, hydrological cycle, and ecosystem.

54 ENVIRONMENTAL SCIENCES↗

Atmospheric river representation in the Energy Exascale Earth System Model (E3SM) version 1.0

Abstract. The Energy Exascale Earth System Model (E3SM) project is an ongoing, state-of-the-science Earth system modeling, simulation, and prediction project developed by the US Department of Energy (DOE). With an emphasis on supporting the DOE's energy mission, understanding and quantifying how well the model simulates water cycle processes is of particular importance. Here, we evaluate E3SM version 1.0 (v1.0) for its ability to represent atmospheric rivers (ARs), which play significant roles in water vapor transport and precipitation. The characteristics and precipitation associated with global ARs in E3SM at standard resolution (1∘ × 1∘) are compared to the Modern-Era Retrospective analysis for Research and Applications, version 2 (MERRA2). Global patterns of AR frequencies in E3SM show high degrees of correlation (≥0.97) with MERRA2 and low mean absolute errors (MAEs; <1 %) annually, seasonally, and across different ensemble members. However, some large-scale condition biases exist, leading to AR biases – most significant of which are the double intertropical convergence zone (ITCZ), a stronger and/or equatorward-shifted subtropical jet during boreal and austral winters, and enhanced Northern Hemisphere westerlies during summer. By comparing atmosphere-only and fully coupled simulations, we attribute the sources of the biases to the atmospheric component or to a coupling response. Using relationships revealed in Dong et al. (2021), we provide evidence showing the stronger North Pacific jet in winter and the enhanced Northern Hemisphere westerlies during summer, associated with E3SM's double ITCZ and related weaker Atlantic meridional overturning circulation (AMOC), respectively, which are significant sources of the AR biases found in the coupled simulations.

58 GEOSCIENCES↗

Metrics tool for for evaluating atmospheric rivers in climate data

The metric tool code is designed for evaluating atmospheric rivers (AR) in climate models and reanalysis. It is python based, with built in metrics of AR frequency, AR precipitation, AR peak day, AR characteristics (width, length, area, latitude and longitude), and output of diagnostic plots. Is there

Dong, Bo↗

HydrogenAR: Interactive Data-Driven Presentation of Dispenser Reliability: Preprint

When delivering presentations to a co-located audience, we typically use slides with text and 2D graphics to complement the spoken narrative. Though presentations have largely been explored on 2D media, augmented reality (AR) allows presentation designers to add data and augmentations to existing physical infrastructure on display. This could provide a more engaging experience to the audience and support comprehension. With HydrogenAR, we present a novel application that leverages the benefits of data-driven storytelling with those of AR to explain the unique challenges of hydrogen dis- penser reliability. Utilizing physical props, situated data, and virtual augmentations and animations, HydrogenAR serves as a unique presentation tool, particularly critical for stakeholders, tour groups, and VIPs. HydrogenAR is a product of multiple collaborative de- sign iterations with a local Hydrogen Fuel research team and is evaluated through interviews with team members and a user study with end-users to evaluate the usability and quality of the interactive AR experience. Through this work, we provide design considera- tions for AR data-driven presentations and discuss how AR could be used for innovative content delivery beyond traditional slide-based presentations.

augmented reality↗

The timing of lunar solidification and mantle overturn recorded in ferroan anorthosite 62237

Ferroan anorthosite suite (FAS) rocks are widely interpreted to represent primordial lunar crust. Despite their importance in pinpointing the timing of lunar crust formation, robust chronological investigations for this rock type are scarce. Here, we report the Ar-Ar, Rb-Sr, and Sm-Nd isotopic systematics for the FAS troctolitic anorthosite 62237. The Ar-Ar isotopic system has been reset by a thermal event at 3710 ± 48 Ma, and the Rb-Sr isotopic systematics has been disturbed such that a Rb-Sr isochron age cannot be determined. However, an internal isochron for the Sm-Nd isotopic system has yielded an age of 4350 ± 73 Ma (MSWD = 2.0) with an initial ε 143 Nd CHUR of -0.53 ± 0.26. The mineral and whole-rock fractions of 62237 plot on the same internal isochron as FAS sample 60025. The combined datasets define an age of 4372 ± 35 Ma (MSWD = 4.0) with an initial ε 143 Nd CHUR of -0.17 ± 0.22. Literature Sm-Nd data for FAS and Mg-suite whole-rocks also plot on the 60025-62237 isochron. The coherence of data from both FAS and Mg-suite rocks examined thus far suggests that both rock suites formed contemporaneously from identical, or nearly identical, sources. In addition, the concordance of FAS and Mg-suite ages suggests that primordial crust solidification either involved both magmatic suites, or that Mg-suite magmatism was contemporaneous with FAS magmatism within resolution of the Sm-Nd chronometer. The ages for FAS and Mg-suite also coincide with the formation ages of the mare basalt source regions and urKREEP. Ferroan anorthosite suite rocks and urKREEP are thought to represent primordial LMO solidification products, whereas Mg-suite and the mare basalt source regions are argued to represent mixtures of various LMO crystallization products that were formed during density-driven overturn of the LMO. The concordance of ages implies that the 4372 ± 35 Ma Sm-Nd isochron records the age of mantle overturn, and that overturn occurred during, or shortly after, solidification of the LMO.

