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At least 235 records · Page 13

Exploring the Meteorological Impacts of Surface and Rooftop Heat Mitigation Strategies Over a Tropical City

Different heat mitigation technologies have been developed to improve the thermal environment in cities. However, the regional impacts of such technologies, especially in the context of a tropical city, remain unclear. The deployment of heat mitigation technologies at city-scale can change the radiation balance, advective flow, and energy balance between urban areas and the overlying atmosphere. We used the mesoscale Weather Research and Forecasting model coupled with a physically based single-layer urban canopy model to assess the impacts of five different heat mitigation technologies on surface energy balance, standard surface meteorological fields, and planetary boundary layer (PBL) dynamics for premonsoon typical hot summer days over a tropical coastal city in the month of April in 2018, 2019, and 2020. Results indicate that the regional impacts of cool materials (CMs), super-cool broadband radiative coolers, green roofs (GRs), vegetation fraction change, and a combination of CMs and GRs (i.e., “Cool city (CC)”) on the lower atmosphere are different at diurnal scale. Results showed that super-cool materials have the maximum potential of ambient temperature reduction of 1.6°C during peak hour (14:00 LT) compared to other technologies in the study. During the daytime hours, the PBL height was considerably lower than the reference scenario with no implementation of strategies by 700 m for super-cool materials and 500 m for both CMs and CC cases; however, the green roofing system underwent nominal changes over the urban area. During the nighttime hours, the PBL height increased by CMs and the CC strategies compared to the reference scenario, but minimal changes were evident for super-cool materials. The changes of temperature on the vertical profile of the heat mitigation implemented city reveal a stable PBL over the urban domain and a reduction of the vertical mixing associated with a pollution dome. This would lead to crossover phenomena above the PBL due to the decrease in vertical wind speed. Therefore, assessing the coupled regional impact of urban heat mitigation over the lower atmosphere at city-scale is urgent for sustainable urban planning.

54 ENVIRONMENTAL SCIENCES↗

Assessing the levelized cost of energy in South Korea

This study evaluates the levelized cost of energy (LCOE) for various energy technologies in the Republic of Korea (Korea) from 2023 to 2050, highlighting cost trajectories and potential crossovers among competing technologies. The analysis projects that, based on our set of assumptions, utility-scale photovoltaic systems achieve lower LCOEs than nuclear by 2030, while fixed offshore wind is expected to become cost-competitive with coal-fired generation around the same time. Floating offshore wind is projected to reach cost parity with coal in the late 2030s. Co-firing with natural gas and green hydrogen is identified as the highest-cost generation option due to high natural gas and green fuel costs and declining capacity utilization. This study further examines the potential for hybrid systems that integrate renewable energy with energy storage to serve as flexible, cost-effective, zero-emission alternatives to green hydrogen-based generation. Spatial LCOE assessments indicate that near-shore offshore wind sites may achieve lower costs despite modest capacity factors, contingent on site-specific factors such as grid integration and social acceptance. The findings indicate that renewable energy technologies are expected to experience continued cost declines, with solar photovoltaic becoming the most competitive energy source in Korea by 2030–2035. Incorporating social costs accelerates this shift from conventional alternatives.

Green hydrogen↗

Development and validation of a gamma-ray detection response model for neutron-diagnosed subcritical experiments

In a neutron-diagnosed subcritical experiment, a highly sensitive and fast detector is required to accurately determine the true fission γ-ray emission rate from an object composed of special nuclear material under interrogation, in addition to a proper detector response model for use in forward modeling. We present the development of a detector response model that is based in GEANT4 and uses post-processing techniques to include photomultiplier tube time and pulse height response effects. We also define a set of detector performance evaluation metrics that emphasized our experimental objectives. A suite of time and pulse height response measurements for several diverse detector assemblies are described. These assemblies were simulated with this response model and benchmarked against the laboratory measurements. This response model reproduces the pulse height curve shapes and performance hierarchy of the measured detectors well. Additionally, the simulated time response curves exhibit reasonable agreement with counterpart measurements. These measurements and simulation results together suggest that a large volume EJ-299-49 plastic scintillator that is mated to an ultraviolet transmitting plastic light guide and relies on total internal reflection for light transport to the photocathode will provide significantly faster timing, increase pulse height by a factor of 3, and require 25% less γ rays to meet experimental needs, compared to the candidate detector design developed prior to the availability of this response model. Application of this response model and associated performance metrics in the context of large-scale design sensitivity studies is also discussed.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗

