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At least 235 records · Page 13

Bedroom Concentrations and Emissions of Volatile Organic Compounds during Sleep

Because humans spend about one-third of their time asleep in their bedrooms and are themselves emission sources of volatile organic compounds (VOCs), it is important to specifically characterize the composition of the bedroom air that they experience during sleep. This work uses real-time indoor and outdoor measurements of volatile organic compounds (VOCs) to examine concentration enhancements in bedroom air during sleep and to calculate VOC emission rates associated with sleeping occupants. Gaseous VOCs were measured with proton-transfer reaction time-of-flight mass spectrometry during a multiweek residential monitoring campaign under normal occupancy conditions. Results indicate high emissions of nearly 100 VOCs and other species in the bedroom during sleeping periods as compared to the levels in other rooms of the same residence. Air change rates for the bedroom and, correspondingly, emission rates of sleeping-associated VOCs were determined for two bounding conditions: (1) air exchange between the bedroom and outdoors only and (2) air exchange between the bedroom and other indoor spaces only (as represented by measurements in the kitchen). VOCs from skin oil oxidation and personal care products were present, revealing that many emission pathways can be important occupant-associated emission factors affecting bedroom air composition in addition to direct emissions from building materials and furnishings.

54 ENVIRONMENTAL SCIENCES↗

Do not forget the electrons: Extending moderately-sized nuclear networks for multidimensional hydrodynamic codes

Context.Nuclear networks are widely used coupled with hydrodynamical simulations of explosive scenarios to account for the change of nuclear species and energy generation rate due to nuclear reactions. In this way, there is a feedback mechanism between the hydrodynamical state and the nuclear processes. Unfortunately, the timescale of nuclear reactions is orders of magnitude smaller than the dynamical timescale that drives hydrodynamical simulations. Therefore, these nuclear networks are usually very small, reduced in most cases to a dozen elements, especially when simulations are carried out in more than one dimension. Aims.We present here an extended nuclear network, with 90 species, designed for being coupled with hydrodynamic simulations, which includes neutrons, protons, electrons, positrons, and the corresponding neutrino and anti-neutrino emission. This network is also coupled with temperature, making it extremely robust and, together with its size, unique of its kind. The inclusion of electron captures on free protons makes the network very appropriate for multidimensional studies of Type Ia supernova explosions, especially when the exploding object is a massive white dwarf. Methods.We perform several tests that are relevant to simulate explosive scenarios, such as Type Ia supernovae and core-collapse supernovae. We compare the results of the 90 nuclei network with a standardα-chain network with 14 elements to evaluate the differences in the energy generation rate. We also evaluate the relevance of including the electrons in the network in terms of generated yields and how it affects the pressure of a degenerate fluid such as that of white dwarfs. The results obtained with the 90-nuclei network have been verified with a much larger 2000-nuclei network built from REACLIB (WinNet), in terms of nuclear energy generation rate, pressure, and produced yields. Results.The results obtained with the proposed medium-sized network compare fairly well, to a few percent, with those computed withWinNetin scenarios reproducing the gross physical conditions of current Type Ia supernova explosion models. In those cases where the carbon and oxygen fuel ignites at high density, the high-temperature plateau typical of the nuclear statistical equilibrium regime is well defined and stable, allowing large integration time steps. We show that the inclusion of electron captures on free protons substantially improves the estimation of the electron fraction of the mixture. Therefore, the pressure is better determined than in networks where electron captures are excluded, which will ultimately lead to more reliable hydrodynamic models. Explosive combustion of helium at low density, occurring near the surface layer of a white dwarf, is also better described with the proposed network, which gives nuclear energy generation rates much closer toWinNetthan typical reduced alpha networks. Conclusions.A nuclear network withN= 90 species, including electrons, aimed at multidimensional calculations of supernova explosions is described and verified. The proposed network is suitable for the study of Type Ia supernova explosions because it provides better values of pressure and electron abundance than other existing networks with smaller or even a similar size but without including electron capture processes.