58 GEOSCIENCES↗

A Heterogeneous Palladium Catalyst for the Polymerization of Olefins Prepared by Halide Abstraction Using Surface R 3 Si + Species

Abstract The silylium‐like surface species [ i Pr 3 Si][(R F O) 3 Al−OSi≡)] activates (N^N)Pd(CH 3 )Cl (N^N=Ar−N=CMeMeC=N−Ar, Ar=2,6‐bis(diphenylmethyl)‐4‐methylbenzene) by chloride ion abstraction to form [(N^N)Pd−CH 3 ][(R F O) 3 Al−OSi≡)] ( 1 ). A combination of FTIR, solid‐state NMR spectroscopy, and reactions with CO or vinyl chloride establish that 1 shows similar reactivity patterns as (N^N)Pd(CH 3 )Cl activated with Na[B(Ar F ) 4 ]. Multinuclear 13 C{ 27 Al} RESPDOR and 1 H{ 19 F} S‐REDOR experiments are consistent with a weakly coordinated ion‐pair between (N^N)Pd−CH 3 + and [(R F O) 3 Al−OSi≡)]. 1 catalyzes the polymerization of ethylene with similar activities as [(N^N)Pd−CH 3 ] + in solution and incorporates up to 0.4 % methyl acrylate in copolymerization reactions. 1 produces polymers with significantly higher molecular weight than the solution catalyst, and generates the highest molecular weight polymers currently reported in copolymerization reactions of ethylene and methylacrylate.

Gao, Jiaxin↗

A Heterogeneous Palladium Catalyst for the Polymerization of Olefins Prepared by Halide Abstraction Using Surface R 3 Si + Species

The silylium-like surface species [ i Pr 3 Si][(R F O) 3 Al-OSi≡)] activates (N^N)Pd(CH 3 )Cl (N^N=Ar-N=CMeMeC=N-Ar, Ar=2,6-bis(diphenylmethyl)-4-methylbenzene) by chloride ion abstraction to form [(N^N)Pd-CH 3 ][(R F O) 3 Al-OSi≡)] ( 1 ). A combination of FTIR, solid-state NMR spectroscopy, and reactions with CO or vinyl chloride establish that 1 shows similar reactivity patterns as (N^N)Pd(CH 3 )Cl activated with Na[B(Ar F ) 4 ]. Multinuclear 13 C{ 27 Al} RESPDOR and 1 H{ 19 F} S-REDOR experiments are consistent with a weakly coordinated ion-pair between (N^N)Pd-CH 3 + and [(R F O) 3 Al-OSi≡)]. 1 catalyzes the polymerization of ethylene with similar activities as [(N^N)Pd-CH 3 ] + in solution and incorporates up to 0.4% methyl acrylate in copolymerization reactions. 1 produces polymers with significantly higher molecular weight than the solution catalyst, and generates the highest molecular weight polymers currently reported in copolymerization reactions of ethylene and methylacrylate.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

High Throughput Argon-37 Field System

We report Pacific Northwest National Laboratory (PNNL) has developed a unique fieldable 37 Ar measurement system designed to measure 37 Ar activity concentrations from soil gas samples to detect above ground and underground nuclear explosions. The Argon-37 Field System is modular in design to accommodate both chemical processing and nuclear detection. The system can be packed into shipping crates and shipped to a location near where the sampling is taking place. The system can process six 2-m 3 whole-air samples in 24 hours and can measure the 37 Ar activity in each of the samples using six proportional counters. The proportional counters, designed and built at PNNL, are surrounded with both active and passive shielding to reduce background and can achieve a minimum detection concentration of 10 mBq/m 3 of 37 Ar in whole-air equivalent. The Argon-37 Field System has undergone extensive testing against rigorous requirements to assure the system meets the needs of the noble gas nuclear explosion monitoring community.