Time-dependent saturation and physics-based nonlinear model of cross-beam energy transfer

The nonlinear physics of cross-beam energy transfer (CBET) for multi-speckled laser beams is examined using large-scale particle-in-cell simulations for a range of laser and plasma conditions relevant to indirect-drive inertial confinement fusion (ICF) experiments. The time-dependent growth and saturation of CBET involve complex, nonlinear ion and electron dynamics, including ion trapping-induced enhancement and detuning, ion acoustic wave (IAW) nonlinearity, oblique forward stimulated Raman scattering (FSRS), and backward stimulated Brillouin scattering (BSBS) in a CBET-amplified seed beam. Ion-trapping-induced detuning of CBET is captured in the kinetic linear response by a new δf-Gaussian-mixture algorithm, enabling an accurate characterization of trapping-induced non-Maxwellian distributions. Ion trapping induces nonlinear processes, such as changes to the IAW dispersion and nonlinearities (e.g., bowing and self-focusing), which, together with pump depletion, FSRS, and BSBS, determine the time-dependent nature and level of CBET gain as the system approaches a steady state. Using VPIC simulations at intensities at and above the onset threshold for ion trapping and the insight from the time-dependent saturation analyses, we construct a nonlinear CBET model from local laser and plasma conditions that predicts the CBET gain and the energy deposition into the plasma. This model is intended to provide a more accurate, physics-based description of CBET saturation over a wide range of conditions encountered in ICF hohlraums compared with linear CBET gain models with ad hoc saturation clamps often used in laser ray-based methods in multi-physics codes.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Direct current response of a thin scCVD diamond detector under increased applied field to 14.1 MeV neutrons

An avalanche effect yielding inherent gain can be exploited in thin, single-crystal chemical vapor deposition (scCVD) diamond. It occurs when a high enough bias is applied across the diamond thickness while avoiding breakdown. This charge multiplication effect was studied previously with alpha particles and heavy ions either by using the transient current technique or by measuring the energy spectrum. The measurements we obtained to evaluate the charge multiplication performance of a 10 μm thick scCVD diamond detector used a novel approach—we employed an electrometer to characterize the response of the detector by performing directly coupled current measurements (time-averaged charge, at 1 Hz sampling) when exposed to 14.1 MeV neutrons from deuterium-tritium fusion. We measured both the dark and irradiated currents from the detector over a range of applied displacement field values from 2 to 75 V/μm. A histogram method with central mean and standard deviation width was used to determine the current over each measurement duration typically from 100 to 300 seconds. The dark-subtracted irradiated current (i.e., contrast) was used to evaluate the gain of the detector at each applied displacement field. The contrast at an applied displacement field between 15 and 20 V/μm was higher than the expected linear increase in contrast proportional to the increased applied bias, indicating the possible presence of avalanche events in the diamond. The detector response also indicated possible polarization and charge depletion effects. These results provide an opportunity to further explore the use of thin scCVD diamond as a fast neutron current mode detector with inherent gain.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗

The MEC-U Project at LCLS

Here, we describe the Matter in Extreme Conditions Upgrade (MEC-U) project, co-locating kilojoule long pulse and high repetition rate petawatt lasers with LCLS in a new experimental hall at SLAC National Accelerator Laboratory.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗

Data Report: High-Resolution Microscopy Images of Sediments from Green Canyon Block 955, Gulf of Mexico

We took Leica microscopy images of sediment samples acquired at Holes H002 (4 samples) and H005 (1 sample) during the UT-GOM2-1 Expedition in Green Canyon Block 955, in the northern Gulf of Mexico. A total of 37 images were acquired. The images document a prevalence of spherical conchoidal minerals, cleavage planes typical of feldspar or mica, and black fragmented minerals which stand out from the surrounding matrix. Drilling mud intrusion is thought to contribute to a grey metallic matrix observed across multiple samples.

