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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 235 records · Page 13
All sourcesNASA NTRSDOE OSTI
NASA NTRS1985

Laboratory glassware rack for seismic safety

A rack for laboratory bottles and jars for chemicals and medicines has been designed to provide the maximum strength and security to the glassware in the event of a significant earthquake. The rack preferably is rectangular and may be made of a variety of chemically resistant materials including polypropylene, polycarbonate, and stainless steel. It comprises a first plurality of parallel vertical walls, and a second plurality of parallel vertical walls, perpendicular to the first. These intersecting vertical walls comprise a self-supporting structure without a bottom which sits on four legs. The top surface of the rack is formed by the top edges of all the vertical walls, which are not parallel but are skewed in three dimensions. These top edges form a grid matrix having a number of intersections of the vertical walls which define a number of rectangular compartments having varying widths and lengths and varying heights.

Cohen, M. M.↗
NASA NTRS1985

Angular particle impingement studies of thermoplastic materials at normal incidence

Scanning electron microscope studies were conducted to characterize the erosion resistance of polymethyl methacrylate (PMMA), polycarbonate (PC), polytetrafluorethylene (PTFE), and ultra-high-molecular-weight polyethylene (UHMWPE). Erosion was caused by a jet of angular microparticles of crushed glass at normal incidence. Material built up above the original surface on all of the materials. As erosion progressed, this buildup disappeared. UHMWPE was the most resistant material and PMMA the least. The most favorable properties for high erosion resistance were high values of ultimate elongation, maximum service temperature, and strain energy and a low value of the modulus of elasticity. Erosion-rate-versus-time curves of PC and PTFE exhibited incubation, acceleration, and steady-state periods. PMMA also exhibited a deceleration period, and an incubation period with deposition was observed for UHMWPE.

Rao, P. V.↗
NASA NTRS1986

Measurement of contact angle in a clearance-fit pin-loaded hole

A technique which measures load-contact variation in a clearance-fit, pin-loaded hole is presented in detail. A steel instrumented pin, which activates a make-or-break electrical circuit in the pin-hole contact region, was inserted into one aluminum and one polycarbonate specimen. The resulting load-contact variations are indicated schematically. The ability to accurately determine the arc of contact at any load was crucial to this measurement. It is noted that this simple experimental technique is applicable to both conducting and nonconducting materials.

Prabhakaran, R.↗
NASA NTRS1986

Dynamic fracture toughness

Dynamic fracture toughness versus crack velocity relations of Homalite-100, polycarbonate, hardened 4340 steel and reaction bonded silicon nitride are reviewed and discrepancies with published data and their probable causes are discussed. Data scatter in published data are attributed in part to the observed fluctuations in crack velocities. The results reaffirmed our previous conclusion that the dynamic fracture toughness versus crack velocity relation is specimen dependent and that the dynamic arrest stress intensity factor is not a unique material property.

Kobayashi, A. S.↗
NASA NTRS1987

Effects of Radiation on Capacitor Dielectrics

Data gathered on key design parameters. Report discusses study of electrical and mechanical properties of irradiated polymer dielectric materials. Data compiled for use by designers of high-energy-density capacitors that operate in presence of ionizing radiation. Study focused on polycarbonates, polyetheretherketones, polymethylpentenes, polyimides (including polyetherimide), polyolefins, polysulfones (including polyethersulfone and polyphenylsulfone), and polyvinylidene fluorides.

Bouquet, F. L.↗
NASA NTRS1987

A micrographic study of bending failure in five thermoplastic/carbon fiber composite laminates

The local deformation and failure sequences of five thermoplastic matrix composites were microscopically observed while bending the samples in a small fixture attached to a microscope stage. The themoplastics are polycarbonate, polysulfone, polyphenylsulfide, polyethersulfone, and polyetheretherketone. Comparison was made to an epoxy matrix composite, 5208/T-300. Laminates tested are (0/90) sub 2S, with outer ply fibers parallel to the beam axis. Four point bending was used at a typical span-to-thickness ratio of 39:1. It was found that all of the thermoplastic composites failed by abrupt longitudinal compression buckling of the outer ply. Very little precursory damage was observed. Micrographs reveal typical fiber kinking associated with longitudinal compression failure. Curved fracture surfaces on the fibers suggest they failed in bending rather than direct compression. Delamination was suppressed in the thermoplastic composites, and the delamination that did occur was found to be the result of compression buckling, rather than visa-versa. Microbuckling also caused other subsequent damage such as ply splitting, transverse ply shear failure, fiber tensile failure, and transverse ply cracking.

Yurgartis, S. W.↗
NASA NTRS1988

Sizing Increases Fiber/Matrix Adhesion

Strengths of graphite fiber/polycarbonate matrix composites increased by precoating fibers with thin layer of polycarbonate. Flexural strengths of composite samples measured to determine effects of different fabrication conditions.

