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At least 235 records · Page 13

Characteristics of a cylindrical collector mirror for laser-produced xenon plasma soft X-rays and improvement of mirror lifetime by buffer gas

The focusing characteristics of a ruthenium-coated cylindrical mirror were investigated on the basis of its ability to collect and focus broadband 5-17-nm soft X-rays emitted from a laser-produced plasma. Based on the plasmas spectral intensity distribution and the reflectivity function of the mirror, we defined the optimum position of the integrated cylindrical mirror at which the X-ray energy flux transported and focused through the mirror was maximum. A minimum spot diameter of 22 mm at a distance of approximately 200 mm from a soft X-ray source was confirmed. The maximum intensity of the collected soft X-rays was 1.3 mJ/cm{sup 2} at the center of the irradiation zone. Thus, the irradiation intensity was improved by approximately 27 times when compared to that of 47 {mu}J/cm{sup 2} without the mirror. The debris sputtering rate on the reflection surface of the mirror can be reduced to 1/110 by argon gas at 11 Pa, while the attenuation rate of the soft X-rays due to absorption by the buffer gas can be suppressed to less than 10% at the focal point. The focusing property of the mirror is expected to be maintained for 3000 h or longer without significant degradation for a 100 W/320 pps laser shot if the ruthenium layer is thicker than 10 {mu}m. These results suggest that a stand-alone broadband soft X-ray processing system can be realized by using laser-produced plasma soft X-rays.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗

Programmable soft valves for digital and analog control

In soft devices, complex actuation sequences and precise force control typically require hard electronic valves and microcontrollers. Existing designs for entirely soft pneumatic control systems are capable of either digital or analog operation, but not both, and are limited by speed of actuation, range of pressure, time required for fabrication, or loss of power through pull-down resistors. Using the nonlinear mechanics intrinsic to structures composed of soft materials—in this case, by leveraging membrane inversion and tube kinking—two modular soft components are developed: a piston actuator and a bistable pneumatic switch. These two components combine to create valves capable of analog pressure regulation, simplified digital logic, controlled oscillation, nonvolatile memory storage, linear actuation, and interfacing with human users in both digital and analog formats. Three demonstrations showcase the capabilities of systems constructed from these valves: 1) a wearable glove capable of analog control of a soft artificial robotic hand based on input from a human user’s fingers, 2) a human-controlled cushion matrix designed for use in medical care, and 3) an untethered robot which travels a distance dynamically programmed at the time of operation to retrieve an object. This work illustrates pathways for complementary digital and analog control of soft robots using a unified valve design.

42 ENGINEERING↗

A SOFT X-RAY REVERBERATION LAG IN THE AGN ESO 113-G010

Reverberation lags have recently been discovered in a handful of nearby, variable active galactic nuclei (AGNs). Here, we analyze a {approx}100 ks archival XMM-Newton observation of the highly variable AGN, ESO 113-G010, in order to search for lags between hard, 1.5-4.5 keV, and soft, 0.3-0.9 keV, energy X-ray bands. At the lowest frequencies available in the light curve ({approx}< 1.5 Multiplication-Sign 10{sup -4} Hz), we find hard lags where the power-law-dominated hard band lags the soft band (where the reflection fraction is high). However, at higher frequencies in the range (2-3) Multiplication-Sign 10{sup -4} Hz we find a soft lag of -325 {+-} 89 s. The general evolution from hard to soft lags as the frequency increases is similar to other AGNs where soft lags have been detected. We interpret this soft lag as due to reverberation from the accretion disk, with the reflection component responding to variability from the X-ray corona. For a black hole mass of 7 Multiplication-Sign 10{sup 6} M{sub Sun} this corresponds to a light-crossing time of {approx}9 R{sub g} /c; however, dilution effects mean that the intrinsic lag is likely longer than this. Based on recent black hole mass scaling for lag properties, the lag amplitude and frequency are more consistent with a black hole a few times more massive than the best estimates, though flux-dependent effects could easily add scatter this large.

