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NASA NTRS1992

External calibration of polarimetric radar images using distributed targets

A new technique is presented for calibrating polarimetric synthetic aperture radar (SAR) images using only the responses from natural distributed targets. The model for polarimetric radars is assumed to be X = cRST where X is the measured scattering matrix corresponding to the target scattering matrix S distorted by the system matrices T and R (in general T does not equal R(sup t)). To allow for the polarimetric calibration using only distributed targets and corner reflectors, van Zyl assumed a reciprocal polarimetric radar model with T = R(sup t); when applied for JPL SAR data, a heuristic symmetrization procedure is used by POLCAL to compensate the phase difference between the measured HV and VH responses and then take the average of both. This heuristic approach causes some non-removable cross-polarization responses for corner reflectors, which can be avoided by a rigorous symmetrization method based on reciprocity. After the radar is made reciprocal, a new algorithm based on the responses from distributed targets with reflection symmetry is developed to estimate the cross-talk parameters. The new algorithm never experiences problems in convergence and is also found to converge faster than the existing routines implemented for POLCAL. When the new technique is implemented for the JPL polarimetric data, symmetrization and cross-talk removal are performed on a line-by-line (azimuth) basis. After the cross-talks are removed from the entire image, phase and amplitude calibrations are carried out by selecting distributed targets either with azimuthal symmetry along the looking direction or with some well-known volume and surface scattering mechanisms to estimate the relative phases and amplitude responses of the horizontal and vertical channels.

Yueh, Simon H.↗

NASA NTRS1993

Advances in spaceborne radar remote sensing

Radar sensors are being more commonly used for spaceborne sensing of Earth and Planetary surfaces and atmosphere. This is a result of advances in: better understanding wave/natural surface interaction mechanisms, measurement techniques, hardware development and data handling/visualization. A number of spaceborne radar systems are presently operational or will be launched in the next few years. In addition airborne instruments utilizing multispectral, polarmetric and interferometric capabilities are opening new vistas which will lead to major advances in radar sensing by the end of the decade. This paper is a review of recent developments and expected future advances.

Elachi, C.↗

NASA NTRS1995

Interstellar Alcohols

We have investigated the gas-phase chemistry in dense cores where ice mantles containing ethanol and other alcohols have been evaporated. Model calculations show that methanol, ethanol, propanol, and butanol drive a chemistry leading to the formation of several large ethers and esters. Of these molecules, methyl ethyl ether (CH3OC2H5) and diethyl ether (C2H5)2O attain the highest abundances and should be present in detectable quantities within cores rich in ethanol and methanol. Gas-phase reactions act to destroy evaporated ethanol and a low observed abundance of gas-phase C,H,OH does not rule out a high solid-phase abundance. Grain surface formation mechanisms and other possible gas-phase reactions driven by alcohols are discussed, as are observing strategies for the detection of these large interstellar molecules.

Charnley, S. B.↗

NASA NTRS1996

Quantum Mechanical Determination of Potential Energy Surfaces for TiO and H2O

We discuss current ab initio methods for determining potential energy surfaces, in relation to the TiO and H2O molecules, both of which make important contributions to the opacity of oxygen-rich stars. For the TiO molecule we discuss the determination of the radiative lifetimes of the excited states and band oscillator strengths for both the triplet and singlet band systems. While the theoretical radiative lifetimes for TiO agree well with recent measurements, the band oscillator strengths differ significantly from those currently employed in opacity calculations. For the H2O molecule we discuss the current results for the potential energy and dipole moment ground state surfaces generated at NASA Ames. We show that it is necessary to account for such effects as core-valence Correlation energy to generate a PES of near spectroscopic accuracy. We also describe how we solve the ro-vibrational problem to obtain the line positions and intensities that are needed for opacity sampling.

