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At least 235 records · Page 13

Synthesis and electrical transport properties of superconducting platinum silicide thin films and devices

Here, we evaluate the material characteristics of superconducting platinum silicide (PtSi) thin films as candidate materials for superconducting quantum information devices compatible with silicon technology. These films were synthesized using magnetron sputtering under ultrahigh vacuum conditions, followed by rapid thermal annealing. Polycrystalline PtSi films synthesized by this method have the favorable properties of superconducting critical temperature of 0.95 K and relatively long zero-temperature Ginzburg-Landau coherence length of 76 nm. We further studied coplanar microbridge devices fabricated by electron beam lithography and chlorine-free reactive ion etching, finding that the temperature-dependent critical current density follows the Ginzburg Landau depairing mechanism.

36 MATERIALS SCIENCE↗

Cost Efficient and Highly Weather-Resistant Solar Panel Backsheet Produced through Continuous Co-Extrusion Processing

The efficient generation and delivery of ‘clean energy” through photovoltaic (PV) technology relies heavily on the cost, performance and reliability of solar panels, along with the individual components used in assembly of those panels. In order to continue towards the Department of Energy’s (DOE) goals of driving costs down, the lifetime of high-output power generation equipment (i.e. solar modules) must be extended to reduce costs associated with power output degradation and replacement of failed or degraded panels. One of the major sources of module failures in the past 30 years has been the failure of the solar panel backsheet. Failure of this component causes severe output losses due to oxidation and yellowing of the module while creating safety concerns as the major electrical insulation of the module is compromised. Tomark-Worthen LLC was formed in 2012 with the goal of designing and manufacturing novel PV backsheets and encapsulants that would be produced in the United States of America and exceed expectations of domestic and international module producers. These backsheets would improve upon known backsheet design failures (i.e. Isovoltaic’s AAA backsheet) and create domestic manufacturing jobs in the PV sector. This goal became a reality with a first-generation product in 2018 and now, with the support of the DOE, Tomark-Worthen has launched a second-generation product known as PhotoMark® Reflections™ 205-3 and 360-3. This 2+ year effort began in late 2017 with a screening of potential polymeric materials and backsheet structural designs. Performance evaluations of each material provided the necessary data needed to select the proper material combinations and move forward into the design of the manufacturing process. These decisions were made by teaming with a local university, well-respected government laboratories, and private research organizations who provided the tools necessary to predict long-term performance of these materials in much shorter periods of time. Once the go/no-go criteria were met at the mid-point of the project, the effort transitioned to predicting 30+ year performance, achieving certifications, and improving manufacturing efficiencies designed to lower costs in order to be competitive in a cost-driven market. Major project accomplishments include recognition of the new backsheet by Underwriters Laboratories (UL) and international certification for 1000V and 1500V modules by TUV Sud. Both 1000V and 1500V products have been proven on several module manufacturing lines and initial customer orders have been received by both domestic and international module producers. Accelerated exposure testing has shown that the performance of this backsheet exceeds the prior polyamide-based backsheet known to fail in the field. Cost-models and initial customer orders have shown the ability to produce this backsheet at a cost acceptable to many domestic manufacturers, while International costs for standard backsheet remains extremely low. Tomark-Worthen remains one of the only U.S. companies manufacturing backsheet domestically and this has drawn interest from many domestic module manufacturers looking to improve their material supply logistics by avoiding long lead times and custom’s headaches while avoiding current tariffs on Chinese-made components. Along with the launch of a new PV backsheet, this project has provided a critical deliverable to the PV R&D community. This deliverable is the knowledge that not all polyamide-containing backsheets are doomed to failure as the earlier versions did. There has been a fear amongst the PV community to consider these materials due to the failure of one design. This effort has brought a new level of interest to the scientific community as it has been shown that polyamides can be used successfully in a well-designed backsheet. As we move forward from this project, we are excited to see how backsheet technology and manufacturing in the U.S. will continue to progress and grow.

14 SOLAR ENERGY↗

Nuclear Criticality Safety in Practice [Slides]

The agenda for the presentation includes the following topics: Requirements; How is criticality safety practiced; criticality safety evaluations; fissionable material operation review; and, procedures.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

Test Plan for Investigation of Hydrogen Generation in SNF Canisters

This report presents a test plan to investigate radiolytic hydrogen generation in spent nuclear fuel (SNF) canisters containing Zr-based cladding materials. The initial primary contributor to the generation of radiolytic hydrogen is estimated to be the residual physisorbed water on the ZrO 2 film, post-dry out. Over the longer term the primary hydrogen source is associated with the aluminum hydroxides and water vapor. The proposed testing to be conducted in FY22 would consist of lab-scale testing on non-radioactive surrogates of oxidized ZIRLO tubing and unalloyed zirconium using a miniature steel canister (“mini-canister") designed to allow intermittent, in-situ sampling of the canister gas during irradiation. The mini-canister approach for irradiation with in-situ monitoring system was used in a recent and on-going study [McNamara and Verst, 2020a & 2020b; Verst et al., 2021] to measure radiolytic hydrogen generation from aluminum SNF cladding surrogate materials. This proposed testing will form part of the overall materials performance evaluation of the commercial SNF-in-canister system and is part of the technical bases for their continued safe dry storage

