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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 253 records · Page 14
All sourcesNASA NTRSDOE OSTI
NASA NTRS1983

A mechanism for plasma waves at the harmonics of the plasma frequency in the electron foreshock boundary

A bump-on-tail unstable reduced velocity distribution, constructed from data obtained at the upstream boundary of the electron foreshock by the GSFC electron spectrometer experiment on the ISEE-1 satellite, is used as the initial plasma state for a numerical integration of the 1D-Vlasov-Maxwell system of equations. The integration is carried through the growth of the instability, beyond its saturation, and well into the stabilized plasma regime. A power spectrum computed for the electric field of the stabilized plasma is dominated by a narrow peak at the Bohm-Gross frequency of the unstable field mode but also contains significant power at the harmonics of the Bohm-Gross frequency. The harmonic power is in sharp peaks which are split into closely spaced doublets. The fundamental peak at the Bohm-Gross frequency is split into a closely spaced triplet. The mechanism for excitation of the second harmonic is shown to be second order wave-wave coupling. Previously announced in STAR as N83-17315

Klimas, A. J.↗
NASA NTRS1984

Spatial mapping of the thermospheric neutral wind field

There are many possible observing strategies available for mapping the thermospheric wind field by using observations of the Doppler shift of the O (1D) airglow with a Fabry-Perot interferometer. The determination of the neutral wind field from observed line-of-sight velocities invariably involves some assumptions about the nature of the wind field. A standard method of observing employs the assumption that horizontal gradients in the wind field are linear. An analysis of measurements from Arecibo, Puerto Rico, that makes use of this assumption, is discussed. For work at high latitudes this assumption may be unrealistic. An alternative approach that requires that local time and longitude be interchangeable but eschews the assumption of linear gradients has been developed and used at Ann Arbor, Michigan, and Calgary, Alberta. These different techniques are examined, and the discussion is illustrated with some typical results.

Tepley, C. A.↗
NASA NTRS1984

Two-frequency microwave resonance measurements from an aircraft - A quantitative estimate of the directional ocean surface spectrum

The use of the two-frequency microwave-resonance technique for airborne measurements of ocean surface-wave spectral components is examined in a summary of experiments conducted with a coherent Ku-band radar flown on a P-3 aircraft in the 1979 MARSEN and 1980 ARSLOE projects. The 1D theoretical formulation used in the analysis of the MARSEN data by Johnson et al. (1982) is extended to the 2D case; the experimental conditions are described in detail; and typical data are presented graphically, analyzed, and compared with independent measurements obtained with a surface-contour radar. The 3.5-deg pencil-beam configuration used in ARSLOE is shown to produce spectra with good directional characteristics (strong resonances at angles of incidence 13-48 deg). It is found that the proper inversion of radar data to surface-elevation spectra requires surface-reflectivity-modulation sources in addition to the long-wave orbital velocity.

Johnson, J. W.↗
NASA NTRS1984

Theoretical electric quadrupole transition probabilities for Ca, Sr and Ba

The 1D-1S quadrupole transition probabilities for Ca, Sr and Ba have been computed using extended GTO and STO valence basis sets and configuration-interaction wavefunctions that include the important core-valence correlation effects. For Ba and Sr, the relativistic contraction of the core orbitals was accounted for in the GTO calculations by a relativistic effective-core potential. The computed Einstein coefficient for Ca of 39.6/s is in excellent agreement with the recent experimental value of 40 + or - 8/s. The best Einstein coefficients for Sr (44.7/s) and Ba (2.98/s) imply increasing quadrupole line strengths down the column. Relativistic effects substantially increase the quadrupole Einstein coefficient for Ba.

Bauschlicher, C. W., Jr.↗
NASA NTRS1984

Oscillator strengths and collision strengths for S III

The present calculation, in a close-coupled approximation for the energy range up to 1,000,000 K, yields collision strengths for the electron impact excitation of S III from the ground 3p2 3P state to the excited states 3s3p3 3D0, 3P0, 3S0, 3d 3D0, 3P0, and 4s 3P0. Also obtained are those transitions' oscillator strengths, and strengths for others involving 3p2 1D and 1S. Configuration-interaction target wave functions yielding oscillator strengths that are accurate to 20 percent are used in collision strength calculations.