Astronomy & Astrophysics↗

Electrostatic electron and ion cyclotron harmonic waves in Neptune's magnetosphere

Voyager 2 observations of electrostatic electron and ion cyclotron waves detected in Neptune's magnetosphere are presented. Both types of emission appear in a frequency band above the electron and ion (proton) cyclotron frequencies, respectively, and are tightly confined to the magnetic equator occurring within a few degrees of it. The electron cyclotron modes including an intense upper hybrid resonance emission excited by an unstable loss cone distribution of low-density superthermal electrons. The ion cyclotron waves are interpreted as hydrogen Bernstein modes including an intense lower hybrid resonance emission excited by an unstable ring distribution of low-density pickup N(+) ions deriving from the satellite Triton.

Barbosa, D. D.↗

Global properties of nuclei at finite-temperature within the covariant energy density functional theory

In stellar environments nuclei appear at finite temperatures, becoming extremely hot in core-collapse supernovae and neutron-star mergers. However, due to theoretical and computational complexity, most model calculations of nuclear properties are performed at zero temperature, while those existing at finite temperatures are limited only to selected regions of the nuclide chart. In this study we perform the global calculation of nuclear properties for even-even 8 ≤ Z ≤ 104 nuclei at temperatures in range 0 ≤ T ≤ 2 MeV. Calculations are based on the finite-temperature relativistic Hartree-Bogoliubov model supplemented by the Bonche-Levit-Vautherin vapor subtraction procedure. We find that near the neutron-drip line the continuum states have significant contribution already at moderate temperature T ≈ 1 MeV, thus emphasizing the necessity of the vapor subtraction procedure. Results include neutron emission lifetimes, quadrupole deformations, neutron-skin thickness, proton and neutron pairing gaps, entropy and excitation energy. Up to the temperature T ≈ 1 MeV, the nuclear landscape is influenced only moderately by the finite-temperature effects, mainly by reducing the pairing correlations. Here, as the temperature increases further, the effects on nuclear structures become pronounced, reducing both the deformations and the shell effects.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗

Energetic particles as a source of flare energy

The production of solar flares by the reservoir of energy generated by sunspot magnetic fields is discussed. Electrons play an important part in the flare process since high energy electrons are responsible for X-ray and radio emission. The energy required in the form of protons trapped in sunspot magnetic fields to produce large solar flares is analyzed. A trigger mechanism is described where the particles can be rapidly dumped into the chromosphere when fast electrons are produced by Coulomb collisions and through pion production by the highest energy protons.

Elliot, H.↗

Upwelling O(+) ion source characteristics

The characteristics of an upwelling ion source are discussed. A typical upwelling event is analyzed using Dynamic Explorer 1 satellite retarding ion mass spectrometer (RIMS) observations of the low-energy plasma, and energetic ion and local electromagnetic field observations. The RIMS spectrograms of the O(+) ion species, radial and axial head data for O(+), and spin plan O(+) distribution functions are examined. The features of the upwelling observed include: (1) transverse ion heating to temperature of 100,000 K, (2) large outward flows of O(+), (3) enhanced flow of H(+) and He (+), (4) moderately strong field-aligned current sheets, (5) an associated intense eastward convection channel, and (6) strong wave emissions in the range near and below the proton gyrofrequency. The association between the upwelling O(+) signature and auroral current is investigated. Plasma wave and electric field environments are studied and plasma flows and densities are derived. It is noted that the mechanism for ion heating which defines the source region for these polar ion outflows is related to field-aligned currents and an associated auroral convection channel or jet.

Moore, T. E.↗

Helium destruction and gamma-ray line emission in accreting neutron stars

The prevalent gamma-ray production channel of a neutron star - emission of 2.2-MeV photons from neutron-proton recombination - is reconsidered. The 2.2-MeV gamma-ray line flux and Compton-scattered continuum are calculated. The flux of gravitationally redshifted 2.2-MeV photons from the brightest accreting X-ray source Scorpius X-1 is about 10 exp -6 gamma/sq cm s, a factor of 20 below the sensitivities on the Compton Gamma-Ray Observatory. The destruction of accreted He-4 leads to significant abundances of lighter elements (D, H-3, He-3) in the upper atmosphere, which are determined. The destroyed He-4 is reformed through fusion reactions a few scale heights beneath the photosphere, and thus does not hamper H-ray bursts.

