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At least 235 records · Page 13

GRCop-84 Rolling Parameter Study

This report is a section of the final report on the GRCop-84 task of the Constellation Program and incorporates the results obtained between October 2000 and September 2005, when the program ended. NASA Glenn Research Center (GRC) has developed a new copper alloy, GRCop-84 (Cu-8 at.% Cr-4 at.% Nb), for rocket engine main combustion chamber components that will improve rocket engine life and performance. This work examines the sensitivity of GRCop-84 mechanical properties to rolling parameters as a means to better define rolling parameters for commercial warm rolling. Experiment variables studied were total reduction, rolling temperature, rolling speed, and post rolling annealing heat treatment. The responses were tensile properties measured at 23 and 500 C, hardness, and creep at three stress-temperature combinations. Understanding these relationships will better define boundaries for a robust commercial warm rolling process. The four processing parameters were varied within limits consistent with typical commercial production processes. Testing revealed that the rolling-related variables selected have a minimal influence on tensile, hardness, and creep properties over the range of values tested. Annealing had the expected result of lowering room temperature hardness and strength while increasing room temperature elongations with 600 C (1112 F) having the most effect. These results indicate that the process conditions to warm roll plate and sheet for these variables can range over wide levels without negatively impacting mechanical properties. Incorporating broader process ranges in future rolling campaigns should lower commercial rolling costs through increased productivity.

Loewenthal, William S.↗

Stopping powers and cross sections due to two-photon processes in relativistic nucleus-nucleus collisions

The effects of electromagnetic-production processes due to two-photon exchange in nucleus-nucleus collisions are discussed. Feynman diagrams for two-photon exchange are evaluated using quantum electrodynamics. The total cross section and stopping power for projectile and target nuclei of identical charge are found to be significant for heavy nuclei above a few GeV per nucleon-incident energy.

Cheung, Wang K.↗

Development of processes for the production of solar grade silicon from halides and alkali metals

High temperature reactions of silicon halides with alkali metals for the production of solar grade silicon in volume at low cost were studied. Experiments were performed to evaluate product separation and collection processes, measure heat release parameters for scaling purposes, determine the effects of reactants and/or products on materials of reactor construction, and make preliminary engineering and economic analyses of a scaled-up process.

Dickson, C. R.↗

Development of processes for the production of solar grade silicon from halides and alkali metals, phase 1 and phase 2

High temperature reactions of silicon halides with alkali metals for the production of solar grade silicon are described. Product separation and collection processes were evaluated, measure heat release parameters for scaling purposes and effects of reactants and/or products on materials of reactor construction were determined, and preliminary engineering and economic analysis of a scaled up process were made. The feasibility of the basic process to make and collect silicon was demonstrated. The jet impaction/separation process was demonstrated to be a purification process. The rate at which gas phase species from silicon particle precursors, the time required for silane decomposition to produce particles, and the competing rate of growth of silicon seed particles injected into a decomposing silane environment were determined. The extent of silane decomposition as a function of residence time, temperature, and pressure was measured by infrared absorption spectroscopy. A simplistic model is presented to explain the growth of silicon in a decomposing silane enviroment.

Dickson, C. R.↗

Emerging Technologies for Decarbonizing Silicon Production

Abstract Silicon (Si) is an important material for alloying, solar photovoltaics, and electronics. However, current methods of producing silicon require energy consumption of around 11–13 kWh/kg Si and direct carbon emissions are 4.7–5 tons CO 2 per ton Si which conflicts with global efforts to limit climate change. In this work, we discuss several promising methods for reducing or eliminating carbon emissions from the silicon production process. Such methods include using biocarbon, integrating the current process with carbon capture and utilization/storage (CCU/CCS), metallothermic reduction, hydrogen reduction, and molten salt electrolysis. We present the positive aspects and challenges of each approach. Biocarbon coupled with CCU/CCS is the most industrially mature technology and can be carbon–neutral or -negative but is not carbon-free. Hydrogen directly reducing silicon dioxide is not thermodynamically favorable, but it may be viable to use hydrogen in conjunction with other processes to reduce emissions. Metallothermic and electrochemical methods of production are promising and have the potential to create high-purity silicon with no reduction-related carbon emissions but have only been demonstrated at lab scale. Economic viability will likely be the next determining factor for which technologies are more widely researched and implemented. Graphical Abstract