79 ASTRONOMY AND ASTROPHYSICS↗

Soft matter roadmap

Soft materials are usually defined as materials made of mesoscopic entities, often self-organised, sensitive to thermal fluctuations and to weak perturbations. Archetypal examples are colloids, polymers, amphiphiles, liquid crystals, foams. The importance of soft materials in everyday commodity products, as well as in technological applications, is enormous, and controlling or improving their properties is the focus of many efforts. From a fundamental perspective, the possibility of manipulating soft material properties, by tuning interactions between constituents and by applying external perturbations, gives rise to an almost unlimited variety in physical properties. Together with the relative ease to observe and characterise them, this renders soft matter systems powerful model systems to investigate statistical physics phenomena, many of them relevant as well to hard condensed matter systems. Understanding the emerging properties from mesoscale constituents still poses enormous challenges, which have stimulated a wealth of new experimental approaches, including the synthesis of new systems with, e.g. tailored self-assembling properties, or novel experimental techniques in imaging, scattering or rheology. Theoretical and numerical methods, and coarse-grained models, have become central to predict physical properties of soft materials, while computational approaches that also use machine learning tools are playing a progressively major role in many investigations. This Roadmap intends to give a broad overview of recent and possible future activities in the field of soft materials, with experts covering various developments and challenges in material synthesis and characterisation, instrumental, simulation and theoretical methods as well as general concepts.

36 MATERIALS SCIENCE↗

Clover: Compiler directed lightweight soft error resilience

This paper presents Clover, a compiler directed soft error detection and recovery scheme for lightweight soft error resilience. The compiler carefully generates soft error tolerant code based on idem-potent processing without explicit checkpoint. During program execution, Clover relies on a small number of acoustic wave detectors deployed in the processor to identify soft errors by sensing the wave made by a particle strike. To cope with DUE (detected unrecoverable errors) caused by the sensing latency of error detection, Clover leverages a novel selective instruction duplication technique called tail-DMR (dual modular redundancy). Once a soft error is detected by either the sensor or the tail-DMR, Clover takes care of the error as in the case of exception handling. To recover from the error, Clover simply redirects program control to the beginning of the code region where the error is detected. Lastly, the experiment results demonstrate that the average runtime overhead is only 26%, which is a 75% reduction compared to that of the state-of-the-art soft error resilience technique.

97 MATHEMATICS AND COMPUTING↗

Operating Experience and Lessons Learned in the Use of Soft-Sided Packaging for Transportation and Disposal of Low Activity Radioactive Waste

This paper describes the operating experience and lessons learned at U.S. Department of Energy (DOE) sites as a result of an evaluation of potential trailer contamination and soft-sided packaging integrity issues related to the disposal of low-level and mixed low-level (LLW/MLLW) radioactive waste shipments. Nearly 4.3 million cubic meters of LLW/MLLW will have been generated and disposed of during fiscal year (FY) 2010 to FY 2015—either at commercial disposal sites or disposal sites owned by DOE. The LLW/MLLW is packaged in several different types of regulatory compliant packaging and transported via highway or rail to disposal sites safely and efficiently in accordance with federal, state, and local regulations and DOE orders. In 1999, DOE supported the development of LLW containers that are more volumetrically efficient, more cost effective, and easier to use as compared to metal or wooden containers that existed at that time. The DOE Idaho National Engineering and Environmental Laboratory (INEEL), working in conjunction with the plastic industry, tested several types of soft-sided waste packaging systems that meet U.S. Department of Transportation requirements for transport of low specific activity and surface contaminated objects. Since then, soft-sided packaging of various capacities have been used successfully by the decontamination and decommissioning (D&D) projects to package, transport, and dispose D&D wastes throughout the DOE complex. The joint team of experts assembled by the Energy Facility Contractors Group from DOE waste generating sites, DOE and commercial waste disposal facilities, and soft-sided packaging suppliers conducted the review of soft-sided packaging operations and transportation of these packages to the disposal sites. As a result of this evaluation, the team developed several recommendations and best practices to prevent or minimize the recurrences of equipment contamination issues and proper use of soft-sided packaging for transport and disposal of waste.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Characterization of the Impact of Soft Errors on Iterative Methods

