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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 235 records · Page 13
All sourcesNASA NTRSDOE OSTI
NASA NTRS1975

Atomic nitrogen measurements in the upper atmosphere

The open-source neutral mass spectrometer (OSS) on the Atmosphere Explorer-C satellite (AE-C) measures the neutral constituents of the upper atmosphere. It has been found that atomic nitrogen densities can be determined at altitudes above 380 km. Most of the nitrogen atoms combine with oxygen adsorbed on the walls of the ion source to form NO. The measured net peaks at 14 amu and 30 amu show the scale height expected for atomic nitrogen; both peaks have a pronounced diurnal variation. Absolute number densities at 400 km are computed for a time period between February and April 1974 when measurements were taken in the northern hemisphere. Minimum and maximum densities of atomic nitrogen occur between 4 and 6 hr LST in the morning and around 16 hr LST in the afternoon, respectively. At 400 km, the minimum particle density is 100,000/cu cm and the maximum density 1.5 million/cu cm. In contrast to the response of N2 to geomagnetic activity, atomic N shows no appreciable effect.

Mauersberger, K.↗
NASA NTRS1992

Semikinetic modeling of the outflow of ionospheric plasma through the topside collisional to collisionless transition region

A collisional semikinetic model is applied to the study of the topside ionosphere transition region. The paper considers the transition from (1) O(+) to H(+) dominance; (2) subsonic to supersonic H(+) flow; and (3) collisional to collisionless plasma. The H(+) ions flow upward from a relatively low altitude of 500-1000 km to a high altitude of 7000 km. These ions are subjected to collisions with O(+) ions and self collisions, as well as the effects of macroscopic forces such as the magnetic mirror force, gravity, and the ambipolar electric force. When supersonic outflow occurs, the H(+) velocity-distribution function shows a large departure from Maxwellian with a large positive and then negative heat flow, particularly in the region where the flow Mach number passes through one. In cases where subsonic outflow occurs and the H(+) density is relatively low, distribution functions with two peaks can occur. In these situations the H(+) ions have large parallel temperatures and large heat flows when the two peaks are of unequal height.

Wilson, G. R.↗
DOE OSTI2020

Impact of a minority relativistic electron tail interacting with a thermal plasma containing high-atomic-number impurities

A minority relativistic electron component can arise in both laboratory and naturally-occurring plasmas. In the presence of high-atomic-number ion species, the ion charge state distribution at low bulk electron temperature can be dominated by relativistic electrons, even though their density is orders of magnitude lower. This is due to the relativistic enhancement of the collisional excitation and ionization cross sections. The resulting charge state effect can dramatically impact the radiative power loss rate and the related Bethe stopping power of relativistic electrons in a dilute plasma.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗
NASA NTRS1972

Lifetime and quenching of CO /a super 3 pi/ produced by recombination of CO2 ions in a helium afterglow.

Demonstration that rapid dissociative recombination of CO2(+) in a flowing, helium afterglow is an efficient source of CO in the a super 3 pi metastable state. Ions produced by mixing CO2 with He(2 super 3 S) recombine to produce a CO metastable afterglow with a number density as great as 10 to the 9th per sq cm. Monitoring of the (a super 3 pi-X super 1 sigma) Cameron transition in CO was used to study the lifetime and quenching of CO (a super 3 pi) by CO2, N2, NO, and He. Recombination of CO2(+) also produces CO in the d super 3 delta and a' super 3 sigma states.

Wauchop, T. S.↗
NASA NTRS1979

Some initial ISEE-1 results on the ring current composition and dynamics during the magnetics storm of December 11, 1977

On December 11, 1977 the ISEE-1 spacecraft traversed the equatorial magnetosphere in the prenoon and dawn sectors during the early recovery phase of a magnetic storm with peak DST of -125 gamma. Along the dayside leg O(+) was comparable to or exceeded H(+) in number density in the energy range 0.1-17 keV. The velocity distribution of O(+) showed a characteristic dispersion, consistent with the ions being transported to the dayside from the dusk to midnight sector. The high-energy slope of the H(+) and O(+) distribution functions showed different radial dependence, with the slope of H(+) being consistent with a harder component carrying most of the energy density.

Lennartsson, W.↗
NASA NTRS1983

The problem of cooling the cold Io torus

Two models are developed for the transport of ions inward from Io's orbit, the first using the assumption that radial diffusion is the dominant transport mechanism while the second uses a combination of diffusive and convective transport. The models include thermal and number density transport, radiation, ionization and pickup of local neutrals, recombination, charge exchange, and Coulomb interactions. It is found that pure diffusive transport can account for the dramatic inward depletion of the torus only by invoking recombination or by postulating a massive increase in the production rate of torus ions sometime prior to the Voyager mission. Recombination is determined to be far too slow to be the cause of the observed density decrease inside of Io. The model combining convection and diffusion is shown to reasonably match the data, but only if a diffusion coefficient 100 times less than that derived from Pioneer observations is used. In addition, it is shown that the Pioneer derived diffusion rate combined with Voyager temperature and density measurements indicate a large nonradiative sink of energy in the inner torus.

