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Methane on Mars: Thermodynamic Equilibrium and Photochemical Calculations

The detection of methane (CH4) in the atmosphere of Mars by Mars Express and Earth-based spectroscopy is very surprising, very puzzling, and very intriguing. On Earth, about 90% of atmospheric ozone is produced by living systems. A major question concerning methane on Mars is its origin - biological or geological. Thermodynamic equilibrium calculations indicated that methane cannot be produced by atmospheric chemical/photochemical reactions. Thermodynamic equilibrium calculations for three gases, methane, ammonia (NH3) and nitrous oxide (N2O) in the Earth s atmosphere are summarized in Table 1. The calculations indicate that these three gases should not exist in the Earth s atmosphere. Yet they do, with methane, ammonia and nitrous oxide enhanced 139, 50 and 12 orders of magnitude above their calculated thermodynamic equilibrium concentration due to the impact of life! Thermodynamic equilibrium calculations have been performed for the same three gases in the atmosphere of Mars based on the assumed composition of the Mars atmosphere shown in Table 2. The calculated thermodynamic equilibrium concentrations of the same three gases in the atmosphere of Mars is shown in Table 3. Clearly, based on thermodynamic equilibrium calculations, methane should not be present in the atmosphere of Mars, but it is in concentrations approaching 30 ppbv from three distinct regions on Mars.

Levine, J. S.↗

Digital tracking loops for a programmable digital modem

In this paper, an analysis and hardware emulation of the tracking loops for a very flexible programmable digital modem (PDM) will be presented. The modem is capable of being programmed for 2, 4, 8, 16-PSK, 16-QAM, MSK, and Offset-QPSK modulation schemes over a range of data rates from 2.34 to 300 Mbps with programmable spectral occupancy from 1.2 to 1.8 times the symbol rate; these operational parameters are executable in burst or continuous mode. All of the critical processing in both the modulator and demodulator is done at baseband with very high-speed digital hardware and memory. Quadrature analog front-ends are used for translation between baseband and the IF center frequency. The modulator is based on a table lookup approach, where precomputed samples are stored in memory and clocked out according to the incoming data pattern. The sample values are predistorted to counteract the effects of the other filtering functions in the link as well as any transmission impairments. The demodulator architecture was adapted from a joint estimator-detector (JED) mathematical analysis. Its structure is applicable to most signalling formats that can be represented in a two-dimensional space. The JED realization uses interdependent, mutually aiding tracking loops with post-detection data feedback. To expedite and provide for more reliable synchronization, initial estimates for these loops are computed in a parallel acquisition processor. The cornerstone of the demodulator realization is the pre-averager received data filter which allows operation over a broad range of data rates without any hardware changes and greatly simplifies the implementation complexity. The emulation results confirmed tracking loop operation over the entire range of operational parameters listed above, as well as the capability of achieving and maintaining synchronization at BER's in excess of 10(exp -1). The emulation results also showed very close agreement with the tracking loop analysis, and validated the resolution apportionment of the various hardware elements in the tracking loops.

Poklemba, John J.↗

Development of an expert system for analysis of Shuttle atmospheric revitalization and pressure control subsystem anomalies

The paper describes the Shuttle Leak Management Expert System (SLMES), a preprototype expert system developed to enable the ECLSS subsystem manager to analyze subsystem anomalies and to formulate flight procedures based on flight data. The SLMES combines the rule-based expert system technology with the traditional FORTRAN-based software into an integrated system. SLMES analyzes the data using rules, and, when it detects a problem that requires simulation, it sets up the input for the FORTRAN-based simulation program ARPCS2AT2, which predicts the cabin total pressure and composition as a function of time. The program simulates the pressure control system, the crew oxygen masks, the airlock repress/depress valves, and the leakage. When the simulation has completed, other SLMES rules are triggered to examine the results of simulation contrary to flight data and to suggest methods for correcting the problem. Results are then presented in form of graphs and tables.