Soft errors caused by transient bit flips have the potential to significantly impact an application’s behavior. This has motivated the design of an array of techniques to detect, isolate, and correct soft errors using microarchitectural, architectural, compilation-based, or application-level techniques to minimize their impact on the executing application. The first step towards the design of good error detection/correction techniques involves an understanding of an application’s vulnerability to soft errors. In this paper, we present the first comprehensive characterization of the impact of soft errors on the convergence characteristics of six iterative methods using application-level fault injection. In particular, we consider the use of iterative methods to incrementally solve a linear systems of equations, which constitutes the core kernel in many scientific applications. We analyze the impact of soft errors in terms of the type of error (single- vs multi-bit), the distribution and location of bits affected, the data structure and the statement impacted, and variation with time. In addition to understanding the vulnerability of iterative solvers to soft errors, this characterization can aid the design of fault injection campaigns that ensure systematic coverage.

fault injection, iterative methods, Silent data co↗

Design and Closed‐Loop Motion Planning of an Untethered Swimming Soft Robot Using 2D Discrete Elastic Rods Simulations

Despite tremendous progress in the development of untethered soft robots in recent years, existing systems lack the mobility, model‐based control, and motion planning capabilities of their piecewise rigid counterparts. As in conventional robotic systems, the development of versatile locomotion of soft robots is aided by the integration of hardware design and control with modeling tools that account for their unique mechanics and environmental interactions. Here, a framework for physics‐based modeling, motion planning, and control of a fully untethered swimming soft robot is introduced. This framework enables offline co‐design in the simulation of robot parameters and gaits to produce effective open‐loop behaviors and enables closed‐loop planning over motion primitives for feedback control of a frog‐inspired soft robot testbed. This pipeline uses a discrete elastic rods (DERs) physics engine that discretizes the soft robot as many stretchable and bendable rods. On hardware, an untethered aquatic soft robot that performs frog‐like rowing behaviors is engineered. Hardware validation verifies that the simulation has sufficient accuracy to find the best candidates for sets of parameters offline. The simulator is then used to generate a trajectory library of the robot's motion in simulation that is used in real‐time closed‐loop path following experiments on hardware.

Huang, Xiaonan↗

Multi-spin soft bootstrap and scalar-vector Galileon

We use the amplitude soft bootstrap method to explore the space of effective field theories (EFT) of massless vectors and scalars. It is known that demanding vanishing soft limits fixes uniquely a special class of EFTs: non-linear sigma model, scalar Galileon and Born-Infeld theories. Based on the amplitudes analysis, we conjecture no-go theorems for higher-derivative vector theories and theories with coupled vectors and scalars. We then allow for more general soft theorems where the non-trivial part of the soft limit of the ( n +1)-pt amplitude is equal to a linear combination of n-pt amplitudes. We derive the form of these soft theorems for general power-counting and spins of particles and use it as an input into the soft bootstrap method in the case of Galileon power-counting and coupled scalar-vector theories. We show that this unifies the description of existing Galileon theories and leads us to the discovery of a new exceptional theory: Special scalar-vector Galileon.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

Geometry of soft scalars at one loop

We extend the soft theorems for scattering amplitudes of scalar effective field theories to one-loop order. Our analysis requires carefully accounting for the fact that the soft limit is not guaranteed to commute with evaluating IR-divergent loop integrals; new results for the soft limit of general scalar one-loop integrals are presented. The geometric soft theorem remains unmodified for any derivatively-coupled scalar effective field theory, and we conjecture that this statement holds to all orders. In contrast, the soft theorem receives nontrivial corrections in the presence of potential interactions, analogous to the case of non-Abelian gauge theories. We derive the universal leading-order correction to the scalar soft theorem arising from potential interactions at one loop. Explicit examples are provided that illustrate the general results.

differential and algebraic geometry↗

Constructing Amplitudes from Their Soft Limits

The existence of universal soft limits for gauge-theory and gravity amplitudes has been known for a long time. The properties of the soft limits have been exploited in numerous ways; in particular for relating an n-point amplitude to an (n-1)-point amplitude by removing a soft particle. Recently, a procedure called inverse soft was developed by which 'soft' particles can be systematically added to an amplitude to construct a higher-point amplitude for generic kinematics. We review this procedure and relate it to Britto-Cachazo-Feng-Witten recursion. We show that all tree-level amplitudes in gauge theory and gravity up through seven points can be constructed in this way, as well as certain classes of NMHV gauge-theory amplitudes with any number of external legs. This provides us with a systematic procedure for constructing amplitudes solely from their soft limits.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

Human attitude analysis based on fuzzy soft differential equations with Bonferroni mean

