Thermal diffusion in the F2-region of the ionosphere
Thermal diffusion effects on F 2 region ion densities, deriving diffusion coefficients for partially ionized atomic oxygen plasma
Schunk, R. W.↗
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OGO-6 observations of 5577 A
A brief review is given of the data obtained by the horizon-scanning 5577-A airglow photometer flown aboard OGO 6. Data are presented which show the contributions to the 5577-A emission from the F-1 region and the Chapman airglow layer. Emission rates are calculated for both regions on the basis of the dissociative-recombination and Chapman reactions, and the atomic oxygen density and downward flux are inferred from the emission rates and several assumptions concerning the temperature dependence of the rate constants. Latitude variations in the emission rates are discussed along with variations in the altitude of the 5577-A airglow. It is shown that there is a large semiannual variation in the average effective transport properties of the lower thermosphere, that the atomic oxygen profiles near 110 km suggest a maximum in eddy diffusion at about that altitude, and that systematic variations in the altitude of the atomic oxygen maximum probably do not exceed 2 km.
Donahue, T. M.↗
The regulation of methane oxidation in soil
The atmospheric concentration of methane, a greenhouse gas, has more than doubled during the past 200 years. Consequently, identifying the factors influencing the flux of methane into the atmosphere is becoming increasingly important. Methanotrophs, microaerophilic organisms widespread in aerobic soils and sediments, oxidize methane to derive energy and carbon for biomass. In so doing, they play an important role in mitigating the flux of methane into the atmosphere. Several physico-chemical factors influence rates of methane oxidation in soil, including soil diffusivity; water potential; and levels of oxygen, methane, ammonium, nitrate, nitrite, and copper. Most of these factors exert their influence through interactions with methane monooxygenase (MMO), the enzyme that catalyzes the reaction converting methane to methanol, the first step in methane oxidation. Although biological factors such as competition and predation undoubtedly play a role in regulating the methanotroph population in soils, and thereby limit the amount of methane consumed by methanotrophs, the significance of these factors is unknown. Obtaining a better understanding of the ecology of methanotrophs will help elucidate the mechanisms that regulate soil methane oxidation.
Review, Academic↗
Single Conductor Alloy as Diffusion Barrier System and Simulataneous OHMIC Contact to N- and P-Type Silicon Carbide
Use of a single alloy conductor to form simultaneous ohmic contacts (SOC) to n- and p-type 4H-SiC. The single alloy conductor also is an effective diffusion barrier against gold (AU) and oxygen (O.sub.2) at high temperatures (e.g., up to 800.degree. C.). The innovation may also provide an effective interconnecting metallization in a multi-level metallization device scheme.
Okojie, Robert S.↗
Satellite observations of 557.7 NM airglow as a diagnostic technique to study the dynamics of the lower thermosphere
Photometric observations of the airglow limb at 557.7 nm have been made from the ISIS 2 satellite since 1971. From an analysis of 32,000 airglow limb observations obtained during the first two years of operation, the major temporal and spatial characteristics of the night airglow have been identified. Maxima occur in mid-October and mid-April at all latitudes. There is a marked variation with latitude during the equinox periods, with peak intensities near 35 degrees in autumn and near 25 degrees in spring. It is possible to gain considerable insight into the behavior of the lower thermosphere by combining the airglow observations with a simple model of the photochemical and dynamical processes. In this way a pattern of the latitude and temporal variation of atomic oxygen concentration at the peak of the layer as well as the eddy diffusion in this altitude region have been inferred. The concentration of atomic oxygen shows midlatitude peaks near equinox, and minima about one month after solstice. Average values at midlatitudes are about 1.3 times those at the equator. The amplitude of the semiannual component is about 20% of the mean value at 35 degrees as compared to 10% at the equator, and the amplitude of 12-month component is about 12% at 35 deg and 5% at the equator. The semiannual component has a minimum that occurs approximately 3 weeks (plus or minus) after solstice at all latitudes, while the 12-month component peaks in the summer hemisphere at solstice (plus or minus 2 months).