08 HYDROGEN↗

Project Task Statement 2 to Umbrella Cooperative Research and Development Agreement between National Energy Technology Laboratory and Ramaco Carbon [Abstract]

NETL and Ramaco will collaborate to characterize domestic coal, beneficiated coal, and coal byproducts to evaluate these materials for rare earth element (REE) content and ease of extraction. Ramaco will provide samples of coal, beneficiated coal, and coal byproducts to NETL, as well as provide research expertise on coal extraction and processing. NETL will characterize these feedstocks using the chemical/physical methods being utilized in its research laboratories. The objectives of this project are: identify promising coal-related REE reserves by testing and analysis of core samples from coal bearing formations; provide insights and expertise into opportunities for the extraction of REEs and other value-added products from domestic coal; and collect data that will be used to create quantitative modeling tools for predicting the likelihood of successful prospecting for REEs in coal, beneficiated and processed coal, and related geologic formation.

01 COAL, LIGNITE, AND PEAT↗

Advanced Modeling and Simulations for Evaluation of Thermal Neutron Scattering Materials [Slides]

In this presentation, researchers detail tradeoffs between two simulation suites for thermal neutron scattering data. OXLIMAX + MCViNE provide a more accurate elastic peak shape and NJOY + MCNP have more accurate spectra between phonon mode peaks (most likely due to multiple neutron scattering). Additionally, some outstanding issues with MCViNE are noted, including multiple neutron scattering and non-uniform (Q,E) grid for data.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗

Production and Separations for High Specific Activity 186 Re, 189 Re and 47 Sc for Research and Clinical Applications: effective design of targets and recycling of targets and radioisotope separation

This grant involved three objectives for producing high specific activity radionuclides using reactor and accelerator technologies that would find use in medical, industrial and research applications. There was a strong emphasis in all projects to develop and train staff and students in all aspects of targetry, reactor and accelerator production, separation of radionuclides from enriched target material, and evaluating the specific activity of the product radionuclides. An additional objective was training of students (undergraduate, graduate, postdoctoral) in all aspects of radiochemistry.

07 ISOTOPE AND RADIATION SOURCES↗

Useability and Optimization Improvements in MOOSE

The Multiphysics Object-Oriented Simulation Environment (MOOSE) framework is a foundational capability used by the Nuclear Energy Advanced Modeling and Simulation (NEAMS) program to create over 15 different simulation tools for advanced nuclear reactors. Due to this broad use, improvements to the framework in support of modeling and simulation goals are critical to the program. These improvements can take many forms, including optimization, improved user experience, streamlined application programming interfaces (APIs), parallelism, and new capabilities. The work transcribed in this report was conducted in direct support of the simulation tools and has already been deployed or will be deployed in the coming months. The capabilities were implemented in the same order as they are covered in this report: increased support of face variables, arbitrary spatial and temporal evaluation of material properties, and the addition of a triangular meshing library in libMesh.

97 MATHEMATICS AND COMPUTING↗

Summary Report for the 2019 Radiation Detection for Nuclear Security Summer School

The Pacific Northwest National Laboratory (PNNL) hosted students from across the United States at the 6th Radiation Detection for Nuclear Security Summer School 17-28 June 2019. The summer school provided students with a unique understanding of nuclear security challenges faced in the field and exposed them to the technical foundations, analyses, and insight that will be required by future leaders in technology development and implementation. The course heavily emphasized laboratory and field demonstrations including measurements of special nuclear material. Student evaluations and feedback from student advisors indicates that the summer school achieved its objectives of 1) exposing students to the range of nuclear security applications for which radiation detection is necessary, 2) articulating the relevance of student research into the broader context, and 3) growing student interest in careers in nuclear security.

