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At least 235 records · Page 13

Effect of Evaporation on Vapor Space Flammability in DWPF Process Vessels - 20278

The Savannah River Site (SRS) Defense Waste Processing Facility (DWPF) processes liquid high-level waste (HLW) and encapsulates it in glass within stainless-steel containers suitable for safe, long-term storage and disposal. Radiolytic and chemical decomposition of the liquid waste generates hydrogen and other flammable gases creating a hazard. The rate of flammable gas generation increases by an order of magnitude as temperature increases from sub-boiling to boiling. DWPF controls this hazard in process tanks by ensuring a minimum purge flow through each tank's head space. The minimum purge flow rate is established assuming dry air and neglecting evaporation. However, this study determined that steam from boiling in a representative process tank is sufficient to dilute flammable gases and, thereby, preclude flammability. For sub-boiling, water vapor is an insufficient diluent considering hydrogen's lower flammable limit (LFL) in air. However, the upper and lower flammable limits approach each other in a hydrogen-air-water-vapor environment as the water vapor concentration increases. This effect may preclude flammable conditions if water vapor concentration is about 60 volume percent or higher. A saturated, constant-pressure air-water system would achieve 60 volume percent water vapor at 86 deg. C. (authors)

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Cryogenic pressurized storage with hump-reinforced vacuum jacket

A cryogenic hydrogen storage vessel includes an outer vacuum vessel, a reinforcement ring on the outer vacuum vessel, an inner pressure vessel inside of the outer vacuum vessel, and a vacuum space between the outer vacuum vessel and the inner pressure vessel. One embodiment of the cryogenic hydrogen storage vessel includes an outer vacuum vessel; a hump-shaped reinforcement ring on the outer vacuum vessel, the hump-shaped reinforcement ring including an external hump portion that protrudes from the hump-shaped reinforcement ring and an internal recess in the hump-shaped reinforcement ring; an inner pressure vessel inside of the outer vacuum vessel, a vacuum space between the outer vacuum vessel and the inner pressure vessel, and a composite support ring in the vacuum space extending from the hump-shaped reinforcement ring on the outer vacuum vessel to the inner pressure vessel, the composite support ring nested in the recess in the hump-shaped reinforcement ring.

Aceves, Salvador M.↗

V31 Test Report

The V31 containment vessel was procured by the US Army Recovered Chemical Material Directorate (RCMD) as a third - generation EDS containment vessel. It is the fifth EDS vessel to be fabricated under Code Case 2564 of the 2019 ASME Boiler and Pressure Vessel Code, which provides rules for the design of impulsively loaded vessels. The explosive rating for the vessel, based on the code case, is twenty-four (24) pounds TNT - equivalent for up to 1092 detonations. This report documents the results of explosive tests that were performed on the vessel at Sandia National Laboratories in Albuquerque, New Mexico to qualify the vessel for field operations use. There were three design basis configurations for qualification testing. Qualification test (1) consisted of a simulated M55 rocket motor and warhead assembly of 24lbs of Composition C-4 (30 lb TNT equivalent). This test was considered the maximum load case, based on modeling and simulation methods performed by Sandia prior to the vessel design phase. Qualification test (2) consisted of a regular, right circular cylinder, unitary charge, located central to the vessel interior of 19.2 lb of Composition C-4 (24 lb TNT equivalent). Qualification test (3) consisted of a 12-pack of regular, right circular cylinders of 2 lb each, distributed evenly inside the vessel (totaling 19.2 lb of C-4, or 24 lb TNT equivalent). All vessel acceptance criteria were met.

42 ENGINEERING↗

V31 Test Report

The V31 containment vessel was procured by the US Army Recovered Chemical Materiel Directorate (RCMD) as a third-generation EDS containment vessel. It is the fifth EDS vessel to be fabricated under Code Case 2564 of the 2019 ASME Boiler and Pressure Vessel Code, which provides rules for the design of impulsively loaded vessels. The explosive rating for the vessel, based on the code case, is twenty-four (24) pounds TNT-equivalent for up to 1092 detonations. This report documents the results of explosive tests that were performed on the vessel at Sandia National Laboratories in Albuquerque, New Mexico to qualify the vessel for field operations use. There were three design basis configurations for qualification testing. Qualification test (1) consisted of a simulated M55 rocket motor and warhead assembly of 24lbs of Composition C-4 (30 lb TNT equivalent). This test was considered the maximum load case, based on modeling and simulation methods performed by Sandia prior to the vessel design phase. Qualification test (2) consisted of a regular, right circular cylinder, unitary charge, located central to the vessel interior of 19.2 lb of Composition C-4 (24 lb TNT equivalent). Qualification test (3) consisted of a 12-pack of regular, right circular cylinders of 2 lb each, distributed evenly inside the vessel (totaling 19.2 lb of C-4, or 24 lb TNT equivalent). All vessel acceptance criteria were met .

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

V28 Test Report

The V28 containment vessel was procured by the US Army Recovered Chemical Material Directorate (RCMD) as a replacement vessel for use on the P2 Explosive Destruction Systems. It is the fourth EDS vessel to be fabricated under Code Case 2564 of the ASME Boiler and Pressure Vessel Code, which provides rules for the design of impulsively loaded vessels. The explosive rating for the vessel, based on the Code Case, is nine (9) pounds TNT- equivalent for up to 637 detonations. This report documents the results of explosive tests that were done on the vessel at Sandia National Laboratories in Albuquerque New Mexico to qualify the vessel for explosive use. The primary qualification test consisted of six, 1.5 pounds charges of Composition C-4 (equivalent to 11.25 pounds TNT) distributed around the vessel in accordance with the User Design Specification. This test was repeated due to a lack of proper clamp settings. Two additional tests using less explosive were performed, one identical in configuration to a test performed in the V27 qualification series as a baseline for comparison, and one where the separation distance of the charges was increased to extend the V27 analysis of distributed load effects on the P2 vessel. All vessel acceptance criteria were met.

45 MILITARY TECHNOLOGY, WEAPONRY, AND NATIONAL DEF↗