Richardson, J. D.↗
NASA NTRS1995

WIND measurements of proton and alpha particle flow and number density

We propose to review measurements of the solar wind proton and alpha particle flow velocities and densities made since launch with the WIND SWE instrument. The SWE Faraday cup ion sensors are designed to be able to determine accurately flow vector directions, and thus can be used to detect proton-alpha particle differential flow. Instances of differential flow, and the solar wind features with which they are associated will be discussed. Additionally, the variability of the percentage of alpha particles as a fraction of the total solar wind ion density will be presented.

Steinberg, J. T.↗
NASA NTRS1978

Fe/+/ ions in the high latitude F-region

Ion mass-spectrometer measurements on Atmosphere Explorer C orbits from December 1974 to December 1976 were surveyed poleward of + or - 30 deg for instances in which the Fe(+) number density exceeded the spectrometer threshold sensitivity of 30/cu cm. The occurrences of Fe(+) within the altitude range covered by the orbit, 220 to 320 km, revealed a distinct pattern apparently associated with regions of upward plasma transport. At night a band of such events occurred between 50 and 60 deg invariant latitude, which typically corresponded to the location of the main ionospheric trough. In this region large upward ion drifts due to the drag of an equatorward-blowing neutral wind are expected. The Fe(+) band extends past 0600 MLT to about 1100 MLT during the summer, but is not observed in the afternoon. The dayside distributions possibly result from the upward drifts of F-region ions detected by backscatter techniques after dawn during summer. At higher latitudes patches of Fe(+) were detected in regions where strong plasma drifts often prevail and hence where poleward E x B drift motions and atmospheric expansion through Joule heating can lift the ions upwards.

Grebowsky, J. M.↗
NASA NTRS1993

Modeling the Europa plasma torus

The existence of a torus of plasma generated by sputtering from Jupiter's satellite Europa has long been suspected but never yet convincingly demonstrated. Temperature profiles from Voyager plasma observations indicate the presence of hot, possibly freshly picked-up ions in the general vicinity of the orbit of Europa, which may be interpreted as evidence for a local plasma torus. Studies of ion partitioning in the outer regions of the Io torus reveal that the oxygen to sulfur mixing ratio varies with radial distance; this may indicates that oxygen-rich matter is injected from a non-Io source, most probably Europa. We have constructed a quantitative model of a plasma torus near the orbit of Europa which takes into account plasma input from the Io torus, sputtering from the surface of Europa, a great number of ionization and charge exchange processes, and plasma loss by diffusive transport. When the transport time is chosen so that the model's total number density in consistent with the observed total plasma density, the contribution from Europa is found to be significant although not dominant. The model predicts in detail the ion composition, charge states, and the relative fractions of hot Europa-generated and (presumed) cold Io-generated ions. The results are generally consistent with observations from Voyager and can in principle (subject to limitations of data coverage) be confirmed in more detail by Ulysses.

Schreier, Ron↗
DOE OSTI2020

Highly-Cyclable Room-Temperature Phosphorene Polymer Electrolyte Composites for Li Metal Batteries

Despite significant interest toward solid-state electrolytes owing to their superior safety in comparison to liquid-based electrolytes, sluggish ion diffusion and high interfacial resistance limit their application in durable and high-power density batteries. Here, a novel quasi-solid Li + ion conductive nanocomposite polymer electrolyte containing black phosphorous (BP) nanosheets is reported. The developed electrolyte is successfully cycled against Li metal (over 550 h cycling) at 1 mA cm -2 at room temperature. The cycling overpotential is dropped by 75% in comparison to BP-free polymer composite electrolyte indicating lower interfacial resistance at the electrode/electrolyte interfaces. Molecular dynamics simulations reveal that the coordination number of Li + ions around (trifluoromethanesulfonyl)imide (TFSI - ) pairs and ethylene-oxide chains decreases at the Li metal/electrolyte interface, which facilitates the Li + transport through the polymer host. Here, density functional theory calculations confirm that the adsorption of the LiTFSI molecules at the BP surface leads to the weakening of N and Li atomic bonding and enhances the dissociation of Li + ions. This work offers a new potential mechanism to tune the bulk and interfacial ionic conductivity of solid-state electrolytes that may lead to a new generation of lithium polymer batteries with high ionic conduction kinetics and stable long-life cycling.