Lafuse, Sharon A.↗

Role of MODIS Vegetation Phenology Products in the ForWarn System for Monitoring of Forest Disturbances in the Conterminous United States

This presentation discusses MODIS vegetation phenology products used in the ForWarn Early Warning System (EWS) tool for near real time regional forest disturbance detection and surveillance at regional to national scales. The ForWarn EWS is being developed by the USDA Forest Service NASA, ORNL, and USGS to aid federal and state forest health management activities. ForWarn employs multiple historical land surface phenology products that are derived from MODIS MOD13 Normalized Difference Vegetation Index (NDVI) data. The latter is temporally processed into phenology products with the Time Series Product Tool (TSPT) and the Phenological Parameter Estimation Tool (PPET) software produced at NASA Stennis Space Center. TSPT is used to effectively noise reduce, fuse, and void interpolate MODIS NDVI data. PPET employs TSPT-processed NDVI time series data as an input, outputting multiple vegetation phenology products at a 232 meter resolution for 2000 to 2011, including NDVI magnitude and day of year products for seven key points along the growing season (peak of growing season and the minima, 20%, and 80% of the peak NDVI for both the left and right side of growing season), cumulative NDVI integral products for the most active part of the growing season and sequentially across the growing season at 8 day intervals, and maximum value NDVI products composited at 24 day intervals in which each product date has 8 days of overlap between the previous and following product dates. MODIS NDVI phenology products are also used to compute nationwide NRT forest change products refreshed every 8 days. These include percent change in forest NDVI products that compare the current NDVI from USGS eMODIS products to historical MODIS MOD13 NDVI. For each date, three forest change products are produced using three different maximum value NDVI baselines (from the previous year, three previous years, and all previous years). All change products are output with a rainbow color table in which forests with the most severe NDVI decreases are assigned hot colors (yellow to red) and forests with prominent NDVI increases are assigned cold colors (blue tones). All mentioned products have been integrated as data layers into ForWarn s geospatial data viewer known as the U.S. Forest Change Assessment Viewer (FCAV). The latter is used to view and assess the context of the mentioned forest change products with respect to ancillary data layers, such as land cover, elevation, hydrologic features, climatic data, storm data, aerial disturbance surveys, fire data, and land ownership. The FCAV also includes a temporal NDVI profiler for viewing phenological change in multi-year NDVI associated with known or suspected regionally apparent forest disturbances (e.g., from fire and insects). ForWarn forest change products have been used to detect, track, and assess several biotic and abiotic regional forest disturbance events across the country, including ephemeral and longer lasting damage from storms, drought, and insects. Such change products are most effective for viewing severe disturbances affecting multiple MODIS pixels. MODIS vegetation phenology products contribute vital current information on forest conditions to the ForWarn system and this role is expected to grow as these products are refined and derivative products are added.

Spruce, Joseph P.↗

Current Pressure Transducer Application of Model-based Prognostics Using Steady State Conditions

Prognostics is the process of predicting a system's future states, health degradation/wear, and remaining useful life (RUL). This information plays an important role in preventing failure, reducing downtime, scheduling maintenance, and improving system utility. Prognostics relies heavily on wear estimation. In some components, the sensors used to estimate wear may not be fast enough to capture brief transient states that are indicative of wear. For this reason it is beneficial to be capable of detecting and estimating the extent of component wear using steady-state measurements. This paper details a method for estimating component wear using steady-state measurements, describes how this is used to predict future states, and presents a case study of a current/pressure (I/P) Transducer. I/P Transducer nominal and off-nominal behaviors are characterized using a physics-based model, and validated against expected and observed component behavior. This model is used to map observed steady-state responses to corresponding fault parameter values in the form of a lookup table. This method was chosen because of its fast, efficient nature, and its ability to be applied to both linear and non-linear systems. Using measurements of the steady state output, and the lookup table, wear is estimated. A regression is used to estimate the wear propagation parameter and characterize the damage progression function, which are used to predict future states and the remaining useful life of the system.

Fault Estimation↗

Determination of the efficiency of a proportional counter for detecting X-rays

A parallel beam of X-rays (approximately monoenergetic) passing through a rectangular slit and scattering from two flat mirrors comprise the X-ray test. The two mirrors are arranged in a periscope geometry so that the final reflected beam is parallel to the incident beam but displaced laterally by given amount. One of the detectors used to intercept the reflected X-rays is a one dimensional gas-filled proportional counter which is sensitive to the position (in 1 dimension) at which the X-rays are incident within its detecting "window". The total length of the anode wire of the proportional counter is 120 mm and this length can be divided electronically into a maximum of 1,024 parts. Hence, the output of an experimental run would be the number of incident X-rays that registered on each of the 1,024 channels. Each channel would represent an X-ray at a different spatial location and, hence, at a different scattering angle. In order to look at a wider range of scattering angles, the detector is placed on an optical table which can be rotated.

