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At least 235 records · Page 13

A Planar-Fluorescence Imaging Technique for Studying Droplet-Turbulence Interactions in Vaporizing Sprays

Droplet turbulence interactions directly affect the vaporization and dispersion of droplets in liquid sprays and therefore play a major role in fuel oxidizer mixing in liquid fueled combustion systems. Proper characterization of droplet turbulence interactions in vaporizing sprays require measurement of droplet size velocity and size temperature correlations. A planar, fluorescence imaging technique is described which is being developed for simultaneously measuring the size, velocity, and temperature of individual droplets in vaporizing sprays. Preliminary droplet size velocity correlation measurements made with this technique are presented. These measurements are also compared to and show very good agreement with measurements made in the same spray using a phase Doppler particle analyzer.

Santavicca, Dom A.↗

Interactions of laser-driven tin ejecta microjets over phase transition boundaries

Ejecta microjets offer an experimental methodology to study high-speed particle laden-flow interactions, as microjets consist of millions of particulates traveling at velocities of several kilometers per second and are easily generated by most common shock drives. Previous experiments on the OMEGA Extended Performance laser found that collisions between two counter-propagating laser-driven tin ejecta microjets varied as a function of drive pressure; jets generated near shock pressures of 10 GPa passed through each other without interacting, whereas jets generated at shock pressures of over 100 GPa interacted strongly, forming a cloud around the center interaction point. In this paper, we present a more systematic scan of tin ejecta microjet collisions over intermediate pressure regimes to identify how and at what shock pressure interaction behavior onsets. Radiographs of interacting microjets at five different laser drive energies qualitatively demonstrate that interaction behavior onsets slowly as a function of laser drive energy. Quantitative mass and density metrics from each radiograph provide trends on jet characteristics and collisional mass dispersion. It is observed that jetting mass, jet densities, and mass dispersion increase with increasing drive pressures and that the increased jet density at the higher drive energies may account for the increased mass dispersion. This work provides an important step in the understanding of tin ejecta microjet collisions and paves the way for future studies on the physics dominating high-speed particle-laden flow interactions.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

Atomically Resolved Acoustic Dynamics Coupled with Magnetic Order in a Van der Waals Antiferromagnet

Magnetoelastic coupling in van der Waals (vdW) magnetic materials enables a unique interplay between the spin and lattice degrees of freedom. Characterizing the elastic responses with atomic and femtosecond resolution across the magnetic transition is essential for guiding the design of magnetically tunable actuators and strain-mediated spintronic devices. Here, ultrafast X-ray diffraction employed at a free-electron laser reveals that the atomic displacements, wave vectors, and dispersion relations of acoustic phonon modes in a vdW antiferromagnet FePS3 are coupled with the magnetic order, by tracking both in-plane and out-of-plane Bragg peaks upon optical excitation across the Néel temperature (TN). One transverse mode shows that a quasi-out-of-plane atomic displacement undergoes a significant directional change across TN. Its quasi-in-plane wave vector is derived by comparing the measured sound velocity and the first-principles calculations. The other transverse mode is an interlayer shear acoustic mode whose amplitude is strongly enhanced in the antiferromagnetic phase, exhibiting eight times stronger amplitude than the longitudinal acoustic mode below TN. The atomically resolved characterization of acoustic phonon dynamics that couple with magnetic ordering opens opportunities for harnessing unique magnetoelastic coupling in vdW magnets on ultrafast timescales.

coherent acoustic phonons↗

Faint and Fading Tails: The Fate of Stripped H i Gas in Virgo Cluster Galaxies

Although many galaxies in the Virgo cluster are known to have lost significant amounts of H i gas, only about a dozen features are known where the H i extends significantly outside its parent galaxy. Previous numerical simulations have predicted that H i removed by ram pressure stripping should have column densities far in excess of the sensitivity limits of observational surveys. We construct a simple model to try and quantify how many streams we might expect to detect. This accounts for the expected random orientation of the streams in position and velocity space as well as the expected stream length and mass of stripped H i. Using archival data from the Arecibo Galaxy Environment Survey, we search for any streams that might previously have been missed in earlier analyses. We report the confident detection of 10 streams as well as 16 other less-certain detections. We show that these well match our analytic predictions for which galaxies should be actively losing gas; however, the mass of the streams is typically far below the amount of missing H i in their parent galaxies, implying that a phase change and/or dispersal renders the gas undetectable. By estimating the orbital timescales, we estimate that dissolution rates of 1–10 M {sub ⊙} yr{sup −1} are able to explain both the presence of a few long, massive streams and the greater number of shorter, less-massive features.

