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At least 235 records · Page 13
All sourcesNASA NTRSDOE OSTI
NASA NTRS1971

Raman scattering studies of pollutant systems.

Results and techniques for laboratory measurements of Raman scattering cross sections and depolarization ratios of atmospheric gases as a function of the incident photon energy are discussed. Referred to N2, the cross section of H2O changes by a factor of 2 as the incident photon energy is changed by 5%. Less striking results are obtained for SO2, NO and other atmospheric gases. Tentative results are given for spectral features of scattering from polluted air-water interfaces. Raman lidar is assessed as a potentially useful aid in remote sensing of atmospheric and water-borne pollution distributions at least in near-source concentrations.

Schwiesow, R. L.↗
NASA NTRS1973

Atmospheric temperature measurements by Raman laser scattering

System makes continuous synoptic measurement of air temperatures and temperature profiles from the ground in real time. Development is based on principle that intensity distribution of Raman scattered laser light is a function of temperature and it is theoretically possible to measure air temperature by analyzing its Raman spectrum.

Masica, W. J.↗
NASA NTRS1973

Determination of the temperature of gas mixtures by using laser Raman scattering

A theoretical model for the Raman rotational spectrum of air was formulated, yielding the spectral temperature dependence; and an error analysis of temperature measurement accuracies was performed. The theoretical spectra and the predicted temperature measurement error of + or - 20 K (7 percent) compared well with experimental data. These experimental data consisted of Raman spectra of air obtained for temperatures ranging from 243 to 313 K at a pressure of 1 atmosphere. The use of selected lines resulted in an experimental accuracy of + or - 13 K (-5 percent).

Coney, T. A.↗
NASA NTRS1973

Remote measurement of atmospheric temperatures by Raman lidar

The Raman shifted return of a lidar system was utilized to make atmospheric temperature measurements. The measurements were made along a horizontal path at temperatures between -20 and +30 C and at ranges of about 100 meters. The temperature data were acquired by recording the intensity ratio of two portions of the rotational Raman spectrum which were simultaneously sampled from a preset range. Measurements were made to an accuracy of + or - 3 C with 1 minute temporal resolution.

Salzman, J. A.↗
NASA NTRS1972

Structure of lunar glasses by Raman and soft X-ray spectroscopy.

X-ray spectra and Raman spectra have been measured from individual particles of lunar glasses. Each particle was analyzed separately by electron microprobe. Silicon emission shifts vary between parent rock types and can be interpreted as a range of Si-O distances from 1.612 to 1.637 A. Aluminum emission shifts relate to the amount of 4- and 6-coordinated Al in the glass. Raman spectra show broadened bands. Certain bands recur in many specimens and relate to the main normative minerals for the glass bulk composition, olivine, pyroxene, and anorthite.

Fabel, G. W.↗
NASA NTRS1973

Remote measurement of atmospheric temperatures by Raman lidar.

The Raman shifted return of a lidar system has been utilized to make atmospheric temperature measurements. The measurements were made along a horizontal path at temperatures between -20 and +30 C and at ranges of about 100 meters. The temperature data were acquired by recording the intensity ratio of two portions of the rotational Raman spectrum which were simultaneously sampled from a preset range. Measurements were made to an accuracy of plus or minus 3 C with 1-minute temporal resolution.

Salzman, J. A.↗
NASA NTRS1974

Atmospheric temperature measurements, using Raman lidar

The Raman-shifted return of a lidar system had been used to make atmospheric temperature measurements. The measurements were made along a horizontal path at temperatures ranging from -30 to 30 C and at ranges of about 100 meters. The temperature data were acquired by recording the intensity ratio of two portions of the rotational Raman spectrum, which were simultaneously sampled from a preset range. These tests verified that the theoretical predictions formulated in the design of the system were adequate. Measurements were made to an accuracy of + or - 4 C with 1-minute temporal resolution.

Salzman, J. A.↗
NASA NTRS1973

Raman scattering applied to gas mixing in the successive channel flow of two gases

The Raman scattering technique has been applied to investigate the effects of fluid undercutting in a simulation of the fluid-piston concept for wind-tunnel design. Measurements of the structure of the driver-driven gas interface and of the effect of undercutting on test duration were performed. Tests were conducted over a Froude number range of 0.0021 to 0.526 at driver-to-driven gas density ratios of 1.103 and 1.573. The effects of inlet design, test-channel inclination angle, and pretest pressurization were also examined. The results are compared with shadowgraph and pressure measurements to illustrate the characteristics of the Raman technique and to explain the discrepancy between the shadowgraph and pressure results.

Hillard, M. E., Jr.↗
NASA NTRS1974

Raman scattering applied to hypersonic air flow

The Raman scattering technique was applied to measure the local static temperature and gas number density over a sharp-edge flat-plate model in a Mach 5 nozzle of the Langley nozzle test chamber with air as the test gas. The angle of attack varied from -5 to 15 deg, and the stagnation temperature varied from 317 to 442 K, with stagnation pressures ranging from 170 kN to 2.8 MN/sq m. The measured values of static temperature and density ranged from 60 to 100 K and from 0.03 to 0.8 kg/cu m, respectively. A comparison with calculated values based on static pressure measurements along the model shows that the Raman scattering technique is a viable measurement method in applications to high-speed three-dimensional flows.

