Engineering Papers⌕ Search

SEARCH · Engineering Papers

Results for “sublimation”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 235 records · Page 13

Study of Aerothermodynamic Modeling Issues Relevant to High-Speed Sample Return Vehicles

This paper examines the application of state-of-the-art coupled ablation and radiation simulations to highspeed sample return vehicles, such as those returning from Mars or an asteroid. A defining characteristic of these entries is that the surface recession rates and temperatures are driven by nonequilibrium convective and radiative heating through a boundary layer with significant surface blowing and ablation products. Measurements relevant to validating the simulation of these phenomena are reviewed and the Stardust entry is identified as providing the best relevant measurements. A coupled ablation and radiation flowfield analysis is presented that implements a finite-rate surface chemistry model. Comparisons between this finite-rate model and a equilibrium ablation model show that, while good agreement is seen for diffusion-limited oxidation cases, the finite-rate model predicts up to 50% lower char rates than the equilibrium model at sublimation conditions. Both the equilibrium and finite rate models predict significant negative mass flux at the surface due to sublimation of atomic carbon. A sensitivity analysis to flowfield and surface chemistry rates show that, for a sample return capsule at 10, 12, and 14 km/s, the sublimation rates for C and C3 provide the largest changes to the convective flux, radiative flux, and char rate. A parametric uncertainty analysis of the radiative heating due to radiation modeling parameters indicates uncertainties ranging from 27% at 10 km/s to 36% at 14 km/s. Applying the developed coupled analysis to the Stardust entry results in temperatures within 10% of those inferred from observations, and final recession values within 20% of measurements, which improves upon the 60% over-prediction at the stagnation point obtained through an uncoupled analysis. Emission from CN Violet is shown to be over-predicted by nearly and order-of-magnitude, which is consistent with the results of previous independent analyses. Finally, the coupled analysis is applied to a 14 km/s Earth entry representative of a Mars sample return. Although the radiative heating provides a larger fraction of the total heating, the influence of ablation and radiation on the flowfield are shown to be similar to Stardust.

Johnston, Christopher O.↗

Development of Naphthalene PLIF for Visualizing Ablation Products From a Space Capsule Heat Shield

The Orion Multi-Purpose Crew Vehicle (MPCV) will use an ablative heat shield. To better design this heat shield and others that will undergo planetary entry, an improved understanding of the ablation process would be beneficial. Here, a technique developed at The University of Texas at Austin that uses planar laser-induced fluorescence (PLIF) of a low-temperature sublimating ablator (naphthalene) to enable visualization of the ablation products in a hypersonic flow is applied. Although high-temperature ablation is difficult and expensive to recreate in a laboratory environment, low-temperature sublimation creates a limited physics problem that can be used to explore ablation-product transport in a hypersonic flow-field. In the current work, a subscale capsule reentry vehicle model with a solid naphthalene heat shield has been tested in a Mach 5 wind tunnel. The PLIF technique provides images of the spatial distribution of sublimated naphthalene in the heat-shield boundary layer, separated shear layer, and backshell recirculation region. Visualizations of the capsule shear layer using both naphthalene PLIF and Schlieren imaging compared favorably. PLIF images have shown high concentrations of naphthalene in the capsule separated flow region, intermittent turbulent structures on the heat shield surface, and interesting details of the capsule shear layer structure. It was shown that, in general, the capsule shear layer appears to be more unsteady at lower angels of attack. The PLIF images demonstrated that during a wind tunnel run, as the model heated up, the rate of naphthalene ablation increased, since the PLIF signal increased steadily over the course of a run. Additionally, the shear layer became increasingly unsteady over the course of a wind tunnel run, likely because of increased surface roughness but also possibly because of the increased blowing. Regions with a relatively low concentration of naphthalene were also identified in the capsule backshell recirculation region and are most likely the result of cross-flow-induced vortices on the capsule afterbody.

