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At least 235 records · Page 13

Graphite-Fiber-Reinforced Glass-Matrix Composite

G/GI structural composite material made of graphite fibers embedded in borosilicate glass exhibit excellent strength, fracture toughness, and dimensional stability at elevated temperatures. It is made by passing graphite-fiber yarn through slurry containing suspension of fine glass particles in carrier liquid and winding on drum to produce prepegged uniaxial tape. After drying, tapes are cut into appropriate lengths and laid up in graphite die in desired stacking scheme. Stack is consolidated by hot pressing in furnace.

Prewo, K. M.↗

Cryogenically formed prestressed composite fiber-metal structures for O2/N2 high pressure gas tanks.

Demonstration of high-structural-performance ARDEFORM cryoformed 301 stainless-steel glass-fiber-reinforced (GFR) vessels by room temperature tests of 13 1/2-in. diam spheres. Tests verified that the structural performance of ARDEFORM spherical GFR vessels not only exceeded that of all metal construction, but also bettered previous GFR experimental results by 50%. Achievement of essentially the full strength of fiberglass in a spherical wrap pattern was again verified. Significant weight advantages for this construction are projected for O2/N2 high-pressure gas tanks for Space Shuttle environmental control/life support system missions.

Gleich, D.↗

Energy Efficient, Incrementally Scalable, Continuous Basalt Fiber Manufacturing Process (Final Technical Report)

This project focused on new materials, bushing materials, that had the ability to produce continuous basalt or glass fiber. The original scope of the project was designed to identify bushing materials and produce fiber, but that scope did change during the program. The team put significant work into bushing material development in the place of producing fiber. The final bushing materials had to be able to produce fiber and the final sets of the project saw single strands of fiber be produced. The final materials selected was a unique MMC bushing composition. Using advanced chemistry, the interface chemistry was tailored between metallic and ceramic powders. Powders and fibers were consolidated using cold isostatic pressing and electrified ceramic hot pressing to form a near net shape composite bushing.

36 MATERIALS SCIENCE↗

Progress in the development of the hollow fiber sodium-sulfur secondary cell

This report describes the development and status of the sodium-sulfur secondary cell which uses fine hollow glass fibers as the electrolyte. Laboratory size cells containing up to 7000 fibers and having capacities up to 5 ampere-hours have been built and operated. These cells have been run at various cycle depths up to 95% of capacity. Lifetime does not depend on depth of discharge up to at least 50% depth and possibly deeper. Rates of charge and discharge of the nominally one hour cells have been varied from three times the design rate to 0.05 times the design rate. Smaller cells operate with essentially no internal resistance increase during their lifetimes of over four months on continuous charge/discharge at the one hour rate. Larger cells assembled with somewhat different mechanical assembly techniques have shorter lives. Two types of failure modes are observed: progressive weakening and breaking of the fibers inside the cell assembly, and fiber breakage at the fiber/tube sheet interface.

Levine, C. A.↗

Optical Fiber Spectroscopy

This is the final report of work done on NASA Grant NAG-1-443. The work covers the period from July 1, 1992 to December 1, 1998. During this period several distinct but related research studies and work tasks were undertaken. These different subjects are enumerated below with a description of the work done on each of them. The focus of the research was the development of optical fibers for use as distributed temperature and stress sensors. The initial concept was to utilize the utilize the temperature and stress dependence of emission from rare earth and transition metal ions substitutionally doped into crystalline or glass fibers. During the course of investigating this it became clear that fiber Bragg gratings provided a alternative for making the desired measurements and there was a shift of research focus on to include the photo-refractive properties of germano-silicate glasses used for most gratings and to the possibility of developing fiber laser sources for an integrated optical sensor in the research effort. During the course of this work several students from Christopher Newport University and other universities participated in this effort. Their names are listed below. Their participation was an important part of their education.

