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At least 235 records · Page 13

Polymer-Based Thermally Stable Chemiresistive Sensor for Real-Time Monitoring of NO 2 Gas Emission

Here, we present a thermally stable, mechanically compliant, and sensitive polymer-based NO 2 gas sensor design. Interconnected nanoscale morphology driven from spinodal decomposition between conjugated polymers tethered with polar side chains and thermally stable matrix polymers offers judicious design of NO 2 -sensitive and thermally tolerant thin films. The resulting chemiresitive sensors exhibit stable NO 2 sensing even at 170 °C over 6 h. Controlling the density of polar side chains along conjugated polymer backbone enables optimal design for coupling high NO 2 sensitivity, selectivity, and thermal stability of polymer sensors. Lastly, thermally stable films are used to implement chemiresistive sensors onto flexible and heat-resistant substrates and demonstrate a reliable gas sensing response even after 500 bending cycles at 170 °C. Such unprecedented sensor performance as well as environmental stability are promising for real-time monitoring of gas emission from vehicles and industrial chemical processes.

47 OTHER INSTRUMENTATION↗

Origin of giant electric-field-induced strain in faulted alkali niobate films

A large electromechanical response in ferroelectrics is highly desirable for developing high-performance sensors and actuators. Enhanced electromechanical coupling in ferroelectrics is usually obtained at morphotropic phase boundaries requiring stoichiometric control of complex compositions. Recently it was shown that giant piezoelectricity can be obtained in films with nanopillar structures. Here, we elucidate its origin in terms of atomic structure and demonstrate a different system with a greatly enhanced response. This is in non-stoichiometric potassium sodium niobate epitaxial thin films with a high density of self-assembled planar faults. A giant piezoelectric coefficient of ~1900 picometer per volt is demonstrated at 1 kHz, which is almost double the highest ever reported effective piezoelectric response in any existing thin films. The large oxygen octahedral distortions and the coupling between the structural distortion and polarization orientation mediated by charge redistribution at the planar faults enable the giant electric-field-induced strain. Our findings demonstrate an important mechanism for realizing the unprecedentedly giant electromechanical coupling and can be extended to many other material functions by engineering lattice faults in non-stoichiometric compositions.

36 MATERIALS SCIENCE↗

First Direct-Detection Results on Sub-GeV Dark Matter Using the SENSEI Detector at SNOLAB

Here, we present the first results from a dark matter search using six Skipper-CCDs in the SENSEI detector operating at SNOLAB. We employ a bias-mitigation technique of hiding approximately 46% of our total data and aggressively mask images to remove backgrounds. Given a total exposure after masking of 100.72 gram-days from well-performing sensors, we observe 55 two-electron events, 4 three-electron events, and no events containing 4–10 electrons. The two-electron events are consistent with pileup from one-electron events. Among the 4 three-electron events, 2 appear in pixels that are likely impacted by detector defects, although not strongly enough to trigger our “hot-pixel” mask. We use these data to set world-leading constraints on sub-GeV dark matter interacting with electrons and nuclei.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗

Internal 2-D Surface Temperature Measurements for Large Complex Geometries

For 2D-temperature monitoring applications, a variant of EIT (Electrical Impedance Tomography) is evaluated computationally in this work. Literature examples of poor sensor performance in the center of the 2D domains away from the side electrodes motivated this study which seeks to overcome some of the previously noted shortcomings. In particular, the use of ‘sensing skins’ with novel tailored baseline conductivities were examined using the EIDORS package for EIT. It was found that the best approach for detecting a hot spot depends on several factors such as the current injection (stimulation) patterns, the measurement patterns, and the reconstruction algorithms. For a well-performing combination of these factors, tailored baseline conductivities were assessed and compared to the baseline uniform conductivity. It was discovered that for some EIT applications, a tailored distribution needs to be smooth and that sudden changes in the conductivity gradients should be avoided. Still, the benefits in terms of improved EIT performance were small for conditions for which the EIT measurements had been ‘optimized’ for the uniform baseline case. Within the limited scope of this study, only two specific cases showed benefits from tailored distributions. For one case, a smooth tailored distribution with increased baseline conductivity in the center provided a better separation of two centrally located hot spots. For another case, a smooth tailored distribution with reduced conductivity in the center provided better estimates of the magnitudes of two hot spots near the center of the sensing skin.

