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At least 235 records · Page 13

The Effects of Heat Treatment and Microstructure Variations on Disk Superalloy Properties at High Temperature

The effects of heat treatment and resulting microstructure variations on high temperature mechanical properties were assessed for a powder metallurgy disk superalloy LSHR. Blanks were consistently supersolvus solution heat treated and quenched at two cooling rates, than aged at varying temperatures and times. Tensile, creep, and dwell fatigue crack growth tests were then performed at 704 C. Gamma' precipitate microstructures were quantified. Relationships between heat treatment-microstructure, heat treatment-mechanical properties, and microstructure-mechanical properties were assessed.

Gabb, Timothy P.↗

Demonstration Testing for Ground Servicing of the Commercial Crew Vehicle Emergency Breathing Air Assembly

The new Commercial crew vehicle (CCV) Breathing Air Assembly (CEBAA) is a Composite Overwrapped Pressure Vessel (COPV) filled with high-pressure air, which is designed to provide portable emergency breathing air for up to five crew in the event of an ammonia leak aboard the International Space Station (ISS). Industrially, several common methods of delivering breathing air exist; however, ground processing constraints and flight requirements necessitate the more unusual approach of servicing a COPV with high purity gaseous nitrogen and oxygen serially to achieve a specific mixture of breathing air at approximately 4000 PSIA. A dwell period allows the gases to mix before sampling for composition verification. The novelty of this approach led to concerns about acceptable gas mixing and the ability to deliver accurate gas compositions. Tests examining mixing rate over a series of post-servicing dwell periods were conducted to determine the optimal time for achieving a homogeneous mixture. Further testing was conducted to examine process accuracy using temperature-pressure load criteria to target a specific concentration of oxygen and nitrogen. Test results show that while some stratification of nitrogen and oxygen was observed, a seven-day dwell is adequate time to achieve an acceptable level of mixing, and that existing ground support equipment can accurately service CEBAA COPVs to the required temperature, pressure and composition for flight.

Active Thermal↗

Demonstration Testing for Ground Servicing of the Commercial Crew Vehicle Emergency Breathing Air Assembly

The new Commercial crew vehicle (CCV) Emergency Breathing Air Assembly (CEBAA) is a Composite Overwrapped Pressure Vessel (COPV) filled with high-pressure air, which is designed to provide portable emergency breathing air for up to five crew in the event of an ammonia leak aboard the International Space Station (ISS). Industrially, several common methods of delivering breathing air exist; however, ground processing constraints and flight requirements necessitate the more unusual approach of servicing a COPV with high purity gaseous nitrogen and oxygen serially to achieve a specific mixture of breathing air at approximately 4000 PSIA. A dwell period allows the gases to mix before sampling for composition verification. The novelty of this approach led to concerns about acceptable gas mixing and the ability to deliver accurate gas compositions. Tests examining mixing rate over a series of post-servicing dwell periods were conducted to determine the optimal time for achieving a homogeneous mixture. Further testing was conducted to examine process accuracy using temperature-pressure load criteria to target a specific concentration of oxygen and nitrogen. Test results show that while some stratification of nitrogen and oxygen was observed, a seven-day dwell is adequate time to achieve an acceptable level of mixing, and that existing ground support equipment can accurately service CEBAA COPVs to the required temperature, pressure and composition for flight.

Active Thermal↗

Evaluation of the cyclic behavior of aircraft turbine disk alloys, part 2

Several nickel-base aircraft turbine disk superalloys were evaluated at 650 C for resistance to fatigue crack initiation and propagation under cyclic and cyclic/dwell conditions. Controlled strain low cycle fatigue (LCF) and controlled load crack propagation tests were performed and results utilized to provide a direct comparison among the alloys. Tests were performed on selected alloys to evaluate the effects of hold times, mean stresses, stress-dwell cycle types, inert environment, and contractor test methods. At the lower total strain ranges of interest, the alloys exhibited generally increasing initiation life with increasing tensile strength for both cyclic (0.33 Hz) and cyclic/dwell (900-sec hold per cycle) conditions. Rank order of the alloys by LCF initiation life changed substantially at higher strain ranges, approaching the rank order expected from monotonic tensile ductilities. The effect of the 900 sec (15 min) hold time fatigue life varied significantly from alloy to alloy. Generally, the higher-strength, finer-grained alloys exhibited more significant reductions in fatigue life due to the dwell. The effects of mean strain were found to be negligible and the effects of mean stress were pronounced. At high strain ranges the mean stress was near zero and did not contribute to reduction in life. At low strain ranges, however, mean stresses were large and significant reductions in LCF lives occurred.