98 NUCLEAR DISARMAMENT, SAFEGUARDS, AND PHYSICAL P↗

Anticipating how rain-on-snow events will change through the 21st century: lessons from the 1997 new year’s flood event

The California-Nevada 1997 New Year’s flood was an atmospheric river (AR)-driven rain-on-snow (RoS) event and remains the costliest in their history. The joint occurrence of saturated soils, rainfall, and snowmelt generated inundation throughout northern California-Nevada. Although AR RoS events are projected to occur more frequently with climate change, the warming sensitivity of their flood drivers across scales remains understudied. We leverage the regionally refined mesh capabilities of the Energy Exascale Earth System Model (RRM-E3SM) to recreate the 1997 New Year’s flood with horizontal grid spacings of 3.5 km across California, with forecast lead times of up to 4 days, and across six warming levels ranging from pre-industrial conditions to +3.5° C. We describe the sensitivity of the flood drivers to warming including AR duration and intensity, precipitation phase, intensity and efficiency, snowpack mass and energy changes, and runoff efficiency. Our findings indicate current levels of climate change negligibly influence the flood drivers. At warming levels ≥ 1.7° C, AR hazard potential increases, snowpack nonlinearly decreases, antecedent soil moisture decreases (except where the snowline retreats), and runoff decreases (except in the southern Sierra Nevada where antecedent snowpack persists). Storm total precipitation increases, but at rates below warming-induced increases in saturation-specific humidity. Warming intensifies short-duration, high-intensity rainfall, particularly where snowfall-to-rainfall transitions occur. This study highlights the nonlinear tradeoffs in 21st-century RoS flood hazards with warming and provides water management and infrastructure investment adaptation considerations.

54 ENVIRONMENTAL SCIENCES↗

Atmospheric and oceanic energy transport during North Atlantic freshening events: influences of moisture transport and hydrologic cycle feedbacks

Analogs of present-day rapid ice melt can be found in episodic discharges of icebergs that occurred during glacial periods called Heinrich events. This introduces excess meltwater into the North Atlantic and weakens the Atlantic thermohaline circulation (AMOC), triggering a hydrologic cycle–AMOC collapse feedback as the atmospheric energy transport compensates for reduced northward heat transport. Here we employ a novel series of 100-year North Atlantic “hosing” simulations to investigate atmospheric and oceanic energy transport response from freshwater forcing, focusing in particular on the role of atmospheric rivers (ARs) within atmospheric energy transport. Importantly, we use an “overwriting” methodology that allow us to attribute AMOC weakening to added North Atlantic meltwater and subsequent hydrologic cycle responses, respectively. In contrast to far-reaching response of transient eddies, our results show a substantial increase in moisture convergence from ARs that is geographically constrained to the North Atlantic midlatitudes. Such AR changes nevertheless comprise an important component of net precipitation changes over the Euro-Atlantic sector, with the amount being comparable to that from transient eddies over the subpolar Atlantic. Over the course of the century-long simulations, we demonstrate that hydrologic cycle responses to North Atlantic freshening and subsequent feedbacks, including those from ARs, account for approximately half of the simulated AMOC collapse. Furthermore, our work highlights the dynamics of atmospheric moisture transport response to North Atlantic freshening events and elucidates how intensifying moisture transport may accelerate AMOC collapse in the future.

Atmospheric Science↗

Antibiotic Resistance in Plastisphere

Microbial life on plastic debris, called plastisphere, has invoked special attention on aquatic ecosystems as emerging habitats for antibiotic resistance genes (ARGs) and antibiotic-resistant bacteria (ARB). There is scarce information concerning how properties of plastics influence ARGs and ARB, the effect of biofilms on enrichment of ARGs and ARB, and, especially, the influence of plastic transformation on ARGs and ARB. Limited research has shown that microplastic (MP) surfaces influence proliferation of antibiotic resistance (AR), aged MPs exhibit increased toxicity due to more adsorption-desorption of AR, and MP transformation is correlated with disseminating AR. Prevention measures of AR include minimizing MP releasing into aquatic environments and sewage treatment plants. The future research should aim to identify the interface mechanisms of transformed MNPs and antibiotics alone, or mixed with other contaminants, property changes of MNPs, and associated toxicity evaluation.