Langhoff, Stephen R.↗

NASA NTRS2001

Soot Surface Growth in Laminar Hydrocarbon/Air Diffusion Flames

The structure and soot surface growth properties of round laminar jet diffusion flames were studied experimentally. Measurements were made along the axes of ethylene-, propylene-propane- and acetylene-benzene-fueled flames burning in coflowing air at atmospheric pressure with the reactants at normal temperature. The measurements included soot structure, soot concentrations, soot temperatures, major gas species concentrations, some radial species (H, OH and O) concentrations, and gas velocities. These measurements yielded the local flame properties that are thought to affect soot surface growth as well as local soot surface growth rates. When present results were combined with similar earlier observations of acetylene-fueled laminar jet diffusion flames, the results suggested that soot surface growth involved decomposition of the original fuel to form acetylene and H, which were the main reactants for soot surface growth, and that the main effect of the parent fuel on soot surface growth involved its yield of acetylene and H for present test conditions. Thus, as the distance increased along the axes of the flames, soot formation (which was dominated by soot surface growth) began near the cool core of the flow once acetylene and H appeared together and ended near the flame sheet when acetylene disappeared. Species mainly responsible for soot oxidation - OH and O2 were present throughout the soot formation region so that soot surface growth and oxidation proceeded at the same time. Present measurements of soot surface growth rates (corrected for soot surface oxidation) in laminar jet diffusion flames were consistent with earlier measurements of soot surface growth rates in laminar premixed flames and exhibited good agreement with existing Hydrogen-Abstraction/Carbon-Addition (HACA) soot surface growth mechanisms in the literature with steric factors in these mechanisms having values on the order of unity, as anticipated.

El-Leathy, A. M.↗

NASA NTRS2003

Soot Surface Growth in Laminar Hydrocarbon/Air Diffusion Flames

The structure and soot surface growth properties of round laminar jet diffusion flames were studied experimentally. Measurements were made along the axes of ethylene-, propylene-propane- and acetylene-benzene-fueled flames burning in coflowing air at atmospheric pressure with the reactants at normal temperature. The measurements included soot structure, soot concentrations, soot temperatures, major gas species concentrations, some radial species (H, OH and 0) concentrations, and gas velocities. These measurements yielded the local flame properties that are thought to affect soot surface growth as well as local soot surface growth rates. When present results were combined with similar earlier observations of acetylene-fueled laminar jet diffusion flames, the results suggested that soot surface growth involved decomposition of the original fuel to form acetylene and H, which were the main reactants for soot surface growth, and that the main effect of the parent fuel on soot surface growth involved its yield of acetylene and H for present test conditions. Thus, as the distance increased along the axes of the flames, soot formation (which was dominated by soot surface growth) began near the cool core of the flow once acetylene and H appeared together and ended near the flame sheet when acetylene disappeared. Species mainly responsible for soot oxidation - OH and 02 were present throughout the soot formation region so that soot surface growth and oxidation proceeded at the same time. Present measurements of soot surface growth rates (corrected for soot surface oxidation) in laminar jet diffusion flames were consistent with earlier measurements of soot surface growth rates in laminar premixed flames and exhibited good agreement with existing Hydrogen-Abstraction/Carbon-Addition (HACA) soot surface growth mechanisms in the literature with steric factors in these mechanisms having values on the order of unity, as anticipated.

El-Leathy, A. M.↗

NASA NTRS2006

A 'Super Bowl' Approach to Mars Rover Touchdown Loads Analysis

Touchdown Driving Requirement: The mechanical system surface element shall be capable of facilitating a safe, stable landing at terrain angles up to 15 degrees, given an initial vertical velocity of 1 m/sec, horizontal velocity of 0.5 m/sec, and Z-axis spin rate of [4] deg/sec.Touchdown Loads Development: A multi-year development effort has been successfully conducted leading to an innovative analytical methodology for the prediction of rover touchdown design loads and the assessment of rover touchdown stability.

landing↗

NASA NTRS2014

Novel Super-Elastic Materials for Advanced Bearing Applications

Tribological surfaces of mechanical components encounter harsh conditions in terrestrial, marine and aerospace environments. Brinell denting, abrasive wear and fatigue often lead to life-limiting bearing and gear failures. Novel superelastic materials based upon Ni-Ti alloys are an emerging solution. Ni-Ti alloys are intermetallic materials that possess characteristics of both metals and ceramics. Ni-Ti alloys have intrinsically good aqueous corrosion resistance (they cannot rust), high hardness, relatively low elastic modulus, are chemically inert and readily lubricated. Ni-Ti alloys also belong to the family of superelastics and, despite high hardness, are able to withstand large strains without suffering permanent plastic deformation. In this paper, the use of hard, resilient Ni-Ti alloys for corrosion-proof, shockproof bearing and gear applications are presented. Through a series of bearing and gear development projects, it is demonstrated that Ni-Tis unique blend of materials properties lead to significantly improved load capacity, reduced weight and intrinsic corrosion resistance not found in any other bearing materials. Ni-Ti thus represents a new materials solution to demanding tribological applications.