Cowles, B. A.↗

VAS applications at Colorado State University

The application of the VAS program is outlined. The initial assessments of VAS radiometer and satellite performance were satisfactory; and VAS operations were smoothly carried out by the NESS SOCC and associated processing and retransmission facilities. The availability of advanced image processing systems, previous studies with the geosynchronous European Space Agency Meteorological Satellite (Meteosat), and the polar orbiter multichannel radiance data enabled the progress of the application. The VAS data are implemented as these data are received in the real time VISSR mode, and as dwell sounding (DS) and multispectral imaging (MSI) radiances on magnetic tapes.

Kruidenier, M.↗

A distributed clients/distributed servers model for STARCAT

STARCAT, the Space Telescope ARchive and CATalogue user interface has been along for a number of years already. During this time it has been enhanced and augmented in a number of different fields. This time, we would like to dwell on a new capability allowing geographically distributed user interfaces to connect to geographically distributed data servers. This new concept permits users anywhere on the internet running STARCAT on their local hardware to access e.g., whichever of the 3 existing HST archive sites is available, or get information on the CFHT archive through a transparent connection to the CADC in BC or to get the La Silla weather by connecting to the ESO database in Munich during the same session. Similarly PreView (or quick look) images and spectra will also flow directly to the user from wherever it is available. Moving towards an 'X'-based STARCAT is another goal being pursued: a graphic/image server and a help/doc server are currently being added to it. They should further enhance the user independence and access transparency.

Pirenne, B.↗

Low strain, long life creep fatigue of AF2-1DA and INCO 718

Two aircraft turbine disk alloys, GATORIZED AF2-DA and INCO 718 were evaluated for their low strain long life creep-fatigue behavior. Static (tensile and creep rupture) and cyclic properties of both alloys were characterized. The cntrolled strain LCF tests were conducted at 760 C (1400 F) and 649 C (1200 F) for AF2-1DA and INCO 718, respectively. Hold times were varied for tensile, compressive and tensile/compressive strain dwell (relaxation) tests. Stress (creep) hold behavior of AF2-1DA was also evaluated. Generally, INCO 718 exhibited more pronounced reduction in cyclic life due to hold than AF2-1DA. The percent reduction in life for both alloys for strain dwell tests was greater at low strain ranges (longer life regime). Changing hold time from 0 to 0.5, 2.0 and 15.0 min. resulted in corresponding reductions in life. The continuous cycle and cyclic/dwell initiation failure mechanism was predominantly transgranular for AF2-1DA and intergranular for INCO 718.

Thakker, A. B.↗

A Time-Varying Model for Predicting Formaldehyde Emission Rates in Homes

Recent studies have succeeded in relating emissions of various volatile organic compounds to material mass diffusion transfer using detailed empirical characteristics of each of the individual emitting materials. While significant, the resulting models are often scenario specific and/or require a host of individual component parameters to estimate emission rates. This study developed an approach to estimate aggregated emissions rates based on a wide number of field measurements. We used a multi-parameter regression model based on previous mass transfer models to predict formaldehyde emission rate for a whole dwelling using field-measured, time-resolved formaldehyde concentrations, air exchange rates, and indoor environmental parameters in 63 California single-family houses built between 2011 and 2017. The resulting model provides time-varying formaldehyde emission rates, normalized by floor area, for each study home, assuming a well-mixed mass balance transport model of the home, and a well-mixed layer transport model of indoor surfaces. The surface layer model asserts an equilibrium concentration within the surface layer of the emitted materials that is a function of temperature and RH; the dwelling ventilation rate serves as a surrogate for indoor concentration. We also developed a more generic emission model that is suitable for broad prediction of emission for a population of buildings. This model is also based on measurements aggregated from 27 homes from the same study. We showed that errors in predicting household formaldehyde concentrations using this approach were substantially less than those using a traditional constant emission rate model, despite requiring less unique building information.