Cogger, L. L.↗
Mathematical model of water transport in Bacon and alkaline matrix-type hydrogen-oxygen fuel cells
Based on general mass continuity and diffusive transport equations, a mathematical model was developed that simulates the transport of water in Bacon and alkaline-matrix fuel cells. The derived model was validated by using it to analytically reproduce various Bacon and matrix-cell experimental water transport transients.
Prokopius, P. R.↗
Effect of Ram and Zenith Exposure on the Optical Properties of Polymers in Space
The temperature of spacecraft is influenced by the solar absorptance and thermal emittance of the external spacecraft materials. Optical and thermal properties can degrade over time in the harsh low Earth orbital (LEO) space environment where spacecraft external materials are exposed to various forms of radiation, thermal cycling, and atomic oxygen. Therefore, it is important to test the durability of spacecraft materials in the space environment. One objective of the Polymers and Zenith Polymers Experiments was to determine the effect of LEO space exposure on the optical properties of various spacecraft polymers. These experiments were flown as part of the Materials International Space Station Experiment 7 (MISSE 7) mission on the exterior of the International Space Station (ISS) for 1.5 years. Samples were flown in ram, wake or zenith directions, receiving varying amounts of atomic oxygen and solar radiation exposure. Total and diffuse reflectance and transmittance of flight and corresponding control samples were obtained post-flight using a Cary 5000 UV-Vis-NIR Spectrophotometer. Integrated air mass zero solar absorptance (s) of the flight and control samples were computed from the total transmittance and reflectance, and compared. The optical data are compared with similar polymers exposed to space for four years as part of MISSE 2, and with atomic oxygen erosion data, to help understand the degradation of these polymers in the space environment. Results show that prolonged space exposure increases the solar absorptance of some materials. Knowing which polymers remain stable will benefit future spacecraft design.
Yuanchun Li↗
The photophysics of monomeric bacteriochlorophylls c and d and their derivatives: properties of the triplet state and singlet oxygen photogeneration and quenching
Measurements of pigment triplet-triplet absorption, pigment phosphorescence and photosensitized singlet oxygen luminescence were carried out on solutions containing monomeric bacteriochlorophylls (Bchl) c and d, isolated from green photosynthetic bacteria, and their magnesium-free and farnesyl-free analogs. The energies of the pigment triplet states fell in the range 1.29-1.34 eV. The triplet lifetimes in aerobic solutions were 200-250 ns; they increased to 280 +/- 70 microseconds after nitrogen purging in liquid solutions and to 0.7-2.1 ms in a solid matrix at ambient or liquid nitrogen temperatures. Rate constants for quenching of the pigment triplet state by oxygen were (2.0-2.5) x 10(9) M-1 s-1, which is close to 1/9 of the rate constant for diffusion-controlled reactions. This quenching was accompanied by singlet oxygen formation. The quantum yields for the triplet state formation and singlet oxygen production were 55-75% in air-saturated solutions. Singlet oxygen quenching by ground-state pigment molecules was observed. Quenching was the most efficient for magnesium-containing pigments, kq = (0.31-1.2) x 10(9) M-1 s-1. It is caused mainly by a physical process of singlet oxygen (1O2) deactivation. Thus, Bchl c and d and their derivatives, as well as chlorophyll and Bchl a, combine a high efficiency of singlet oxygen production with the ability to protect photochemical and photobiological systems against damage by singlet oxygen.