materials↗

NASA NTRS2014

Thermophysical Property Variations Across Dione and Rhea

Maps of the variation in bolometric Bond albedo and thermal inertia across Rhea and Dione have been produced using various day and nighttime observations, taken by Cassini's Composite Infrared Spectrometer (CIRS). The albedo maps show the same trend that has been previously observed on these satellites from reflected sunlight and thermal observations: a higher albedo on their leading hemispheres. The thermal inertia maps show two previously unknown anomalous high thermal inertia regions: low latitudes on Dione's leading hemisphere and the bright ejecta blanket of Rhea's Inktomi crater. The thermal inertia on Dione increases modestly from a background value of 8 J m(exp -2) K(exp -1) s(exp -1/2) to 11 J m(exp -)2 K(exp -1) s(exp -1/2) in a region preferentially bombarded by high-energy electrons. We believe that this region on Dione is probably analogous to the thermally anomalous regions recently discovered at equivalent locations on Mimas and Tethys, dubbed Pac-Man features. The smaller magnitude of Dione's thermal anomaly, compared to that of Mimas and Tethys, provides additional evidence that surface alteration by high-energy electrons produces these anomalies, as the high-energy electron flux decreases with increasing distance from Saturn. However, unlike on Mimas and Tethys, the thermally anomalous region on Dione does not display a spatially correlated decrease in the IR/UV (0.930 micrometers/0.338 micrometers) color ratio, implying that the minimum electron energy threshold of the IR/UV ice surface darkening mechanism is not met on Dione. The average of the mapped bolometric Bond albedos on the leading and trailing hemispheres of Dione are 0.49 +/- 0.11 and 0.44 +/- 0.13 respectively. On Rhea the thermal inertia increases from a background value of 10 J m(exp -2) K (exp -1) s(exp -1/2) to 19 J m(exp -2) K(exp -1) s(exp -1/2) on the ejecta blanket of Inktomi crater, probably due to a mixture of high and low thermal inertia material in this region, such as a fine- and large-grain ice mixture. This is the first time a thermal inertia anomaly has been associated with an impact crater on an icy saturnian satellite. On Rhea the average of the mapped bolometric Bond albedos on the leading and trailing hemispheres are 0.59 +/- 0.11 and 0.56 +/- 0.13 respectively.

Saturn↗

NASA NTRS2015

Synthesis and Properties of Cross-Linked Polyamide Aerogels

We report the first synthesis of cross-linked polyamide aerogels through step growth polymerization using a combination of diamines, diacid chloride and triacid chloride. Polyamide oligomers endcapped with amines are prepared as stable solutions in N-methylpyrrolidinone from several different diamine precursors and 1,3-benzenedicarbonyl dichloride. Addition of 1,3,5-benzenetricarbonyl trichloride yields gels which form in under five minutes according to the scheme shown. Solvent exchange of the gels into ethanol, followed by drying using supercritical CO2 extraction gives colorless aerogels with densities around 0.1 to 0.2 gcm3. Thicker monolithes of the polyamide aerogels are stiff and strong, while thin films of certain formulations are highly flexible, durable, and even translucent. These materials may have use as insulation for deployable space structures, rovers, habitats or extravehicular activity suits as well as in many terrestrial applications. Strucure property relationships of the aerogels, including surface area, mechanical properties, and thermal conductivity will be discussed.

Aerogel↗

NASA NTRS2016

Diverse Eruptions at Approximately 2,200 Years B.P. on the Great Rift, Idaho: Inferences for Magma Dynamics Along Volcanic Rift Zones

Compositionally and morphologically diverse lava flows erupted on the Great Rift of Idaho approximately 2.2 ka (kilo-annum, 1000 years ago) during a volcanic "flare-up" of activity following an approximately 2 ky (kiloyear, 1000 years) hiatus in eruptions. Volcanism at Craters of the Moon (COTM), Wapi and Kings Bowl lava fields around this time included primitive and evolved compositions, separated over 75 kilometers along the approximately 85 kilometers-long rift, with striking variability in lava flow emplacement mechanisms and surface morphologies. Although the temporal associations may be coincidental, the system provides a planetary analog to better understand magma dynamics along rift systems, including that associated with lunar floor-fractured craters. This study aims to help bridge the knowledge gap between ancient rift volcanism evident on the Moon and other terrestrial planets, and active rift volcanism, e.g., at Hawai'i and Iceland.