08 HYDROGEN↗

Comparing first- and second-generation bioethanol by-products from sugarcane: Impact on soil carbon and nitrogen dynamics

The first- and second-generation bioethanol by-products (bagasse and fermentation by-product, respectively) have different biochemical characteristics relating to carbon (C) and nitrogen (N) due to their production processes. To examine the impacts of fermentation by-product and bagasse on soil C and N dynamics, a 120 day laboratory incubation experiment was conducted by applying these amendments in soil at an equal carbon application rate (2.2 g C kg -1 soil). There was a significant increase in overall cumulative CO 2 -C production from amended soil compared to the control soil, though the loss was greatest in bagasse amended soil. However, δ13C-CO 2 measurements suggested that fermentation by-product addition suppressed native soil C mineralization and prompted strong negative C priming (-57%). In contrast, bagasse amendment maintained similar native soil C mineralization to control soil. Decreased microbial biomass turnover time appears to be the major driving force for increased CO 2 -C production and soil C loss following bioethanol by-product amendments. Increased mineral N production indicated net N mineralization after fermentation by-product addition, while addition of bagasse resulted in lower N availability and N immobilization. Overall, results suggested that fermentation by-product application is advantageous in maintaining native soil C stock and N mineralization compared to bagasse. Thus, in a sustainable second-generation bioethanol production system, bagasse may be used for second-generation bioethanol production and the cogenerated by-product could be used as an amendment to improve soil C stock and N availability.

09 BIOMASS FUELS↗

Switchgrass Steroidal Saponins Reduce Fungal Disease but Decrease Yeast Fermentation Yield

Increasing the production of bioproducts from lignocellulosic feedstocks requires improvement in both field production and biorefinery efficiency. When plant traits arise that improve field production but decrease biofuel yield, these trade-offs can represent challenges in the entire production process. To examine trade-offs between field and production traits, we examined factors underlying switchgrass resistance to fungal rust pathogens in field conditions and factors that impede yeast fermentation in the lab using repeated measurements on a switchgrass genetic diversity panel. We found that the same switchgrass genotypes that showed high fungal pathogen resistance also showed recalcitrance to yeast fermentation. These switchgrass genotypes were mostly from the Atlantic genetic group, which had high levels of specialized metabolites of the saponin class. Among 1589 metabolites identified through metabolomics, we found that saponins were among the most likely to explain variation in both rust infection and fermentation yield using random forest feature selection, and that only four of these were sufficient to explain 57.9% of the variation in rust susceptibility. Through follow-up testing in recalcitrant biomass, we found that the bacterium Zymomonas mobilis does not suffer the same inhibition as the yeast Saccharomyces cerevisiae, and that the addition of ergosterol (thought to be the fungal cellular target of saponin inhibition) rescues yeast fermentation. Several lines of evidence point to a central role for saponins as key metabolites protecting switchgrass from fungal pathogens and interfering with yeast fermentation, underscoring an ongoing need for collaboration between plant breeders and biofuel production scientists.

VanWallendael, Acer [North Carolina State Universi↗

Solar thermochemical process interface study

The design and analyses of a subsystem of a hydrogen production process are described. The process is based on solar driven thermochemical reactions. The subject subsystem receives sulfuric acid of 60% concentration at 100 C, 1 atm pressure. The acid is further concentrated, vaporized, and decomposed (at a rate of 122 g moles/sec H2SO4) into SO2, O2, and water. The produce stream is cooled to 100 C. Three subsystem options, each being driven by direct solar energy, were designed and analyzed. The results are compared with a prior study case in which solar energy was provided indirectly through a helium loop.