79 ASTRONOMY AND ASTROPHYSICS↗

IUE spectroscopy, visible-band photometry, and polarimetry of HD 47732 (V641 Monocerotis)

Several high- and low-dispersion IUE spectra are described for the hot, massive close binary HD 47732. The stellar silicon lines do not show theoretically expected strength, the weakness being attributed to incipicent emission. A weak stellar wind is measurable with an expansion velocity of about 500 km/s. There is difficulty in fitting a model atmosphere to all of the IUE continuum and visible band and IR measures. These difficulties are resolved by appealing to a 22,500 K model atmosphere and a distinctive interstellar extinction law. Numerous V band measures show the polarization to be variable, but not strongly in a phased-locked way. This suggests sporadic outbursts of gas feeding the shell. Several seasonal V band light curves are discussed, and the seasonal variations among them are attributed to variable developments of a systemic shell which scatters the photospheric light and dilutes to a variable degree the light variation due to ellipticity of figure of the component stars.

Koch, R. H.↗

Angular momentum regulation in low-mass young stars surrounded by accretion disks

From study of a sample of 34 T Tauri stars with photometrically derived rotation periods and spectral types later than KS, we find that the observed periods appear to be related to the presence or absence of an accretion disk. Those stars which we infer to be surrounded by accretion disks have rotation periods P(rot) over 4 days with a most probable P(rot) of about 8.5 days, while those stars which lack accretion disk signatures cover a wide range of P(rot) from 1.5 to 16 days, including a significant number of objects with P(rot) less than 4 days. This suggests the possibility that the 'initial' angular momentum of a star is not established until it dissipates its circumstellar accretion disk. During the disk accretion phase, the stellar angular velocity appears to be regulated at a low value, countering the tendency of the star to spin up both from contraction toward the main sequence and from the accretion of inner disk material of high specific angular momentum. When the accretion disk is dissipated, this regulation mechanism will cease to function. At this point, the star is no longer maintained at a low angular velocity, but is 'free' to conserve its angular momentum, and thus to increase its angular velocity in response to contraction and changes in moment of inertia. This hypothesis, combined with a spread in disk dispersal time scales, provides a context for explaining the observed distribution of stellar rotational velocities for stars on the ZAMS in young clusters.

Edwards, Suzan↗

ASCA observation of NGC 4636: Dark matter and metallicity gradient

We present our analysis of ASCA PV phase observation of the elliptical galaxy NGC 4636. Solid state imaging spectrometer (SIS) spectra in six concentric annuli centered on NGC 4636 are used to derive temperature, metallicity, and column density profiles for the hot interstellar medium. Outside of the central 3 min the temperature is roughly constant at approximately 0.85 keV, while the metallicity decreases from greater than 0.36 solar at the center to less than 0.12 solar at R approximately 9 min. The implications of this gradient for elliptical galaxy formation and the enrichment of intracluster gas are discussed. We derive a detailed mass profile consistent with the stellar velocity dispersion and with ROSAT position sensitive proportional counter (PSPC) and ASCA SIS X-ray temperature profiles. We find that NGC 4636 becomes dark matter dominated at roughly the de Vaucouleurs radius, and, at r approximately 100 kpc, the ratio of dark to luminous matter density is approximately 80 and solar mass/solar luminosity approximately equal to 150. Evidence for the presence of a cooling flow is also discussed.

Mushotzky, R. F.↗

Resolving the Massive Binary Wind Interaction Of Eta Carinae with HST/STIS

We have resolved the outer structures of the massive binary interacting wind of Eta Carinae using the HST/STIS. They extend as much as 0.7' (1600AU) and are highly distorted due to the very elliptical orbit of the binary system. Observations conducted from 1998.0 to 2004.3 show spatial and temporal variations consistent with a massive, low excitation wind, seen by spatially resolved, velocity-broadened [Fe II], and a high excitation extended wind interaction region, seen by[Fe III], in the shape of a distorted paraboloid. The highly excited [Fe III] structure is visible for 90% of the 5.5-year period, but disappears as periastron occurs along with the drop of X-Rays as seen by RXTE. Some components appear in [Fe II] emission across the months long minimum. We will discuss the apparent differences between the bowshock orientation derived from the RXTE light curve and these structures seen by HST/STIS. Monitoring the temporal variations with phase using high spatial resolution with appropriate spectral dispersions proves to be a valuable tool for understanding massive wind interactions.

