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At least 235 records · Page 13
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DOE OSTI2020

Negative capacitance regime in ferroelectrics demystified from nonequilibrium molecular dynamics

Negative capacitance regime in ferroelectrics is associated with the negative slope in the dependence of the polarization on electric field and is prohibited by the laws of equilibrium thermodynamics. Very recently, it developed into a controversial but very productive area with a promise for next generation low-power transistors. At least, in part, the controversies arise from the lack of direct experimental insight into the mechanism for such phenomena. Although the experimental insight is, indeed, challenging at present, we probe the effect in ferroelectric PbTiO 3 bulk and a thin film with realistic first-principles-based nonequilibrium molecular dynamics simulations which model most closely experimental conditions. Here, the following insights emerge from the simulations: (i) the ferroelectric never enters the thermodynamically forbidden region even under extreme rates of electric-field application; (ii) the negative slope naturally arises when the compensating charge is either scarce or slowed down by the external circuitry; (iii) the negative slope is well controlled by the interplay between the applied step pulse field and the amount of the screening charge. The latter can be used to design the negative capacitance regime.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
NASA NTRS1979

An experimental study of the noise generating mechanisms in supersonic jets

Flow fluctuation measurements with normal and X-wire hot-wire probes and acoustic measurements with a traversing condenser microphone were carried out in small air jets in the Mach number range from M = 0.9 to 2.5. One of the most successful studies involved a moderate Reynolds number M = 2.1 jet. The large scale turbulence properties in the jet, and the noise radiation were characterized. A parallel study involved similar measurements on a low Reynolds number M = 0.9 jet. These measurements show that there are important differences in the noise generation process of the M = 0.9 jet in comparison with low supersonic Mach number (M = 1.4) jets. Problems encounted while performing X-wire measurements in low Reynolds number jets of M = 2.1 and 2.5, and in installing a vacuum pump are discussed.

Mclaughlin, D. K.↗
NASA NTRS1982

Polymer research at NASA Langley Research Center

Polymer synthesis programs involve the development of Novel thermoplastics, pseudothermoplastics, and thermosets. These systems are prepared to elucidate structure-property relationships involving thermal capabilities, toughness, processability and environmental stability. Easily processable polyimides, solvent-resistant polysulfones and polyphenylquinoxalines, and tougher high and intermediate temperature polymers were developed. Characterization efforts included high pressure liquid chromatography methodology, the development of toughness tests for fiber reinforced composites, a study of electrical properties of metal ion filled polyimides, and a study of the mutagenicity of aromatic diamines. Also the mechanism of cure/degradation of experimental polymers was studied by rheology, mechanical behavior, separation techniques and spectroscopy. The degradative crosslinking of alkyl-containing polyimides, the separation and identification of crosslinked phenylquinoxalines, the rheological behavior of hot-melt polyimides, and the elucidation of the cure of norbornene endcapped imides were also studied.

Terry L. St. Clair↗
NASA NTRS1983

Experimentally determined factors influencing electrical coupling mechanisms

Measurements of the time-dependent electric field in the stratosphere and mesosphere above a thunderstorm have made it possible to construct an equivalent circuit model of a thunderstorm involving capacitive as well as resistive elements. The model illustrates how charge is coupled to the global circuit and how the circuit can be modulated. The average current from the thunderstorm cell to the global circuit is largely controlled by the rate of cloud-to-earth flashes, which can be affected in marginal cases by external influences. The combined effect of the earth's magnetic field and the extreme nonuniformity of mesospheric conductivity cause a large fraction of the current from nighttime thunderstorm to flow downward through the mesosphere in high-latitude regions, thus facilitating coupling between thunderstorms and high-latitude phenomena.

Hale, L. C.↗
NASA NTRS1984

Experimental and analytical analyses of the mechanisms governing the dispersion of flammable clouds formed by liquid hydrogen spills

This paper presents the initial findings of hydrogen vapor cloud dispersion experiments conducted by NASA. The experiments were performed to obtain basic information regarding the physical phenomena governing the dispersion of flammable clouds formed as the result of spills of large quantities of liquid hydrogen. The experiments consisted of ground spills of up to 5.7 cu m of liquid hydrogen with spill durations of approx. 35 s. Instrumented towers, located downwind of the spill site, gathered data on the temperature, hydrogen concentration and turbulence levels as the hydrogen vapor cloud drifted downwind. Preliminary results of the experiments indicate that, for rapid spills, thermal and momentum-induced turbulences cause the cloud to disperse to safe concentration levels and become positively buoyant long before mixing due to normal atmospheric turbulence becomes a major factor. An adiabatic mixing model has been developed to deduce hydrogen-air mixture ratios for temperature measurements obtained within the cloud formed by liquid hydrogen spills.

Witcofski, R. D.↗
NASA NTRS1992

Mechanical properties of triaxially braided composites: Experimental and analytical results

This paper investigates the unnotched tensile properties of two-dimensional triaxial braid reinforced composites from both an experimental and analytical viewpoint. The materials are graphite fibers in an epoxy matrix. Three different reinforcing fiber architectures were considered. Specimens were cut from resin transfer molded (RTM) composite panels made from each braid. There were considerable differences in the observed elastic constants from different size strain gage and extensometer readings. Larger strain gages gave more consistent results and correlated better with the extensometer readings. Experimental strains correlated reasonably well with analytical predictions in the longitudinal, zero degree, fiber direction but not in the transverse direction. Tensile strength results were not always predictable even in reinforcing directions. Minor changes in braid geometry led to disproportionate strength variations. The unit cell structure of the triaxial braid was discussed with the assistence of computer analysis of the microgeometry. Photomicrographs of the braid geometry were used to improve upon the computer graphics representations of unit cells. These unit cells were used to predict the elastic moduli with various degrees of sophistication. The simple and the complex analyses were generally in agreement but none adequately matched the experimental results for all the braids.