2D materials↗
DOE OSTI2023

Engineering Functionalized 2D Metal-Organic Frameworks Nanosheets with Fast Li + Conduction for Advanced Solid Li Batteries

Solid-state batteries can ensure high energy density and safety in lithium metal batteries, while polymer electrolytes are plagued by slow ion kinetics and low selective transport of Li + . Metal-organic frameworks (MOFs) are proposed as emerging fillers for solid-state poly(ethylene oxide)(PEO) electrolytes, however, developing functionalized MOFs and understanding their roles on ion transfer has proven challenging. Herein, combining computational and experimental results, the functional group regulation in MOFs can effectively change surficial charge distribution and limit anion movement is revealed, providing a potential solution to these issues. Specifically, functionalized 2D MOF sheets are designed through molecular engineering to construct high-performance composite electrolytes, where the electron-donating effect of substituents in 2D-MOFs effectively limits the movement of ClO 4 - and promotes mechanical properties and ion migration numbers (0.36 up to 0.64) of PEO. As a result, Li/Li cells with composite electrolyte exhibit superior cyclability for 1000 h at a current density of 0.2 mA cm -2 . Meanwhile, the solid LiFePO 4 /Li battery delivers highly reversible capacities of 148.8 mAh g -1 after 200 cycles. In conclusion, these findings highlight a new approach for anion confinement through the use of functional group electronic effects, leading to enhanced ionic conductivity, and a feasible direction for high-performance solid-state batteries.

25 ENERGY STORAGE↗
NASA NTRS2006

Laboratory Spectroscopy of CH(+) and Isotopic CH

The A1II - X1(Epsilon) electronic band of the CH(+) ion has been used as a probe of the physical and dynamical conditions of the ISM for 65 years. In spite of being one of the first molecular species observed in the ISM and the very large number of subsequent observations with large derived column densities, the pure rotational spectra of CH+ has remained elusive in both the laboratory and in the ISM as well. We report the first laboratory measurement of the pure rotation of the CH(+) ion and discuss the detection of CH-13(+) in the ISM. Also reported are the somewhat unexpected chemical conditions that resulted in laboratory production.

Pearson, John C.↗
NASA NTRS1991

Theoretical prediction of the impact of Auger recombination on charge collection from an ion track

The theoretical analysis presented indicates that Auger recombination can reduce charge collection from very dense ion tracks in silicon devices. It is of marginal importance for tracks produced by 270-MeV krypton, and therefore it is of major importance for ions exhibiting a significantly larger loss. The analysis shows that recombination loss is profoundly affected by track diffusion. As the track diffuses, the density and recombination rate decrease so fast that the linear density (number of electron-hole pairs per unit length) approaches a nonzero limiting value as t approaches infinity. Furthermore, the linear density is very nearly equal to this limiting value in a few picoseconds or less. When Auger recombination accompanies charge transport processes that have much longer time scales, it can be simulated by assigning a reduced linear energy transfer to the ion.

Edmonds, Larry D.↗
DOE OSTI2022

Ultra‐Thin Single‐Particle‐Layer Sodium Beta‐Alumina‐Based Composite Polymer Electrolyte Membrane for Sodium‐Metal Batteries

Inorganic/organic composite polymer electrolytes (CPEs) with good flexibility and electrode contact have been pursued for solid-state sodium-metal batteries. However, the application of CPEs for high energy density solid-state sodium-metal batteries is still limited by the low Na + conductivity, large thickness, and low ion transference number. Herein, an ultra-thin single-particle-layer (UTSPL) composite polymer electrolyte membrane with a thickness of ≈20 µm straddled by a sodium beta-alumina ceramic electrolyte (SBACE) is presented. A ceramic Na + -ion electrolyte that bridges or percolates across an ultra-thin and flexible polymer membrane provides: 1) the strength and flexibility from the polymer membrane, 2) excellent electrolyte/electrode interfacial contact, and 3) a percolation path for Na + -ion transfer. Owing to this novel design, the obtained UTSPL-35SBACE membrane exhibits a high Na+-ion conductivity of 0.19 mS cm -1 and a transference number of 0.91 at room temperature, contributing to long-term cycling stability of symmetric sodium cells with a small overpotential. The assembled quasi-solid-state cell with the as-prepared UTSPL-35SBACE membrane displays superior cycling performance with a discharge capacity of 105 mAh g -1 at 0.5 °C rate after 100 cycles and excellent rate performance (82 mAh g -1 at 5 °C rate) at room temperature with the potassium manganese hexacyanoferrate (KMHCF)@CNTs/CNFs cathode, where KMHCF refers to potassium manganese hexacyanoferrate.