Cizmecioglu, Muzaffer↗
NASA NTRS1986

Partial analysis of experiment LDEF A-0114

Due to delays in manifesting the return of the Long Duration Exposure Facility from space, attention was concentrated on extracting the maximum information from the EIOM-2 (oxygen interaction with materials experiment) flown on STS-8 in September 1983. An analysis was made of the optical surfaces exposed during that flight and an assessment made of the effect of the 5 eV atomic oxygen upon their physical and chemical properties. The surfaces studied were of two types: high-purity thin films sputtered or evaporated onto 2.54-cm diam lambda/20 fused silica optical flats, and highly polished bulk samples. Rapid etching of carbon and carbonaceous surfaces was observed with polycarbonate CR-39 showing the largest etch of any substrate flown and measured. Of the metals tested, only osmium and silver showed large effects, the former being heavily etched and the later forming a very thick layer of oxide. The first measurable effects on iridium, aluminum, nickel, tungsten and niobium thin films are reported.

Gregory, J. C.↗
NASA NTRS1988

Interlaminar fracture toughness of thermoplastic composites

Edge delamination tension and double cantilever beam tests were used to characterize the interlaminar fracture toughness of continuous graphite-fiber composites made from experimental thermoplastic polyimides and a model thermoplastic. Residual thermal stresses, known to be significant in materials processed at high temperatures, were included in the edge delamination calculations. In the model thermoplastic system (polycarbonate matrix), surface properties of the graphite fiber were shown to be significant. Critical strain energy release rates for two different fibers having similar nominal tensile properties differed by 30 to 60 percent. The reason for the difference is not clear. Interlaminar toughness values for the thermoplastic polyimide composites (LARC-TPI and polyimidesulfone) were 3 to 4 in-lb/sq in. Scanning electron micrographs of the EDT fracture surfaces suggest poor fiber/matrix bonding. Residual thermal stresses account for up to 32 percent of the strain energy release in composites made from these high-temperature resins.

Hinkley, J. A.↗
NASA NTRS1988

Surface and interfacial properties of carbon fibers

Differences in the adhesion of three carbon fibers (Hercules AS1 and AS4, and Hysol-Grafil XAS) to polycarbonate (PC) have been shown to correlate with the absorptivity of PC on the three fiber types. The absorptivity (energy of absorption) was determined using retention time liquid chromatography and the adhesion was measured using the single embedded filament tensile test. A correlation was also found between adhesion strength and the O/N surface element ratio using XPS analysis. The chemical details for these correlations have not yet been determined. A study of filament fracture statistics has been initiated using single and multiple embedded filament tensile tests. Filament fracture has been measured as a function of strain and for different interfiber distances. Preliminary results indicate that fiber fracture is a discontinuous function of increasing strain and may in fact occur at discrete strain intervals. Fiber-fiber interaction effects on fiber fracture have been found for interfiber distances of up to two to three fiber diameters.

Bascom, W. D.↗
NASA NTRS1988

A micrographic study of bending failure in five thermoplastic-carbon fibre composite laminates

The local deformation and failure sequences of five thermoplastic matrix composites were microscopically observed while bending the samples in a small fixture attached to a microscope stage. The thermoplastics are polycarbonate, polysulfane, polyphenylsulfide, polyethersulfane, and polyetheretherketone. Comparison was made to an epoxy matrix composite, 5208/T-300. Laminates tested are (0/90) sub 2S, with outer ply fibers parallel to the beam axis. Four point bending was used at a typical span-to-thickness ratio of 39:1. It was found that all of the thermoplastic composites failed by abrupt longitudinal compression buckling of the outer ply. Very little precursory damage was observed. Micrographs reveal typical fiber kinking associated with longitudinal compression failure. Curved fracture surfaces on the fibers suggest they failed in bending rather than direct compression. Delamination was suppressed in the thermoplastic composites, and the delamination that did occur was found to be the result of compression buckling, rather than vice-versa. Microbuckling also caused other subsequent damage such as ply splitting, transverse ply shear failure, fiber tensile failure, and transverse ply cracking.

Yurgartis, S. W.↗
NASA NTRS1988

Research on high energy density capacitor materials

The Pulsed Plasma thruster is the simplest of all electric propulsion devices. It is a pulsed device which stores energy in capacitors for each pulse. The lifetimes and energy densities of these capacitors are critical parameters to the continued use of these thrusters. This report presents the result of a research effort conducted by JPL into the materials used in capacitors and the modes of failure. The dominant failure mechanism was determined to be material breakdown precipitated by heat build-up within the capacitors. The presence of unwanted gas was identified as the source of the heat. An aging phenomena was discovered in polycarbonate based capacitors. CO build-up was noted to increase with the number of times the capacitor had been discharged. Improved quality control was cited as being essential for the improvement of capacitor lifetimes.