NASA Discipline Number 52-30↗
Charge state distributions of oxygen and carbon in the energy range 1 to 300 keV/e observed with AMPTE/CCE in the magnetosphere
Observations of charge state distributions of oxygen and carbon are presented that were obtained with the charge-energy-mass spectrometer onboard the AMPTE/CCE spacecraft. Data were selected for two different local time sectors (apogee at 1300 LT and 0300 LT, respectively), three L-ranges (4-6, 6-8, and greater than 8), and quiet to moderately disturbed days (Kp less than or equal to 4). The charge state distributions reveal the existence of all charge states of oxygen and carbon in the magnetosphere. The relative importance of the different charge states strongly depends on L and much less on local time. The observations confirm that the solar wind and the ionosphere contribute to the oxygen population, whereas carbon only originates from the solar wind. The L-dependence of the charge state distributions can be interpreted in terms of these different ion sources and of charge exchange and diffusion processes that largely influence the distribution of oxygen and carbon in the magnetosphere.
Kremser, G.↗
Why does preferential diffusion strongly affect premixed turbulent combustion?
Combustion of premixed reactants in a turbulent flow is a classical but unresolved problem. The key problem is to explain the following data: the maximal turbulent and laminar burning velocities u(sub t) and u(sub L) occur at different equivalence ratios Phi. It is known that the equivalence ratio varies along a curved flame if molecular diffusivity D(sub fuel) does not equal D(sub oxygen). However, the mean flame radius of curvature is much larger than the laminar flame thickness delta-L. Therefore, significant influence of preferential diffusion should occur only if the flame propagation speed varies with flame curvature. This conclusion agrees with Zel'dovich's long-standing idea about the important role of leading points of a flame. The main objective of this paper is to prove Zel'dovich's hypothesis. An equation for the mean flame surface area density (MFSAD) is employed for this purpose. The second objective of this paper is to suggest a different approach to the derivation of the equation for MFSAD. It is based on the pdf equation for the reaction progress variable C and the relation between the pdf and MFSAD. This treatment suggests an entirely different closure assumption.
Kuznetsov, Vadim R.↗
High Temperature Degradation Mechanisms in Polymer Matrix Composites
Polymer matrix composites are increasingly used in demanding structural applications in which they may be exposed to harsh environments. The durability of such materials is a major concern, potentially limiting both the integrity of the structures and their useful lifetimes. The goal of the current investigation is to develop a mechanism-based model of the chemical degradation which occurs, such that given the external chemical environment and temperatures throughout the laminate, laminate geometry, and ply and/or constituent material properties, we can calculate the concentration of diffusing substances and extent of chemical degradation as functions of time and position throughout the laminate. This objective is met through the development and use of analytical models, coupled to an analysis-driven experimental program which offers both quantitative and qualitative information on the degradation mechanism. Preliminary analyses using coupled diffusion/reaction model are used to gain insight into the physics of the degradation mechanisms and to identify crucial material parameters. An experimental program is defined based on the results of the preliminary analysis which allows the determination of the necessary material coefficients. Thermogravimetric analyses are carried out in nitrogen, air, and oxygen to provide quantitative information on thermal and oxidative reactions. Powdered samples are used to eliminate diffusion effects. Tests in both inert and oxidative environments allow the separation of thermal and oxidative contributions to specimen mass loss. The concentration dependency of the oxidative reactions is determined from the tests in pure oxygen. Short term isothermal tests at different temperatures are carried out on neat resin and unidirectional macroscopic specimens to identify diffusion effects. Mass loss, specimen shrinkage, the formation of degraded surface layers and surface cracking are recorded as functions of exposure time. Geometry effects in the neat resin, and anisotropic diffusion effects in the composites, are identified through the use of specimens with different aspect ratios. The data is used with the model to determine reaction coefficients and effective diffusion coefficients. The empirical and analytical correlations confirm the preliminary model results which suggest that mass loss at lower temperatures is dominated by oxidative reactions and that these reaction are limited by diffusion of oxygen from the surface. The mechanism-based model is able to successfully capture the basic physics of the degradation phenomena under a wide range of test conditions. The analysis-based test design is successful in separating out oxidative, thermal, and diffusion effects to allow the determination of material coefficients. This success confirms the basic picture of the process; however, a more complete understanding of some aspects of the physics are required before truly predictive capability can be achieved.