Ho, Y. K.↗
NASA NTRS1985

Radar and photometric measurements of an intense type A red aurora

On the evening of March 5, 1981, an intense, type A red aurora appeared over southern Alaska. Radar and photometric measurements were made of the aurora from the Chatanika radar site. The line of sight intensity of the 630.0-nm emissions exceeded 150 kR and was accompanied by enhanced emissions at 486.1 and 427.8 nm. The Chatanika radar measured electron densities of 10 to the 6th per cu cm and electron temperatures of 6000 K at an altitude of 400 km and an invariant latitude of 59 deg in association with the aurora. Comparison of optical and radar measurements indicated that the 630.0-nm emissions were produced to a large degree by thermal excitation of O(1D) in the region of high electron temperatures and densities. Model calculations indicate that the observed density and temperature enhancements and the related optical emissions were the results of a relatively short duration (5-10 min) pulse of precipitating, low-energy (about 30 eV) electrons. Whereas conventional stable auroral red arcs are associated with a gradual decrease in ring current energy density during the recovery phase of a magnetic storm, the type A red aurora may be produced by impulsive ring current energy loss during the main phase.

Robinson, R. M.↗
NASA NTRS1985

Brightness of the O2 atmospheric bands in the daytime thermosphere

The Fabry-Perot interferometer on Dynamics Explorer 2 was used as a low sensitivity photometer to study the O2 Atmospheric A band during the daytime. A study of the brightness of the emission showed that the assumed source of O2(b1Sigma g +) in the thermosphere, O(1D), can account for the observed intensity up to about 250 km but with a significantly different scale height. This combined with an enhanced brightness above this altitude suggests an additional source for this emission.

Skinner, W. R.↗
NASA NTRS1985

Redistribution of radiation in the absence of collisions

Redistribution and depolarization of near-resonant radiation is studied for the He 2(1P)-3(1D) line (668 nm) and some data for H-alpha (656 nm) are also presented. A Nd:YAG pumped dye laser, with a bandwidth of 0.1/cm and a power density of 100 kW/sq cm, is used in the experiment. The transitions have lower levels with natural line widths that are large compared with their upper-level natural widths, and, under experimental conditions, their collisional widths are also small. The ratio of fluorescence to Rayleigh intensity is measured and the results indicate that while the Rayleigh emission has the same temporal development as the laser pulse (5 ns FWHM), the fluorescent intensity has a decay time determined by the radiative decay lifetime and by collisional quenching. The prediction that redistribution of radiation occurs in the absence of collisions for transitions having significant lower-level radiative widths is confirmed. Depolarization rates by collisions with helium are also inferred from the measurements.

Lombardi, G. G.↗
NASA NTRS1985

Oscillator strengths and collision strengths for neutral sulfur

Configuration-interaction target wave functions are used in the present calculation of collision strengths, for electron impact excitation of neutral sulfur from the group 3p4 3P state to excited states 3p3 4s 3S0, 3p3(4S0)3d 3D0, and 3p3 4s 3P0, in a close coupling approximation for the energy range up to 1,000,000 K. Configuration-interaction target wave functions are used in the calculation of collision strengths, and oscillator strengths for various triplet transitions are reported together with transitions between 3p4 1D and 3p4 1S and other singlet-excited states.