Williams, A. C.↗

Stratospheric ozone measurements using a ground-based, high-power lidar

A lidar facility has been established at the JPL-Table Mountain Observatory at an altitude of 2300 m in the San Gabriel Mountains northeast of Los Angeles. This facility uses the laser remote sensing technique of differential absorption lidar (DIAL) to derive atmospheric ozone concentration profiles. Two separate systems are used to obtain the ozone profile: an Nd:YAG based troposphere system will measure from the ground to 20 km and an excimer based system measures from 15 km to 50 km. The systems are designed to make long-term measurements so that small changes in the ozone abundance can be detected. This paper will describe the stratospheric ozone lidar system and present some of the results which have been obtained since it began routine operation in January 1988.

Mcdermid, I. Stuart↗

NASA Tech Briefs, November 2009

Topics covered include: Cryogenic Chamber for Servo-Hydraulic Materials Testing; Apparatus Measures Thermal Conductance Through a Thin Sample from Cryogenic to Room Temperature; Rover Attitude and Pointing System Simulation Testbed; Desktop Application Program to Simulate Cargo-Air-Drop Tests; Multimodal Friction Ignition Tester; Small-Bolt Torque-Tension Tester; Integrated Spacesuit Audio System Enhances Speech Quality and Reduces Noise; Hardware Implementation of a Bilateral Subtraction Filter; Simple Optoelectronic Feedback in Microwave Oscillators; Small X-Band Oscillator Antennas; Free-Space Optical Interconnect Employing VCSEL Diodes; Discrete Fourier Transform Analysis in a Complex Vector Space; Miniature Scroll Pumps Fabricated by LIGA; Self-Assembling, Flexible, Pre-Ceramic Composite Preforms; Flight-speed Integral Image Analysis Toolkit; Work Coordination Engine; Multi-Mission Automated Task Invocation Subsystem; Autonomously Calibrating a Quadrupole Mass Spectrometer; Determining Spacecraft Reaction Wheel Friction Parameters; Composite Silica Aerogels Opacified with Titania; Multiplexed Colorimetric Solid-Phase Extraction; Detecting Airborne Mercury by Use of Polymer/Carbon Films; Lattice-Matched Semiconductor Layers on Single Crystalline Sapphire Substrate; Pressure-Energized Seal Rings to Better Withstand Flows; Rollerjaw Rock Crusher; Microwave Sterilization and Depyrogenation System; Quantifying Therapeutic and Diagnostic Efficacy in 2D Microvascular Images; NiF2/NaF:CaF2/Ca Solid-State High-Temperature Battery Cells; Critical Coupling Between Optical Fibers and WGM Resonators; Microwave Temperature Profiler Mounted in a Standard Airborne Research Canister; Alternative Determination of Density of the Titan Atmosphere; Solar Rejection Filter for Large Telescopes; Automated CFD for Generation of Airfoil Performance Tables; Progressive Classification Using Support Vector Machines; Active Learning with Irrelevant Examples; A Data Matrix Method for Improving the Quantification of Element Percentages of SEM/EDX Analysis; Deployable Shroud for the International X-Ray Observatory; Improved Model of a Mercury Ring Damper; Optoelectronic pH Meter: Further Details; X-38 Advanced Sublimator; and Solar Simulator Represents the Mars Surface Solar Environment.

Source record↗

Bi-Axial Load Testing of a Woven-Webbing Inflatable Space Habitat Restraint Layer Component

This report discusses testing of a bi-axial woven panel consisting of high-strength webbings that represent a portion of the structural restraint layer of an inflatable space structure. Inflatable softgoods vessels are being researched for human space missions as possible habitats, airlocks and tunnel elements. Understanding the complex behavior of the softgoods restraint layer and maturing finite element analysis capabilities to model these structures is critical to their successful implementation. The primary goal of this research is to study the load-up and load distribution in a weave of webbings, before and after the loss of tension in one of the webbings. In addition, a key objective is to evaluate the ability to convert strains measured via photogrammetry using digital image correlation to loads in the weave. The report gives an introduction and objectives for the test program and a description of the test fixture, setup and procedure. This is followed by a section focusing on the test data and associated discussion. To streamline presentation of the data, one focus case is detailed in the main text. (Comprehensive data set can be found in Appendix A for the three remaining test cases.) In addition to the load and time histories for one case, summary charts and tables that incorporate data from all four test cases are provided. The concluding remarks include major findings, lessons learned and recommendations for future work. Appendix B provides complementary full-field strain results when considering the existing woven webbing data as a fabric. These types of results could inform models intended for global representation. Appendix C contains a description from a series of exploratory instrumented hammer tap tests and results on the weave. These tests describe an area of research for the biaxial test fixture beyond the current testing studying the propagation and detection of vibrations in a tensioned weave that has applications in impact and damage detection.

