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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 235 records · Page 13
All sourcesNASA NTRSDOE OSTI
NASA NTRS2014

Detection and Quantification of Nitrogen Compounds in the First Drilled Martian Solid Samples by the Sample Analysis at Mars (SAM) Instrument Suite on the Mars Science Laboratory (MSL)

The Sampl;e Analysis at Mars (sam) instrument suite on the Mars Science Laboratory (MSL) Curiosity Rover detected both reduced and oxidized nitrogen bearing compounds during the pyrolysis of surface materials from the three sites at Gale Crater. Preliminary detections of nitrogen species include No, HCN, ClCN, and TFMA ((trifluoro-N-methyl-acetamide), Confirmation of indigenous Martian nitrogen-bearing compounds requires quantifying N contribution from the terrestrial derivatization reagents carried for SAM's wet chemistry experiment that contribute to the SAM background. Nitrogen species detected in the SAM solid sample analyses can also be produced during laboratory pyrolysis experiments where these reagents are heated in the presence of perchlorate a compound that has also been identified by SAM in Mars solid samples.

Stern, Jennifer C.↗
NASA NTRS2017

Identification of Phyllosilicates in Mudstone Samples Using Water Releases Detected by the Sample Analysis at Mars (SAM) Instrument in Gale Crater, Mars

The Sample Analysis at Mars (SAM) instrument on board the Curiosity Rover has detected high temperature water releases from mud-stones in the areas of Yellowknife Bay, Pahrump Hills, Naukluft Plateau, and Murray Buttes in Gale crater. Dehydroxylation of phyllosilicates may have caused the high temperature water releases observed in these samples. Because each type of phyllosilicate undergoes dehydroxylation at distinct temperatures, these water releases can be used to help constrain the type of phyllosilicate present in each sample.

Hogancamp, J. V. (Clark)↗
NASA NTRS2018

High Priority Samples to Characterize the Habitability of Groundwaters and Search for Rock-Hosted Life on Mars with Sample Return

Objective 1.1 of the iMOST sample return objectives is to establish the geologic context, interpret the potential habitability, and evaluate the potential for biosignature preservation in samples from an environment hypothesized to have had elevated potential for Martian life. Here, we describe the strategies required to understand the geologic context and habitability of Martian groundwater aquifers and to search for evidence of life in the Martian subsurface using samples.

Source record↗
NASA NTRS2018

A Study of Various Beacon Antennas for an Orbiting Sample Container of a Future Mars Sample Return Mission

This paper presents some results of a study of various options for a near-omnidirectional low-gain antenna at UHF frequencies, for a Mars Orbiting Sample Return Container (OS). The OS is part of a concept study for a future mission to return samples from Mars. It would be a critical component of such a mission, which would contain the Mars samples. The notional OS would be returned by a separate spacecraft to Earth. The OS would be identified and located by the spacecraft for pick-up from orbit by a beacon signal broadcast via a surface antenna. Several antenna designs were considered, but two promising ones are presented here which have good patterns with a better than 2:1 VSWR (Voltage Standing Wave Ratio), but meet different criteria for OS design options. One is a patch-type antenna and the other a slot-type antenna. Some data and test results of a fabricated breadboard antenna as well as discussions are provided.

Jamnejad, Vahraz↗
NASA NTRS2020

Dynamic Modeling, Simulation, and Analysis of Orbiting Sample Capture for Potential Mars Sample Return

The current notional architecture for the Mars Sample Return (MSR) campaign would require autonomous on-orbit rendezvous and capture of a sample container after it has been delivered to Mars orbit by a preceding MSR mission. As part of the complete orbital payload known as the Capture, Contain, and Return System (CCRS), a concept has been developed for autonomously sensing and capturing this Orbiting Sample (OS) container. The concept, comprised of a capture mechanism and multiple optical break-beam arrays, would detect and enclose the OS into CCRS, and engage a dust-tight seal to prevent the escape of the OS or other unsterilized particles. A challenging goal for the system is to close the lid prior to the OS coming into physical contact after entering CCRS in order to reduce the risk of unsterilized Mars particles on the surface of the OS from contaminating the outside of the spacecraft. The mechanical and sensor performance requirements were driven by the broader architecture of CCRS, OS rendezvous parameters, and Planetary Protection requirements regarding the interaction and handling of the OS. The mechanism and break-beam array concepts were designed accordingly, and kinematic simulations of the mechanism’s behavior, combined with a Monte-Carlo simulation of OS rendezvous/collision behaviors and corresponding breakbeam sensor responses verify compliance.

Ishigo, Alyssa↗
DOE OSTI2015

Theoretically informed Monte Carlo simulation of liquid crystals by sampling of alignment-tensor fields

A theoretically informed coarse-grained Monte Carlo method is proposed for studying liquid crystals. The free energy functional of the system is described in the framework of the Landau-de Gennes formalism. The alignment field and its gradients are approximated by finite differences, and the free energy is minimized through a stochastic sampling technique. The validity of the proposed method is established by comparing the results of the proposed approach to those of traditional free energy minimization techniques. Its usefulness is illustrated in the context of three systems, namely, a nematic liquid crystal confined in a slit channel, a nematic liquid crystal droplet, and a chiral liquid crystal in the bulk. It is found that for systems that exhibit multiple metastable morphologies, the proposed Monte Carlo method is generally able to identify lower free energy states that are often missed by traditional approaches. Importantly, the Monte Carlo method identifies such states from random initial configurations, thereby obviating the need for educated initial guesses that can be difficult to formulate.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗
NASA NTRSDate not supplied