03 NATURAL GAS↗

Impacts of Siting Considerations on Offshore Wind Technical Potential in the United States

We estimated the technical potential for the offshore wind (OSW) resource in the United States under two siting regimes to characterize the uncertainty pertaining to the local drivers of siting within a national context. We established Open Access and Limited Access regimes to represent upper and lower bounds on OSW deployment, respectively. These included spatial constraints such as technology depth limits, military use areas, protected areas, existing infrastructure, shipping lanes and more. The same spatial considerations are also considered in the Limited Access regime, but with additional buffers to existing infrastructure as well as a reduced capacity density assumption. Capacity density is the concentration of wind energy development for a given area specified in terms of megawatts (MW) per square kilometer (km 2 ). In the Open-Access regime we used a 5 MW/km 2 assumption, while in the Limited Access scenario we assumed 3 MW/km 2 . This difference reflects our intention for the Open-Access scenario to serve as an upper bound for OSW technical potential, with the Limited-Access scenario as a lower bound. We also applied three technology advancement scenarios to each of the siting regimes. The three technology scenarios (Conservative, Moderate, and Advanced) represent plausible improvements in turbine technology including increased rated power and higher hub heights.

17 WIND ENERGY↗

Opportunities for Hydrogen to Green Industry

Presentation summarizes results from H2@Scale Technical and Economic Potential report with a focus on industrial applications. It also includes a few musings on what would be necessary for hydrogen to support greening high-temperature manufacturing.

39 EE - Hydrogen and Fuel Cell Technologies (EE-3F↗

Ternary molecular switching in a single-crystal optical actuator with correlated crystal strain

A growing portfolio of single-crystal optical actuators is forging a new class of photonic materials that hold prospects for quantum technologies. Ruthenium-based complexes that exhibit this phenomenon via SO 2 -linkage photoisomerisation are of particular interest since they display multiple metastable states, once induced by green light; yet, complete photoconversion into each SO 2 -isomeric state is rarely achieved. We discover a new complex, trans-[Ru(SO 2 )(NH 3 ) 4 (4-bromopyridine)]tosylate 2 , that produces 100% photoconverted η 1 -OSO isomeric crystal structures at 90 K, which fully transition into η 2 -(OS)O photoisomers upon warming to 100 K, while the dark-state η 1 -SO 2 structure is wholly recovered by heating the crystal to room temperature. Crystal structures and optical-absorption profiles of each state are captured via in-situ light-induced single-crystal X-ray diffraction and optical-absorption spectroscopy. Results show that both photoisomeric species behave as optical switches, but with distinct optical properties. The photoisomerisation process causes thermally-reversible micro- and nanoscopic crystal strain, as characterised by optical microscopy and in-situ light-induced atomic-force microscopy.

actuators↗

Oxidative instability of ionomers in hydroxide-exchange-membrane water electrolyzers

Hydroxide-exchange membrane (HEM) electrolyzers can produce green H 2 with only earth-abundant catalysts and electrolyte-free (nominally pure) water feed, significantly decreasing system cost and complexity. However, HEM technology suffers from short lifetimes, attributed in part to poor stability of anion-exchange polymers used in the membrane and catalyst layers. We use electrochemical analysis and ex situ characterization techniques to study anion-exchange-polymer degradation in electrolyzers. Using multiple ionomers, catalyst-layer additives, and electrolyte feed, we show how anode-ionomer oxidation is the dominant degradation mechanism for all HEM-based electrolyzer cells tested. Here, we find improved device stability using oxidation-resistant catalyst-layer binders and propose new design strategies for advanced ionomer and catalyst-layer development.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

American Made Challenges Battery Voucher Program Cooperative Research and Development Agreement (Cooperative Research and Development Final Report, CRADA Number CRD-21-17533)