In this paper, we model a system of fuzzy soft differential equations to analyze the behavior over the time of an individual depending on their companion’s actions under any particular situation against some decision. The Bonferroni mean (BM) is a very useful tool for group decision-making problems when arguments are interrelated to each other as Bonferroni mean can capture the interrelationship of the individual arguments. Using this ability of BM, we define Bonferroni fuzzy soft matrix (BFSM) and weighted Bonferroni fuzzy soft matrix (WBFSM) for data representation. WBFSM is a decision matrix and provide the optimum fuzzy soft constant (OFSC) which is the key element of fuzzy soft differential equation. By utilizing the OFSC, we develop a system of fuzzy soft differential equations to study a dynamical process with nonlinear uncertain and vague data. Second, we present a novel efficient technique for analyzing the future attitude of people due to their present decisions. To illustrate the practicality and feasibility of proposed technique an illustrative example is also discussed with the help of phase portrait and line graphs.

97 MATHEMATICS AND COMPUTING↗

Resonant soft X-ray scattering for polymer materials

Resonant Soft X-ray Scattering (RSoXS) was developed within the last few years, and the first dedicated resonant soft X-ray scattering beamline for soft materials was constructed at the Advanced Light Source, LBNL. RSoXS combines soft X-ray spectroscopy with X-ray scattering and thus offers statistical information for 3D chemical morphology over a large length scale range from nanometers to micrometers. Using RSoXS to characterize multi-length scale soft materials with heterogeneous chemical structures, we have demonstrated that soft X-ray scattering is a unique complementary technique to conventional hard X-ray and neutron scattering. Its unique chemical sensitivity, large accessible size scale, molecular bond orientation sensitivity with polarized X-rays, and high coherence have shown great potential for chemically specific structural characterization for many classes of materials.

36 MATERIALS SCIENCE↗

Impact of Computed Tomography Image Quality on Image-Guided Radiation Therapy Based on Soft Tissue Registration

Purpose: In image-guided radiation therapy (IGRT), different computed tomography (CT) modalities with varying image quality are being used to correct for interfractional variations in patient set-up and anatomy changes, thereby reducing clinical target volume to the planning target volume (CTV-to-PTV) margins. We explore how CT image quality affects patient repositioning and CTV-to-PTV margins in soft tissue registration-based IGRT for prostate cancer patients. Methods and Materials: Four CT-based IGRT modalities used for prostate RT were considered in this study: MV fan beam CT (MVFBCT) (Tomotherapy), MV cone beam CT (MVCBCT) (MVision; Siemens), kV fan beam CT (kVFBCT) (CTVision, Siemens), and kV cone beam CT (kVCBCT) (Synergy; Elekta). Daily shifts were determined by manual registration to achieve the best soft tissue agreement. Effect of image quality on patient repositioning was determined by statistical analysis of daily shifts for 136 patients (34 per modality). Inter- and intraobserver variability of soft tissue registration was evaluated based on the registration of a representative scan for each CT modality with its corresponding planning scan. Results: Superior image quality with the kVFBCT resulted in reduced uncertainty in soft tissue registration during IGRT compared with other image modalities for IGRT. The largest interobserver variations of soft tissue registration were 1.1 mm, 2.5 mm, 2.6 mm, and 3.2 mm for kVFBCT, kVCBCT, MVFBCT, and MVCBCT, respectively. Conclusions: Image quality adversely affects the reproducibility of soft tissue-based registration for IGRT and necessitates a careful consideration of residual uncertainties in determining different CTV-to-PTV margins for IGRT using different image modalities.

62 RADIOLOGY AND NUCLEAR MEDICINE↗

Hard–Soft Acid–Base Theory Explains Photoexcited Carrier Dynamics in Porphyrin/CNT Nanohybrids: Time-Domain Atomistic Analysis