Karen H Lyle↗

Continuation of Long-Term Global SO2 Pollution Monitoring from OMI to OMPS

Over the past 20 years, advances in satellite remote sensing of pollution-relevant species have made space-borne observations an increasingly important part of atmospheric chemistry research and air quality management. This progress has been facilitated by advanced UV-vis spectrometers, such as the Ozone Monitoring Instrument (OMI) on board the NASA Earth Observing System (EOS) Aura satellite, and continues with new instruments, such as the Ozone Mapping and Profiler Suite (OMPS) on board the NASA-NOAA Suomi National Polar-orbiting Partnership (SNPP) satellite. In this study, we demonstrate that it is possible, using our state-of-the-art principal component analysis (PCA) retrieval technique, to continue the long-term global SO2 pollution monitoring started by OMI with the current and future OMPS instruments that will fly on the NOAA Joint Polar Satellite System (JPSS) 1, 2, 3, and 4 satellites in addition to SNPP, with a very good consistency of retrievals from these instruments. Since OMI SO2 data have been primarily used for (1) providing regional context on air pollution and long-range transport on a daily basis and (2) providing information on point emission sources on an annual basis after data averaging, we focused on these two aspects in our OMI-OMPS comparisons. Four years of retrievals (2012-2015) have been compared for three regions: eastern China, Mexico, and South Africa. In general, the comparisons show relatively high correlations (r = 0. 79-0.96) of daily regional averaged SO2 mass between the two instruments and near-unity regression slopes (0.76-0.97). The annual averaged SO2 loading differences between OMI and OMPS are small (< 0.03 Dobson unit (DU) over South Africa and up to 0.1 DU over eastern China). We also found a very good correlation (r = 0. 92-0.97) in the spatial distribution of annual averaged SO2 between OMI and OMPS over the three regions during 2012-2015. The emissions from ∼ 400 SO2 sources calculated with the two instruments also show a very good correlation (r = ∼ 0.9) in each year during 2012-2015. OMPS-detected SO2 point source emissions are slightly lower than those from OMI, but OMI-OMPS differences decrease with increasing strength of source. The OMI-OMPS SO2 mass differences on a pixel by pixel (daily) basis in each region can show substantial differences. The two instruments have a spatial correlation coefficient of 0.7 or better on < ∼ 50 % of the days. It is worth noting that consistent SO2 retrievals were achieved without any explicit adjustments to OMI or OMPS radiance data and that the retrieval agreement may be further improved by introducing a more comprehensive Jacobian lookup table than is currently used.