Bildsten, Lars↗

Comparing Solar-Flare Acceleration of >-20 MeV Protons and Electrons Above Various Energies

A large fraction (up to tens of percent) of the energy released in solar flares goes into accelerated ions and electrons, and studies indicate that these two populations have comparable energy content. RHESSI observations have shown a striking close linear correlation between the 2.223 MeV neutron-capture gamma-ray line and electron bremsstrahlung emission >300 keV, indicating that the flare acceleration of >^20 MeV protons and >300 keV electrons is roughly proportional over >3 orders of magnitude in fluence. We show that the correlations of neutron-capture line fluence with GOES class or with bremsstrahlung emission at lower energies show deviations from proportionality, primarily for flares with lower fluences. From analyzing thirteen flares, we demonstrate that there appear to be two classes of flares with high-energy acceleration: flares that exhibit only proportional acceleration of ions and electrons down to 50 keV and flares that have an additional soft, low-energy bremsstrahlung component, suggesting two separate populations of accelerated electrons. We use RHESSI spectroscopy and imaging to investigate a number of these flares in detail.

Shih, Albert Y.↗

Gamma-ray and microwave evidence for two phases of acceleration in solar flares

Relativistic electrons in large solar flares produce gamma ray continuum by bremsstrahlung and microwave emission by gyrosynchrotron radiation. Using observations of the 1972, August 4 flare, the electron spectrum and the physical properties of the common emitting region of these radiations were evaluated. Information was also obtained on energetic protons in this flare by using gamma ray lines. From the electron spectrum, the proton-to-electron ratio, and the time dependences of the microwave emission, the 2.2 MeV line and the gamma ray continuum, it was concluded that in large solar flares relativistic electrons and energetic nuclei are accelerated by a mechanism which is different from the mechanism which accelerates approximately less than 100 keV electrons in flares.

Bai, T.↗

Inferring relative dose-dependent color center populations in proton irradiated thoria single crystals using optical spectroscopy

In this work, we have utilized photoluminescence spectroscopy and optical ellipsometry to characterize the dose-dependence of the photoluminescence emission intensity and changes in optical absorption of thoria single crystals subject to irradiation with energetic protons at room- and elevated-temperatures. The photoluminescence peaks and the optical absorption bands are attributed to creation of new electronic states emerging from defects resulting from displacement damage. These bands are most likely associated with electrons trapped at the oxygen vacancy sites similar to color centers formed in other irradiated oxides and halides. Our experimental observations are supported by a standard density functional theory calculation of the electronic structure in pristine and oxygen vacancy-bearing thoria crystals. The dose-dependence of the intensity of the photoluminescence peaks is used to parameterize a rate theory model that estimates the concentration of color centers in the irradiated crystals. This parameterization provides optimized migration barrier parameters for oxygen interstitials and vacancies that simultaneously capture the optical response of the crystals irradiated at room- and elevated-temperature. These optical spectroscopy techniques offer a promising pathway to characterize the population of color centers formed at the sites of oxygen anion vacancies, particularly in irradiated nuclear fuels, where atomic-level defects cannot be readily imaged using electron microscopy. When combined with other direct and indirect characterization tools, our approach can provide new insight into defect formation and accumulation in energy materials over single atomic to extended length scales.

36 MATERIALS SCIENCE↗

Gamma-ray and microwave evidence for two phases of acceleration in solar flares

Relativistic electrons in large solar flares produce gamma-ray continuum by bremsstrahlung and microwave emission by gyrosynchrotron radiation. Using observations of the August 4, 1972, flare, a detailed evaluation is made of the electron spectrum and the physical properties (density, magnetic field, size, and temperature) of the common emitting region of these radiations. Information is also obtained on energetic protons in this flare by using gamma-ray lines. From the electron spectrum, the proton-to-electron ratio, and the time dependences of the microwave emission, the 2.2-MeV line, and the gamma-ray continuum, it is concluded that relativistic electrons and energetic nuclei are accelerated in large solar flares by a mechanism which is different from the mechanism which accelerates electrons with energies not exceeding about 100 keV in flares.