RIFT ZONEs↗

NASA NTRS2018

Maps of Tethys' Thermophysical Properties

On 11th April 2015 Cassini's Composite Infrared Spectrometer (CIRS) made a series of observations of Tethys’ daytime anti-Saturn hemisphere over a nine-hour time period. During this time the sub-spacecraft position was remarkably stable (0.3° S to 3.9° S; 153.2° W to 221.8° W), and so these observations provide unprecedented coverage of diurnal temperature variations on Tethys’ anti-Saturn hemisphere. In 2012 a thermal anomaly was discovered at low latitudes on Tethys’ leading hemisphere; it appears cooler during the day and warmer at night than its surroundings (Howett et al., 2012) and is spatially correlated with a decrease in the IR3/UV3 visible color ratio (Schenk et al., 2011). The cause of this anomaly is believed to be surface alteration by high-energy electrons, which preferentially bombard low-latitudes of Tethys’ leading hemisphere (Schenk et al., 2011; Howett et al., 2012; Paranicas et al. 2014; Schaible et al., 2017). The thermal anomaly was quickly dubbed “Pac-Man” due to its resemblance to the 1980s video game icon. We use these daytime 2015 CIRS data, along with two sets of nighttime CIRS observations of Tethys (from 27 June 2007 and 17 August 2015) to make maps of bolometric Bond albedo and thermal inertia variations across the anti-Saturn hemisphere of Tethys (including the edge of its Pac-Man region). These maps confirm the presence of the Pac-Man thermal anomaly and show that while Tethys’ bolometric Bond albedo varies negligibly outside and inside the anomaly (0.69 plus or minus 0.02 inside, compared to 0.71 plus or minus 0.04 outside) the thermal inertia varies dramatically (29 plus or minus 10 J m−2 K−1 s−1/2 inside, compared to 9 plus or minus 4 J m−2 K−1 s−1/2 outside). These thermal inertias are in keeping with previously published values: 25 plus or minus 3 J m−2 K−1 s−1/2 inside, and 5 ± 1 J m−2 K−1 s−1/2 outside the anomaly (Howett et al., 2012). A detailed analysis shows that on smaller spatial-scales the bolometric Bond albedo does vary: increasing to a peak value at 180° W. For longitudes between approximately 100° W and approximately 160° W the thermal inertia increases from northern to southern latitudes, while the reverse is true for bolometric Bond albedo. The thermal inertia on Tethys generally increases towards the center of its leading hemisphere but also displays other notable small-scale variations. These thermal inertia and bolometric Bond albedo variations are perhaps due to differences in competing surface modification by E ring grains and high-energy electrons which both bombard Tethys’ leading hemisphere (but in different ways). A comparison between the observed temperatures and our best thermal model fits shows notable discrepancies in the morning warming curve, which may provide evidence of regional variations in surface roughness effects, perhaps again due to variations in surface alteration mechanisms.

Howett, C. J. A.↗

NASA NTRS2016

Comparison of Quantum Mechanical and Empirical Potential Energy Surfaces and Computed Rate Coefficients for N2 Dissociation

Comparisons are made between potential energy surfaces (PES) for N2 + N and N2 + N2 collisions and between rate coefficients for N2 dissociation that were computed using the quasiclassical trajectory method (QCT) on these PESs. For N2 + N we compare the Laganas empirical LEPS surface with one from NASA Ames Research Center based on ab initio quantum chemistry calculations. For N2 + N2 we compare two ab initio PESs (from NASA Ames and from the University of Minnesota). These use different methods for computing the ground state electronic energy for N4, but give similar results. Thermal N2 dissociation rate coefficients, for the 10,000K-30,000K temperature range, have been computed using each PES and the results are in excellent agreement. Quasi-stationary state (QSS) rate coefficients using both PESs have been computed at these temperatures using the Direct Molecular Simulation of Schwartentruber and coworkers. The QSS rate coefficients are up to a factor of 5 lower than the thermal ones and the thermal and QSS values bracket the results of shock-tube experiments. We conclude that the combination of ab initio quantum chemistry PESs and QCT calculations provides an attractive approach for the determination of accurate high-temperature rate coefficients for use in aerothermodynamics modeling.