Cunningham, Ronan A.↗
High Temperature Degradation Mechanisms in Polymer Matrix Composites
Polymer matrix composites are increasingly used in demanding structural applications in which they may be exposed to harsh environments. The durability of such materials is a major concern, potentially limiting both the integrity of the structures and their useful lifetimes. The goal of the current investigation is to develop a mechanism-based model of the chemical degradation which occurs, such that given the external chemical environment and temperatures throughout the laminate, laminate geometry, and ply and/or constituent material properties, we can calculate the concentration of diffusing substances and extent of chemical degradation as functions of time and position throughout the laminate. This objective is met through the development and use of analytical models, coupled to an analysis-driven experimental program which offers both quantitative and qualitative information on the degradation mechanism. Preliminary analyses using a coupled diffusion/reaction model are used to gain insight into the physics of the degradation mechanisms and to identify crucial material parameters. An experimental program is defined based on the results of the preliminary analysis which allows the determination of the necessary material coefficients. Thermogravimetric analyses are carried out in nitrogen, air, and oxygen to provide quantitative information on thermal and oxidative reactions. Powdered samples are used to eliminate diffusion effects. Tests in both inert and oxidative environments allow the separation of thermal and oxidative contributions to specimen mass loss. The concentration dependency of the oxidative reactions is determined from the tests in pure oxygen. Short term isothermal tests at different temperatures are carried out on neat resin and unidirectional macroscopic specimens to identify diffusion effects. Mass loss, specimen shrinkage, the formation of degraded surface layers and surface cracking are recorded as functions of exposure time. Geometry effects in the neat resin, and anisotropic diffusion effects in the composites, are identified through the use of specimens with different aspect ratios. The data is used with the model to determine reaction coefficients and effective diffusion coefficients. The empirical and analytical correlations confirm the preliminary model results which suggest that mass loss at lower temperatures is dominated by oxidative reactions and that these reaction are limited by diffusion of oxygen from the surface. The mechanism-based model is able to successfully capture the basic physics of the degradation phenomena under a wide range of test conditions. The analysis-based test design is successful in separating out oxidative, thermal, and diffusion effects to allow the determination of material coefficients. This success confirms the basic picture of the process; however, a more complete understanding of some aspects of the physics are required before truly predictive capability can be achieved.
Cunningham, Ronan A.↗
Computation Of Facilitated Transport of O2 In Hemoglobin
Report describes computations of unsteady facilitated transport of oxygen through liquid membrane of hemoglobin. Used here, "facilitated transport" means diffusion of permeant through membrane in which that diffusion enhanced by reversible chemical reaction between permeant and membrane. In this case, reversible reactions between hemoglobin and oxygen.
Davis, Sanford↗
A model of concurrent flow flame spread over a thin solid fuel
A numerical model is developed to examine laminar flame spread and extinction over a thin solid fuel in lowspeed concurrent flows. The model provides a more precise fluid-mechanical description of the flame by incorporating an elliptic treatment of the upstream flame stabilization zone near the fuel burnout point. Parabolic equations are used to treat the downstream flame, which has a higher flow Reynolds number. The parabolic and elliptic regions are coupled smoothly by an appropriate matching of boundary conditions. The solid phase consists of an energy equation with surface radiative loss and a surface pyrolysis relation. Steady spread with constant flame and pyrolysis lengths is found possible for thin fuels and this facilitates the adoption of a moving coordinate system attached to the flame with the flame spread rate being an eigen value. Calculations are performed in purely forced flow in a range of velocities which are lower than those induced in a normal gravity buoyant environment. Both quenching and blowoff extinction are observed. The results show that as flow velocity or oxygen percentage is reduced, the flame spread rate, the pyrolysis length, and the flame length all decrease, as expected. The flame standoff distance from the solid and the reaction zone thickness, however, first increase with decreasing flow velocity, but eventually decrease very near the quenching extinction limit. The short, diffuse flames observed at low flow velocities and oxygen levels are consistent with available experimental data. The maximum flame temperature decreases slowly at first as flow velocity is reduced, then falls more steeply close to the quenching extinction limit. Low velocity quenching occurs as a result of heat loss. At low velocities, surface radiative loss becomes a significant fraction of the total combustion heat release. In addition, the shorter flame length causes an increase in the fraction of conduction downstream compared to conduction to the fuel. These heat losses lead to lower flame temperatures, and ultimately, extinction. This extinction mechanism differs from that of blowoff, where the flame is unable to be stabilized due to the high flow velocity.
