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At least 235 records · Page 13

NO sub x deposited in the stratosphere by the space shuttle, phase 1

The results of calculations to determine the amount of NOx deposited in the stratosphere by space shuttle solid rocket motors (SRM) are presented. Flow properties and chemical composition in the exhaust nozzle and plume were analyzed. The nozzle calculations show that about 4.5 lbm/sec of NOx leaves the two SRMs. The total amount of NOx deposited in the stratosphere is related to the amount leaving the nozzle via an overall plume enhancement factor (OPEF), which depends upon the influence of afterburning and shocks in enhancing the exit plane NOx mole fraction. Calculations show that the OPEF is approximately 2, indicating the mass flow of NOx in the plume to be approximately l0 lbm/sec at 30 km altitude with a possible error factor of 4. For a vehicle velocity of 3750 ft/sec, therefore, the NOx deposition rate in the stratosphere is about 2.7 x 10(-3) lbm/ft.

Pergament, H. S.↗

Fault-Tolerant, Multiple-Zone Temperature Control

A computer program has been written as an essential part of an electronic temperature control system for a spaceborne instrument that contains several zones. The system was developed because the temperature and the rate of change of temperature in each zone are required to be maintained to within limits that amount to degrees of precision thought to be unattainable by use of simple bimetallic thermostats. The software collects temperature readings from six platinum resistance thermometers, calculates temperature errors from the readings, and implements a proportional + integral + derivative (PID) control algorithm that adjusts heater power levels. The software accepts, via a serial port, commands to change its operational parameters. The software attempts to detect and mitigate a host of potential faults. It is robust to many kinds of faults in that it can maintain PID control in the presence of those faults.

Granger, James↗

On the oblateness and rotation rate of Neptune's atmosphere

Recent observations of a stellar occultation by Neptune give an oblateness of 0.022 + or - 0.004 for Neptune's atmosphere at the 1-microbar pressure level. This results is consistent with hydrostatic equilibrium at a uniform atmospheric rotation period of 15 hours, although the error bars on quantities used in the calculation are such that an 18-hour period is not excluded. The oblateness of a planetary atmosphere is determined from stellar occultations by measuring the times at which a specified point on immersion or emersion occultation profiles is reached. Whether this standard procedure for deriving the shape of the atmosphere is consistent with what is known about vertical and horizontal temperature gradients in Neptune's atmosphere is evaluated. The nature of the constraint placed on the interior mass distribution by an oblateness determined in this manner is consided, as is the effects of possible differential rotation. A 15-hour Neptune internal mass distribution is approximately homologous to Uranus', but an 18-hour period is not. The implications for Neptune's interior structure if its body rotation period is actually 18 hours are discussed.

Hubbard, W. B.↗

Uncertainty in Heart Rate Complexity Metrics Caused by R-Peak Perturbations

Heart rate complexity (HRC) is a proven metric for gaining insight into human stress and physiological deterioration. To calculate HRC, the detection of the exact instance of when the heart beats, the R-peak, is necessary. Electrocardiogram (ECG) signals can often be corrupted by environmental noise (e.g., from electromagnetic interference, movement artifacts), which can potentially alter the HRC measurement, producing erroneous inputs which feed into decision support models. Current literature has only investigated how HRC is affected by noise when R-peak detection errors occur (false positives and false negatives). However, the numerical methods used to calculate HRC are also sensitive to the specific location of the fiducial point of the R-peak. This raises many questions regarding how this fiducial point is altered by noise, the resulting impact on the measured HRC, and how we can account for noisy HRC measures as inputs into our decision models. This work uses Monte Carlo simulations to systematically add white and pink noise at different permutations of signal-to-noise ratios (SNRs), time segments, sampling rates, and HRC measurements to characterize the influence of noise on the HRC measure by altering the fiducial point of the R-peak. Using the generated information from these simulations provides improved decision processes for system design which address key concerns such as permutation entropy being a more precise, reliable, less biased, and more sensitive measurement for HRC than sample and approximate entropy.