We employ the fundamental chemical concepts of hard− soft acid−base to formulate general principles governing excited-state dynamics in zinc porphyrin (ZnP)/carbon nanotube (CNT) hybrids for energy photoconversion. Atomistic quantum dynamics simulations demonstrate that electron-withdrawing and donating substituents at the ZnP β-pyrrolic position strongly influence the dynamics. ZnP photoexcitation produces subpicosecond electron transfer (ET) from ZnP to CNT, in agreement with the experiment. Substitutions of CN by H and tBu accelerate the ET. The trend is directly related to the hard−soft acid−base concept because the soft−soft interaction between the t Bu- ZnP acid and the mild CNT base enhances the donor−acceptor coupling. Longer coherence and more active vibrational modes facilitate the ET in t Bu-ZnP/CNT. Electron−hole recombination in CN-ZnP/CNT occurs on a hundred picosecond time scale, nicely corroborated by the experiment. The exciton lifetime is extended beyond a nanosecond by the substitutions. The soft−soft interaction in t Bu-ZnP/ CNT increases the splitting between the highest occupied orbitals of the two subsystems, reduces their mixing, and decreases nonadiabatic coupling between the ground and excited states. Rapid decoherence and involvement of low-frequency vibrations favor longer lifetimes. Our investigation reveals that larger p K a of the β-pyrrolic acid gives rapid ET and slow recombination and provides detailed mechanistic information, essential for future optoelectronic applications.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Soft elasticity optimises dissipation in 3D-printed liquid crystal elastomers

Soft-elasticity in monodomain liquid crystal elastomers (LCEs) is promising for impact-absorbing applications where strain energy is ideally absorbed at constant stress. Conventionally, compressive and impact studies on LCEs have not been performed given the notorious difficulty synthesizing sufficiently large monodomain devices. Here, we use direct-ink writing 3D printing to fabricate bulk (>cm 3 ) monodomain LCE devices and study their compressive soft-elasticity over 8 decades of strain rate. At quasi-static rates, the monodomain soft-elastic LCE dissipated 45% of strain energy while comparator materials dissipated less than 20%. At strain rates up to 3000 s –1 , our soft-elastic monodomain LCE consistently performed closest to an ideal-impact absorber. Drop testing reveals soft-elasticity as a likely mechanism for effectively reducing the severity of impacts – with soft elastic LCEs offering a Gadd Severity Index 40% lower than a comparable isotropic elastomer. Lastly, we demonstrate tailoring deformation and buckling behavior in monodomain LCEs via the printed director orientation.

36 MATERIALS SCIENCE↗

What dictates soft clay-like lithium superionic conductor formation from rigid salts mixture

Abstract Soft clay-like Li-superionic conductors, integral to realizing all-solid-state batteries, have been recently synthesized by mixing rigid-salts. Here, through computational and experimental analysis, we clarify how a soft clay-like material can be created from a mixture of rigid-salts. Using molecular dynamics simulations with a deep learning-based interatomic potential energy model, we uncover the microscopic features responsible for soft clay-formation from ionic solid mixtures. We find that salt mixtures capable of forming molecular solid units on anion exchange, along with the slow kinetics of such reactions, are key to soft-clay formation. Molecular solid units serve as sites for shear transformation zones, and their inherent softness enables plasticity at low stress. Extended X-ray absorption fine structure spectroscopy confirms the formation of molecular solid units. A general strategy for creating soft clay-like materials from ionic solid mixtures is formulated.

25 ENERGY STORAGE↗

Ultracompact mirror device for forming 20-nm achromatic soft-X-ray focus toward multimodal and multicolor nanoanalyses

Abstract Nanoscale soft-X-ray microscopy is a powerful analysis tool in biological, chemical, and physical sciences. To enhance its probe sensitivity and leverage multimodal soft-X-ray microscopy, precise achromatic focusing devices, which are challenging to fabricate, are essential. Here, we develop an ultracompact Kirkpatrick-Baez (ucKB) mirror, which is ideal for the high-performance nanofocusing of broadband-energy X-rays. We apply our advanced fabrication techniques and short-focal-length strategy to realize diffraction-limited focusing over the entire soft-X-ray range. We achieve a focus size of 20.4 nm at 2 keV, which represents a significant improvement in achromatic soft-X-ray focusing. The ucKB mirror extends soft-X-ray fluorescence microscopy by producing a bicolor nanoprobe with a 1- or 2-keV photon energy. We propose a subcellular chemical mapping method that allows a comprehensive analysis of specimen morphology and the distribution of light elements and metal elements. ucKB mirrors will improve soft-X-ray nanoanalyses by facilitating photon-hungry, multimodal, and polychromatic methods, even with table-top X-ray sources.

Science & Technology - Other Topics↗