Masters, John E.↗
NASA NTRS1993

Mechanical properties of triaxially braided composites - Experimental and analytical results

This paper investigates the unnotched tensile properties of two-dimensional (2D) triaxial braid-reinforced composites both experimentally and analytically. The materials are graphite fibers in an epoxy matrix. Three different reinforcing fiber architectures were considered. There were considerable differences in the observed elastic constants from different size strain gage and extensometer readings. Larger strain gages gave more consistent results and correlated better with the extensometer readings. Experimental strains correlated reasonably well with analytical predictions in the longitudinal, 0 deg, fiber direction but not in the transverse direction. Tensile strength results were not always predictable even in reinforcing directions. Minor changes in braid geometry led to disproportionate strength variations. The unit cell structure of the triaxial braid was discussed with the assistance of computer analysis of the microgeometry. Photomicrographs of braid geometry were used to improve upon the computer graphics representations of unit cells. These unit cells were used to predict the elastic moduli with various degrees of sophistication. The simple and the complex analyses were generally in agreement, but none adequately matched the experimental results for all the braids.

Masters, John E.↗
NASA NTRS1940

Mechanism of Flutter A Theoretical and Experimental Investigation of the Flutter Problem

The results of the basic flutter theory originally devised in 1934 and published as NACA Technical Report no. 496 are presented in a simpler and more complete form convenient for further studies. The paper attempts to facilitate the judgement of flutter problems by a systematic survey of the theoretical effects of the various parameters. A large number of experiments were conducted on cantilever wings, with and without ailerons, in the NACA high-speed wind tunnel for the purpose of verifying the theory and to study its adaptability to three-dimensional problems. The experiments included studies on wing taper ratios, nacelles, attached floats, and external bracings. The essential effects in the transition to the three-dimensional problem have been established. Of particular interest is the existence of specific flutter modes as distinguished from ordinary vibration modes. It is shown that there exists a remarkable agreement between theoretical and experimental results.

Theodorsen, Theodore↗
NASA NTRS1992

Mechanical properties of triaxially braided composites: Experimental and analytical results

The unnotched tensile properties of 2-D triaxial braid reinforced composites from both an experimental and an analytical viewpoint are studied. The materials are graphite fibers in an epoxy matrix. Three different reinforcing fiber architectures were considered. Specimens were cut from resin transfer molded (RTM) composite panels made from each braid. There were considerable differences in the observed elastic constants from different size strain gage and extensometer reading. Larger strain gages gave more consistent results and correlated better with the extensometer reading. Experimental strains correlated reasonably well with analytical predictions in the longitudinal, 0 degrees, fiber direction but not in the transverse direction. Tensile strength results were not always predictable even in reinforcing directions. Minor changes in braid geometry led to disproportionate strength variations. The unit cell structure of the triaxial braid was discussed with the assistance of computer analysis of the microgeometry. Photomicrographs of braid geometry were used to improve upon the computer graphics representations of unit cells. These unit cells were used to predict the elastic moduli with various degrees of sophistication. The simple and the complex analyses were generally in agreement but none adequately matched the experimental results for all the braids.

Masters, John E.↗
NASA NTRS1987

Experimental and theoretical investigation of boundary-layer instability mechanisms on a swept leading edge at Mach 3.5

A brief outline of the experimental and theoretical investigation of boundary layer instability mechanisms on a swept leading edge at Mach 3.5 is presented. Transition is affected by wind tunnel noise only when roughness is present. Local bar-R sub * Reynolds number and k/eta sub * are useful correlation parameters for a wide range of free stream Mach numbers. Stability theory is in good agreement with the experimental cross flow vortex wavelength. These conclusions are briefly discussed.

Creel, Theodore R., Jr.↗
NASA NTRS1971

Metal fatigue damage - Mechanism, detection, avoidance, and repair.

Collection of theoretical and experimental studies covering basic mechanisms of fatigue in the subcreep and creep ranges, fatigue damage detection, field practices for fatigue damage repair in jet engine components, and fatigue damage avoidance and control. Individual items are abstracted in this issue.

Manson, S. S.↗
NASA NTRS2000

An Interconnected Network of Core-Forming Melts Produced by Shear Deformation

The formation mechanism of terrestrial planetary is still poorly understood, and has been the subject of numerous experimental studies. Several mechanisms have been proposed by which metal-mainly iron with some nickel-could have been extracted from a silicate mantle to form the core. Most recent models involve gravitational sinking of molten metal or metal sulphide through a partially or fully molten mantle that is often referred to as a'magma ocean. Alternative models invoke percolation of molten metal along an interconnected network (that is, porous flow) through a solid silicate matrix. But experimental studies performed at high pressures have shown that, under hydrostatic conditions, these melts do not form an interconnected network, leading to the widespread assumption that formation of metallic cores requires a magma ocean. In contrast, here we present experiments which demonstrate that shear deformation to large strains can interconnect a significant fraction of initially isolated pockets of metal and metal sulphide melts in a solid matrix of polycrystalline olivine. Therefore, in a dynamic (nonhydrostatic) environment, percolation remains a viable mechanism for the segregation and migration of core-forming melts in a solid silicate mantle.

Bruhn, D.↗