Renewance is a Phase II winner of the U.S. Department of Energy Lithium-ion Battery Recycling Prize. The Prize is designed to incentivize American entrepreneurs to develop and demonstrate processes that, when scaled, have the potential to profitably capture 90% of all discarded or spent lithium-based batteries (LIB) in the Unites States for eventual recovery of key materials for re-introductions into the U.S. supply chain. The objective of this work is to enable a more efficient evaluation of battery sources for second life applications prior to ultimately being recycled, through evaluation of chemistry characteristics, projected battery lifetime, and application history. This work will develop the capability to identify groups of batteries that may be useful for second life and reduce the cost of end-of-life (EOL) LIB evaluation and repurposing. To meet the objective, NREL will use existing and new data to create a refined algorithm that could be used to evaluate batches of batteries for potential reuse based on manufacturing date and historical use characteristics. Based on current battery market prices and compiled literature data, a starting-point estimate of the market value of the batteries for reuse based on expected lifetime will be included in the algorithm. With the projected surge in LIB demand, battery second life is a new area ripe for development and investment from companies like Renewance. With so few large format batteries reaching EOL to date, this is a new market with a variety of areas for optimization and adding value. This work with Renewance is an example of how existing expertise in battery degradation at NREL can be used to reduce the cost of shifting a battery into a second life application. With these cost reductions, this work is also facilitating the development of a battery circular economy in the United States. A robust circular economy can maximize the utilization of critical metals demanded by battery technology such as nickel and cobalt while also reducing the costs of batteries in the marketplace for the many end-uses needed for the green energy transition. The supply of these metals is limited, and we face a supply chain shortage both domestically and globally unless we can ensure they are being used to their maximum potential. This research can improve the economics of a battery circular economy to make it a more likely path for EOL batteries with critical metals. CRADA benefit to DOE, Participant, and US Taxpayer: assists laboratory in achieving programmatic scope competencies, uses the laboratory's core competencies.

25 ENERGY STORAGE↗

DOE Award No.: DE-FE0023919 Phase 3 Scientific/Technical Report

This is the Phase 3 Report for the ‘Deepwater Methane Hydrate Characterization and Scientific Assessment or Genesis of Methane Hydrates in the Gulf of Mexico (GOM2)’ research project (DOE Award No. DE-FE0023919). The report summarizes activities from January 16, 2018 to September 30, 2019. The project is led by the University of Texas at Austin (UT). The objective is to gain insight into the nature, formation, occurrence and physical properties of methane hydrate-bearing sediments for the purpose of methane hydrate resource appraisal through the planning and execution of drilling, coring, logging, testing and analytical activities that assess the geologic occurrence, regional context, and characteristics of marine methane hydrate deposits in the Gulf of Mexico outer continental shelf (OCS). We determined that it would not be possible to pursue the project with the International Ocean Discovery Program (IODP) and then developed a revised science and operations plan to maximize the science using a commercial vessel within the budget that is available. We improved the scientific capability of the UT pressure core center by adding the ability to X-ray pressure cores, and the ability to cut and store multiple core samples for experimental analysis. We transferred pressure cores to peer institutions, including the National Energy Technology Lab (NETL) the United States Geological Survey (USGS Woods Hole). We made advances in understanding the composition and source of gasses locked in the methane hydrate from Green Canyon 955 (GC-955). We developed approaches to determine the in-situ salinity of hydrate-bearing samples, revealing that the in situ salinity of the GC 955 reservoir is just above that of seawater. We determined that the GC-955 hydrate reservoir is composed of sandy silt with a high concentration of hydrate interbedded with clayey silt with no hydrate present. We determined that some or all of the intervals bounding the hydrate reservoir are composed of material similar to the reservoir (sandy silt with hydrate and clayey silt with no hydrate), but with a lower net to gross. We determined that the reservoir effective permeability at a hydrate saturation of ~80-90 % is ~0.1 mD (or 1.0×10-16 m2) to ~0.5 mD (or 5.0×10-16 m2) and the intrinsic permeability is ~12 mD (or 1.2×10-14 m2). The GC-955 reservoir in-situ porosity of sandy silt is 0.38 to 0.40 and is largely independent of effective stress, and that the porosity of clayey silt is 0.33 at an in situ effective stress of 3.8 MPa to ~0.37 at zero effective stress. We developed a systematic, repeatable approach to studying hydrate reservoir properties by reconstituting individual lithofacies from dissociated pressure cores. We determined index properties of GC-955 reservoir, including liquid limit and plasticity, porosity, capillary behavior, and particle size distribution. We developed a more robust pressure coring technology. We finalized and published the UT-GOM2-1 Expedition Volume and we finalized a dedicated volume on the UT-GOM2-1 expedition that will be published in the American Association of Petroleum Geologists Bulletin (AAPG) in spring 2020.