Ferkul, Paul V.↗
Radial diffusion and ion partitioning in the Io torus
A model is presented for radial diffusion and charge state partitioning of sulfur and oxygen ions in the Io torus, including effects of electron impact and charge exchange. When applied to Voyager 1 radial profiles of total ion flux tube content, the model shows that the ion residence time in the torus, tau(D), as defined in spectroscopic studies of ion partitioning, is related to the radial diffusion coefficient, D(LL), at L = 7 by tau(D) approximately 8/D(LL)(7). This result appears to bring spectroscopic estimates of the ion residence time (tau/D/ greater than about 60 to 100 days) into reasonable agreement with estimates of D(LL) from magnetospheric diffusion studies, D(LL) equals approximately 10 to the -6th/s.
Cheng, A. F.↗
Self-organized Spiral and Circular Waves in Premixed Gas Flames
A diffusive-thermal high Lewis number (Le) gas-phase oscillator has been observed in premixed flames using a lean mixture of butane and oxygen diluted with helium (Le approx. 3.0). This reactive-diffusive system exhibits both propagating radial pulsations and rotating spiral waves perhaps,analogous to those observed in other excitable media such as the Belousov-Zhabotinsky reaction.
Pealman, Howard G.↗
Molecular oxygen measurements at 200 km from AE-D near winter solstice, 1975
Utilizing the fly-through mode, the open source neutral mass spectrometer on Atmosphere Explorer-D (AE-D) has measured O2 densities, as well as N2 densities and in situ neutral temperatures, at midmorning during winter solstice over the latitude range 90 degrees S to 90 degrees N. The expected seasonal variation in N2 was found at 200 km together with a more complex behavior in molecular oxygen than might be expected from a diffusive equilibrium model with constant lower boundary values. Under geomagnetically quiet conditions the equatorial 200 km value of O2 was about 1.7 x 10 to the 8th/cu cm. A local maximum in the 200 km O2 densities was found near 70 degrees N, where an average quiet time value was 2.5 x 10 to the 8th/cu cm, implying a 120 km density of 8.3 x 10 to the 10th/cu cm. The in situ temperature measurements confirm the presence of higher temperatures near 70 degrees N latitude, even during geomagnetically quiet conditions.
Kayser, D. C.↗
Energetic heavy ions with nuclear charge Z greater than or equal to 4 in the equatorial radiation belts of the earth - Magnetic storms
Direct in situ observations of trapped energetic heavy ions with nuclear charge Z greater than or equal to 4 at energies in the lower MeV range made with Explorer 45 during the period June-December 1972 are presented. It is noted that all measurements were carried out in the vicinity of the geomagnetic equatorial plane and that the data show the varying effects of four major magnetic storm periods. Orders of magnitude increases in the trapped heavy ion population are seen deep within the radiation belts following the August 1972 solar flare and magnetic storm events. Fluxes of the Z greater than or equal to 4 ions are found to decay faster than those of helium ions of comparable energies; typical decay times for these ions are found to be 24-40 days at L less than or equal to 4 and shorter at higher L shells. The observations are compared with the expected post-injection long-term behavior of atomic oxygen ions deduced from charge exhange, radial diffusive transport, and Coulomb collisions. Good agreement is found between theory and observations.
Spjeldvik, W. N.↗