satellite remote sensing of pollution↗

Monitoring Airspace Complexity and Determining Contributing Factors

The national airspace has evolved over many years to accommodate increased traffic demand [1] while simultaneously maintaining one of the safest forms of transportation [2], [3]. One of the reasons for this success is the ability of the system and the operators to adapt and accommodate to situations that routinely disrupt optimal operations. These situations may include: adverse weather, delays, early arrivals, equipment outages, and other factors that are outside the operators ability to control. These factors can lead to states where automation is unable to properly handle these issues and therefore air traffic controllers and pilots have to intervene, ultimately increasing communication between operators resulting in higher workload. As controller workload increases to handle sub-optimal operating conditions this can be viewed as an increase in complexity. The reasoning for this is because humans are now required to make tactical decisions in response to external factors, resulting in a departure from the strategic plan where operations would be more efficiently managed. Human operators control airspace complexity under rigid regulations that are constantly changing. The airspace is divided into sectors and the number of aircraft assigned to each controller is limited for safe handling. There has been past work that devised airspace complexity metrics in commercial aviation and related these metrics to controller workload (e.g., [4],[5]). The upper bounds on the system load are pre-determined. Such bounds on complexity make for a safe system, but the system cannot scale and adapt to autonomous, dense, and heterogeneous traffic, including the many types of Unmanned Aerial Vehicles (UAVs) envisioned to be added to the operations. We hypothesize that, as traffic density and heterogeneity grow, and other key metrics change, there will be phase transitions at which the way traffic should be managed changes significantly [6]. We offer a method for in-time detection of contributing factors that lead to phase transitions, characterized by increased complexity. To the best of our knowledge, there is no tool similar to our proposed effort that identifies such contributing factors or precursor patterns. To define the scope we are proposing to measure complexity from the viewpoint of the Terminal Radar Approach Control Facilities (TRACON) controller’s perspective. In particular we are analyzing arrivals into KSFO. With safety as the top concern for airspace operators, it is important to recognize that as density and heterogeneity grow, the focus of the system will change. Times of the day when the airspace has low density and heterogeneity, the flights will follow more efficient paths where the aircraft move on established routes that are more or less directly to the destination. However, when density and heterogeneity increases, the system will begin changing focus to avoiding conflicts and collisions and route the flights in a more flexible way. Higher flexibility requires more communication and coordination between controllers and pilots which the current automation is unable to handle. This paper proposes a novel approach that monitors airspace complexity at multiple scales, uses a Machine Learning-based tool that predicts when operations will transition to a regime of greater complexity, and identifies actions that can reduce the complexity while still maintaining efficient and safe operations. We demonstrate our proposed approach using data from multiple complementary sources. This includes, but is not limited to: historical aircraft surveillance data from NASA’s Sherlock Data Warehouse [7], METAR weather data, and airport configuration data from Aviation System Performance Metrics (ASPM). The surveillance data flight paths are sampled at a variable sample rate — increasing as the aircraft approaches the airport. This is due to how Sherlock manages flight track stitching between different radar facilities which have different sampling rates. The weather and performance data are logged at defined intervals throughout the day at a courser refresh rate. In addition to the logged data and metrics, we leverage pre-defined Standard Terminal Arrival Routes (STARs) procedures to characterize the path of each flight. Each flight files for one of these routes in the flight plan well before entering the terminal airspace, and approximately follows the route until it leaves the STAR, typically on the final fix of a runway transition. However, most flights do not always fly the full STAR procedure to completion [8], but the majority do adhere to the fixes within the common route of the procedure. Our approach leverages fixes in the common route of each of the STARs to build a reference path to the airport. This allows us to characterize the flight paths in what we are defining as the “maneuvering area” (the airspace between the STAR and before the flight is lined up on the runway’s final approach) to determine how off nominal the flights are to calculate its complexity score. Determining airspace complexity is a concept that does not have a concrete answer. In designing this metric, we consider what increases the workload for the air traffic controllers. Consequently more specialized vectoring maneuvers results in higher workload. Accordingly, we start with a theory: each flight has a direct path it takes from the STAR’s common route to the final approach’s outer marker fix for the flight’s landing runway. It is important to note that the direct path is only used as a reference. If the majority of the flights have a large consistent offset as compared to other routes it does not necessarily mean that those flights have higher complexity. We are merely building a distribution based on this direct path for that particular STAR and runway pair to determine the normal mode of operations for that route. Flights that are in the upper tail of these distributions will result in higher complexity scores and flights that fly in the median will represent the normal mode of operations and therefore will have lower complexity scores. Since flights following each STAR route take different paths to the airport, we have a different distribution for each STAR route and therefore can model these distributions to compute a complexity score from their respective normalized distributions. To evaluate the effectiveness of our proposed airspace complexity metric we will compare against an established approach based on trajectory clustering [9]. This unsupervised learning technique consists of the following steps: (1) identify the general maneuvering areas (waypoints) by performing $\kappa$-means or DBSCAN clustering on locations where aircraft frequently turn based on the surveillance radar track data, (2) map flight trajectories onto sequences of waypoints, and (3) cluster the sequences based on their common subsequences. From a high-level perspective, this baseline model learns nominal operations in the airspace through the sequence of waypoints that are representative of where aircraft change direction and defines deviations from the nominal operations as “complex.” Therefore, more deviations from the nominal operations correspond to higher complexity values. For our validation, we re-implemented this technique and tune model hyper-parameters to correctly detect waypoints for the arrival traffic into the San Francisco bay area. We will compute the complexity measure over a one-year period using our proposed technique as well as the baseline. Our validation will be based on each technique’s ability to detect a set of undesirable outcomes (e.g., go-arounds, holding patterns, average time in the airspace, etc.). Since our current complexity metric is derived from the offset from the direct reference path, it’s important to understand what causes these offsets. In many of the flights with high offset distance, flights performing holding patterns and S turns can be observed. These maneuvering tactics are utilized to add distance between the aircraft and the destination runway to prevent multiple flights from having conflicting arrival times. In order to predict a rise in complexity (or the precursor to complexity), it’s necessary to be able to identify these potential conflicts (which in turn, result in higher offsets). To do this, we define a “representative flight” for each STAR route and runway pair. This flight is approximately the path the flight would take if there was a clear path with no other flights in the airspace — including the time remaining to the airport. We first identify the flights for a given STAR runway pair using the offset to the reference path distributions that fall between the 44-55 percentiles. This yields the flights that conform to the most normal mode of operation. Each of these flights is partitioned based on the percent complete from the entry point into the maneuvering areas from 0\% – 100\% complete. Then for each percent “bin”, we take the median value of the flight’s latitude/longitude coordinates, airspeed, and (non causal) time remaining to the airport to construct a lookup table for each percent complete bin on a given route. As a flight enters the maneuvering area, we can find the estimated arrival time of a flight to the airport by finding the closest point to the representative path’s percent complete bin (relative to the flight’s current position at any snapshot in the airspace) and therefore retrieve the corresponding remaining time left on the “representative path”. We assume that the flight will follow the representative path to completion when deriving these estimates. We can then compare these estimated arrival times against other flights for the same snapshot in time to identify potential conflicts. If more flights are estimated to arrive within a tolerance window than there are runways available, then we have a potential conflict. We can use this derived measure along with other factors expected to add disruption to the operation such as weather and runway configuration changes as an input to machine learning tools to detect precursors that increases in our complexity measure. This novel method will assist in uncovering insights into the contributing factors that lead to increased complexity that may allow for in-time responses to avoid reaching a high complexity state in the airspace.