Napoli, Nicholas J.↗

Accurate Identification of Deamidation and Citrullination from Global Shotgun Proteomics Data Using a Dual-Search Delta Score Strategy

While proteins with deamidated/citrullinated amino acids play critical roles in the pathogenesis of many human diseases, identifying these modifications in complex biological samples has been an ongoing challenge. Herein we present a method to accurately identify these modifications from shotgun proteomics data from a deep proteome profiling study of human pancreatic islets obtained by laser capture microdissection. All MS/MS spectra were searched against database by MSGF+ twice with or without a +0.9840 Da mass shift on amino acids asparagine, glutamine, and arginine (NQR) as a dynamic modification. Consequently, for each spectrum the resulting two peptide-to-spectrum matches (PSM) with their respective MSGF+ scores were used for Delta Score calculation. It was observed that all PSMs with positive Delta Score values were clustered with mass errors around 0 ppm, while PSMs with negative Delta Score values were distributed nearly equally within the defined mass error range (20 ppm) for database searching. To estimate false discovery rate (FDR), a “pseudo-decoy” approach was applied whether datasets were searched against a database with a “real modification” mass shift (+0.9840 Da) and a “mock modification” mass shift (+1.0227 Da). FDR was controlled to ~2% with a Delta Score filter greater than zero. Manual inspection of spectra showed that PSMs with positive Delta Score value contained deamidated/citrullinated fragments in their MS/MS spectra. Finally, the results demonstrated that in-situ deamidated/citrullinated peptides can be accurately identified from shotgun tissue proteomics data by the Dual-search Delta Score Strategy.

59 BASIC BIOLOGICAL SCIENCES↗

Mass measurement of 27 P to constrain type-I x-ray burst models and validate the isobaric multiplet mass equation for the $A = 27, T = \frac{3}{2}$ isospin quartet

Background: Light curves are the primary observable of type-I x-ray bursts. Computational x-ray burst models must match simulations to observed light curves. Most of the error in simulated curves comes from uncertainties in rp process reaction rates, which can be reduced via precision mass measurements of neutron-deficient isotopes in the rp process path. Purpose: Perform a precise atomic mass measurement of 27 P. Use this new measurement to calculate rp process reaction rates and input these rates into an x-ray burst model to reduce simulated light curve uncertainty. Use the mass measurement of 27 P to validate the isobaric multiplet mass equation (IMME) for the A = 27 T = 3/2 isospin quartet which 27 P belongs to. Method: High-precision Penning trap mass spectrometry utilizing the time-of-flight ion cyclotron resonance technique was used to determine the atomic mass of 27 P. The MESA code (Modules for Experiments in Stellar Astrophysics) was then used to simulate x-ray bursts using a one-dimensional multizone model to produce updated light curves. Results: The mass excess of 27 P was measured to be –670.7(6) keV, a 14-fold precision increase over the mass reported in the 2020 Atomic Mass Evaluation (AME2020). The 26 Si(p, $γ$) 27 P– 27 P($γ$, p) 26 Si rate equilibrium has been determined to a higher precision based on the precision mass measurement of 27 P. x-ray burst light curves were produced with the MESA code using the new reaction rates. Changes in the mass of 27 P seem to have minimal effect on light curves, even in burster systems tailored to maximize impact. Conclusion: The mass of 27 P does not play a significant role in x-ray burst light curves. It is important to understand that more advanced models do not just provide more precise results, but often qualitatively different ones. This result brings us a step closer to being able to extract stellar parameters from individual x-ray burst observations. In addition, the IMME has been validated for the A = 27, T = 3/2 quartet. The normal quadratic form of the IMME using the latest data yields a reduced $χ$ 2 of 2.9. Finally, the cubic term required to generate an exact fit to the latest data matches theoretical attempts to predict this term.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗

Experiences Detecting Defective Hardware in Exascale Supercomputers

In May 2022, the newest supercomputer to top the TOP 500 list was Frontier at Oak Ridge National Laboratory, demonstrating the capability of computing more than 1.1 quintillion (1018) floating-point calculations every second. Driving this ground-breaking rate of computing is Frontier’s more than 37,000 graphics processing units (GPUs) and 9,408 central processing units (CPUs). In total, Frontier contains more than 60 million parts. At this scale, the smallest margin of error may generate hundreds of hardware errors across the system. These errors are capable of directly hindering world-class science performed on Frontier if not found. In this work, we describe and evaluate two strategies for finding hardware-level faults in Frontier’s 9,408 compute nodes. There are two strategies developed: the first uses the Slurm scheduler to scavenge available compute time to run the node screen, the second builds upon the lessons learned in the first strategy and enforces a weekly screen of each node. Using June 2023 as a case study, we find that the first scheduling strategy consumed more than ten times the resources as the second scheduling strategy, but successfully detected five hardware defects in Frontier. We summarize the lessons learned while developing and running a node screen on the world’s first exascale supercomputer.

