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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 235 records · Page 13
All sourcesNASA NTRSDOE OSTI
NASA NTRS1979

Friction and transfer of copper, silver, and gold to iron in the presence of various adsorbed surface films

Sliding friction experiments were conducted with the noble metals copper, silver, and gold and two binary alloys of these metals contacting iron in the presence of various adsorbates including, oxygen, methyl mercaptan, and methyl chloride. A pin on disk specimen configuration was used with a load of 100 grams, sliding velocity of 60 mm/min; at 25 C with the surfaces saturated with the adsorbates. Auger emission spectroscopy was used to monitor surface films. Results of the experiments indicate that friction and transfer characteristics are highly specific with respect to both the noble metal and surface film present. With all three metals and films transfer of the noble metal to iron occurred very rapidly. With all metals and films transfer of the noble metal to iron continuously increased with repeated passes except for silver and copper sliding on iron sulfide.

Buckley, D. H.↗
NASA NTRS1980

Scattering defects in silver mirror coatings

Scatter centers common to protected silver have been investigated on a variety of space flight quality mirrors. The defects have been characterized as to number density, size, location within the film layer structure, and dependence on illumination angle. In addition the total integrated scatter values as a function of wavelength, humidity test soak time, and temperature have been determined for some mirrors. These submicrometer sized defects are believed to be the precursors of silver corrosion spots. A mechanism for their generation is proposed, and measures to reduce their occurrence are suggested.

Pellicori, S. F.↗
NASA NTRS1984

Preliminary Silver-hydrogen Cell Test Results

Silver-hydrogen cells were tested. The objective of the test was to estimate useful life by operation at accelerated, simulated geosynchronous orbit conditions. Ten simulated seasons were run and are summarized. The results to-date reflect stable, trouble-free performance and indicate that the silver-hydrogen couple shows promise as a lightweight alternative to the nickel systems.

Lurie, C.↗
NASA NTRS1989

Auger electron intensity variations in oxygen-exposed large grain polycrystalline silver

Auger electron spectroscopic studies of the grains in oxygen-charged polycrystal-line silver show significant intensity variations as a function of crystallographic orientation. These intensity variations were observed by studies of the Auger images and line scans of the different grains (randomly selected) for each silver transition energy. The results can be attributed to the diffraction of the ejected Auger electrons and interpreted by corresponding changes in the electron mean-free path for inelastic scattering and by oxygen atom accumulation in the subsurface. The subsurface (second layer) octahedral sites increased in size because of surface relaxation and serve as a stable reservoir for the dissolved oxygen.

Lee, W. S.↗
NASA NTRS1991

A new method for measuring low resistivity contacts between silver and YBa2Cu3O(7-x) superconductor

Several methods of measuring contact resistivity between silver electrodes and YBa2Cu3O(7-x) superconductors were investigated; including the two-point, the three point, and the lap-joint methods. The lap-joint method was found to yield the most consistent and reliable results and is proposed as a new technique for this measurement. Painting, embedding, and melting methods were used to apply the electrodes to the superconductor. Silver electrodes produced good ohmic contacts to YBa2Cu3O(7-x) superconductors with contact resistivities as low as 1.9 x 10 to the -9th ohm sq cm.

Hsi, Chi-Shiung↗
NASA NTRS1991

Assessment of atomic oxygen erosion of silver interconnects on Intelsat 6, F3

Intelsat 6 F-3 was launched from Cape Canaveral on a Titan 3 launch vehicle. Failure of the launch vehicle resulted in the satellite being marooned in Low Earth Orbit (LEO). During its sojourn in LEO, Intelsat 6 is exposed to an unanticipated environment consisting primarily of atomic oxygen, which will subject the unprotected silver interconnects (nominally 12.5 microns thick) on the solar panel to oxidation and erosion. Rescue by Space Shuttle is being examined. Consequently, Intelsat and Comsat have joined in an effort to determine the condition of the silver interconnects at the anticipated time of reboost and to assess the long term risks to the intended geostationary mission. Ground based tests, theoretical analysis, and a flight experiment aboard STS-41 were executed, and new software was written to calculate the expected total atomic oxygen fluence on the interconnects.