Source record↗

A Comparison of the GPROF Algorithm Results in the 2A-CLIM and 2A Data Products

The GPROF algorithm is used to retrieve precipitation values from all the GPM mission partner radiometers (i.e. GMI, MHS, ATMS, SSMIS, AMSR2). GPM produces two precipitation retrieval products (processing at level 2) using the GPROF algorithm. One has the type designation 2A and the other the designation 2A-CLIM. As a result understanding the difference between the two products is important for using and understanding them. Both of these GPROF products use exactly the same algorithm and a-priori databases. The only difference between the two types is the ancillary products used in the initial processing step. In the case of the 2A-CLIM products, ECMWF ERA-I is used as ancillary data. In the case of the 2A products, JMA's GANAL product is used as ancillary data. This presentation will provide a comparison between the two products using zonal mean comparisons. It will provide comparisons separately for land and ocean retrievals. It will compare the GMI differences over the entire current GPM mission life. As the only difference between the two products is the ancillary information used to create them, the comparison provides an elementary sensitivity study of the variables used from the reanalysis products and their impact on the GPROF retrieval. The purpose of the presentation is to provide users with an insight into the two GPROF products and provide them key information useful when using either of the products in scientific studies. Lastly, the presentation also discusses the reasons why only the 2A-CLIM product can be produced for the 17+ years of TRMM era data products.

GPM↗

Rapid Characterization Tools for Process Optimization: Cooperative Research and Development (Final Report)

In this project Prenexus Health, Inc. (Prenexus) and NLR will develop rapid characterization tools to improve the Prenexus production process. First, we will develop a tool to predict the overall performance of the Prenexus manufacturing process converting high-fiber sugarcane to xylo-oligosaccharides (XOS) (both the overall process yield and the composition of the XOS product) using rapid characterization of the incoming feedstock and knowledge of key process parameters. This tool will dramatically increase Prenexus’ understanding of the overall process. Second, we will develop a tool to predict the concentration of soluble oligomeric and monomeric xylose and organic acids in multiple process streams at-line in the Prenexus process, enabling real-time process control of the conversion process.

09 BIOMASS FUELS↗

Software Engineering Laboratory (SEL) cleanroom process model

The Software Engineering Laboratory (SEL) cleanroom process model is described. The term 'cleanroom' originates in the integrated circuit (IC) production process, where IC's are assembled in dust free 'clean rooms' to prevent the destructive effects of dust. When applying the clean room methodology to the development of software systems, the primary focus is on software defect prevention rather than defect removal. The model is based on data and analysis from previous cleanroom efforts within the SEL and is tailored to serve as a guideline in applying the methodology to future production software efforts. The phases that are part of the process model life cycle from the delivery of requirements to the start of acceptance testing are described. For each defined phase, a set of specific activities is discussed, and the appropriate data flow is described. Pertinent managerial issues, key similarities and differences between the SEL's cleanroom process model and the standard development approach used on SEL projects, and significant lessons learned from prior cleanroom projects are presented. It is intended that the process model described here will be further tailored as additional SEL cleanroom projects are analyzed.

Green, Scott↗

Land Surface Reflectances from Geostationary Sensors

GEONEX is a processing pipeline that produces a suite of satellite land surface products using data streams from the latest geostationary (GEO) sensors including the GOES016/ABI and the Himawari-8/AHI. The suite, created collaboratively by scientists from NASA and NOAA, includes top-of-atmosphere (TOA) reflectances, land surface reflectances (LSRs), vegetation indices, LAI/fPAR, and other downstream products. As a key component of the GEONEX product processing, we have adapted the Multi-Angle Implementation of Atmospheric Correction (MAIAC) algorithm to produce LSRs from the TOA data. Because the algorithm depends on building "stacks" of images, we first run internal geo-registration checks to ensure geo-spatial accuracy and consistency of the input (L1B) data before transferring them from the geostationary projection into a tile system in geographic grids. Scan-time is inferred from metadata and applied to calculate the sun-sensor angles for each grid cell. The MAIAC algorithm is run to detect clouds/shadows, estimate aerosol optical thickness (AOT), perform atmospheric corrections, and generate LSRs. We have processed 18-months (from 2016/04 onward) of AHI data over East Asia and Oceania at a 10-minute time step and 10-months (from 2018/01 onward) of ABI data over North and South Americas at a 15-minute time step. As a verification measure, we compare the GEONEX (AHI/ABI) surface reflectances with the standard MODIS products (MOD09GA) and the MODIS MAIAC products over pixels that have similar sun-view geometries. The results indicate general linear relationships between GEONEX and corresponding MODIS LSRs. In particular, the RMSEs between GEONEX and MOD09 data are comparable to those between MOD09 and MODIS MAIAC products, suggesting that the uncertainties of GEONEX LSRs fall into an acceptable range. However, direct comparisons of LSRs over pixels with different sun-view angles are not as straightforward and require more modeling efforts to correct the directional effects. Evaluation of such angular influences on the downstream products (e.g., vegetation indices) is also under investigation.