Hagerty, Nick↗

Anomaly Detection in Liquid Sodium Cold Trap Operation with Multisensory Data Fusion Using Long Short-Term Memory Autoencoder

Sodium-cooled fast reactors (SFR), which use high temperature fluid near ambient pressure as coolant, are one of the most promising types of GEN IV reactors. One of the unique challenges of SFR operation is purification of high temperature liquid sodium with a cold trap to prevent corrosion and obstructing small orifices. We have developed a deep learning long short-term memory (LSTM) autoencoder for continuous monitoring of a cold trap and detection of operational anomaly. Transient data were obtained from the Mechanisms Engineering Test Loop (METL) liquid sodium facility at Argonne National Laboratory. The cold trap purification at METL is monitored with 31 variables, which are sensors measuring fluid temperatures, pressures and flow rates, and controller signals. Loss-of-coolant type anomaly in the cold trap operation was generated by temporarily choking one of the blowers, which resulted in temperature and flow rate spikes. The input layer of the autoencoder consisted of all the variables involved in monitoring the cold trap. The LSTM autoencoder was trained on the data corresponding to cold trap startup and normal operation regime, with the loss function calculated as the mean absolute error (MAE). The loss during training was determined to follow log-normal density distribution. During monitoring, we investigated a performance of the LSTM autoencoder for different loss threshold values, set at a progressively increasing number of standard deviations from the mean. The anomaly signal in the data was gradually attenuated, while preserving the noise of the original time series, so that the signal-to-noise ratio (SNR) averaged across all sensors decreased below unity. Results demonstrate detection of anomalies with sensor-averaged SNR < 1.

21 SPECIFIC NUCLEAR REACTORS AND ASSOCIATED PLANTS↗

Operational fitness of box truss antennas in response to dynamic slewing

A parametric study was performed to define slewing capability of large satellites along with associated system changes or subsystem weight and complexity impacts. The satellite configuration and structural arrangement from the Earth Observation Spacecraft (EOS) study was used as the baseline spacecraft. Varying slew rates, settling times, damping, maneuver frequencies, and attitude hold times provided the data required to establish applicability to a wide range of potential missions. The key elements of the study are: (1) determine the dynamic transient response of the antenna system; (2) calculate the system errors produced by the dynamic response; (3) determine if the antenna has exceeded operational requirements at completion of the slew, and if so; (4) determine when the antenna has settled to the operational requirements. The slew event is not considered complete until the antenna is within operational limits.

Bachtell, E. E.↗

Kinetics of the reaction O + ClO yields Cl + O2

The kinetics of the reaction O + ClO yields Cl + O2 (k1) were studied by using resonance fluorescence to monitor the decay of O atoms which had been generated from the laser photolysis of ClO. A discharge flow system was used to generate the ClO and its concentration was measured directly by multipass absorption spectrometry. The results are k1(298) = (4.2 + or -0.8) x 10 to the -11th cu cm/s (including systematic errors) with E/R determined to lie in the range + or - 200 K. The literature data are reviewed and a composite value of k1(T) = 6.0 x 10 to the -11th exp-(100/T) is recommended for stratospheric modeling calculations. The atmospheric implications of the revised rate constant are discussed briefly.

Margitan, J. J.↗

Estimation of monthly rainfall over Japan and surrounding waters from a combination of low-orbit microwave and geosynchronous IR data

A method is described for estimating the mean monthly rainfall data for climate studies by combining the geosynchronous IR and low-orbit microwave data. The microwave technique uses the brightness temperature at 37 and 86 GHz from the Special Sensor Microwave/Imager instrument on board the DMSP satellite to define raining areas over water and land, and the 86-GHz scattering signal to assign rain rate based on cloud model-microwave calculations. The IR estimates are initially computed separately, using hourly data from the Japanese Geostationary Meteorological Satellite. Results show that, in areas where the microwave technique performs well, the combined microwave-IR monthly total estimates have better error statistics than either the microwave of the IR techniques individually.