25 ENERGY STORAGE↗
NASA NTRS1982

Plasmaspheric helium ion distribution from satellite observations of He II 304-A

High sensitivity and spatial resolution observations of the He II 304-A emission line intensity in the earth's nightglow have been carried out by the extreme ultraviolet telescope on the Apollo-Soyuz mission in July, 1975. The data, obtained over a wide range of plasmasphere parameters, are compared to the predictions of a kinetic equilibrium model of plasmaspheric ion density. Excellent agreement between observation and theory is found using as inputs a temperature model, solar flux and H(+) and O(+) number densities determined by extrapolating nearly simultaneous Atmospheric Explorer C measurements at 300 km. The observations in the Northern Hemisphere are well fit by a model having 285 He(+) ions/cu cm at 500 km independent of latitude or longitude, while those in the south require 430 He(+) ions/cu cm at the same altitude. This result is consistent with available information on the interhemispheric asymmetry of He(+) observed by a mass spectrometer on Explorer 32 and on the winter neutral helium bulge.

Chakrabarti, S.↗
NASA NTRS1987

Ultraviolet spectrophotometry of Comet Giacobini-Zinner during the ICE encounter

The IUE's UV spectrophotometer was used to monitor Comet Giacobini-Zinner's H2O production rate from June to October, 1985, in support of the International Cometary Explorer (ICE) mission. Observation results for the spatial and temporal variation and the abundance or upper limits of C, CO, CO(+), CO2(+), CS, H, Mg(+), O, OH, and S, between September 9 and 12, included the time of the ICE encounter: at this time, the H2O production rate obtained was consistent with a number of gas production rates derived indirectly from the ICE experiments. A comparison of the CO2(+) ion abundance with the total electron density measured by the plasma electron and radio science experiments on ICE implies an ion deficiency relative to electrons, so that the satisfaction of charge balance criteria requires the presence of a major ion population not detected by remote sensing.

Mcfadden, Lucy A.↗
NASA NTRS2004

Direct Electrolytic Deposition of Mats of Mn(x)O(y) Nanowires

Mats of free-standing manganese oxide (MnxOy) nanowires have been fabricated as experimental electrode materials for rechargeable electrochemical power cells and capacitors. Because they are free-standing, the wires in these mats are electrochemically accessible. The advantage of the mat-of-nanowires configuration, relative to other configurations of electrode materials, arises from the combination of narrowness and high areal number density of the wires. This combination offers both high surface areas for contact with electrolytes and short paths for diffusion of ions into and out of the electrodes, thereby making it possible to charge and discharge at rates higher than would otherwise be possible and, consequently, to achieve greater power densities. The nanowires are fabricated in an electrolytic process in which there is no need for an electrode binder material. Moreover, there is no need to incorporate an electrically conductive additive into the electrode material; the only electrically conductive material that must be added is a thin substrate contact film at the anchored ends of the nanowires. Hence, the mass fraction of active electrode material is close to 100 percent, as compared with about 85 percent in conventional electrodes made from a slurry of active electrode material, binder, and conductive additive pressed onto a metal foil. The locations and sizes of the nanowires are defined by holes in templates in the form of commercially available porous alumina membranes. In experiments to demonstrate the present process, alumina membranes of various pore sizes and degrees of porosity were used. First, a film of Au was sputtered onto one side of each membrane. The membranes were then attached, variously, to carbon tape or a gold substrate by use of silver or carbon paste. Once thus attached, the membranes were immersed in a plating solution comprising 0.01 M MnSO4 + 0.03 M (NH4)2SO4. The pH of the solution was kept constant at 8 by addition of H2SO4 or NH4OH as needed. Mn(x)O(y) nanowires were potentiostatically electrodeposited in the pores in the alumina templates. Depending on the anodic deposition potentials, Mn(x)O(y) was deposited in various oxidation states [divalent (Mn3O4), trivalent (Mn2O3), or tetravalent (MnO2)]. The Mn(x)O(y) wires were made free-standing (see figure) by dissolving the alumina templates, variously, in KOH or NaOH at a concentration of 20 volume percent.

Myung, Nosang↗
NASA NTRS2011

The Evaluation of Triphenyl Phosphate as a Flame Retardant Additive to Improve the Safety of Lithium-Ion Battery Electrolytes

NASA is actively pursuing the development of advanced electrochemical energy storage and conversion devices for future lunar and Mars missions. The Exploration Technology Development Program, Energy Storage Project is sponsoring the development of advanced Li-ion batteries and PEM fuel cell and regenerative fuel cell systems for the Altair Lunar Lander, Extravehicular Activities (EVA), and rovers and as the primary energy storage system for Lunar Surface Systems. At JPL, in collaboration with NASA-GRC, NASA-JSC and industry, we are actively developing advanced Li-ion batteries with improved specific energy, energy density and safety. One effort is focused upon developing Li-ion battery electrolyte with enhanced safety characteristics (i.e., low flammability). A number of commercial applications also require Li-ion batteries with enhanced safety, especially for automotive applications.

Li-ion batteries↗