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At least 235 records · Page 13

Flammability of photovoltaic modules

A series of Class B burning-brand tests were performed on experimental modules using high-temperature, back-surface materials to develop the technology base required to construct fire-ratable modules. Results indicate the existence of synergistic relationships between hydrocarbon encapsulation materials and the experimental module configurations that provide increased fire resistance. These configurations use Kapton, fiberglass, neoprene rubber, stainless-steel foil or aluminum foil as the back surface. Successful test results occur when the structural integrity of the module back surface is maintained. Test failures of these modules always occur for one of three reasons: the outermost back cover melts, rips, or is too porous. In each case flammable molten encapsulant, its gaseous byproducts, or both, penetrates the back surface of the module and bursts into flame. Future efforts to complete the technology base will concentrate on the spread-of-flame test, focusing on the more promising configurations identified in the initial series of tests.

Sugimura, R. S.↗

The integration of bypass diodes with terrestrial photovoltaic modules and arrays

Bypass diodes are often required to limit the potential for reverse voltage 'hot-spot' heating in high voltage arrays or in arrays that undergo periodic operation near the short-circuit point. In addition, when properly applied, bypass diodes can minimize the effect of shadowing and various internal module failures on the array energy output. This paper discusses the mechanical and electrical integration of bypass diodes beginning with the array-level considerations which influence the selection of an implementation approach. Concepts for the mounting of these diodes, both internally within the module encapsulant and externally to the exposed rear surface of the module, are described. Factors affecting the reliability of bypass diodes, including the control of junction temperature through adequate heat sinking and the derating of reverse voltage, are discussed.

Shepard, N. F., Jr.↗

Predicting electrochemical breakdown in terrestrial photovoltaic modules

Electrochemical corrosion of PV cells can cause a cell-to-frame short circuit with two undesirable resuits: (1) catastrophic loss of source-circuit power; and (2) high field maintenance (module replacement) costs. Parameter dependencies are determined and encapsulated two-cell coupons are exposed to a range of voltage differences, temperatures, and relative humidities. Material relative performance is assessed. Nine different metallization-encapsulation combinations are tested.

Mon, G. R.↗

Hermetic Edge Seals for Photovoltaic Modules

Corrosive atmospheric agents excluded to prolong cell life. Combination of two sealing techniques makes possible to protect solar cells from water vapor, oxygen, and other corrosive atmospheric constituents. Using three-step process, glass-to-metal hermetic seal formed around edge of solar-cell module. Elastomer seals used previously not as effective because they are permeable to water vapor and atmospheric gases.

Nowlan, M. J.↗

Reliability and engineering of thin-film photovoltaic modules

Objectives were to: examine thin-film cell attributes that influence module performance and reliability, explore the lessons and applicability of crystalline-silicon module technology to thin-film modules, review the current status of thin-film module technologies, and identify problem areas and needed research. A major need is to separate the effects and resons for reversible degradatin from nonreversible degradation. Amorphous-silicon (a-Si) reliability investigations are focusing on exploratory research investigations, accelerated Arrhenius-type testing of a-Si cells, real-time outdoor exposure testing of a-Si cells, cell failure analysis, and failure mechanism research. Studies included the reduction in strength of glass by high temperature depositions on glass and laser scribing, encapsulation materials development needs, and the testing of modules. The new materials and processes in thin-film modules will require a delinquent reliability effort, including: establishment of mechanism-specific reliability goals; quantification of mechanism parameter dependencies; prediction of expected long-term degradation; identification of cost-effective solutions; and testing and failure analysis of trial solutions.

Royal, E. L.↗

Photovoltaics module interface: General purpose primers

The interfacial chemistry established between ethylene vinyl acetate (EVA) and the aluminized back surface of commercial solar cells was observed experimentally. The technique employed is called Fourier Transform Infrared (FTIR) spectroscopy, with the infrared signal being reflected back from the aluminum surface through the EVA film. Reflection infrared (IR) spectra are given and attention is drawn to the specific IR peak at 1080/cm which forms on hydrolytic aging of the EVA/aluminum system. With this fundamental finding, and the workable experimental techniques, candidate silane coupling agents are employed at the interface, and their effects on eliminating or slowing hydrolytic aging of the EVA/aluminum interface are monitored.

Boerio, J.↗

Assessing photovoltaic module life from long-term environmental tests

An assessment is made of results obtained by an experimental program having as its aim the identification of critical temperature-humidity bias degradation mechanisms in solar cell modules intended to have an operating lifetime of the order of 20-30 years. These mechanisms are studied in the context of conditions encountered over the course of long term operation in various sites in the U.S. Accelerated tests for the assessment of product lifetime entail the development of a correlation between test and application conditions; this has been accomplished through an analytical procedure for the correlation of time-varying field exposures to constant-stress accelerated environments.