Adler, Robert F.↗

Optical communications link design for the tracking and data acquisition system

The communications performances of laser intersatellite links for a future NASA data-relay system are analyzed, and block diagrams of necessary optical terminals are generated based on technology projected to be available by 1992. Direct-detection optical communications subsystems are selected to interconnect two geosynchronous (GEO) satellites separated by 160 deg along the GEO arc and to interconnect a low-earth-orbit (LEO) satellite and either of the GEO satellites. The terminal designs are based on power budget calculations performed for the various links with and without an optical background in either the receiver or transmitter fields of view (FOVs). Optical antennas with 18-cm and 30-cm primary mirror diameters on the LEO and GEO satellites can achieve a 0.000001 average bit error rate during normal operations in each of the forward and return optical links with beginning-of-life (BOL) power margins of approximately 7 dB. With an optical background in the receiver FOV, communications in the GEO-GEO return link are interrupted, the LEO-GEO return link is undegraded, and the GEO-GEO and LEO-GEO forward links remain functional with reduced BOL power margins. With an optical background in the transmitter FOV, the GEO-GEO forward and return links are noticeably degraded, the LEO-GEO return link is only slightly degraded, and the LEO-GEO forward link remains undegraded.

Marshalek, R. G.↗

Stochastic Microgrid Scheduling With Chance‐Constrained Resilience Consideration

Traditionally, it is assumed that microgrids transition seamlessly from grid‐connected operation to islanded mode in the event of sudden main grid outages. In reality, the islanding process, especially unintentional islanding, is rarely seamless. Instead, it is subject to voltage and frequency fluctuations caused by the instantaneous disconnection of the point of common coupling (PCC) switch, variations in loads and renewable generation output and even the protection tripping of distributed energy resources (DERs). To mitigate these fluctuations and facilitate a smooth islanding process, we propose a stochastic microgrid scheduling model that incorporates chance‐constrained resilience measures. Specifically, the resilience measure is defined as the probability of successful islanding (PSI), that is, the probability that a microgrid can mitigate the generation‐demand imbalance caused by the disconnection of the PCC switch, variations in load and renewable generation and DER tripping. This measure is modelled using chance constraints. Unlike existing reliability and resilience indices, which typically neglect the possibility of microgrid/DER failure under extreme events and assume their survival while primarily focussing on reducing impact duration or magnitude, the proposed PSI‐based framework explicitly addresses microgrid and DER survival during the islanding transition. The formulated nonlinear chance constraints are approximated using a multiinterval approach and equivalently represented as a mixed‐integer linear programming (MILP) formulation. Case study results validate the proposed method, showing that the PSI estimation error is reduced to less than 8%, compared to approximately 28% with existing methods. Various sensitivity analyses on the DER tripping rate and PSI settings were performed to validate the robustness of the proposed method. In particular, the necessity of accounting for DER tripping in the PSI calculation was demonstrated.

chance constrained optimization↗

Multiresolution GPC-Structured Control of a Single-Loop Cold-Flow Chemical Looping Testbed

Chemical looping is a near-zero emission process for generating power from coal. It is based on a multi-phase gas-solid flow and has extremely challenging nonlinear, multi-scale dynamics with jumps, producing large dynamic model uncertainty, which renders traditional robust control techniques, such as linear parameter varying H ∞ design, largely inapplicable. This process complexity is addressed in the present work through the temporal and the spatiotemporal multiresolution modeling along with the corresponding model-based control laws. Namely, the nonlinear autoregressive with exogenous input model structure, nonlinear in the wavelet basis, but linear in parameters, is used to identify the dominant temporal chemical looping process dynamics. The control inputs and the wavelet model parameters are calculated by optimizing a quadratic cost function using a gradient descent method. The respective identification and tracking error convergence of the proposed self-tuning identification and control schemes, the latter using the unconstrained generalized predictive control structure, is separately ascertained through the Lyapunov stability theorem. The rate constraint on the control signal in the temporal control law is then imposed and the control topology is augmented by an additional control loop with self-tuning deadbeat controller which uses the spatiotemporal wavelet riser dynamics representation. The novelty of this work is three-fold: (1) developing the self-tuning controller design methodology that consists in embedding the real-time tunable temporal highly nonlinear, but linearly parametrizable, multiresolution system representations into the classical rate-constrained generalized predictive quadratic optimal control structure, (2) augmenting the temporal multiresolution loop by a more complex spatiotemporal multiresolution self-tuning deadbeat control loop, and (3) demonstrating the effectiveness of the proposed methodology in producing fast recursive real-time algorithms for controlling highly uncertain nonlinear multiscale processes. The latter is shown through the data from the implemented temporal and augmented spatiotemporal solutions of a difficult chemical looping cold flow tracking control problem.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Error growth in operational ECMWF forecasts