Combs, C. S.↗

Iodine Propellant Feed System Flow Modeling

The use of solid iodine as a propellant in Hall-effect thrusters (HETs) is currently being investigated for small-satellite applications. CubeSats offer an inexpensive mode of access to space; however, they currently lack significant propulsion capability. A high specific impulse (I (sub sp)) propulsion system would permit a significant change in velocity, delta v, to be imparted for orbital maintenance, transfers, or de-orbit maneuvers. An electric propulsion system that uses iodine as a propellant has a number of advantages. It has an exceptionally high rho times I (sub sp) figure of merit (density multiplied by the specific impulse), meaning that it can achieve a large total delta v with a relatively low combination of propellant mass and propellant tank volume. Also, the propellant feed system operates at low pressures (a few psia at most), as opposed to the use of super-critical xenon stored at very high pressure. Low pressure operation can lower system mass while greatly reducing the risk of propellant tank rupture, making low pressure a vitally important property for propellants on secondary payloads like CubeSats, where risks must be minimized. The iSAT mission aims to demonstrate iodine-fed HET technology, flying it in space onboard a 12U 912-unit) CubeSat. In the iSAT propellant feed system (PFS), solid iodine is sublimed through heating to produce gaseous propellant that is conducted through tubing to the thruster and cathode. The sublimation process is governed by the iodine (I2) vapor pressure, which is shown as a function of temperature in figure 1. As gaseous I2 flows out of the tank, the gas pressure in the volume containing the solid iodine propellant is reduced until a balance between the flow of iodine out of the tank and the sublimation rate of solid iodine at the equilibrium gas pressure and chosen tank temperature is reached.

Martin, A. K.↗

Chemical regeneration of emitter surface increases thermionic diode life

Chemical regeneration of sublimated emitter electrode increases the operating efficiency and life of thermionic diodes. A gas which forms chemical compounds with the sublimated emitter material is introduced into the space between the emitter and the collector. The compounds migrate to the emitter where they decompose and redeposit the emitter material.

Breiteieser, R.↗

Fire retardancy using applied materials

An example of advanced technology transfer from the Little Joe, Surveyor, Comsat, re-entry and Apollo age to everyday fire protection needs is presented. Utilizing the principle of sublimation cooling for thermostatic temperature control, the material meets a wide range of fire retardancy and heat transmission control requirements. Properties vary from flexible tape for conduits and electrical cables to rigid coatings for column protection, with a broad spectrum of sublimation temperatures available. The material can be applied in the field or in the factory, utilizing mass production techniques, yielding a product that is reliable, effective, widely available and low in cost.

Feldman, R.↗

Adavanced RTG and thermoelectric materials study

A comprehensive, generalized two-dimensional RTG analysis computer program was developed. This program is capable of analyzing any specified RTG design under a wide range of transient as well as steady-state operating conditions. The feasibility of a new concept for the design of segmented (or single-phase) thermoelectric couples was demonstrated. A SiGe-PbTe segmented couple involving pressure contacted junctions at the intermediate- and hot-junction temperatures was successfully encapsulated in a hermetically sealed bellows enclosure. This bellows-encapsulated couple was operated between a hot- and cold-junction temperature of 1200 K and 450 K, respectively, with a measured energy conversion efficiency of 7.6 + or - .5 per cent. An experimental study of selected sublimation barrier schemes revealed that a significant reduction in the sublimation rate of p-type PbTe could be achieved by using multiple layers of SiO2 fibers. A comparison of the barrier effectiveness is given for three different barrier designs.

Eggers, P. E.↗

Technical, analytical and computer support

The development of a rigorous mathematical model for the design and performance analysis of cylindrical silicon-germanium thermoelectric generators is reported that consists of two parts, a steady-state (static) and a transient (dynamic) part. The material study task involves the definition and implementation of a material study that aims to experimentally characterize the long term behavior of the thermoelectric properties of silicon-germanium alloys as a function of temperature. Analytical and experimental efforts are aimed at the determination of the sublimation characteristics of silicon germanium alloys and the study of sublimation effects on RTG performance. Studies are also performed on a variety of specific topics on thermoelectric energy conversion.

Source record↗

Shuttle active thermal control system development testing. Volume 6: Water ejector plume tests

Results are given of vacuum testing of nozzles designed to eject water vapor away from the space shuttle to prevent contamination of the spacecraft surfaces and payload. The water vapor is generated by an active cooling system which evaporates excess fuel cell water to supplement a modular radiator system (MRS). The complete heat rejection system including the MRS, flash evaporator or sublimator and nozzle were first tested to demonstrate the system operational characteristics. The plume tests were performed in two phases and the objectives of this test series were: (1) to determine the effectiveness of a supersonic nozzle and a plugged nozzle in minimizing impingement upon the spacecraft of water vapor exhausted by an active device (flash evaporator or sublimator); and (2) to obtain basic data on the flow fields of exhaust plumes generated by these active devices, both with and without nozzles installed.