Gull, Theodore↗

A double-moment multiple-phase four-class bulk ice scheme, Part 1: Description

A detailed ice-phase bulk microphysical scheme has been developed for simulating the hydrometeor distributions of convective and stratiform precipitation in different large-scale environmental conditions. The proposed scheme involves 90 distinct microphysical processes, which predict the mixing ratios and the number concentrations of small ice crystals, snow, graupel, and frozen drops/hail, as well as the mixing ratios of liquid water on wet precipitation ice (snow, graupel, frozen drops). The number of adjustable coefficients has been significantly reduced in comparison with other bulk schemes. Additional improvements have been made to the parameterization in the following areas: (1) representing small ice crystals with nonzero terminal fall velocities and dispersive size distributions, (2) accurate and computationally efficient calculations of precipitation collection processes, (3) reformulating the collection equation to prevent unrealistically large accretion rates, (4) more realistic conversion by riming between different classes of precipitation ice, (5) preventing unrealistically large rates of raindrop freezing and freezing of liquid water on ice, (6) detailed treatment of various rime-splintering ice multiplication mechanisms, (7) a simple representation of the Hobbs-Rangno ice enhancement process, (8) aggregation of small ice crystals and snow, and (9) allowing explicit competition between cloud water condensation and ice deposition rates rather than using saturation adjustment techniques. For the purposes of conserving the higher moments of the particle distributions, preserving the spectral widths (or slopes) of the particle spectra is shown to be more important than strict conservation of particle number concentration when parameterizing changes in ice-particle number concentrations due to melting, vapor transfer processes (sublimation of dry ice, evaporation from wet ice), and conversion between different hydrometeor species. The microphysical scheme is incorporated into a nonhydrostatic cloud model in Part 2 of this study. The model performed well in simulating the radar and microphysical structures of a midlatitude-continental squall lines and a tropical-maritime squall system with minimal tuning of the parameterization, even though the vertical profiles of radar reflectivity differed substantially between these storms.

Ferrier, Brad Shoenberg↗

The Longitudinal Properties of a Solar Energetic Particle Event Investigated Using Modern Solar Imaging

We use combined high-cadence, high-resolution, and multi-point imaging by the Solar-Terrestrial Relations Observatory (STEREO) and the Solar and Heliospheric Observatory to investigate the hour-long eruption of a fast and wide coronal mass ejection (CME) on 2011 March 21 when the twin STEREO spacecraft were located beyond the solar limbs. We analyze the relation between the eruption of the CME, the evolution of an Extreme Ultraviolet (EUV) wave, and the onset of a solar energetic particle (SEP) event measured in situ by the STEREO and near-Earth orbiting spacecraft. Combined ultraviolet and white-light images of the lower corona reveal that in an initial CME lateral "expansion phase," the EUV disturbance tracks the laterally expanding flanks of the CME, both moving parallel to the solar surface with speeds of approx 450 km/s. When the lateral expansion of the ejecta ceases, the EUV disturbance carries on propagating parallel to the solar surface but devolves rapidly into a less coherent structure. Multi-point tracking of the CME leading edge and the effects of the launched compression waves (e.g., pushed streamers) give anti-sunward speeds that initially exceed 900 km/s at all measured position angles. We combine our analysis of ultraviolet and white-light images with a comprehensive study of the velocity dispersion of energetic particles measured in situ by particle detectors located at STEREO-A (STA) and first Lagrange point (L1), to demonstrate that the delayed solar particle release times at STA and L1 are consistent with the time required (30-40 minutes) for the CME to perturb the corona over a wide range of longitudes. This study finds an association between the longitudinal extent of the perturbed corona (in EUV and white light) and the longitudinal extent of the SEP event in the heliosphere.

acceleration of particles↗

Experimental study of flash boiling spray with isooctane, hexane, ethanol and their binary mixtures