Otth, D. H.↗

Electrochemical aging effects in photovoltaic modules

Leakage currents were experimentally measured in PV modules undergoing natural aging outdoors, and in PV modules undergoing accelerated aging in laboratory environmental chambers. The significant contributors to module leakage current were identified with a long range goal to develop techniques to reduce or stop module leakage currents. For outdoor aging in general, module leakage current is relatively insensitive to temperature fluctuations, but is very sensitive to moisture effects such as dew, precipitation, and fluctuations in relative humidity. Comparing ethylene vinyl acetate (EVA) and polyvinyl butyral (PVB), module leakage currents are much higher in PVB as compared to EVA for all environmental conditions investigated. Leakage currents proceed in series along two paths, bulk conduction followed by interfacial (surfaces) conduction.

Mon, G. R.↗

Ultralight amorphous silicon alloy photovoltaic modules for space applications

Ultralight and ultrathin, flexible, rollup monolithic PV modules have been developed consisting of multijunction, amorphous silicon alloys for either terrestrial or aerospace applications. The rate of progress in increasing conversion efficiency of stable multijunction and multigap PV cells indicates that arrays of these modules can be available for NASA's high power systems in the 1990's. Because of the extremely light module weight and the highly automated process of manufacture, the monolithic a-Si alloy arrays are expected to be strongly competitive with other systems for use in NASA's space station or in other large aerospace applications.

Hanak, J. J.↗

Electrochemical degradation of amorphous-silicon photovoltaic modules

Techniques of module electrochemical corrosion research, developed during reliability studies of crystalline-silicon modules (C-Si), have been applied to this new investigation into amorphous-silicon (a-Si) module reliability. Amorphous-Si cells, encapsulated in the polymers polyvinyl butyral (PVB) and ethylene vinyl acetate (EVA), were exposed for more than 1200 hours in a controlled 85 C/85 percent RH environment, with a constant 500 volts applied between the cells and an aluminum frame. Plotting power output reduction versus charge transferred reveals that about 50 percent a-Si cell failures can be expected with the passage of 0.1 to 1.0 Coulomb/cm of cell-frame edge length; this threshold is somewhat less than that determined for C-Si modules.

Mon, G. R.↗

Space Station Photovoltaic power modules

Silicon cell Photovoltaic (PV) power modules are key components of the Space Station Electrical Power System (EPS) scheduled to begin deployment in 1994. Four PV power modules, providing 75 KWe of user ac power, form the cornerstone of the EPS; which is comprised of Photovoltaic (PV) power modules, Solar Dynamic (SD) power modules, and the Power Management and Distribution (PMAD) system. The PV modules are located on rotating outboard sections of the Space Station (SS) structure and each module incorporates its own nickel-hydrogen energy storage batteries, its own thermal control system, and some autonomous control features. The PV modules are a cost-effective and technologically mature approach for providing reliable SS electrical power and are a solid base for EPS growth, which is expected to reach 300 KWe by the end of the Space Station's 30-year design lifetime.

Tatro, Charles A.↗

Characterizing photovoltaic backsheet adhesion degradation using the wedge and single cantilever beam tests, Part I: Field Modules

Photovoltaic backsheets are exposed to harsh outdoor weathering conditions throughout their service lives that can compromise their protective function, through adhesive debonding between their constituent layers and between the backsheet and the module. We report a large-scale study on adhesive degradation was conducted on 37 field-exposed modules, that spanned 19 different module manufacturers, that were deployed among six Köppen–Geiger climatic zones, and that were fielded between 0 and 28 years. Six outer layer polymer classes were identified among the backsheets: polyamide (PA), polyethylene terephthalate (PET), polyvinyl fluoride (PVF), polyvinylidene fluoride (PVDF), fluoroethylene vinyl ether copolymer (FEVE), and tetrafluoroethylene hexafluoropropylene vinylidene fluoride copolymer (THV). Two adhesion tests were used to measure the adhesive strength: the wedge test and the width-tapered single-cantilever beam (SCB) test. Adhesion energies were compared across exposure time and Köppen–Geiger climatic zone. Many of the PET-, PVF-, and PVDF-based backsheets experienced degradation of the adhesive layer between the backsheet outer and core layers. A consistent trend of decreasing adhesion energy with exposure time was observed in five out of the six backsheet types. Trends among adhesion energy and climatic zone, while expected, were not observed, possibly due to broad ranges in temperature, humidity, and precipitation defining Köppen–Geiger climatic zones. The cantilever beam measurements produced an upper cutoff of approximately 100 J/m 2 , above which no modules exhibited field delamination. The results are part of a two-part study quantifying adhesion in both field-weathered and indoor-exposed PV backsheets.

14 SOLAR ENERGY↗

EFG solar modules

Six photovoltaic modules using solar cells fabricated from silicon ribbons were assembled and delivered to JPL. Each module was comprised of four separate submodules which were parallel connected. The submodules contained 45 EFG cells which were series interconnected by a shingle or overlapping design. The inherent rectangular shape of the cells allowed a high packing factor to be achieved. The average efficiency of the six modules, corrected to AM1 at 28 C was 8.7%, which indicates that the average encapsulated cell efficiency was 10.0%.

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