Somoano, Robert↗
NASA NTRS1988

Radiation effects on polymeric materials

It is important to study changes in properties of polymeres after irradiation with charged particles, with ultraviolet radiation, and with combinations of both. An apparatus for this purpose has been built at the NASA Langley Research Center. It consists of a chamber 9 inches in diameter and 9 inches high with a port for an electron gun, another port for a mass spectrometer, and a quartz window through which an ultraviolet lamp can be focused. The chamber, including the electron gun and the mass spectrometer, can be evacuated to a pressure of 10 to the 8th power torr. A sample placed in the chamber can be irradiated with electrons and ultraviolet radiation separately, sequentially, or simultaneously, while volatile products can be monitored during all irradiations with the mass spectrometer. The apparatus described above has been used to study three different polymer films: lexan; a polycarbonate; P1700, a polysulfone; and mylar, a polyethylene terephthalate. All three polymers had been studied extensively with both electrons and ultraviolet radiation separately, but not simultaneously. Also, volatile products had not been monitored during irradiation for the materials. A high electron dose rate of 530 Mrads/hr was used so that a sufficient concentration of volatile products would be formed to yield a reasonable mass spectrum.

Kiefer, Richard L.↗
NASA NTRS1988

Space Shuttle Orbiter windshield bird impact analysis

The NASA Space Shuttle Orbiter's windshield employs three glass panes separated by air gaps. The brittleness of the glass offers much less birdstrike energy-absorption capability than the laminated polycarbonate windshields of more conventional aircraft; attention must accordingly be given to the risk of catastrophic bird impact, and to methods of strike prevention that address bird populations around landing sites rather than the modification of the window's design. Bird populations' direct reduction, as well as careful scheduling of Orbiter landing times, are suggested as viable alternatives. The question of birdstrike-resistant glass windshield design for hypersonic aerospacecraft is discussed.

Edelstein, Karen S.↗
NASA NTRS1989

A petrographic thin sectioning technique for evaluating composite materials

Petrographic thin sectioning by a low-speed diamond saw has been used in conjunction with transmission polarized light microscopy for the characterization of the microstructure and deformation mechanisms of a variety of polymer systems. It has proven possible by these means to study three types of thermoplastic matrices for composite applications: PEEK, BPA-based polycarbonate (PC), and a rubber-modified PC. The reinforcing fibers for these matrices were in all cases AS4 carbon fibers, unidirectionally arrayed. Superior analyzability of matrix morphology and subsurface fracture processes is achieved by thin sectioning.

Parker, D. S.↗
NASA NTRS1990

The effect of thermal damage on the mechanical properties of polymer regrinds

Reprocessed polymers are subjected to high processing temperatures that result in the breakdown of molecular chains and changes in the molecular structures. These phenomena are reflected in the mechanical properties of materials. Practically every regrind is seen as a new material. These experiments deal with the molding, regrinding, and reprocessing of test specimens for the study of their mechanical properties. The comparative test data from each recycled material would give students an insight of the molecular structures and property degradation. Three important rheological and mechanical properties such as melt flow, impact strength, and flexural strength are to be determined. These properties play key roles in the selection of engineering materials. The material selected for demonstration was Makrolon 3000L, a polycarbonate thermoplastic from Bayer AG. The thermal degradation due to repeated processing is reflected in the decrease in molecular weight and breakdown of molecular chains causing increase in melt flow. The Izod-impact resistance and the flexural strength deteriorate gradually.

Kundu, Nikhil K.↗
NASA NTRS1990

Fractography of composite delamination

The microdamage that occurs for Mode 1 and Mode 2 delamination was examined by potting delaminated specimens in a clear epoxy, sectioning through the damage, polishing the cut sections and examining using light microscopy. For Mode 1 delamination of unidirectional carbon fiber reinforced plastic (CFRP) composites, the major observation was fiber bridging including large ligaments of fiber bundles. The Mode 2 delamination of unidirectional laminates revealed a very narrow crack opening with only occasional fiber bridging. Impact testing by repetitive impacts with increasing energy was studied and it was found that this technique does not discern changes in the type of damage with increasing cumulative impact energy. Instead, the changes in the impact response, notably stiffness, are the result of changes in the extent of damage. For laminates with a brittle thermoplastic matrix, 3501-6, there were distinct changes in stiffness that corresponded to the development of through the thickness damage and then to the extension of the damage to the specimen edges. For PEEK and polycarbonate, the changes in stiffness were not as abrupt as for the thermoset. None the less, the damage progressed in the same manner.

Bascom, W. D.↗