complexity↗

Analysis of STS-134 Hail Event at Pad 39A, March 30, 2011

During the late afternoon of March 30, 2011 at approximately 21:25 - 21:30 GMT, hail monitor stations at Pad 39A recorded rice to pea size hail. The duration of the event was approximately 5 minutes. The maximum size detected by the three hail monitors was 10 - 12 mm. The 12 mm marble size value was measured by the active impact sensor at site #2, which experienced high winds. This 12 mm measurement may be artificially higher by one or two mm due to the extra hail kinetic energy resulting from the extreme horizontal winds. High winds from the west produced a few notable long streak-like dents in the hail pads. High winds were also responsible for damage to facilities near hail monitor site #2 on the west side of pad A (a dumpster was overturned, and a picnic table roof was demolished). NWS radar volume scan (see Figure I) showed 60-65 dBZ reflectivity values in the lowest 4 scan elevations around and over the pad 39A area. Since the lowest 0.5 degree scan showed a definite 65 dBZ signature, it is unlikely that hail had an opportunity to melt before reaching the ground. Some of the larger passive hail pad dents were shallower than what would be expected from solid frozen ice hydrometeor dents. Therefore, it is possible that the larger pea size hail may have been softer than the smaller rice size hail. This would be consistent with some melting before reaching the ground.

Lane, John E.↗

Measurement of atmospheric composition by the ATMOS instrument from Table Mountain Observatory

Following its first flight on board the Space Shuttle 'Challenger' as part of the Spacelab 3 payload, the Atmospheric Trace Molecule Spectroscopy (ATMOS) instrument has been operated at the Jet Propulsion Laboratory's Table Mountain Observatory (TMO; 34.4 deg N, 117.7 deg W, 2.23 km altitude) in the San Gabriel Mountains of Southern California. With the delay in the resumption of regular Shuttle flights, ATMOS has acquired a large number of high-quality, high-resolution infrared solar absorption spectra, spanning a period between late-1985 and mid-1990. These spectra are being analyzed to derive the column abundances of several atmospheric species including O3, HCl, HF, and HNO3. Although limited in temporal coverage, the preliminary results for these gases are discussed here in the context of the requirement and contribution to be made by similar instruments in detecting long term changes in stratospheric composition.