61 RADIATION PROTECTION AND DOSIMETRY↗

Assessment of tank designs for hydrogen storage on heavy duty vehicles using metal hydrides

The objective of this project was to evaluate material-based hydrogen storage solutions as a replacement for high-pressure hydrogen gas or liquid hydrogen on Class 7 or 8 tractor fuel cell electric vehicles. The project focused on low-density main-group hydrides, a well-known class of materials for hydrogen storage. Prior research has considered metal amides as storage materials for light-duty vehicles but not for heavy-duty applications. The project established the basis for further development of storage systems of this type for heavy duty vehicles (HDV). Systems analysis of an HDV storage system comprised of a tank and associated balance of plant (piping, coolant tubes, burner) was performed to determine the usable hydrogen capacity. A composite storage material comprised of a metal hydride mixed with a high thermal-conductivity carbon is predicted to have a usable hydrogen volumetric capacity comparable to or exceeding that of 700 bar pressurized hydrogen gas. The gravimetric capacity of this material is also predicted to be competitive with pressurized gas, particularly if costly carbon fiber composite Type III or Type IV tanks are excluded. The storage system design parameters and material properties served as inputs to a second model that simulates fuel cell operation in conjunction with the storage system during an HDV drive cycle. The results show that sufficient hydrogen pressure can be produced to operate a Class 8 HDV, yielding a range of ~480 miles. These results are particularly relevant for high-impact regions, such as the South Coast Air Quality Management District, for which an economical vehicular hydrogen storage system with minimal impact on cargo capacity could accelerate adoption of heavy-duty fuel cell electric vehicles. An additional benefit is that knowledge generated by this project can assist in development of material-based storage for stationary applications such as microgrids and backup power for data centers.

08 HYDROGEN↗

Material Control and Accounting for Liquid-Fueled Molten Salt Reactors: Material Control and Holdup Considerations

The US Nuclear Regulatory Commission (NRC) will likely require license applicants for liquid-fueled molten salt reactors (MSRs) with circulating fuel to submit a nuclear material control and accounting (MC&A) plan or detailed MC&A program description for the facility. In liquid-fueled MSRs with special nuclear material (SNM) in bulk (i.e., not in discrete items) form and rapidly changing quantities due to fuel transmutation and depletion, using traditional nuclear material accounting methods with material balance evaluations is challenging. In reactors with changing inventories, these expected quantities of SNM must be calculated based on operational parameters. Reducing uncertainties on these expected quantities is challenging in the case of MSRs without decades of operational experience to verify and validate predictive computational codes. Moreover, many areas in MSRs are inaccessible because of high-temperature and high-radiation environments, making measurements challenging.

22 GENERAL STUDIES OF NUCLEAR REACTORS↗

Control Boundary Analysis for Liquid-Fueled Molten Salt Reactors

The US Nuclear Regulatory Commission (NRC) will likely require license applicants for liquid-fueled molten salt reactors (MSRs) with circulating fuel to submit a nuclear material control and accounting (MC&A) plan or provide a detailed MC&A program description for the facility. In liquid-fueled MSRs with special nuclear material (SNM) in bulk form (i.e., not in discrete items) and with rapidly changing quantities due to fuel transmutation and depletion, a novel MC&A approach is needed because traditional nuclear material accounting methods with material balance evaluations will not be sufficient. This report details the continued efforts carried out at Oak Ridge National Laboratory (ORNL) during FY 2025 to develop a distinct MC&A approach suitable specifically for domestic safeguards of the first-of-a-kind MSRs. These efforts are built on previous ORNL efforts reported in ORNL/SPR-2023/3181 and ORNL/SPR-2024/3555.

22 GENERAL STUDIES OF NUCLEAR REACTORS↗

FY25 Task 5: Small-Scale Mixing

The U.S. Department of Energy (DOE) Hanford Site has 177 underground storage tanks that contain a complex and diverse mix of chemical and radioactive wastes from past nuclear fuel reprocessing and waste management operations. The strategy of the DOE Hanford Field Office is to retrieve this waste, ~20 vol% of which is in the form of insoluble undissolved solids (UDS) or sludge, and treat it via immobilization at the Hanford Waste Treatment and Immobilization Plant (WTP). The diverse properties and characteristics of Hanford tank waste lead to major challenges related to its transport from the underground tanks to the WTP. These challenges, however, can be addressed by investigating the behavior of tank waste samples and simulant materials and evaluating their behavior against the capabilities of mixing and transport system designs that may be incorporated to retrieve and treat the waste.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Impact of Biodiesel, Renewable Diesel, 1-Octanol, Dibutoxymethane, n-Undecane, Hexyl hexanoate and 2-Nonanone with Infrastructure Plastics as Blends with Diesel

In this work the volume and hardness were measured for thermoplastics and thermosetting resins with diesel containing up to 30% of the following blend stocks: biodiesel, renewable diesel, n-undecane, dibutoxymethane, 1-octanol, hexyl hexanoate, and 2-nonanone. Thermoplastics included polyphenylene sulfide (PPS), polyethylene terephthalate (PET), polytetrafluoroethylene (PTFE), polyvinylidene fluoride (PVDF), polyoxymethylene (POM), polybutylene terephthalate (PBT), polypropylene (PP), high density polyethylene (HDPE), nylons, acetals, polyetherimide (PEI), polyetheretherketone (PEEK), a PET co-polymer, polyphthalamides (PPAs), polyarylamide (PARA) and ethylene tetrafluoroethylene (ETFE). Three thermosetting resins were also evaluated. The material specimens were exposed to the test fuels under ambient conditions for 16 weeks. In general, the volume and hardness of the specimens were relatively unaffected following exposure to the test fuels; however, n-undecane produced significant swelling in polypropylene and may not be suitable for use with this material. N-undecane, along with hexyl hexanoate and 2-nonanone also caused low levels of swelling in nylon, which was not significant enough to preclude the use of nylons in sealing applications with these fuels.