Buoncristiani, A. M.↗

Recirculating sprayer for fiber-filled paints

Recirculating paint sprayer applies spray of coarse filler in highly volatile solvent. Sprayer was developed for applying insulation material containing epxoy resin, glass fibers, and inert fillers suspended in chlorinated solvents. Sprayer resists abrasive action of fiberglass filler and chemical activity of solvent. Pump and position ensure more uniform pressure at spray gun without backpressure regulator, which tended to clog in old sprayer.

Major, R. K.↗

Performance of cross-flow turbines with varying blade materials and unsupported blade span

Cross-flow turbines could play a larger role in the diversification of the global energy supply if the impact of more cost-competitive design choices on performance and rotor dynamics was better understood. This study focuses on rotor performance and blade strain measurements while varying the following parameters: blade materials and blade free end length by changing strut support position. Towing tank experiments were performed with a modular 1-meter diameter cross-flow turbine consisting of three NACA 0018 blades with two support struts. One strut was fixed at the lower end of the turbine, while the second strut was adjustable, thereby changing the length of the free end. The blade materials tested were carbon, E-glass, and hollow E-glass fiber composites, in decreasing order of stiffness and cost. High-resolution distributed fiber optic sensors were embedded in two of the three rotor blades for each material and provided hundreds of strain measurements per blade. Turbine performance and blade strain were measured while varying tow speed and tip speed ratio. Performance tests were conducted at towing speeds sufficiently high for the performance to be independent of Reynolds number. E-glass blades and carbon blades performed similarly for the most rigid strut configurations. Higher strain was measured on the E-glass blades, and their performance was reduced for less rigid configurations compared to the carbon fiber blades. The performance of the highly deflective hollow E-glass blades was lower overall and became even more degraded for longer unsupported blade span. Furthermore, the results provide insight into the use of various blade materials in cross-flow turbines and guidance on allowable free end length for each material type.

16 TIDAL AND WAVE POWER↗

Determining and analyzing the strength and impact resistance of high modulus glass

An error was noticed recently in the computer program used to reduce the laboratory sonic measurements to tabulated values of Young's modulus of the bulk samples of experimental glasses. Correction of this error gave revised values for the last fifty experimental glasses prepared in this laboratory. This corrected data, when examined as input material for the calculation of Young's modulus of bulk glasses from composition by the C. J. Phillips procedure, resulted in new values for the contribution per mol of several oxides. The new value for the zinc oxide molal factor is especially significant since it is slightly greater than the factor for beryllia for the types of glasses melted in the UARL research program. This discovery provides a new tool in the search for nontoxic, i.e. without beryllia, high modulus glass fibers particularly when coupled with recent measurements that showed zinc oxide contributes significantly to increased impact strength. New glass compositions prepared in this period and the latest impact strength values measured are also included.

Bacon, J. F.↗

Advanced composites in sailplane structures: Application and mechanical properties

Advanced Composites in sailplanes mean the use of carbon and aramid fibers in an epoxy matrix. Weight savings were in the range of 8 to 18% in comparison with glass fiber structures. The laminates will be produced by hand-layup techniques and all material tests were done with these materials. These values may be used for calculation of strength and stiffness, as well as for comparison of the materials to get a weight-optimum construction. Proposals for material-optimum construction are mentioned.

Muser, D.↗

Infrared fiber coupled acousto-optic tunable filter spectrometer

A spectrometer design is introduced which combines an acoustooptic tunable filter (AOTF) and IR-transmitting flouride-glass fibers. The AOTF crystal is fabricated from TeO2 and permits random access to any wavelength in less than 50 microseconds, and the resulting spectrometer is tested for the remote analysis of gases and hydrocarbons. The AOTF spectrometer, when operated with a high-speed frequency synthesizer and optimized algorithms, permits accurate high-speed spectroscopy in the mid-IR spectral region.