The main goal of this study is to understand the effect of fuel properties on flash boiling sprays using multi-hole injectors. Macroscopic characteristics were investigated using Diffused Backlight Imaging (DBI) and quantified with liquid penetration length and spray angles. Phase Doppler Anemometry (PDA) was applied to measure the droplet size and velocity. Behaviors of spray with three single-component fuels (isooctane, hexane, ethanol) under different ambient pressures (100 kPa, 80 kPa, 50 kPa, 22 kPa) as well as their binary mixtures under different blend ratios (10%, 30%, 85%) were reported and analyzed. The results showed that adding ethanol or hexane to isooctane could both promote flash boiling by increasing the overall vapor pressure thus superheated degree. Under mixing ratios of 10% and 30%, sprays with ethanol blends showed more severe flash boiling comparing with sprays with hexane blends. Shorter liquid penetration and better liquid dispersion have been observed. Comparing with isooctane spray, the droplet size continuously decreased with increasing hexane content due to enhanced breakup and faster vaporization. Sprays with ethanol mixtures showed a different trend. Noticeable droplet size reduction has been observed for spray with 10% ethanol content. However, droplet size did not further decrease with higher blend ratios regardless of higher flash boiling intensity. Such observations indicate severe vaporization inhibition caused by the high latent heat of vaporization of ethanol. For sprays with all test fuels, collapsing occurred when the pressure ratio of ambient pressure to saturation pressure (Rp) dropped below 0.3.

03 NATURAL GAS↗

Single-crystalline orthorhombic GdAlGe as a rare-earth magnetic Dirac nodal-line metal

Crystal engineering is a method for discovering new quantum materials and phases, which may be achieved using external pressure or strain. Chemical pressure is unique in that it generates internal pressure perpetually to the lattice. As an example, GdAlSi from the rare-earth (𝑅) 𝑅⁢Al⁢𝑋 (𝑋=Si or Ge) family of Weyl semimetals is considered. Replacing Si with the larger isovalent element Ge creates sufficiently large chemical pressure to induce a structural transition from the tetragonal structure of GdAlSi, compatible with a Weyl semimetallic state, to an orthorhombic phase in GdAlGe, resulting in an inversion-symmetry-protected nodal-line metal. We find that GdAlGe hosts an antiferromagnetic ground state with two successive orderings, at 𝑇 N ⁢1=35K and 𝑇 N ⁢2=30K. In-plane isothermal magnetization shows a magnetic field induced metamagnetic transition at 6.2 T for 2 K. Furthermore, electron-hole compensation gives rise to a large magnetoresistance of ∼100% at 2 K and 14 T. Angle-resolved photoemission spectroscopy measurements and density functional theory calculations reveal a Dirac-like linear band dispersion over an exceptionally large energy range of ∼1.5eV with a high Fermi velocity of ∼10 6 m/s, a rare feature not observed in any magnetic topological materials.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

Coronal gas in the Galaxy. II - A statistical analysis of O VI absorptions

This paper deals with general inferences about the low-density phase of interstellar gas having temperatures well above 200,000 K (the 'coronal gas') which can be drawn from O VI absorption data for 72 stars. Attention is given to the behavior of radial velocities, possible evidence for circumstellar O VI, the space distribution of the O VI gas, crowding of normal interstellar gas, and temperature distributions for the coronal gas. A model is adopted in which the coronal gas is contained within randomly distributed and nonoverlapping parcels, each with a size, pressure, and internal temperature distribution that do not vary markedly from one unit to the next. It is shown that the one-dimensional velocity dispersion for O VI regions (26 km/s) is substantially higher than the value for ordinary interstellar clouds (6.4 km/s).

Jenkins, E. B.↗

SPiRaL: a multiresolution global tomography model of seismic wave speeds and radial anisotropy variations in the crust and mantle