Mcginnis, F. K.↗

Ablative overlays for Space Shuttle leading edge ascent heat protection

Ablative overlays were evaluated via a plasma-arc simulation of the ascent pulse on the leading edge of the Space Shuttle Orbiter. Overlay concepts included corkboard, polyisocyanurate foam, low-density Teflon, epoxy, and subliming salts. Their densities ranged from 4.9 to 81 lb per cu ft, and the thicknesses varied from 0.107 to 0.330 in. Swept-leading-edge models were fabricated from 30-lb per cu ft silicone-based ablators. The overlays were bonded to maintain the surface temperature of the base ablator below 500 F during ascent. Foams provided minimum-weight overlays, and subliming salts provided minimum-thickness overlays. Teflon left the most uniform surface after ascent heating.

Strauss, E. L.↗

Explosive and pyrotechnic aging demonstration

The survivability was experimentally verified of fine selected explosive and pyrotechnic propellant materials when subjected to sterilization, and prolonged exposure to space environments. This verification included thermal characterization, sterilization heat cycling, sublimation measurements, isothermal decomposition measurements, and accelerated aging at a preselected elevated temperature. Temperatures chosen for sublimation and isothermal decomposition measurements were those in which the decomposition processess occurring would be the same as those taking place in real-time aging. The elevated temperature selected (84 C) for accelerated aging was based upon the parameters calculated from the kinetic data obtained in the isothermal measurement tests and was such that one month of accelerated aging in the laboratory approximated one year of real-time aging at 66 C. Results indicate that HNS-IIA, pure PbN6, KDNBF, and Zr/KC10 are capable of withstanding sterilization. The accelerated aging tests indicated that unsterilized HNS-IIA and Zr/KC104 can withstand the 10 year, elevated temperature exposure, pure PbN6 and KDNBF exhibit small weight losses (less than 2 percent) and B/KC104 exhibits significant changes in its thermal characteristics. Accelerated aging tests after sterilization indicated that only HNS-IIA exhibited high stability.

Rouch, L. L., Jr.↗

Ice in space: An experimental and theoretical investigation

The thermodynamics of water ice formation was experimentally investigated under a wide variety of conditions, including those of outer space. This information, and in particular, the lifetime of ice particles as a function of solar distance is an absolute requirement for proper interpretation of photometric profiles of comets. The sublimation of ice particles in a nonequilibrium situation was studied. An oscillating fiber microbalance was used to measure the sublimation rate of water droplets (which were suspended on a long quartz fiber which was oscillating in a vacuum chamber). The influence of particle size, surface temperature, and the index refraction from simulated solar radiation were studied in relation to ice formation. Also examined was the influence of impurities (clathrates) on ice formation. Windows in the vacuum chamber allowed the ice particles to be exposed to a 1 kilowatt xenon arc lamp which was used to simulate solar radiation. Ice is proposed as a possible energy source for comets, as amorphous water ice and ammonia in low temperature and pressure environments demonstrated a clear energy release upon warming. Motion pictures of ice formation were taken and photographs are shown.

Patashnick, H.↗

Tubular sublimatory evaporator heat sink

An evaporative refrigerator or cooler comprising a bundle of spaced, porous walled tubes closed at one of their ends and vented to a vacuum at the other end is disclosed. The tube bundle is surrounded by a water jacket having a hot water inlet distribution manifold and a cooled water outlet through a plenum chamber. Hot water is pumped into the jacket to circulate around the tubes, and when this water meets the vacuum existing inside the tubes, it evaporates thereby cooling the water in the jacket. If cooling proceeds to the point where water penetrating or surrounding all or part of the tubes freezes, operation continues with local sublimation of the ice on the tubes while the circulating water attempts to melt the ice. Both sublimation and evaporation may take place simultaneously in different regions of the device.