54 ENVIRONMENTAL SCIENCES↗

Energy Efficient Thermoplastic Composite Manufacturing

The objective of the project was to establish an effective and affordable method to lay-up and consolidate/join large thermoplastic composite aerospace structure with cycle times measured in minutes rather than hours. Composite airplane designs have proven efficient and effective however future potential product production rates are challenging what the current systems can efficiently produce due to material lay-down constraints and extended thermal cycle times. The ability to lay-up then rapidly heat, consolidate, and cool large complex composite structures plus very accurately tool them (i.e. matching CTE of composite materials) along with very precise thermal control is a difficult challenge. Current systems such as autoclave processing of thermoset materials require long cycle times due to method of heating and the large associated thermal masses. These extended cycle times inhibit the ability to meet higher rate production scenarios due to the need for multiple sets of equipment and tools. Thermoplastic composite materials were used to facilitate more rapid cycle times via the elimination of a need for a cure dwell at temperature. Also, utilized induction heating along with smart susceptors to enable the quick cycle times needed while providing precise intrinsic thermal control. The intrinsic control of the induction heating process via the smart susceptors along with the use of laser assisted fiber placement were the key innovations areas developed. The ability to rapidly heat and then precisely control the temperature of the consolidation component was paramount to the success of this project. It is this unique processing attribute coupled with the thermoplastic material characteristics along with rapid lay-up methods that are novel and advantageous. While many requirements and influencing factors decide the materials and processes utilized for future airplane construction, the forecast of accelerated production rates and the recent performance successes of composites in airplane construction provide an opportunity for this processing technology to have significant influence. During the course of this project a number of key accomplishments were completed. They are as follows: The needed laser assisted fiber placement capabilities have been developed and validated on a component of meaningful scale and complexity. Subsequently, a thermoplastic preform of the part scale-up part design was laser assisted fiber placed and made availalbe for consolidation. An induction consolidation system was sized, designed, and fabricated resulting in the full capability to consolidate the scale-up component. The tool for induction consolidating of the scale-up component was designed and fabricated. An aluminum pressure bladder was welded and formed for use as the pressurization membrane to perform the needed application of pressure on the part at temperature to achieve consolidation. The induction consolidation system consisting of the restraint, induction power supply, induction tool with integrated induction coils and smart susceptor liners, along with the aluminum bladder were successfully used to consolidate a large thermoplastic skin. The capability of accomplishing rapid heat-up rates and cool down rates for consolidation of large thermoplastic skins with precise thermal control and even pressure application at the consolidation temperature was validated. The general conclusion is that the use of induction consolidation with smart susceptors is an effective method to rapidly and efficiently consolidate large thermoplastic composite components and enable affordable high rate manufacturing of composites. More specific conclusions generated by this project are as follows: A restraint type induction consolidation system provides an affordable option over the standard press when using the induction consolidation processing method. Aluminum bladders can be formed to the complex shapes needed and supply uniform pressure for consolidation and co-consolidation of thermoplastic composite materials. Straightforward modifications can be made to existing fiber placement robotic systems to enable their use for thermoplastic lay-up applications.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

Viscoplastic Characterization of Ti-6-4: Experiments

As part of a continued effort to improve the understanding of material time-dependent response, a series of mechanical tests have been conducted on the titanium alloy, Ti-6Al-4V. Tensile, creep, and stress relaxation tests were performed over a wide range of temperatures and strain rates to engage various amounts of time-dependent behavior. Additional tests were conducted that involved loading steps, overloads, dwell periods, and block loading segments to characterize the interaction between plasticity and time-dependent behavior. These data will be used to characterize a recently developed, viscoelastoplastic constitutive model with a goal toward better estimates of aerospace component behavior, resulting in improved safety.

mechanical properties↗

Time composite sounding

In the time composite sounding mode, the Vertical Atmospheric Sounder (VAS) data is collected in a series of images of one spin each rather than in the dwell sound mode where single lines are repeatedly scanned. A drawback of the time composite method is temporal smearing of the data, but to compensate this there is also the chance that shifting cloud patterns will permit better spatial coverage. Time composite sounding was performed for a single case study, June 14, 1984. Four, ten minute single spin swaths were processed. The principal conclusion was that the time composite results were at least equivalent to the conventional dwell sounding results, despite the fact that compositing was done in a less than optimum way because of software limitations.