SUMMARY SPiRaL is a joint global-scale model of wave speeds (P and S) and anisotropy (vertical transverse isotropy, VTI) variations in the crust and mantle. The model is comprised of >2.1 million nodes with five parameters at each node that capture velocity variations for P- and S-waves travelling at arbitrary directions in transversely isotropic media with a vertical symmetry axis (VTI). The crust (including ice, water, sediments and crystalline layers) is directly incorporated into the model. The default node spacing is approximately 2° in the lower mantle and 1° in the crust and upper mantle. The grid is refined with ∼0.25° minimum node spacing in highly sampled regions of the crust and upper mantle throughout North America and Eurasia. The data considered in the construction of SPiRaL includes millions of body wave traveltimes (crustal, regional and teleseismic phases with multiples) and surface wave (Rayleigh and Love) dispersion. A multiresolution inversion approach is employed to capture long-wavelength heterogeneities commonly depicted in global-scale tomography images as well as more localized details that are typically resolved in more focused regional-scale studies. Our previous work has demonstrated that such global-scale models with regional-scale detail can accurately predict both teleseismic and regional body wave traveltimes, which is necessary for more accurate location of small seismic events that may have limited signal at teleseismic distances. SPiRaL was constructed to predict traveltimes for event location and long-period waveform dispersion for seismic source inversion applications in regions without sufficiently tuned models. SPiRaL may also serve as a starting model for full-waveform inversion (FWI) with the goal of fitting waves with periods 10–50 s over multiple broad regions (thousands of kilometres) and potentially the globe. To gain insight to this possibility, we simulated waveforms for a small set of events using SPiRaL and independent waveform-based models for comparison. For the events tested, the performance of the traveltime-based SPiRaL model is shown to be generally on par with regional 3-D waveform-based models in three regions (western United States, Middle East, Korean Peninsula) suggesting SPiRaL may serve as a starting model for FWI over broad regions.

58 GEOSCIENCES↗

Intermittency, bursty turbulence, and ion and electron phase-space holes formation in collisionless current-carrying plasmas

In the previous studies of nonlinear saturation of the Buneman instability caused by high electron drift velocity relative to ions, the phase-space holes and the plateau on the electron velocity distribution function were identified as features of the saturation stage of instability [notably in the paper by Omura et al., J. Geophys. Res. 108, 1197 (2003)]. We have performed a much longer simulation of the Buneman instability and observed a secondary instability. This secondary instability generates fast electron-acoustic waves. By analyzing the phase-space plot of ions and electrons, we show that the fast electron heating and the formation of the plateau of electron velocity distribution function are not due to the quasi-linear diffusion but due to the nonlinear interaction of ion- and electron-acoustic solitary waves (phase-space holes) by exchange of trapped electrons in each wave. We also report the details on the intermittent and bursty nature of turbulence driven by this instability.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Properties of a fading AGN from SDSS-IV MaNGA

ABSTRACT We identify a fading AGN SDSS J220141.64+115124.3 from the internal Product Launch-11 (MPL-11) in Mapping Nearby Galaxies at Apache Point Observatory (MaNGA) survey. The central region with a projected radius of $\sim$2.4 kpc is characterized as LINER-like line ratios while the outskirts extended to $\sim$15 kpc show Seyfert-like line ratios. The ${\rm{[O {\small III}]}}$$\lambda$5007 luminosity of the Seyfert regions is a factor of 37 (2) higher than the LINER regions without (with) dust attenuation correction, suggesting that the AGN activity decreases at least $\sim$8 $\times$ 10$^3$ yr ($\sim$2.4 kpc/light-speed) ago. We model the emission line spectra in the central region with double Gaussian components (a narrow core and a broad wing) and analyse the properties of each component. The narrow core component mostly co-rotates with the stellar disc, whereas the broad wing component with a median of the velocity dispersion $\sim$300 km s$^{-1}$ is related to a wind outflow. The kinematic position angle (PA) of the ionized gas shows an $\sim 20^{\circ }$ twist from the galaxy centre to 1.5 effective radius. The median of the PA difference between the gas and stellar components is as large as $\sim 50^{\circ }$ within 0.4 effective radius. The tidal feature in DESI image and star–gas misalignment suggest this galaxy is a merger remnant. Combining all these observational results as well as public available X-ray and MIR luminosities, we confirm this is a fading AGN, the merger process kick-started the central engine to quasar phase which ionized gas composed of tidal debris, and now the activity of the central black hole decreases. The discontinuity in ${\rm{[O {\small III}]}}$$\lambda$5007 flux and EQW maps is due to multiple AGN outbursts triggered by merger remnant gas inflows.