Levin, K. H.↗

Fiber optic electric field sensor technology

The properties of piezoactive plastics are reviewed as well as the fiber-optic electric field sensors studied so far. A particular configuration consisting of a concentric piezoactive jacket on the glass fiber is discussed in detail and the frequency response of this sensor is projected over a wide range of frequencies. The present design has the practical advantages of leading to a compact lightweight sensor; longer fiber lengths may be used to increase sensitivity. It is predicted that, at low frequencies, a fiber-optic antenna using a 1-km length of fiber would be capable of detecting a minimum electric field of 43 microV/m assuming a minimum phase sensitivity of 10 to the -6th radians for the optical Mach-Zehnder interferometer.

Jarzynski, J.↗

Melt-processing of lunar ceramics

The goal of this project is to produce useful ceramics materials from lunar resources using the by products of lunar oxygen production processes. Emphasis is being placed on both fabrication of a variety of melt-processed ceramics, and on understanding the mechanical properties of these materials. Previously, glass-ceramics were formed by casting large glass monoliths and heating these to grow small crystallites. The strengths of the resulting glass-ceramics were found to vary with the inverse square root of the crystal grain size. The highest strengths (greater than 300 MPa) were obtained with the smallest crystal sizes (less than 10 microns). During the past year, the kinetics of crystallization in simulated lunar regolith were examined in an effort to optimize the microstructure and, hence, mechanical properties of glass ceramics. The use of solar energy for melt-processing of regolith was examined, and strong (greater than 630 MPa) glass fibers were successfully produced by melt-spinning in a solar furnace. A study of the mechanical properties of simulated lunar glasses was completed during the past year. As on Earth, the presence of moisture was found to weaken simulated lunar glasses, although the effects of surface flaws was shown to outweigh the effect of atmospheric moisture on the strength of lunar glasses. The effect of atmospheric moisture on the toughness was also studied. As expected, toughness was found to increase only marginally in an anhydrous atmosphere. Finally, our efforts to involve undergraduates in the research lab fluorished this past year. Four undergraduates worked on various aspects of these projects; and two of them were co-authors on papers which we published.

Fabes, B. D.↗

Development of advanced fuel cell system, phase 3

A multiple task research and development program was performed to improve the weight, life, and performance characteristics of hydrogen-oxygen alkaline fuel cells for advanced power systems. Gradual wetting of the anode structure and subsequent long-term performance loss was determined to be caused by deposition of a silicon-containing material on the anode. This deposit was attributed to degradation of the asbestos matrix, and attention was therefore placed on development of a substitute matrix of potassium titanate. An 80 percent gold 20 percent platinum catalyst cathode was developed which has the same performance and stability as the standard 90 percent gold - 10 percent platinum cathode but at half the loading. A hybrid polysulfone/epoxy-glass fiber frame was developed which combines the resistance to the cell environment of pure polysulfone with the fabricating ease of epoxy-glass fiber laminate. These cell components were evaluated in various configurations of full-size cells. The ways in which the baseline engineering model system would be modified to accommodate the requirements of the space tug application are identified.

Handley, L. M.↗

The combined effect of temperature and seawater on the compression properties of carbon fiber vinyl ester composites for sandwich structures

For naval applications, composite sandwich structures are of significant interest, and are often manufactured using thin (2 to 4 mm) composite facings made from carbon or glass fiber reinforcement, attached to a thick (25 to 50 mm) section of PVC cellular foam or balsa wood-based core materials using a suitable polymeric resin. In the present study, we focus on the hygrothermal effect on the fiber-dominated compression properties of carbon fiber reinforced vinyl ester resin based polymeric composite (CF/VE), used as “skin” for a polymeric composite sandwich material. Hygrothermal conditioning is achieved by saturating samples in simulated seawater at 40°C. Compression properties are evaluated for coupons extracted along warp and fill undergoing- no conditioning, conditioning till saturation (up to 6 months), and long-term conditioning (2 years). Sea-water saturation yields in up to 12% drop in compression strength with a further 3–4% drop resulting from long-term conditioning. No statistically significant modulus degradation is noticed due to short or long-term hygrothermal exposure. The failure mechanism of the warp extracted coupon, which fails in a splitting failure mode originating due to the delamination between the 0/90 interface, or the fill extracted coupon, which fails due to the instability caused by tow micro-buckling, remains unchanged due to combined exposure (short or long-term) of seawater and temperature. The loss in strength is attributed to the degradation of the fiber-matrix interface, which is validated via conducting single fiber push-in tests with a nominal diameter of 7 micron for conditioned and unconditioned coupons.