Ho, Y. K.↗
NASA NTRS1986

Spectra of noise and amplified turbulence emanating from shock-turbulence interaction: Two scenarios

This work is a small extension of NACA studies of the early fifties that predicted amplification of turbulence on passing through a shock wave (observed for turbulent boundary layers), as well as the generation of intense noise (observed for supersonic jets). The first solved the basic gasdynamics problem of the interaction of an infinite planar shock with a single three-dimensional spectrum component of turbulence (an oblique sinusoidal shear wave). The second developed the comprehensive 3D spectrum analysis necessary to generalize the scenario to the interaction of a shock wave with convected homogeneous turbulence. Numerical calculations were carried out to yield curves (vs. Mach number) of rms sound pressure, temperature fluctuation, and two components of turbulent velocity downstream of the shock, for two cases of preshock turbulence. The present numerical study reproduces these for one case and provides in addition their one-dimensional power spectra (vs. wavenumber or frequency). Ratios of the several postshock spectra to the longitudinal preshock turbulence spectrum (1D) have been computed for a wide range of Mach numbers; curves vs. wavenumber are presented for two scenarios of preshock turbulence: isotropy and axisymmetry, both based on the von Karman 3D spectrum.

Ribner, H. S.↗
NASA NTRS1985

The thermal structure of the dayside upper atmosphere of Venus above 125 km

A one-dimensional model of the Venus thermosphere has been constructed which includes computation of the heating efficiency of solar ultraviolet radiation, heat loss by radiation to space of infrared-active species, thermal transport by molecular and eddy conduction, and viscous dissipation. By comparing model predictions with results obtained from the Pioneer Venus Orbiter spacecraft, the results indicate that energy transport parameterized by eddy heat conduction plays a dominant role in determining thermospheric temperature. It is suggested that there exists a feedback mechanism linking heating and thermospheric circulation such that eddy cooling maintains an asymptotic temperature of about 300 K for both solar-maximum and solar-minimum conditions. The variation in thermospheric temperature with solar zenith angle, atomic oxygen-mixing ratio, rate of vibrational excitation of CO2 by ground-state O atoms, and the assumed transfer of O(1D) electronic energy to CO2 vibrational energy are also studied.

Hollenbach, D. J.↗
NASA NTRS1985

What we do not know about cometary ices - A review of the incomplete evidence

Only two features seem rather well established about the cometary nucleus: it is an icy conglomerate that contains a large amount of volatile ices, and its major constituent seems to be water ice. The evidence on all the minor constituents is incomplete and fragmentary and there are still major difficulties in establishing a complete list of the parent molecules from the numerous radicals, ions, and atoms observed in the coma. In particular, the case of the forbidden lines of oxygen is discussed here in detail; new arguments are shown to contradict the need for CO2 as a major source of O(1D).

Delsemme, A. H.↗
NASA NTRS1985

Theory and calculation of resonances and autoionization of two-electron atoms and ions

Techniques for calculating the electron scattering from one-electron hydrogen-like targets on the basis of the Feshback formalism, are discussed. The principal similarities between resonance parameters in the Feshbach formalism and the corresponding Breit-Wigner quantities, are described in detail. Special attention is devoted to a description of the Fano line shape parameter q, and a technique for formulating it in terms of a projector operator is proposed. The theoretical methods are illustrated by numerical calculations for 1S, 3P, and 1D states of H(-) below the first excited threshold of the target atom. Calculations of 1,3S 1,3P, 1,3D states for He are also presented.

Temkin, A.↗
NASA NTRS1986

The O2 atmospheric dayglow in the thermosphere

Spectral measurements (Delta lambda = 8A) from Spacelab 1 of the O2 atmospheric bands in the dayglow at thermospheric altitudes are reported for a tangent ray height of 150 km. Vibrational levels up to nu-prime = 4 are found in the data, requiring a source in addition to the energy transfer from O(1D) to O2. It is suggested that this source is the collisional deactivation of N(2D) by O2.

Torr, M. R.↗
NASA NTRS1985

LIMS data - Inferred stratospheric distribution of NOx and HOx trace constituents and the calculated odd nitrogen budget