A. Dunnet↗
NASA NTRS1991

The effect of ion plated silver and sliding friction on tensile stress-induced cracking in aluminum oxide

A Hertzian analysis of the effect of sliding friction on contact stresses in alumina is used to predict the critical load for crack generation. The results for uncoated alumina and alumina coated with ion plated silver are compared. Friction coefficient inputs to the analysis are determined experimentally with a scratch test instrument employing an 0.2 mm radius diamond stylus. A series of scratches were made at constant load increments on coated and uncoated flat alumina surfaces. Critical loads for cracking are detected by microscopic examination of cross sections of scratches made at various loads and friction coefficients. Acoustic emission (AE) and friction trends were also evaluated as experimental techniques for determining critical loads for cracking. Analytical predictions correlate well with micrographic evidence and with the lowest load at which AE is detected in multiple scratch tests. Friction/load trends are not good indicators of early crack formation. Lubrication with silver films reduced friction and thereby increased the critical load for crack initiation in agreement with analytical predictions.

Sliney, Harold E.↗
NASA NTRS1992

Attitude stability of LDEF: Refinement of results from the silver pinhole camera

A measurement was previously described of the angular offset and attitude stability of the LDEF spacecraft using a simple pinhole camera device in the UAH experiment A0114. This device uses a silver surface to record the impact zone of atmospheric atomic oxygen passing through a small pinhole on the front surface of the satellite. The shape and size of this zone are well defined if the satellite velocity and gas temperature are known. The circular symmetry of the zone would be distorted by oscillation of the LDEF about its stable attitude, or by the effect of the co-rotation of the Earth's atmosphere for cases of satellites in nonequatorial orbits. The observed ellipticity of 1.05 with the major axis in the yaw direction is equivalent to an oscillation of + or - 0.2 deg about the stable attitude. The uncertainty in that measurement was estimated at about 0.1 deg. A refined analysis based on summing distributions of flux versus incidence angle for a large number of orbital positions, and including a co-rotating atmosphere, indicates that the combined distributions produce a result consistent with the measured exposed spot. It is suggested that, within the precision of the measurements, no actual oscillation of the LDEF is required to produce the results. Thus, the LDEF may have maintained a stable attitude to better than 0.1 deg, even under conditions of maximum aerodynamic perturbation when the silver oxygen record was made. This error is some two orders of magnitude lower than the predicted uncertainty in yaw oscillation and may indicate that the predict methodologies are too conservative.

Peters, P. N.↗
NASA NTRS1993

The effect of ion-plated silver and sliding friction on tensile stress-induced cracking in aluminum oxide

A Hertzian analysis of the effect of sliding friction on contact stresses in alumina is used to predict the critical load for crack generation. The results for uncoated alumina and alumina coated with ion plated silver are compared. Friction coefficient inputs to the analysis are determined experimentally with a scratch test instrument employing an 0.2 mm radius diamond stylus. A series of scratches were made at constant load increments on coated and uncoated flat alumina surfaces. Critical loads for cracking are detected by microscopic examination of cross sections of scratches made at various loads and friction coefficients. Acoustic emission (AE) and friction trends were also evaluated as experimental techniques for determining critical loads for cracking. Analytical predictions correlate well with micrographic evidence and with the lowest load at which AE is detected in multiple scratch tests. Friction/load trends are not good indicators of early crack formation. Lubrication with silver films reduced friction and thereby increased the critical load for crack initiation in agreement with analytical predictions.

Sliney, Harold E.↗
NASA NTRS1995

Screen-Cage Ion Plating Of Silver On Polycrystalline Alumina

Screen-cage ion plating (SCIP) cost-effective technique offering high throwing power for deposition of adherent metal films on ceramic substrates. Applies silver films to complexly shaped substrates of polycrystalline alumina. Silver adheres tenaciously and reduces friction. SCIP holds promise for applying lubricating soft metallic films to high-temperature ceramic components of advanced combustion engines. Other potential uses include coating substrates with metal for protection against corrosion, depositing electrical conductors on dielectric substrates, making optically reflective or electrically or thermally conductive surface layers, and applying decorative metal coats to ceramic trophies or sculptures.

Spalvins, Talivaldis↗
NASA NTRS1995

Thallium 2223 high T(sub c) superconductor in a silver matrix and its magnetic shielding, hermalcycle and time aging properties

Superconducting Tl2Ba2Ca2Cu3O10 (Tl2223) was ground to powder. Mixture with silver powder (0-80% weight) and press to desired shape. After proper annealing, one can get good silver-content Tl2223 bulk superconductor. It is time-stable and has good superconducting property as same as pure Tl2223. It also has better mechanical property and far better thermal cycle property than pure Tl2223.