47 OTHER INSTRUMENTATION↗

Monitoring the corrosion resistance of cold-spray coatings with membrane-based sensors

In this presentation, the MBES shows the ability to detect the change in exposed environment even with cold-spray coatings. Corrosion rates from the cold-spray coating were comparable to a 316 stainless steel sample. Defects in the coating did not impact sensor performance in terms of corrosion rate or water content detection. Energy dispersive X-ray spectroscopy was used to document ion migration into the membrane.

Rendon, Arnaldo↗

Optimization of Conditions for Photoluminescence-Based Sensing of Critical Minerals: Strategies and Outlook

Economically critical minerals and metals are vital to America’s security, with application areas in energy, advanced technologies, and defense systems. The growing implementation of renewable energy sources such as electric vehicles is expected to significantly increase demand for these minerals, while the global supply is monopolistic, with most of the production occurring in a few countries outside of the US. To mitigate potential supply chain vulnerabilities, the domestic production of economically critical metals has become a bipartisan priority of the US government, and unconventional sources such as coal and its utilization byproducts such as fly ash and acid mine drainage are being actively explored as an alternative method for meeting domestic demand. Slow and expensive characterization methods for critical metals present a significant pain point for domestic production, which has led to the exploration of alternative low-cost, portable platforms capable of detecting target metals during resource prospecting and downstream process monitoring. The National Energy Technology Laboratory has developed a portable fiber optic-based luminescence spectrometer that utilizes a metal-organic framework (MOF) material to detect and distinguish parts-per-billion levels of the visible-emitting rare earth elements terbium, dysprosium, samarium, and europium, which are all economically critical metals. Although preliminary results with this system are promising, a crucial barrier to practical deployment is the ability to operate in low pH, high ionic strength environments, as acidic conditions and the presence of other metal ions can significantly reduce luminescence signal. Here, current strategies related to sample treatment, material design, and sensor configuration are discussed in the context of improving sensor performance in application-relevant conditions. Additionally, future opportunities, such as the optimization of the sensing binding environment through computational methods and specific metals to be removed for treatment will be discussed, presenting a forward-looking view for innovation in luminescent sensing of critical metals.

36 MATERIALS SCIENCE↗

Harnessing Quantum Information Science for Enhancing Sensors in Harsh Fossil Energy Environments

The main goals of this project are to utilize real-time quantum dynamics simulations and quantum optimal control algorithms to (1) harness near-surface nitrogen vacancy (NV) centers to detect chemical analytes in harsh fossil energy environments, and (2) design optimally constructed electromagnetic fields for initializing these near-surface NV center spins for efficient sensor performance and detectivity.

20 FOSSIL-FUELED POWER PLANTS↗

Skylab 3 preliminary reference Earth Resources Experiment Package (EREP) pass planning document. Volume 2: EREP sites and S190 swath study of selected revs

The ground tracks and S190 swaths are presented of selected revolutions over areas containing earth resources experiment package (EREP) sites. The following eight EREP disciplines are shown: sensor performance evaluation, forestry, geology, hydrology, land use mapping, oceanography, pollution, and weather. Most of the data reported consists of passes over the continental United States.

Lunde, A. N.↗

Physiological factors and optical parameters as bases of vegetation discrimination and stress analysis.

The successful application of photographic, optical-mechanical scanning, and other sensing techniques to vegetation must be based on an understanding of the biological and physical principles involved. The objective is to review the biological and optical characteristics of vegetation and to discuss how knowledge of them can support operational programs by aiding in wavelength selection, timing of missions, and discriminations between vegetation types as well as between healthy and stressed plants of the same type. Both laboratory situations, in which relatively pure spectral data are obtained, and field situations are considered. In the latter, sensor performance and background variables affect data quality.

Wiegand, C. L.↗

A follow-on study for miniature solid-state pressure transducer

The activities of a developmental program to design, fabricate and test an absolute pressure transducer based upon the piezojunction properties of silicon are summarized. The prime problem addressed is the development of a housing capable of applying the high stress levels needed for sensitive piezojunction operation but at the same, free from the creep effects and the fragility that limit the usefulness of previous designs. The first part of the report describes the initial fabrication and test and reviews the theory of sensor performance. The second part incorporates two recommendations of the first part (the use of commercially manufactured silicon planar mesa diodes and the adoption of an all-silicon structure for loading) and presents some preliminary test data on the transducers thus fabricated. These initial measurements show much improved performance over any previously fabricated piezojunction transducers but testing is incomplete and several problems in manufacturing technology remain.