Hayden, C.↗

Observation of early events in the photoactivation of Myxobacterial phytochrome using time-resolved serial femtosecond crystallography

Myxobacteria are non-photosynthetic, soil-dwelling bacteria distinguished by a multicellular stage in their life cycle known as fruiting bodies that are stimulated by light. Myxobacterial phytochromes are candidates for the perception of red-light. The mechanism how light is perceived and converted to a physiological response is unknown. Here, time-resolved serial femtosecond crystallographic (TR-SFX) experiments were conducted on microcrystals of the photosensory core module of the Stigmatella aurantiaca bacteriophytochrome 2 (SaBphP2). Initial events of the Z to E isomerization reaction of the covalently bound, open-chain tetrapyrrole biliverdin (BV) chromophore were determined. At 3 ps after light activation, the BV ring-D assumes a configuration needed for the isomerization. At 100 ps, a mixture of BV in the Z or E configuration is observed in subunit A, while in the other subunit the chromophore remains in the Z configuration. In conjunction with prior results, these structures reveal the molecular mechanism of phytochrome activation in the photomorphogenesis of the myxobacteria and provide the molecular foundation for physiological responses to red light in other bacteria.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Infrared triggered dwell and active cooling thermal control effects on microstructural uniformity in DED

Directed Energy Deposition (DED) offers rapid large scale fabrication, but difficulty in delivering consistent microstructures and properties hinders the use of DED fabricated components in safety or performance critical applications. Variability stems from the complex thermal cycles generated by the toolpath used to print the required geometry. Several practical methods have become established in DED to regulate overheating, such as active cooling of the baseplate structure or the use of an infrared camera to inject interlayer pauses to ensure the top layer of the component cools to a set temperature, which have been shown to affect microstructure. However, no critical assessment has been performed as to how effective these controls are in promoting microstructural uniformity in the context of complex layer timing commonly generated by non-prismatic geometries. Here we show how controls influence the thermal field, phase transformations, and dynamic annealing of a low-temperature transformation steel using infrared imaging and operando neutron diffraction. Counterintuitively, common thermal homogenization process controls can reduce microstructural uniformity because these approaches stabilize peak temperature while overlooking temperatures near the solid-state phase transformation fronts. Instead, the cyclic reheating induces spatially-variant dynamically annealed regions which can be modulated via control parameters. We show that these controls have spatially linked effects centimeters away from the active weld, which implies that microstructure control must co-optimize thermal input across many subsequent layers. In conclusion, our results demonstrate the pressing need for higher order controls that integrate predictive elements of simulation data to stabilize printed properties for future qualification of DED components.

Directed energy deposition↗

Breaking Down the Computational Barriers to Real-Time Urban Flood Forecasting

Flooding impacts are on the rise globally, and concentrated in urban areas. Currently, there are no operational systems to forecast flooding at spatial resolutions that can facilitate emergency preparedness and response actions mitigating flood impacts. We present a framework for real-time flood modeling and uncertainty quantification that combines the physics of fluid motion with advances in probabilistic methods. The framework overcomes the prohibitive computational demands of high-fidelity modeling in real-time by using a probabilistic learning method relying on surrogate models that are trained prior to a flood event. This shifts the overwhelming burden of computation to the trivial problem of data storage, and enables forecasting of both flood hazard and its uncertainty at scales that are vital for time-critical decision-making before and during extreme events. The framework has the potential to improve flood prediction and analysis and can be extended to other hazard assessments requiring intense high-fidelity computations in real-time.

54 ENVIRONMENTAL SCIENCES↗

Liquid Motion Experiment Flight Test Results

The Liquid Motion Experiment (LME), designed to study the effects of liquid motion in rotating tanks, was flown on STS 84. LME was essentially a spin table that created a realistic nutation motion of scale-model tanks containing liquid. TWo spherical and two cylindrical transparent tanks were tested simultaneously, and three sets of such tanks were employed to vary liquid viscosity, fill level, and propellant management device (PMD) design. All the tanks were approximately 4.5 inches diameter. The primary test measurements were the radial and tangential torques exerted on the tanks by the liquid. Resonant frequencies and damping of the liquid oscillations were determined by sine sweep tests. For a given tank shape, the resonant frequency depended on fill level. For the cylindrical tanks, the resonances had somewhat different frequencies for the tangential axis (0.55 to 0.75 times spin rate) and the radial axis (0.73 to 0.78 times spin rate), and the tangential axis resonance agreed more closely with available analytical models. For the spherical tanks, the resonant frequencies were between 0.74 to 0.77 times the spin rate and were the same for the tangential and radial axes. The damping coefficients varied from about I% to 3% of critical, depending on tank shape, fill level, and liquid viscosity. 'Me viscous energy dissipation rates of the liquid oscillations were determined from sine dwell tests. The LME energy dissipation rates varied from 0.3 to 0.5 times the estimates obtained from scaling previous ground tests and spacecraft flight data. The PNDs sometimes enhanced the resonances and energy dissipation rates and sometimes decreased them, which points out the need to understand better the effects of PMD on liquid motion as a function of PMD and tank design.