Gunson, Michael R.↗

Wilson Corners Solid Waste Management Unit (SWMU) 001: 2021 Annual Long-Term Monitoring Report, Kennedy Space Center, Florida

This report presents a summary of the long-term monitoring (LTM) activities that occurred in 2021 at Wilson Corners, Solid Waste Management Unit (SWMU) 001, at Kennedy Space Center (KSC), Florida. The site is monitored under KSC’s Resource Conservation and Recovery Act (RCRA) Corrective Action Program. Adaptive site management is being utilized through ongoing assessment, design, and interim measures (IM). Annual LTM of the groundwater is also being conducted at the site. This approach also meets the requirements of Chapter 62-780, Florida Administrative Code (F.A.C.). The goal of LTM at this site is threefold: to determine groundwater flow characteristics, monitor the downgradient concentration trends, and monitor select locations internal to the groundwater plume. Every 5 years, upgradient and side-gradient monitoring wells are sampled to verify delineation. The last time this was performed was in 2015. The sampling of these wells in 2020 was replaced with the direct push technology (DPT) investigations completed in October 2020 and April 2021. This DPT groundwater data was presented in an Advance Data Package (ADP) in September 2021 and discussed in the Implementation Work Plan (IWP) dated November 2021 for installation of an air sparge (AS) system. Based on results from groundwater sampling activities performed during the previous reporting period, including the 2020 and 2021 DPT groundwater sampling, it was determined that the LTM sampling plan was no longer meeting the goal of LTM because delineation was not verified. The 2021 LTM sampling plan was modified to include the sampling of monitoring wells located around the perimeter of the low concentration plume (LCP); the area with concentrations of contaminants of concern [COCs] greater than Groundwater Cleanup Target Levels [GCTLs]), and sampling of 10 monitoring wells proposed for installation (April 2021 KSC Remediation Team (KSCRT) Meeting, Decision 2104-D32). The modified LTM plan received team consensus at the September 2021 KSCRT Meeting (Decision Number 2109-D03), and sampling of the existing monitoring wells was completed in December 2021. The proposed monitoring wells are planned for installation in late 2022, concurrent with ongoing IM construction activities. December 2021 LTM data was presented at the May 2022 KSCRT Meeting, and activities are summarized in this report. The activities presented in this report include the December 2021 groundwater gauging of 42 monitoring wells and sampling of 44 monitoring wells. During the December 2021 event, the low flow sampling method was used, and samples were analyzed for a select list of volatile organic compounds (VOCs), including 1,1,2-trichloro-1,2,2-trifluoroethane (Freon 113). The following conclusions can be made based on the 2021 LTM results: - In December 2021, groundwater flow for the site was generally to the west at all intervals. This is generally consistent with historical observations at the site, with the exception of a southwest and southeast flow component observed at 34 to 48 feet below land surface (bls). - The vertical extent of VOCs was historically delineated by monitoring wells screened greater than 48 feet bls. The results from the two vertical extent monitoring wells, WILC-MW0078 (screened 65 to 70 feet bls) and WILC-MW0130 (screened 56 to 66 feet bls) that were sampled during the 2021 LTM indicate that groundwater vinyl chloride (VC) concentrations in both wells were greater than the GCTL. The Remediation Team has previously agreed to delay deeper DPT investigations in this area to prevent the creation of additional pathways for vertical migration. - The LCP continues to extend both horizontally, predominantly to the west, and vertically beyond the current monitoring well network, with some retraction observed to the southeast. Evaluation of this data combined with data from the 2020 and 2021 DPT sampling event indicate that the LCP encompasses an estimated 20.7 acres based on an expanded sampling area, as compared to the 2020 LCP footprint of 17.0 acres. - Freon 113 was not detected above GCTLs during the 2021 LTM event. Based on groundwater sampling activities performed in 2021, including April 2021 DPT groundwater sampling, the following recommendations are provided: - Perform the next LTM sampling event, targeted to occur in 2023, concurrently with the IM baseline sampling prior to AS system installation; - Include sampling from nine monitoring wells that are planned to be installed in late 2022, concurrent with upcoming IM construction activities. Installation of one deep vertical well, screened 70 to 80 feet bls, will be delayed to prevent the creation of an additional pathway for vertical migration; - Continue to sample under the modified annual LTM plan as presented in Table 4-1 concurrently with IM baseline sampling; and - Once the AS system install and start-up is complete, select monitoring wells from the LTM program will transition into the performance monitoring plan, and LTM will be temporarily discontinued. Performance monitoring will be performed quarterly, and the monitoring well network will be evaluated following the first performance monitoring sampling event.

long-term monitoring (LTM)↗

Differential absorption lidar systems for tropospheric and stratospheric ozone measurements

A lidar facility has been established at the Jet Propulsion Laboratory-Table Mountain Facility located at an altitude of 2300 m in the San Gabriel Mountains in Southern California. This facility is using the technique of differential absorption lidar to measure atmospheric ozone concentration profiles. Two separate systems are needed to obtain the profile from the ground up to an altitude of 45 to 50 km. An Nd:YAG-based system is described for measurements from the ground up to 15 to 20 km altitude, and an excimer-laser-based system for measurements from 15 km to 45 to 50 km altitude. The systems were designed to make high-precision, long-term measurements to aid in the detection of changes in the atmospheric ozone abundance through participation in the Network of Detection of Stratospheric Change.