Webbon, B. W.↗

Analysis of the thermal reaction products of para polyphenylene by combined gas chromatography-mass spectrometry

Analysis of the volatiles and sublimate produced when para-polyphenylene is pyrolyzed to constant weight under vacuum in the temperature range from 380 to 1000 C indicates that the polymer undergoes thermal degradation in two stages. The first stage involved dehydrohalogenation, which is essentially a curing reaction that produces crosslinking between polyphenylene chains resulting from the loss of chlorine from the polymer in the form of hydrogen chloride. The second stage of the thermal degradation is dehydrogenation because hydrogen is the major volatile species. Increasing amounts of polycyclic aromatic hydrocarbons (phenanthrene and 9, 10 benzphenanthrene) in the sublimate, concomitant with increasing C/H ratios of the polymeric residue with pyrolysis temperature, is consistent with the buildup of polynuclear structures in the polymer matrix.

Fewell, L. L.↗

Erosion of Galilean satellite surfaces by Jovian magnetosphere particles

The effects on the surfaces of the Galilean satellites Europa, Ganymede and Callisto of impacts by particles of the Jupiter magnetosphere in which they are immersed are estimated. Differential ion fluxes measured by the Voyager low-energy magnetosphere particle analyzer as a function of ion energy were used to calculate ice erosion fluxes for the satellites under the assumption that each is 50% ice covered. Calculations were performed on the basis of laboratory data concerning the ice sputtering coefficients of protons and oxygen ions of various energies. A water erosion rate of greater than 10 to the 10th/sq cm per sec is obtained for Europa, which implies a total erosion over 1 billion years of an ice layer 100 m deep. Atmospheric column densities of the H2O molecules sputtered from the surface but not escaping the satellites are also calculated for the three satellites assuming a sputtered ion temperature of 2000 K, and are found to dominate those produced by sublimation. Finally, estimates are presented of the source and loss processes for an oxygen atmosphere around Ganymede created by sputtering or sublimation.

Johnson, R. E.↗

Pluto's atmospheric bulk near perihelion

The detection of CH4 frost on Pluto's surface implies a significant atmosphere for Pluto. Although Pluto's mass is small, about 7% of Triton's mass, the rapid escape ('blowoff') of gaseous CH4 can be prevented by the presence of a heavy gas mixed with the CH4. The resulting slow escape ('Jeans escape') of CH4 can be accommodated by sublimation of the surface CH4 frost so that an atmosphere exists in the steady state. A heavier gas must exist, otherwise the CH4 frost would have sublimated away long ago because of solar heat and rapid blowoff of gaseous CH4. Pluto is currently near perihelion where the CH4 component of the atmosphere may be 500 times denser than at apehelion. Significant seasonal changes in the atmospheric bulk are therefore possible.

Trafton, L.↗

On observing comets for nuclear rotation

The prevalent non-gravitational motions among comets demonstrate that the sublimination does not reach a maximum at the instant of maximum insolation on the nucleus. The occurrence of halos or "parabolic" envelopes in the comae of some comets and of jets, rays, fans, streamers and similar phenomena very near the nucleus in the brightest comets demonstrates that the sublimation process is not uniform over the nuclei. In other words, the nuclei of many comets contain relatively small active regions which provide much or most of the sublimation when these areas are turned toward the Sun. The period of rotation can be determind by measurement of the diameters of the halos or of the latus recta of the "parabolic" envelopes, if the expansion velocities are averaged from observations as a function of solar distance. Experience from analyses of some 80 well observed comets shows that the nuclei are "spotted" for more than a third of all comets, regardless of the "age" as measured by the original inverse semimajor axis including correction for planetary perturbations.

Whipple, F. L.↗

Thermal modeling of cometary nuclei

A model of the sublimation of volatile ices from a cometary nucleus is presented which includes the effects of (1) diurnal heating and cooling, (2) rotation period and pole orientation, (3) the thermal properties of the ice and subsurface layers, and (4) the contributions from coma opacity, scattering and thermal emission where the properties of the coma are derived from the integrated rate of volatile production by the nucleus. In applying the model to the case of the 1986 apparition of Halley's comet, it is found that the generation of a cometary dust coma increases the total energy reaching the Halley nucleus due to the greater geometrical cross-section of the coma as compared with the bare nucleus. The calculated coma opacity of Halley is about 0.2 at 1 AU from the sun and 1.2 at perihelion. Possible consequences of the results obtained for the generation of nongravitational forces, volatile production rates for comets and cometary lifetimes against sublimation are discussed.

Weissman, P. R.↗