Engineering↗

Three-dimensional finite element simulation of intermingled-fiber hybrid composite behavior

Three-dimensional finite element methods and the intraply hybrid micromechanics equations are used to predict composite properties for a unidirectional graphite-epoxy primary composite with S-glass fibers used as hybridizing fibers. The micromechanics equations are embedded in a computer code ICAN (Integrated Composites Analyzer). The three-dimensional finite element model consists of three-by-three unit cell array, with a total fiber volume ratio of 0.54. There is a good agreement between the composite properties and microstresses obtained from both methods. The results indicate that the finite element methods and micromechanics equations can be used to obtain the properties of intermingled hybrid composites needed for analysis/design of hybrid composite structures.

Mital, Subodh K.↗

Processing Temperature Effect on Failure Behavior of Unidirectional Thermoplastic Polymer-fiber-reinforced Polymers (PFRPs)

This study aimed to examine the influence of processing temperature on the mechanical and morphological characteristics of unidirectional (UD) thermoplastic polymer-fiber-reinforced polymers (PFRPs), utilizing UHMWPE-polymer-fiber-reinforced HDPE composites as an example. To achieve this objective, UD thermoplastic PFRPs were produced through filament winding and hot pressing techniques, employing five distinct processing temperatures within the range spanning from the melting onset temperature of the polymer matrix to the melting peak temperature of the reinforcing polymer fiber. By conducting the uni-axial tensile tests on the UD UHMWPE-polymer-fiber-reinforced HDPE composites fabricated at different processing temperatures, it was shown that the optimal longitudinal tensile properties of the composites, comparable with glass-fiber-reinforced thermoset or thermoplastic polymers (GFRPs or GFRTPs) can be achieved when the processing temperature does not significantly exceeds the melting onset temperature of the reinforcing polymer fiber. However, when the processing temperature exceeds this threshold, the mechanical properties of the composites are significantly reduced, as evidenced by the transition in the failure morphology from the presence of significant splitting cracks to the occurrence of plastic necking due to the complete melting of the reinforcing polymer fibers in a composite. Particularly, the ductile behavior of the optimal thermoplastic PFRPs investigated in this study is superior than that of carbon-fiber-reinforced thermoset or thermoplastic polymers (CFRPs or CFRTPs) and even GFRPs and GFRTPs. This study not only provides valuable insights into the proper fabrication of high-performance thermoplastic PFRPs but also offers useful experimental data that can aid in the validation and development of computational models, particularly those related to processing modeling.

Qiao, Yao↗

AVIRIS foreoptics, fiber optics and on-board calibrator

The foreoptics, fiber optic system and calibration source of the Airborne Visible/Infrared Imaging Spectrometer (AVIRIS) are described. The foreoptics, based on a modified Kennedy scanner, is coupled by optical fibers to the four spectrometers. The optical fibers allow convenient positioning of the spectrometers in the limited space and enable simple compensation of the scanner's thermal defocus (at the -23 C operating temp) by active control of the fiber focal plane position. A challenging requirement for the fiber optic system was the transmission to the spectral range 1.85 to 2.45 microns at .45 numerical aperture. This was solved with custom fluoride glass fibers from Verre Fluore. The onboard calibration source is also coupled to the spectrometers by the fibers and provides two radiometric levels and a reference spectrum to check the spectrometers' alignment. Results of the performance of the assembled subsystems are presented.

Chrisp, Michael P.↗