LIMS, SAMS, SBUV and in-situ data have been used to infer species not measured but which are of photochemical interest, e.g., O(3P), O(1D), NO, N2O5, OH, HO2, ClO and HCl. (LIMS = limb infrared monitor of the stratosphere; SAMS = stratospheric and mesospheric sounder; and SBUV = solar backscattered ultraviolet instrument.) Production and loss of odd nitrogen have been calculated and estimates have been made of the odd nitrogen transport due to adiabatically driven circulation derived from LIMS data. Data used from LIMS include O3, NO2, HNO3, H2O and T. CH4 and N2O were taken from SAMS and the UV solar flux from the SBUV instrument. Species were inferred for periods in October, December, March and May. Results for December are discussed. Results indicate: (1) maximum stratospheric odd nitrogen levels of 25 ppbv; (2) evidence of odd nitrogen transport from the mesosphere appearing at 25 km in the wintertime polar latitudes; (3) the polar night build-up of high levels of N2O5 beginning after the autumnal equinox; and (4) the possibility of large downward fluxes of odd nitrogen into the troposphere during the winter at latitudes poleward of 60 degrees.

Callis, L. B.↗
NASA NTRS1987

Potential energy surfaces for atomic oxygen reactions: Formation of singlet and triplet biradicals as primary reaction products with unsaturated organic molecules

The experimental study of the interaction of atomic oxygen with organic polymer films under LEO conditions has been hampered by the inability to conduct detailed experiments in situ. As a result, studies of the mechanism of oxygen atom reactions have relied on laboratory O-atom sources that do not fully reproduce the orbital environment. For example, it is well established that only ground electronic state O atoms are present at LEO, yet most ground-based sources are known to produce singlet O atoms and molecules and ions in addition to O(3P). Engineers should not rely on such facilities unless it can be demonstrated either that these different O species are inert or that they react in the same fashion as ground state atoms. Ab initio quantum chemical calculations have been aimed at elucidating the biradical intermediates formed during the electrophilic addition of ground and excited-state O atoms to carbon-carbon double bonds in small olefins and aromatic molecules. These biradicals are critical intermediates in any possible insertion, addition and elimination reaction mechanisms. Through these calculations, we will be able to comment on the relative importance of these pathways for O(3P) and O(1D) reactions. The reactions of O atoms with ethylene and benzene are used to illustrate the important features of the mechanisms of atomic oxygen reaction with unsaturated organic compounds and polymeric materials.

Jaffe, Richard L.↗
NASA NTRS1987

Potential surfaces for O atom-polymer reactions

Ab initio quantum chemistry methods are used to study the energetics of interactions of O atoms with organic compounds. Polyethylene (CH2)n has been chosen as the model system to study the interactions of O(3P) and O(1D) atoms with polymers. In particular, H abstraction is investigated and polyethylene is represented by a C3 (propane) oligomeric model. The gradient method, as implemented in the GRADSCF package of programs, is used to determine the geometries and energies of products and reactants. The saddle point, barrier geometry is determined by minimizing the squares of the gradients of the potential with respect to the internal coordinates. To correctly describe the change in bonding during the reaction at least a two configuration MCSCF (multiconfiguration self consistent field) or GVB (generalized valence bond) wave function has to be used. Basis sets include standard Pople and Dunning sets, however, increased with polarization functions and diffuse p functions on both the C and O atoms. The latter is important due to the O(-) character of the wave function at the saddle point and products. Normal modes and vibrational energy levels are given for the reactants, saddle points and products. Finally, quantitative energetics are obtained by implementing a small CAS (complete active space) approach followed by limited configuration interaction (CI) calculations. Comparisons are made with available experimental data.

Laskowski, B. C.↗
NASA NTRS1985

High spectral resolution Fabry-Perot interferometer measurements of Comet Halley at H-alpha and 6300 A

A 40.6-cm Newtonian telescope was interfaced to the Fabry-Perot interferometer at the Arecibo Observatory to make high-spectral-resolution measurements of Comet Halley emissions at 6562.72 A (H-alpha) and 6300.3 A (O I). The atomic hydrogen outflow velocity was found to be approximately 7.9 + or - 1.0 km/s. In general, the H-alpha spectra are highly structured, and indicative of a multiple component atomic hydrogen velocity distribution. For O (1D), implied production rates of 6.44 + or - 3.0 x 10 to the 28th/s and 5.66 + or - 2.7 x 10 to the 28th/s were found on March 15 and 17, respectively.

Kerr, R. B.↗