A parameterization scheme used at the European Centre for Medium Range Forecasting to model the average growth of the difference between forecasts on consecutive days was extended by including the effect of error growth on forecast model deficiencies. Error was defined as the difference between the forecast and analysis fields during the verification time. Systematic and random errors were considered separately in calculating the error variance for a 10 day operational forecast. A good fit was obtained with measured forecast errors and a satisfactory trend was achieved in the difference between forecasts. Fitting six parameters to forecast errors and differences that were performed separately for each wavenumber revealed that the error growth rate grew with wavenumber. The saturation error decreased with the total wavenumber and the limit of predictability, i.e., when error variance reaches 95 percent of saturation, decreased monotonically with the total wavenumber.

Kalnay, E.↗

Small Scale Mass Flow Plug Calibration

A simple control volume model has been developed to calculate the discharge coefficient through a mass flow plug (MFP) and validated with a calibration experiment. The maximum error of the model in the operating region of the MFP is 0.54%. The model uses the MFP geometry and operating pressure and temperature to couple continuity, momentum, energy, an equation of state, and wall shear. Effects of boundary layer growth and the reduction in cross-sectional flow area are calculated using an in- integral method. A CFD calibration is shown to be of lower accuracy with a maximum error of 1.35%, and slower by a factor of 100. Effects of total pressure distortion are taken into account in the experiment. Distortion creates a loss in flow rate and can be characterized by two different distortion descriptors.

mass-flow measurements↗

NASA’s MODIS/VIIRS Global Water Reservoir Product Suite from Moderate Resolution Remote Sensing Data

Global reservoir information can not only benefit local water management but can also improve our understanding of the hydrological cycle. This information includes water area, elevation, and storage; evaporation rate and volume values; and other characteristics. However, operational wall-to-wall reservoir storage and evaporation monitoring information is lacking on a global scale. Here we introduce NASA’s new MODIS/VIIRS Global Water Reservoir product suite based on moderate resolution remote sensing data—the Moderate Resolution Imaging Spectroradiometer (MODIS), and the Visible Infrared Imaging Radiometer Suite (VIIRS). This product consists of 8-day (MxD28C2 and VNP28C2) and monthly (MxD28C3 and VNP28C3) measurements for 164 large reservoirs (MxD stands for the product from both Terra (MOD) or Aqua (MYD) satellites). The 8-day product provides area, elevation, and storage values, which were generated by first extracting water areas from surface reflectance data and then applying the area estimations to the pre-established Area–Elevation (A–E) relationships. These values were then further aggregated to monthly, with the evaporation rate and volume information added. The evaporation rate and volume values were calculated after the Lake Temperature and Evaporation Model (LTEM) using MODIS/VIIRS land surface temperature product and meteorological data from the Global Land Data Assimilation System (GLDAS). Validation results show that the 250 m area classifications from MODIS agree well with the high-resolution classifications from Landsat (R^(2) = 0.99). Validation of elevation and storage products for twelve Indian reservoirs show good agreement in terms of R^(2) values (0.71–0.96 for elevation, and 0.79–0.96 for storage) and normalized root-mean-square error (NRMSE) values (5.08–19.34% for elevation, and 6.39–18.77% for storage). The evaporation rate results for two reservoirs (Lake Nasser and Lake Mead) agree well with in situ measurements (R^(2) values of 0.61 and 0.66, and NRMSE values of 16.25% and 21.76%). Furthermore, preliminary results from the VIIRS reservoir product have shown good consistency with the MODIS based product, confirming the continuity of this 20-year product suite. This new global water reservoir product suite can provide valuable information with regard to water-sources-related studies, applications, management, and hydrological modeling and change analysis such as drought monitoring.

Yao Li↗

Horizon sensor errors calculated by computer models compared with errors measured in orbit

Using a computer program to model the earth's horizon and to duplicate the signal processing procedure employed by the ESA (Earth Sensor Assembly), errors due to radiance variation have been computed for a particular time of the year. Errors actually occurring in flight at the same time of year are inferred from integrated rate gyro data for a satellite of the TIROS series of NASA weather satellites (NOAA-A). The predicted performance is compared with actual flight history.

Ward, K. A.↗