Sample Processor for Life on Icy Worlds (SPLIce): Monolithic Manifold-Based System to Recover, Prepare, and Deliver Samples and Standards to Instrumentation Suites for Ocean World Life-Search Missions

A claim of life detection on one of the solar system’s icy ocean worlds would necessitate extraordinarily convincing evidence. Limited energy availability in the oceans of such bodies as Europa and Enceladus argues for microbes as most probable among possible life forms, but evidence of their existence in the surface layers of an icy moon or in a frozen plume ejected into space could take various forms, pointing to instrumentation suites as a preferred means to detect diverse molecular and morphological life indicators. Multiple disparate categories of positive detections could provide truly convincing evidence from samples that may be only a few micro-liters. SPLIce’s Foundation. Teams led by NASA’s Ames Research Center have developed and operated numerous small, live-biology and astrobiology science payloads in space over two decades. Since 2016, we have adapted and augmented their biological sample-handling systems to create compact, robust search-for-life fluidic processors designed to function after a decade or more in transit, in environments with very little gravity and lots of radiation: up to 100’s of kilorads.

Instrumentation suite↗
DOE OSTI2019

Mercury Concentrations in the Two-Toed Amphiuma ( Amphiuma means ) and the Lesser Siren ( Siren intermedia ): Validating Non-lethal Sampling Methods in Southeastern Aquatic Salamanders

The global decline of amphibians is a major conservation issue. Many stressors are recognized for this decline including exposure to environmental contaminants. Mercury (Hg) is an environmental contaminant that bioaccumulates in wildlife and can cause a variety of negative impacts across taxa, including amphibians. Amphiuma and Siren spp. can comprise a large portion of biomass within their respective ecosystems, and thus, likely serve as important predators or prey in wetland communities. However, due to their cryptic nature, little is known about their ecology, diet, and accumulation potential. Here, we sought to validate a non-lethal sampling method to quantify total mercury (THg) in two enigmatic species of aquatic salamanders: the two-toed amphiuma (Amphiuma means) and the lesser siren (Siren intermedia). We examined relationships between THg content in lethal (whole-body) and non-lethal (tail clip) samples. Tail clips were significant predictors of whole body THg (all p < 0.001), explaining 84-89% of variation in whole body THg. Average whole-body THg (mg/kg did not significantly differ between the two species (p = 0.97), and overall, they had similar whole body THg content (LESI = 0.330 ± 0.04, n = 18; AMME = 0.333 ± 0.07, n = 11). To our knowledge, these data represent the first reported Hg burdens in A. means and S. intermedia.

63 RADIATION, THERMAL, AND OTHER ENVIRON. POLLUTAN↗
DOE OSTI2019

Ultra-High Resolution Elemental/Isotopic Mass Spectrometry (m/?m> 1,000,000): Coupling of the Liquid Sampling-Atmospheric Pressure Glow Discharge with an Orbitrap Mass Spectrometer for Applications in Biological Chemistry and Environmental Analysis

Many fundamental questions of astrophysics, biochemistry, and geology rely on the ability to accurately and precisely measure the mass and abundance of isotopes. Taken a step further, the capacity to perform such measurements on intact molecules provides insights into processes in diverse biological systems. Described here is the coupling of a combined atomic and molecular (CAM) ionization source, the liquid sampling-atmospheric pressure glow discharge (LS-APGD) microplasma, with a commercially available ThermoScientific Fusion Lumos mass spectrometer. Demonstrated for the first time is the ionization and isotopically-resolved fingerprinting of a long-postulated, but never mass-spectrometrically observed, bi-metallic complex Hg:Se-cysteine. Such a complex has been implicated as having a role in observations of Hg detoxification by selenoproteins/amino acids. Demonstrated as well is the ability to mass spectrometrically-resolve the geochronologically important isobaric 87Sr and 87Rb species (?m ~ 0.3 mDa, mass resolution m/?m ? 1,700,000). The mass difference in this case reflects the beta-decay of the 87Rb to the stable Sr isotope. These two demonstrations highlight what may be a significant change in bioinorganic and atomic mass spectrometry, with impact expected across a broad spectrum of the physical, biological and geological sciences.

Hoegg, Edward D.↗
DOE OSTI2015

Accelerating ab initio path integral molecular dynamics with multilevel sampling of potential surface

A multilevel approach to sample the potential energy surface in a path integral formalism is proposed. The purpose is to reduce the required number of ab initio evaluations of energy and forces in ab initio path integral molecular dynamics (AI-PIMD) simulation, without compromising the overall accuracy. To validate the method, the internal energy and free energy of an Einstein crystal are calculated and compared with the analytical solutions. As a preliminary application, we assess the performance of the method in a realistic model—the FCC phase of dense atomic hydrogen, in which the calculated result shows that the acceleration rate is about 3 to 4-fold for a two-level implementation, and can be increased up to 10 times if extrapolation is used. With only 16 beads used for the ab initio potential sampling, this method gives a well converged internal energy. The residual error in pressure is just about 3 GPa, whereas it is about 20 GPa for a plain AI-PIMD calculation with the same number of beads. The vibrational free energy of the FCC phase of dense hydrogen at 300 K is also calculated with an AI-PIMD thermodynamic integration method, which gives a result of about 0.51 eV/proton at a density of r{sub s}=0.912.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