Chato David J.↗

A Novel Modeling Framework for Computationally Efficient and Accurate Real-Time Ensemble Flood Forecasting With Uncertainty Quantification

A novel modeling framework that simultaneously improves accuracy, predictability, and computational efficiency is presented. It embraces the benefits of three modeling techniques integrated together for the first time: surrogate modeling, parameter inference, and data assimilation. The use of polynomial chaos expansion (PCE) surrogates significantly decreases computational time. Parameter inference allows for model faster convergence, reduced uncertainty, and superior accuracy of simulated results. Ensemble Kalman filters assimilate errors that occur during forecasting. To examine the applicability and effectiveness of the integrated framework, we developed 18 approaches according to how surrogate models are constructed, what type of parameter distributions are used as model inputs, and whether model parameters are updated during the data assimilation procedure. We conclude that (1) PCE must be built over various forcing and flow conditions, and in contrast to previous studies, it does not need to be rebuilt at each time step; (2) model parameter specification that relies on constrained, posterior information of parameters (so-called Selected specification) can significantly improve forecasting performance and reduce uncertainty bounds compared to Random specification using prior information of parameters; and (3) no substantial differences in results exist between single and dual ensemble Kalman filters, but the latter better simulates flood peaks. The use of PCE effectively compensates for the computational load added by the parameter inference and data assimilation (up to ~80 times faster). Therefore, the presented approach contributes to a shift in modeling paradigm arguing that complex, high-fidelity hydrologic and hydraulic models should be increasingly adopted for real-time and ensemble flood forecasting.

54 ENVIRONMENTAL SCIENCES↗

Modal test - Measurement and analysis requirements

Data from the Viking Orbiter Modal Test Program are used to illustrate modal test measurement and analysis requirements. The test was performed using a multiple shake dwell technique where data were acquired one channel at a time and recorded on paper tape. Up to ten shakers were used simultaneously, with a complete set of data consisting of 290 strain-gage readings and 125 accelerometer readings. The data analysis provided information sufficient to minimize errors in the data. The list of analyses in order of value is orthogonality, residual mass, frequency sweep, data checks to assure good test data, multilevel trends, global kinetic energy, and global strain energy.

Wada, B. K.↗

Rapid Identification of Synthetic Routes to Functional Metastable Phases Using X-ray Probed Laser Anneal Mapping (XPLAM) Time-Temperature Quench Maps

Many material systems have known or predicted functional phases that are metastable at standard temperature and pressure. While substantial advances have been made in the high-throughput and combinatorial synthesis of materials with a range of stoichiometries, investigation of thermal processing remains largely the domain of iterative uniform anneals or static gradients. Here we develop X-ray probed laser anneal mapping (XPLAM), a high throughput technique coupling spatially resolved X-ray diffraction with microsecond to millisecond laser gradient anneals to produce temperature–dwell–transformation (TDT) diagrams of the phase as a function of quench time and temperature. In addition to showing regimes where specific metastable phases form preferentially, TDT diagrams provide insight into the submillisecond kinetics of solid–solid phase transitions. This is a unique tool for mapping reaction pathways for metastable phases. As a first demonstration of XPLAM, we study Bi2O3, which has a rich set of polytypes, including the d-phase with an exceptionally high oxygen ion conductivity. We demonstrate the first annealing-driven synthesis of room temperature d-Bi2O3. We expect XPLAM to prove a powerful technique for rapid identification of synthetic routes to metastable phases and to generate the exhaustive data sets required for machine learning-guided exploration of materials processing.

36 MATERIALS SCIENCE↗