Hillard, M. E., Jr.↗
NASA NTRS1975

A tunable line filter polychromator for gas temperature measurements using laser Raman scattering

A proprietary laser line filter spectrograph (LLFS) was modified to test for improved remote measurement of atmospheric temperature by Raman spectroscopy of the rotational bands of N2 and O2. Both grating scan measurements with fixed PMT and polychromator image plane PMT scans with fixed grating setting were made using HeNe and Ar(+) lasers. The LLFS was found to have a laser line rejection ratio at 6A from the laser line and provides resolved rotational Raman spectral display at the polychromator exit plane. Spectral resolution is adequate to measure and correct for background in the Stokes spectrum. It is anticipated that this system should allow measurement of gas or atmospheric temperature to + or - 1 C.

Grossman, J. J.↗
NASA NTRS1974

Pre-resonance Raman spectra of some simple gases

The pre-resonance Raman spectra of SO2, N2O, and H2S were investigated using the 4880 A, 4727 A, and 4579 A lines of the argon ion laser. Although these molecules have electronic absorption bands in the near ultraviolet, none exhibit any pre-resonance enhancement within our experimental error of + or - 10%. Possible explanations taking into account the current theories for resonance Raman are discussed.

Low, P. W.↗
NASA NTRS1974

Remote measurement of atmospheric temperatures by Raman lidar

The Raman shifted return of a lidar system has been utilized to make atmospheric temperature measurements. The measurements were made along a horizontal path at temperatures ranging from -30 C to +30 C and at ranges of about 100 meters. The temperature data were acquired by recording the intensity ratio of two portions of the rotational Raman spectrum which were simultaneously sampled from a preset range. A temperature measurement accuracy of plus or minus 4 C and a temporal resolution of one minute were realized with this system. The combined results of the theoretical analysis and the experimentation indicate that system improvements will significantly increase both accuracy and range.

Coney, T. A.↗
NASA NTRS1975

A theoretical/experimental program to develop active optical pollution sensors: Quantitative remote Raman lidar measurements of pollutants from stationary sources

Typical pollutant gas concentrations at the stack exits of stationary sources can be estimated to be about 500 ppm under the present emission standards. Raman lidar has a number of advantages which makes it a valuable tool for remote measurements of these stack emissions. Tests of the Langley Research Center Raman lidar at a calibration tank indicate that night measurements of SO2 concentrations and stack opacity are possible. Accuracies of 10 percent are shown to be achievable from a distance of 300 m within 30 min integration times for 500 ppm SO2 at the stack exits. All possible interferences were examined quantitatively (except for the fluorescence of aerosols in actual stack emissions) and found to have negligible effect on the measurements. An early test at an instrumented stack is strongly recommended.

Poultney, S. K.↗
NASA NTRS1977

On probing the outer planets with the Raman effect

The paper examines the feasibility of using the H2 rotational Raman spectrum to study the physical structure of the atmospheres of the outer planets. Computations of the strengths of the S(0) and S(1) lines are made for a wide range of physical conditions on the basis of a semi-infinite homogeneous pure H2 atmospheric model. Initial applications of the Raman probe technique to Jupiter and Uranus are reported.

Price, M. J.↗
NASA NTRS1977

Quantitative remote measurements of pollutants from stationary sources using Raman lidar

The several advantages of Raman lidar for remote measurements of stationary source emissions were quantitatively evaluated using a calibration tank at a distance of 300 m at night. Measurements of approximately 10 to the 3rd ppm SO2 with a 12% accuracy were demonstrated in an observation time of 15 min using a 1.5-J ruby laser at 30 pulses/min, 6-m range resolution, interference filters, photon counting detection, and a 20-cm receiver. Measurement accuracy was checked by measuring known concentrations of SO2 in the tank, by tuning the interference filters through the SO2 Raman line, and by varying the CO2 concentration to very high levels during the SO2 measurements. Evaluation of the seriousness of induced fluorescence from plume aerosols failed due to the inability to simulate the plume aerosols.

Poultney, S. K.↗
NASA NTRS1979

Remote sensing of subsurface water temperature by Raman scattering

The application of Raman scattering to remote sensing of subsurface water temperature and salinity is considered, and both theoretical and experimental aspects of the technique are discussed. Recent experimental field measurements obtained in coastal waters and on a trans-Atlantic/Mediterranean research cruise are correlated with theoretical expectations. It is concluded that the Raman technique for remote sensing of subsurface water temperature has been brought from theoretical and laboratory stages to the point where practical utilization can now be developed.

Leonard, D. A.↗
NASA NTRS1981

Raman scattering in the Jovian atmosphere

On December 8 and 9, 1976, the 1024 channel Reticon silicon photodiode array detector in the coude spectrograph of a 2.7 m telescope was used to obtain spectra of Jupiter and the moon. Three separate data sets were obtained, including one of the Jovian equatorial region, one of the Jovian north polar cap, and one of Mare Serenetatis on the moon. A correlation analysis was conducted. The autocorrelation function of the Jovian spectrum was calculated and the autocorrelation function of the lunar spectrum was subtracted from it. The analysis made it possible to detect Raman scattering by H2 in the atmosphere of Jupiter. The pure rotational H2 S(0) and S(1) lines were detected. The ratio of the relative number of Raman scattered photons in the S(0) and S(1) features indicate that the H2 in the Jovian atmosphere is in the equilibrium, rather than the normal state. Therefore some sort of nonradiative process is responsible for transitions between the ortho and para states of H2.

Cochran, W. D.↗
NASA NTRS1981

Observation and measurement of molecular flow using stimulated Raman gain spectroscopy

The observation and measurement of frequency shifts in stimulated Raman gain spectroscopy resulting from subsonic molecular nitrogen flows emerging from a simple nozzle are reported. The flow velocity in the region of the measurement was determined to be 145 m/s with an accuracy of plus or minus 30 m/s. It is expected that significantly better flow-velocity resolution will be obtained in future experiments using inverse Raman scattering.

Herring, G. C.↗