Fei, X.↗
NASA NTRSDate not supplied

Double ChemFET for the In-Line Monitoring of Silver Dosing in Potable Water Systems

With NASA Advanced Exploration Systems (AES) Life Support Systems (LSS) baselining ionic silver (Ag+) as the biocide of choice, development in silver monitoring technologies becomes necessary to monitor and control Ag+ release. Ion-selctive field effect transistors (ISFETs) and chemically-sensitive field effect transistors (ChemFETs) are capable of selective detection of Ag+ with reversible and low detection limit responses. However, one major hurdle to ChemFET technologies is the requirement of a reference electrode, which can leak its fill solution into the potable water system and is prone to drift requiring frequent calibration. To circumvent this issue, we are developing a double chemically-sensitive field effect transistor (dChemFET). The dChemFET uses a second ChemFET to selectively monitor the counter ion and serves in place of the reference electrode. We report our work in developing the dChemFET, starting with the development of the Ag+ and NO3- ion selective memberanes (ISMs) to be used in the ChemFETs. The Ag+ ISM has a detection range of 50-105 ppb . The counter ion ISM, NO3- ISM, has shown a detection range of 400-105 ppb. NO3- ISMs are limited in detecting at lower ppb levels required for the dChemFET application on the potable water system. In response to this issue, we also report our studies in using the Ag+ ISM to measure deionized (DI) water as a reference measurement to be implemented in-line before the Ag+ is dosed.

Lance Dean Delzeit↗
NASA NTRSDate not supplied

Evaluation of Iodine and Silver as Biocides for Potable Water in Human Missions beyond Low Earth Orbit

Chemical biocides play an important role in potable water storage and distribution systems. They provide protection against microbial growth that can negatively impact efficient water transport and crew health. Molecular iodine and ionic silver have been used on the International Space Station for decades. Future orbiting and surface habitats will have potable water systems that will require reliable potable water storage and challenging transport schemes during daily operations with potentially lengthy and repeated periods of non-use. Based on a review of literature, experimental data, and flight data this paper categorizes the advantages and disadvantages of the two heritage biocides on ISS: iodine and silver. The history of biocide practices on ISS is compared to requirements of future human missions beyond low Earth Orbit. The upstream water quality supply and downstream water uses are defined with respect to the two biocides. The methods of injection and removal of the two biocides are compared for a range of downstream water uses including drinking water, hygiene water, technical water, oxygen generation water, and extravehicular activity water. The paper provides mission planners with a technical and engineering assessment of the two biocides and identifies gaps in knowledge and on-orbit experiences.

Dean Muirhead↗
DOE OSTI2022

REBCO -- a silver bullet for our next high-field magnet and collider budget?

High-field superconducting magnets with a dipole field of 16 T and above enable future energy-frontier circular particle colliders. Although we believe these magnets can be built, none exists today. They can also be a showstopper for future high-energy machines due to a prohibitively high price tag based on the current conductor and magnet fabrication cost. The high-temperature superconducting REBCO coated conductor can address both the technical and cost issues, a silver bullet to lay both monsters to rest. The challenges and unknowns, however, can be too arduous to make the silver bullet. We lay out a potential road forward and suggest key action items. As a contribution from the accelerator community, we attempt to clarify for our theorist and experimenter colleagues a few aspects about the future high-field superconducting magnets. We hope to stimulate an effective plan for the 2023 P5 process that can lead to a cost-effective high-field magnet technology for future colliders and the exciting physics they can steward.

43 PARTICLE ACCELERATORS↗
DOE OSTI2022

Lamellar and Hexagonal Assemblies of PEG-Grafted Silver Nanoparticles: Implications for Plasmonics and Photonics

Assembly of silver nanoparticles (AgNPs) grafted with thiolated poly(ethylene glycol) (PEG-SH) with various molecular weights is reported. Synchrotron-based X-ray surface-sensitive diffraction methods are used to determine the nature of two-dimensional (2D) assemblies at liquid/vapor interfaces, and small-angle X-ray scattering (SAXS) is used to monitor the three-dimensional (3D) assemblies in bulk suspensions. We find that assembly can be induced either by the addition of K 2 CO 3 or polyacrylic acid (PAA) to the PEG-AgNP aqueous suspensions. The addition of K 2 CO 3 induces a 2D hexagonal structure at the liquid/vapor interface and a 3D hexagonal columnar structure in solutions, where the columns consist of tethered PEG-AgNP chains. On the other hand, the addition of PAA leads to the formation of a 2D lamella-like distorted hexagonal sheet at the liquid/vapor interface and a 3D lamellar superstructure formed by stacked 2D sheets in the PEG-AgNP suspension. Effects of the core type of nanoparticles on the assembly can be used to control structures for potential applications in plasmonics and photonics.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