Mcdermid, I. Stuart↗

Multi-Beam Laser Beacon Propagation Over Lunar Distance: Comparison of Predictions and Measurements

A multi-beam beacon was transmitted from the Optical Communication Telescope Laboratory (OCTL) located at Table Mountain, CA to the Lunar Laser Space Terminal (LLST), on-board the Lunar Atmospheric Dust and Environment Explorer (LADEE) spacecraft, during NASA’s recent Lunar Laser Communication Demonstration (LLCD). The laser beacon (1568?0.1 nm) was square wave modulated and sensed by a LLST quadrant sensor to enable link acquisition and tracking. LLST computed the mean received beacon power and returned 5 kHz sampled power time series over the downlink. Post-processing of the decoded downlink received at OCTL retrieved the uplink power recorded at LLST. The predicted mean irradiance delivered to LLST consistently agreed with the variable beam divergence transmitted from OCTL to within < 1 decibel (dB). Irradiance fluctuations detected at LLST were reconciled with an uplink wave-propagation model derived using independently monitored atmospheric parameters. We report good agreement of the scintillation index and atmospheric coherence time.

Biswas, A↗

A high capability raman lidar for upper troposhperic and lower stratospheric water vapor measurements

A new Water Vapor Raman lidar is being built at the Table Mountain Facility (TMF) of the Jet Propulsion Laboratory (JPL) in California (34.4N, 117.7W). The new system is designed to reach accuracies better than 5% anywhere up to 12 km altitude, and with the capability to measure water vapor mixing ratios as low as 1 ppm near the tropopause and in the lower stratosphere. The principal components of the proposed lidar, a high-energy Nd:YAG laser and a large telescope, are already available at TMF. The lidar receiver system, and data acquisition hardware and software are currently being implemented. The initial system in a non-optimized configuration already showed promising results, as water vapor lidar returns were clearly detected up to 20 km altitude. The initial configuration, and preliminary results are discussed in this short paper. The optimized configuration of the system, and the first calibrated water vapor profiles obtained from this optimized system will be shown at the conference.

Walsh, Daniel T.↗

Multi-Epoch XMM Observations of NGC4258

The goal of this project was detection of variability in the X-ray absorption column of the AGN in NGC4258 through monitoring with the XMM satellite. We have accomplished this goal and submitted the results to ApJ for publication in a paper entitled, "X-ray Luminosity and Absorption Column Fluctuations in the H2O Maser Galaxy NGC4258 from Weeks to Years," by Fruscione, A., Greenhill, L.J., Filippedco, A.V., Moran, J.M., Hermstein, J.R., and Galle, E. We have received a favorable referee report and expect the article will appear in 2005. To complete the project, we reduced our four epochs of XMM data for NGC4258, one archival XMM observation, and all existing Chandra datasets for NGC4258 (with the latest calibration tables and a grid of corrections for pileup). Self-consistent reduction of all these data permitted detailed comparison that could not have been accomplished simply by taking published model fits that appear in the literature. To accumulate a broader monitoring record, we combined the Chandra and XMM results with those published for SAX and ASCA. We modeled the Chandra and XMM data self-consistently with partially absorbed, hard power-law, soft thermal plasmas, and soft power-law components. Over nine years, the photo-electric absorbing column exhibited a 40% drop between two ASCA epochs separated by 3 years and a 60% rise between two XMM epochs separated by just 5 months. In contract, uncorrelated factor of of 2-3 changes were seen in absorbed flux on te timescale of years, which suggests intrinsic variability of the central engine. The warped disk that is a known source of H2O maser emission in 4258 is believed to cross the line of sight to the central engine. We have proposed that the variations in absorbing column arise from inhomogeneities in the rotating disk, as they sweep across the line of sight. We estimate from the XMM data that the inhomogeneities are about 1E+15 cm in size at radii greater than 0.27 pc. This is consistent with the estimated radius of the disk crossing estimated entirely independently, and it solidifies evidence that the warped accretion disk is the absorber in this (and possible other) AGN.

Greenhill, Lincoln J.↗