Source record↗

New development in high reliability strapdown platforms using TDF sensors

New development in high reliability strapdown navigation platform using two-degree-of-freedom sensors and redundancy concept is presented in this paper. The development is based on the assumption that each axis of the sensor can fail without affecting the remaining axis. The systems reliability is investigated, the optimum redundancy configurations are proposed, a technique of sensor performance management is developed for the proposed systems.

Tsuei, Y. D.↗

Fabrication and evaluation of polymeric early-warning fire-alarm devices

The electrical resistivities were investigated of some polymers known to be enhanced by the presence of certain gases. This was done to make a device capable of providing early warning to fire through its response with the gases produced in the early phases of combustion. Eight polymers were investigated: poly(phenyl acetylene), poly(p-aminophenyl acetylene), poly(p-nitrophenyl acetylene), poly(p-formamidophenyl acetylene), poly(ethynyl ferrocene), poly(ethynyl carborane), poly(ethynyl pyridine), and the polymer made from 1,2,3,6 tetramethyl pyridazine. A total of 40 usable thin-film sandwich devices and a total of 70 usable interdigitated-electrode lock-and-key devices were fabricated. The sandwich devices were used for measurements of contact linearity, polymer conductivity, and polymer dielectric constant. The lock-and-key devices were used to determine the response of the polymers to a spectrum of gases that included ammonia, carbon nonoxide, carbon dioxide, sulfur dioxide, ethylene, acrolein, water vapor, and normal laboratory air. Strongest responses were to water vapor, ammonia, and acrolein, and depending on the polymer, weaker responses to carbon dioxide, sulfur dioxide, and carbon monoxide were observed. A quantitative theory of device operation, capable of accounting for observed device leakage current and sensitivity, was developed. A prototype detection/alarm system was designed and built for use in demonstrating sensor performance.

Senturia, S. D.↗

CAT LIDAR wind shear studies

The studies considered the major meteorological factors producing wind shear, methods to define and classify wind shear in terms significant from an aircraft perturbation standpoint, the significance of sensor location and scan geometry on the detection and measurement of wind shear, and the tradeoffs involved in sensor performance such as range/velocity resolution, update frequency and data averaging interval.

Goff, R. W.↗

A rocket ozonesonde for geophysical research and satellite intercomparison

The in-situ rocketsonde for ozone profile measurements developed and flown for geophysical research and satellite comparison is reviewed. The measurement principle involves the chemiluminescence caused by ambient ozone striking a detector and passive pumping as a means of sampling the atmosphere as the sonde descends through the atmosphere on a parachute. The sonde is flown on a meteorological sounding rocket, and flight data are telemetered via the standard meteorological GMD ground receiving system. The payload operation, sensor performance, and calibration procedures simulating flight conditions are described. An error analysis indicated an absolute accuracy of about 12 percent and a precision of about 8 percent. These are combined to give a measurement error of 14 percent.

Hilsenrath, E.↗

Considerations on real-time processing of spaceborne synthetic aperture radar data

This paper comprises a description of Synthetic Aperture Radar (SAR) processing approaches and a discussion on the processor complexity measures. The objective of the paper is to provide basic system knowledge on the design of a real-time signal processor for spaceborne synthetic aperture radar. A review of SAR sensor performance capability and general electronic processing approaches will be given first. The discussion of SAR processor complexity is divided into two areas: the arithmetic complexity and the control complexity. A generalized treatment of these subjects is provided. The results could be readily extended to special cases.

Wu, C.↗

Recent advances in remote sensing; Proceedings of the First International Geoscience and Remote Sensing Symposium, Washington, DC, June 8-10, 1981

The state of the art in remote sensing of the earth and the planets was discussed in terms of sensor performance, signal processing, and data interpretation. Particular attention was given to lidar for characterizing atmospheric particulates, the modulation of short waves by long ocean gravity waves, and runoff modeling for snow-covered areas. The use of NOAA-6 spacecraft AVHRR data to explore hydrologic land surface features, the effects of soil moisture and vegetation canopies on microwave and thermal microwave emissions, and regional scale evapotranspiration rate determination through satellite IR data are examined. A Shuttle experiment to demonstrate high accuracy global time and frequency transfer is described, along with features of the proposed Gravsat, radar image processing for rock-type discrimination, and passive microwave sensing of temperature and salinity in coastal zones.

Mcintosh, R.↗