quasiclassical trajectory method↗

NASA NTRSDate not supplied

Computational Approaches for Li-O2 Battery Design

Threshold energy densities for general aviation electric aircraft are 400 Wh/kg with more ambitious air vehicles having significantly higher requirements. Li-O2 batteries, with the highest theoretical capacity, are one of the few “beyond Li-ion” chemistries that might satisfy the extraordinary specific capacity as well as specific power requirements of electric aircraft. However, side reactions at interfaces, in particular at the cathode, over the charge-discharge cycles result in very short cycle-life and dramatic reduction of capacity. Addressing these issues, in addition to others, are crucial for realizing practical, high performance Li-O2 batteries. In this talk, we discuss atomistic computational work to understand and mitigate some of the issues, including those at interfaces, that affect the Li-O2 electrochemistry. To start, we discuss the deposition mechanisms, both surface and solution based, of Li2O2 and their dependence on external potential. Next, we explore molten salt electrolytes as a stable alternative to organic electrolytes and approaches taken to develop new practical molten salt eutectic mixtures. Finally, we address the issue of reactive carbon-cathodes and possible cathode-candidates that were identified throughput high-throughput computations.

Li-Air battery↗

NASA NTRSDate not supplied

Material Response Modeling of Ablative Thermal Protection Systems using PATO

Developing thermal protection systems (TPS) for future space vehicles involves an extensive design and test cycle. A key component of the cycle is determining margins for a safe design that rely on confidence in the performance of the TPS. Predicting the complicated multiphysics phenomena that occur during atmospheric entry requires high-fidelity modeling tools. To this end, the Porous-material Analysis Toolbox based on OpenFOAM (PATO) has been developed. PATO is an open-source software for computing material response of reactive porous materials submitted to high-temperature environments. Recent applications of PATO include computation of the full heatshield 3D material response from the Mars Science Laboratory atmospheric entry and ablation during arc jet testing. Current efforts are underway to loosely couple PATO with other discipline specialized codes including hypersonic computational fluid dynamics (CFD) to assess the effects of pyrolysis-gas blowing into the boundary layer and computational solid mechanics to address modeling of mechanical erosion. Surface phenomena modeling capabilities to address the effects of silicone-based coatings applied to the TPS during flight preparation are also being added.

Thermal Protection Systems↗

NASA NTRSDate not supplied

Material Response Modeling of Ablative Thermal Protection Systems using PATO

Thermal Protection Systems↗

NASA NTRSDate not supplied

Active Region Simulation with EBTEL

Active regions (ARs) are areas in the sun’s upper atmosphere that are bright in the extreme ultraviolet (EUV) and X-ray spectrum. Coronal loops are one key feature of an AR. They can be described as arcs of plasma resulting from loop-shaped magnetic fields on the sun. The average temperature of these loops is over one million kelvin, which is significantly hotter than the sun’s surface. The mechanism for the heat transfer of these high temperatures remains unknown and is referred to as the coronal heating problem. One leading hypothesis regarding this mystery is that small, impulsive heating events called nanoflares are a major contributor. Here, we explore the contribution of nanoflares in the heating of AR plasma. We utilize the Enthalpy-Based Thermal Evolution of Loops (EBTEL) program to simulate NOAA 12846, as observed on July 25, 2021. We then use that simulation to analyze how the frequency of nanoflare heating events affects the EUV and X-ray observations in existing instruments, including SDO’s AIA and Hinode’s XRT. We also predict how this AR would appear in recently developed X-ray instruments, such as NASA’s MaGIXS.

Active region↗

NASA NTRS1995

High pressure mechanical seal

A relatively impervious mechanical seal is formed between the outer surface of a tube and the inside surface of a mechanical fitting of a high pressure fluid or hydraulic system by applying a very thin soft metal layer onto the outer surface of the hard metal tube and/or inner surface of the hard metal fitting, prior to swaging the fitting onto the tube. The thickness of such thin metal layer is independent of the size of the tube and/or fittings. Many metals and alloys of those metals exhibit the requisite softness, including silver, gold, nickel, tin, platinum, indium, rhodium and cadmium. Suitably, the coating is about 0.0025 millimeters (0.10 mils) in thickness. After swaging, the tube and fitting combination exhibits very low leak rates on the order or 10.sup.-8 cubic centimeters per second or less as meaured using the Helium leak test.

Babel, Henry W.↗