03 NATURAL GAS↗

Policies and Programs Available in the United States in Support of Carbon Capture and Utilization

The article seeks to compile policies and programs that provide revenue and financing support for carbon capture and utilizations projects, which are available in the United States. Often technically minded entrepreneurs and investors new to this space are unaware of available support, which could help successful development of carbon capture and utilization projects.Covered in this article are the 45Q tax credit, green bonds, loan guarantee programs, the regional greenhouse gas initiative, and low carbon fuel standards.1This article covers the eligibility and effect of each policy and program. The article also briefly reviews the current state of technology and summarizes how each technology pathway pairs with the policies covered in the article.The goal of the article is to serve as a primer for lawyers, corporate development professionals, and practitioners, who seek to learn about policies and programs available to support carbon capture and utilization (CCU) projects.

29 ENERGY PLANNING, POLICY, AND ECONOMY↗

Abstract for CRADA between NETL and Rivalia Chemical Co

The National Energy Technology Laboratory (NETL) will assist Rivalia Chemical Co (Participant) with system analyses to aid the Participant with setting priorities and securing funding. The Participant is an early-stage startup pioneering new chemical extraction technology to solve two important problems: critical mineral scarcity and coal ash waste management. The U.S. generates coal fly ash from coal combustion for power generation and has amassed over two billion metric tons of ash, which contains valuable rare earth elements. The ash is often stored in unlined ponds and frequently contaminates the local environment. The Participant’s patent-pending process harvests rare earths from ash, then transforms the residual ash for use in green concrete, providing an economic pathway for utilities to empty and remediate the ash ponds. Founder Laura Stoy created the company in July 2022 after developing the core intellectual property during her Ph.D. at the Georgia Institute of Technology. Stoy is currently participating in the Chain Reactions Innovations (CRI) program at the U.S. Department of Energy (DOE) Argonne National Laboratory (ANL) where she will be optimizing the core technology and scaling from bench scale to demonstration scale. The technology has been validated at bench scale (TRL3); the goal is to approach TRL5 by the conclusion of the CRI program and prepare to raise capital investment for a pilot facility. NETL and the Participant will develop an updated technoeconomic analysis (TEA) and identify key sustainability performance parameters to inform ’s research and development priorities and de-risk the technology. NETL will also provide the Participant with guidance to prepare a more detailed life cycle assessment (LCA), and a narrative on the Participant’s product markets. These tools will aid the Participant with the next steps of commercialization.

01 COAL, LIGNITE, AND PEAT↗

Delivery of a Solar-Powered Forward Osmosis Seawater Desalination Plant: Trevi’s 500 m3/day Zero-Carbon FO Seawater Desalination Plant at NELHA

This paper presents an account of Trevi’s delivery of a 500 m3/day solar powered forward osmosis (FO) seawater desalination plant at the Ocean Science and Technology Park of the Natural Energy Laboratory of Hawaii Authority (NELHA). The project aimed to demonstrate the viability of solar thermal-powered desalination for agricultural applications through the integration of a 2MW micro-dish solar thermal array with a state-of-the-art FO system. Highlighted in the paper are the three distinct project phases; Planning and Design, System Construction, Installation & Testing followed finally by System Operation and Optimization. Results and decisions which led to the final plant design will be shared, highlighting how Trevi Systems succeeded in producing a zero-carbon FO seawater desalination plant with a projected Levelized Cost of Water (LCOW) estimate competitive with existing carbon-intensive RO technologies (based on some assumptions and the cost of heat which is required for FO.

14 SOLAR ENERGY↗