Geostationary satellite; Remote Sensing; Atmospher↗

Photon pair production in astrophysical transrelativistic plasmas

Photon pair-production processes in marginally relativistic (transrelativistic) accretion plasmas are investigated in both Planckian and non-Planckian cases. Pair production in a plasma with an equilibrium (Planck) spectrum is reviewed, and pair-concentration calculations are performed for three general non-Planckian situations most relevant to black-hole accretion scenarios: steady-state transrelativistic plasmas of relatively high density characterized by a pure bremsstrahlung spectrum, a comptonized bremsstrahlung spectrum, and an unsaturated Compton scattering spectrum. The results obtained indicate that for transrelativistic temperatures (600 million to 6 billion K) photon pair production is not generally a dominant process for a plasma with a pure bremsstrahlung spectrum, but becomes dominant for plasmas where comptonization is important. It is also shown that photon pair-creation processes in a transrelativistic bremsstrahlung-radiating plasma that is more than marginally optically thick to Compton scattering significantly alter the plasma's spectrum by forcing it to become black-body before it reaches relativistic temperatures. Pair production and instabilities in unsteady-state plasmas are briefly considered

Stoeger, W. R.↗

Process engineering concerns in the lunar environment

The paper discusses the constraints on a production process imposed by the lunar or Martian environment on the space transportation system. A proposed chemical route to produce oxygen from iron oxide bearing minerals (including ilmenite) is presented in three different configurations which vary in complexity. A design for thermal energy storage is presented that could both provide power during the lunar night and act as a blast protection barrier for the outpost. A process to release carbon from the lunar regolith as methane is proposed, capitalizing on the greater abundance and favorable physical properties of methane relative to hydrogen to benefit the entire system.

Sullivan, T. A.↗

Boron-carbon-silicon polymers and ceramic and a process for the production thereof

The present invention relates to a process for the production of an organoborosilicon preceramic polymer of the structure: wherein R 1 is selected from alkyl having from 1 to 10 carbon atoms or phenyl, and x is selected from 0, 1, 2 or 3; which is pyrolyzable to produce a refractory material comprising inorganic compounds of Si, C and B, which process comprises: contacting a silicon containing compound of the structure: (R 1 ) x --Si--(CH=CH 2 ) 4- x or (R 1 ) x Si--(C=CH) 4- x with a boron containing compound selected from H 3 B:BH 3 , H 3 B:NH 3 , BH 3 :N(R 2 ) 3 wherein R 2 is selected from methyl, ethyl, propyl, butyl or phenyl in an inert atmosphere at a temperature of between about 90° and 170° C. for between about 0.1 and 20 hr and recovering the prepolymer. The prepolymer is pyrolyzed to produce a ceramic article useful in high temperature (e.g., aerospace) or extreme environmental applications.

Salvatore Riccitiello↗

Production and use of metals and oxygen for lunar propulsion

Production, power, and propulsion technologies for using oxygen and metals derived from lunar resources are discussed. The production process is described, and several of the more developed processes are discussed. Power requirements for chemical, thermal, and electrical production methods are compared. The discussion includes potential impact of ongoing power technology programs on lunar production requirements. The performance potential of several possible metal fuels including aluminum, silicon, iron, and titanium are compared. Space propulsion technology in the area of metal/oxygen rocket engines is discussed.

Hepp, Aloysius F.↗

Production and use of metals and oxygen for lunar propulsion

Production, power, and propulsion technologies for using oxygen and metals derived from lunar resources are discussed. The production process is described, and several of the more developed processes are discussed. Power requirements for chemical, thermal, and electrical production methods are compared. The discussion includes potential impact of ongoing power technology programs on lunar production requirements. The performance potential of several possible metal fuels including aluminum, silicon, iron, and titanium are compared. Space propulsion technology in the area of metal/oxygen rocket engines is discussed.

Hepp, Aloysius F.↗