Bai, T.↗

A three dimensional dynamic study of electrostatic charging in materials

A description is given of the physical models employed in the NASCAP (NASA Charging Analyzer Program) code, and several test cases are presented. NASCAP dynamically simulates the charging of an object made of conducting segments which may be entirely or partially covered with thin dielectric films. The object may be subject to either ground test or space user-specified environments. The simulation alternately treats (1) the tendency of materials to accumulate and emit charge when subject to plasma environment, and (2) the consequent response of the charged particle environment to an object's electrostatic field. Parameterized formulations of the emission properties of materials subject to bombardment by electrons, protons, and sunlight are presented. Values of the parameters are suggested for clean aluminum, Al2O3, clean magnesium, MgO, SiO2 kapton, and teflon. A discussion of conductivity in thin dielectrics subject to radiation and high fields is given, together with a sample calculation.

Katz, I.↗

Interplanetary particle beams

This paper reviews observations of interplanetary particle beams of the kind that frequently accompany a solar flare. It is shown that the most frequently observed beams are beams of electrons which are associated with radio bursts of type III, but occasionally with flares and X-ray bursts. Although the main features of these beams and their associated plasma waves and radio bursts are known, uncertainties remain in terms of the correlation between electron beams and filamentary structures, the relative importance of the quasi-linear and the nonlinear wave emissions as the dominant process, and the mechanism of conversion of some of the Langmuir wave energy into radio emissions. Other particle beams discussed are those composed of protons, neutrons, He ions, or heavy ions. While most of these beams originate from sun flares, the source of some of particle beams may be the earth, Jupiter, or other planets as well as comets.

Dulk, G. A.↗

The EPIC-MOS Particle-Induced Background Spectrum

We have developed a method for constructing a spectrum of the particle-induced instrumental background of the XMM-Newton EPIC MOS detectors that can be used for observations of the diffuse background and extended sources that fill a significant fraction of the instrument field of view. The strength and spectrum of the particle-induced background, that is, the background due to the interaction of particles with the detector and the detector surroundings, is temporally variable as well as spatially variable over individual chips. Our method uses a combination of the filter-wheel-closed data and a database of unexposed-region data to construct a spectrum of the "quiescent" background. We show that, using this method of background subtraction, the differences between independent observations of the same region of "blank sky" are consistent with the statistical uncertainties except when there is clear evidence of solar wind charge exchange emission. We use the blank sky observations to show that contamination by SWCX emission is a strong function of the solar wind proton flux, and that observations through the flanks of the magnetosheath appear to be contaminated only at much higher solar wind fluxes. We have also developed a spectral model of the residual soft proton flares, which allows their effects to be removed to a substantial degree during spectral fitting.

Kuntz, K. D.↗

Tanami Blazars in the IceCube Pev Neutrino Fields

The IceCube Collaboration has announced the discovery of a neutrino flux in excess of the atmospheric background. Owing to the steeply falling atmospheric background spectrum, events at PeV energies most likely have an extraterrestrial origin. We present the multiwavelength properties of the six radio-brightest blazars that are positionally coincident with these events using contemporaneous data of the TANAMI blazar sample, including high-resolution images and spectral energy distributions. Assuming the X-ray to γ-ray emission originates in the photoproduction of pions by accelerated protons, the integrated predicted neutrino luminosity of these sources is high enough to explain the two detected PeV events.

TANAMI↗

Nuclear gamma rays and interplanetary proton events

From February 1980 - February 1982, the Gamma Ray Spectrometer on the Solar Maximum Mission satellite observed the impulsive phases of sixteen western hemisphere flares that were associated with prompt solar proton events. Six of these flares had a detectable excess in the 4-8 MeV window and four others had detectable continuum emission above 300 keV. As indicated in earlier studies based on fewer events, a lack of correlation is found between the peak 10 MeV near-earth proton fluxes and prompt gamma-ray-line fluences. The two largest proton events in the sample did not have detectable emission above 300 keV. For the 9 December event, an upper limit for the density of the ion acceleration region of 8 billion/cu cm or less is obtained for an acceleration time constant of 1500 s.

Cliver, E. W.↗