Mo, Hao (ORCID:0000000234430768)↗

Bubble Generation in a Flowing Liquid Medium and Resulting Two-Phase Flow in Microgravity

The present investigation reports a study of bubble generation under reduced gravity conditions, using both a co-flow and a cross-flow configuration. This study may be used in the conceptual design of a space-based thermal management system. Ensuing two-phase flow void fraction can be accurately monitored using a single nozzle gas injection system within a continuous liquid flow conduit, as utilized in the present investigation. Accurate monitoring of void fraction leads to precise control of heat and mass transfer coefficients related to a thermal management system; hence providing an efficient and highly effective means of removing heat aboard spacecraft or space stations. Our experiments are performed in parabolic flight aboard the modified DC-9 Reduced Gravity Research Aircraft at NASA Lewis Research Center, using an air-water system. For the purpose of bubble dispersion in a flowing liquid, we use both a co-flow and a cross-flow configuration. In the co-flow geometry, air is introduced through a nozzle in the same direction with the liquid flow. On the other hand, in the cross-flow configuration, air is injected perpendicular to the direction of water flow, via a nozzle protruding inside the two-phase flow conduit. Three different flow conduit (pipe) diameters are used, namely, 1.27 cm, 1.9 cm and 2.54 cm. Two different ratios of nozzle to pipe diameter (D(sub N))sup * are considered, namely (D(sub N))sup * = 0.1 and 0.2, while superficial liquid velocities are varied from 8 to 70 cm/s depending on flow conduit diameter. It is experimentally observed that by holding all other flow conditions and geometry constant, generated bubbles decrease in size with increase in superficial liquid velocity. Detached bubble diameter is shown to increase with air injection nozzle diameter. Likewise, generated bubbles grow in size with increasing pipe diameter. Along the same lines, it is shown that bubble frequency of formation increases and hence the time to detachment of a forming bubble decreases, as the superficial liquid velocity is in-creased. Furthermore, it is shown that the void fraction of the resulting two-phase flow increases with volumetric gas flow rate Q(sub d), pipe diameter and gas injection nozzle diameter, while they decrease with surrounding liquid flow. The important role played by flowing liquid in detaching bubbles in a reduced gravity environment is thus emphasized. We observe that the void fraction can be accurately controlled by using single nozzle gas injection, rather than by employing multiple port injection, since the later system gives rise to unpredictable coalescence of adjacent bubbles. It is of interest to note that empirical bubble size and corresponding void fraction are somewhat smaller for the co-flow geometry than the cross-flow configuration at similar flow conditions with similar pipe and nozzle diameters. In order to supplement the empirical data, a theoretical model is employed to study single bubble generation in the dynamic (Q(sub d) = 1 - 1000 cu cm/s) and bubbly flow regime within the framework of the co-flow configuration. This theoretical model is based on an overall force balance acting on the bubble during the two stages of generation, namely the expansion and the detachment stage. Two sets of forces, one aiding and the other inhibiting bubble detachment are identified. Under conditions of reduced gravity, gas momentum flux enhances, while the surface tension force at the air injection nozzle tip inhibits bubble detachment. In parallel, liquid drag and inertia can act as both attaching and detaching forces, depending on the relative velocity of the bubble with respect to the surrounding liquid. Predictions of the theoretical model compare well with our experimental results. However, at higher superficial liquid velocities, as the bubble loses its spherical form, empirical bubble size no longer matches the theoretical predictions. In summary, we have developed a combined experimental and theoretical work, which describes the complex process of bubble generation and resulting two-phase flow in a microgravity environment. Results of the present study can be used in a wide range of space-based applications, such as thermal energy and power generation, propulsion, cryogenic storage and long duration life support systems, necessary for programs such as NASA's Human Exploration for the Development of Space (HEDS).

Pais, S. C.↗

Extended anharmonic collapse of phonon dispersions in SnS and SnSe

The lattice dynamics and high-temperature structural transition in SnS and SnSe are investigated via inelastic neutron scattering, high-resolution Raman spectroscopy and anharmonic first-principles simulations. We uncover a spectacular, extreme softening and reconstruction of an entire manifold of low-energy acoustic and optic branches across a structural transition, reflecting strong directionality in bonding strength and anharmonicity. Further, our results solve a prior controversy by revealing the soft-mode mechanism of the phase transition that impacts thermal transport and thermoelectric efficiency. Our simulations of anharmonic phonon renormalization go beyond low-order perturbation theory and capture these striking effects, showing that the large phonon shifts directly affect the thermal conductivity by altering both the phonon scattering phase space and the group velocities. These results provide a detailed microscopic understanding of phase stability and thermal transport in technologically important materials, providing further insights on ways to control phonon propagation in thermoelectrics, photovoltaics, and other materials requiring thermal management.

36 MATERIALS SCIENCE↗