09 BIOMASS FUELS↗

Effects of Accident Thermal Loading on In-Plane Shear Behavior of Steel-Plate Composite Walls

Structural walls in safety-related nuclear facilities are required to be designed for seismic and accident thermal (due to postulated high-energy pipe break events) loading combination. Current U.S. and international codes provide limited guidance for analysis and design of walls for this loading combination. This paper describes the experimental results and observations from tests conducted on a laboratory-scale (1:4 to 1:5) test unit representing steel-plate composite (SC) walls subjected to combined in-plane (seismic) and accident thermal loading. The test unit was subjected to surface temperatures of up to 450°F in combination with cyclic in-plane loading. Results of similar experiments recently conducted in Japan are also summarized (with surface temperatures up to 570°F). Surface heating combined with the low thermal conductivity and high specific heat of concrete resulted in nonlinear thermal gradients through the thickness of the specimens. These nonlinear thermal gradients and the associated self- or internal restraint led to extensive concrete cracking. This concrete cracking reduced the initial and secant stiffness of the specimens. The initial stiffness of the heated specimens reduced to 30 to 40% of the initial stiffness of the control (unheated) specimen. The secant stiffness of the heated specimens reduced up to 50% of the secant stiffness of the control (unheated) specimen. However, the in-plane shear strength of the heated SC specimens was still approximately 10 to 30% greater than the nominal in-plane shear strength calculated, for the limit state of steel plate von Mises yielding, using AISC N690 equations and measured material properties. Evaluation of the experimental results and observations suggests that the in-plane shear strength of SC walls subjected to typical accident surface temperatures (up to 570°F) can be estimated conservatively using the current provisions of AISC N690. The stiffness for accident thermal loading combinations can be considered to reduce from cracked composite stiffness at ambient temperature to fully cracked—that is, steel-only stiffness as the surface temperature increases up to typical accident value.

Construction & Building Technology↗

Electric Motor Thermal Management

The poster reports the accomplishments of EDT-Electric Motor Thermal Management consortium project for 2024 VTO Annual Merit Review (AMR). The overall aims of the project are to support research enabling compact, reliable, low-cost, and efficient electric machines aligned with roadmap research areas; to collaborate with ORNL, Ames, and SNL to provide motor thermal analysis support, reliability evaluation, and material measurements on related motor research at national laboratories; and collaborate with university partners including Georgia Institute of Technology and University of Wisconsin Madison to support university-led motor thermal management research efforts.

ADVANCED PROPULSION SYSTEMS↗

FY24 progress report on A709 mechanical properties data development and A709 thermal aging status

The report provides the status of the creep, fatigue, and creep-fatigue testing to date conducted at Idaho National Laboratory to generate the data package. This data package evaluates the material performance from three commercial heats to support the Alloy 709 qualification in American Society of Mechanical Engineers, Boiler and Pressure Vessel Code, Section III, Division 5. First procured heat was manufactured by G.O. Carlson with heat number 58776. Second and third heats were fabricated by ATI Specialty Rolled Products with heat numbers 529900 and 530843, respectively. A series of creep and cyclic specimens were fabricated from these three heats and tests were performed. A list of finished, ongoing, and planned test are presented for creep, fatigue, and creep-fatigue tests. Cyclic properties of three commercial heats are compared.

36 MATERIALS SCIENCE↗

FY24 progress report on A709 mechanical properties data development and A709 thermal aging status

The report provides the status of the creep, fatigue, and creep-fatigue testing to date conducted at Idaho National Laboratory to generate the data package. This data package evaluates the material performance from three commercial heats to support the Alloy 709 qualification in American Society of Mechanical Engineers, Boiler and Pressure Vessel Code, Section III, Division 5. First procured heat was manufactured by G.O. Carlson with heat number 58776. Second and third heats were fabricated by ATI Specialty Rolled Products with heat numbers 529900 and 530843, respectively. A series of creep and cyclic specimens were fabricated from these three heats and tests were performed. A list of finished, ongoing, and planned test are presented for creep, fatigue, and creep-fatigue tests. Cyclic properties of three commercial heats are compared.

36 - MATERIALS SCIENCE↗