59 BASIC BIOLOGICAL SCIENCES↗

Future Warming and Intensification of Precipitation Extremes: A “Double Whammy” Leading to Increasing Flood Risk in California

This study focuses on quantifying future anthropogenic changes in surface runoff associated with extreme precipitation in California's Sierra Nevada. The method involves driving a land surface model with output from a high resolution regional atmospheric simulation of the most extreme atmospheric rivers (ARs). AR events were selected from an ensemble of global climate model simulations of historical and late 21st century climate under the “high-emission” RCP8.5 scenario. Average precipitation during the future ARs increases by ~25% but a much lower proportion falls as snow. The resulting future runoff increase is dramatic—nearly 50%, reflecting both the precipitation increase and simultaneous conversion of snow to rain. The “double whammy” impact on runoff is largest in the 2,000–2,500 m elevation band, where the snowfall loss and precipitation increase are both especially large. Overall, this huge increase in runoff during the most extreme AR events could present major flood control challenges for the region.

54 ENVIRONMENTAL SCIENCES↗

Atmospheric Rivers Impacting Northern California Exhibit a Quasi-Decadal Frequency

Periods of water surplus and deficit in Northern California follow a pronounced quasi-decadal cycle. This cycle is largely driven by the frequency of atmospheric rivers (ARs), affecting the region’s wet and dry periods. Our analyses demonstrate that the quasi-decadal cycle of AR frequency relies on moisture transport associated with the position and intensity of the Aleutian Low. In observations, the Aleutian Low is shown to covary with tropical Pacific sea surface temperature anomalies. A modeling experiment, which incorporates ocean observations from the equatorial Pacific into the fully coupled climate model, provides support that the quasi-decadal cycle of the Aleutian Low is forced by the tropical Pacific. Subsequently, the tropical Pacific modulates the wet season moisture transport toward California on decadal time scales, affecting AR frequency. These results provide metrics for improving interannual-to-decadal prediction of AR activity, which drives hydrological cycles in Northern California.

54 ENVIRONMENTAL SCIENCES↗

Atmospheric River Response to Arctic Sea Ice Loss in the Polar Amplification Model Intercomparison Project

The atmospheric river (AR) response to Arctic sea ice loss in the Northern hemisphere winter is investigated using simulations from the Polar Amplification Model Intercomparison Project. Results have shown that the midlatitude responses are dominated by dynamic effects. Poleward of around 60°N, the dynamic and thermodynamic effects cancel each other, resulting in relatively small responses. The response uncertainty can be characterized by leading uncertainty modes, with the responses over the Pacific and Atlantic projecting onto the northeastward extension and equatorward shift mode, respectively. In addition, the responses seem to be mean state-dependent: under the same forcing, models with more poleward-located climatological ARs tend to show stronger equatorward shifts over the Atlantic; over the Pacific, models with more westward-located climatological AR core tend to show stronger northeastward extensions. Finally, these relationships highlight the importance of improving the AR climatology representation on reducing the response uncertainty to Arctic sea ice loss.

54 ENVIRONMENTAL SCIENCES↗

Radiation exposure induces cross-species temporal metabolic changes that are mitigated in mice by amifostine

Exposure to acute, damaging radiation may occur through a variety of events from cancer therapy and industrial accidents to terrorist attacks and military actions. Our understanding of how to protect individuals and mitigate the effects of radiation injury or Acute Radiation Syndrome (ARS) is still limited. There are only a few Food and Drug Administration-approved therapies for ARS; whereas, amifostine is limited to treating low dose (0.7–6 Gy) radiation poisoning arising from cancer radiotherapy. An early intervention is critical to treat ARS, which necessitates identifying diagnostic biomarkers to quickly characterize radiation exposure. Towards this end, a multiplatform metabolomics study was performed to comprehensively characterize the temporal changes in metabolite levels from mice and non-human primate serum samples following γ-irradiation. The metabolomic signature of amifostine was also evaluated in mice as a model for radioprotection. The NMR and mass spectrometry metabolomics analysis identified 23 dysregulated pathways resulting from the radiation exposure. These metabolomic alterations exhibited distinct trajectories within glucose metabolism, phospholipid biosynthesis, and nucleotide metabolism. A return to baseline levels with amifostine treatment occurred for these pathways within a week of radiation exposure. Together, our data suggests a unique physiological change that is independent of radiation dose or species. Furthermore, a metabolic signature of radioprotection was observed through the use of amifostine prophylaxis of ARS.

59 BASIC BIOLOGICAL SCIENCES↗