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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 235 records · Page 13

All sources NASA NTRS DOE OSTI

DOE OSTI2023

Vehicle Localization in 3D World Coordinates Using Single Camera at Traffic Intersection

Optimizing traffic control systems at traffic intersections can reduce the network-wide fuel consumption, as well as emissions of conventional fuel-powered vehicles. While traffic signals have been controlled based on predetermined schedules, various adaptive signal control systems have recently been developed using advanced sensors such as cameras, radars, and LiDARs. Among these sensors, cameras can provide a cost-effective way to determine the number, location, type, and speed of the vehicles for better-informed decision-making at traffic intersections. In this research, a new approach for accurately determining vehicle locations near traffic intersections using a single camera is presented. For that purpose, a well-known object detection algorithm called YOLO is used to determine vehicle locations in video images captured by a traffic camera. YOLO draws a bounding box around each detected vehicle, and the vehicle location in the image coordinates is converted to the world coordinates using camera calibration data. During this process, a significant error between the center of a vehicle’s bounding box and the real center of the vehicle in the world coordinates is generated due to the angled view of the vehicles by a camera installed on a traffic light pole. As a means of mitigating this vehicle localization error, two different types of regression models are trained and applied to the centers of the bounding boxes of the camera-detected vehicles. The accuracy of the proposed approach is validated using both static camera images and live-streamed traffic video. Based on the improved vehicle localization, it is expected that more accurate traffic signal control can be made to improve the overall network-wide energy efficiency and traffic flow at traffic intersections.

47 OTHER INSTRUMENTATION↗

DOE OSTI2016

“Straining” to Separate the Rare Earths: How the Lanthanide Contraction Impacts Chelation by Diglycolamide Ligands

The subtle energetic differences underpinning adjacent lanthanide discrimination are explored with diglycolamide ligands. Our approach converges liquid–liquid extraction experiments with solution-phase X-ray absorption spectroscopy (XAS) and density functional theory (DFT) simulations, spanning the lanthanide series. The homoleptic [(DGA)3Ln]3+ complex was confirmed in the organic extractive solution by XAS, and this was modeled using DFT. An interplay between steric strain and coordination energies apparently gives rise to a nonlinear trend in discriminatory lanthanide ion complexation across the series. Our results highlight the importance of optimizing chelate molecular geometry to account for both coordination interactions and strain energies when designing new ligands for efficient adjacent lanthanide separation for rare-earth refining.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

DOE OSTI2018

Novel red-emitting phosphor Ba3ZrNb4O15:Pr3+: The structure, characteristic photoluminescence property and thermal quenching behaviour investigation

Highlights: • Novel red emitting phosphors BZN:Pr{sup 3+} were successfully synthesized. • Phase purity, morphology and luminescent property of BZN:Pr{sup 3+} were studied. • Different concentration behavior and related mechanism were discussed. • Decay times and the fluorescence dynamics process were investigated. • Temperature sensitive thermal quenching behavior and mechanism was studied. - Abstract: Pr{sup 3+} activated niobate phosphors Ba{sub 3-x}ZrNb{sub 4}O{sub 15}:xPr{sup 3+} were firstly synthesized through high temperature solid-state method. The phase purity, crystal structure, morphology, luminescence property as well as thermal quenching behavior were carefully determined by using X-ray diffractometer, scanned electron microscope, photoluminescence and temperature dependent emission spectra, respectively. The luminescent property showed that Ba{sub 3-x}ZrNb{sub 4}O{sub 15}:xPr{sup 3+} (0.002 ≤ x ≤ 0.03) had dominate excitation around 451 nm and could exhibit red emissions peaking at 608, 618 and 651 nm, attributed to the {sup 1}D{sub 2}-{sup 3}H{sub 4}, {sup 3}P{sub 0}-{sup 3}H{sub 6} and P{sub 0}-{sup 3}F{sub 2} transitions of Pr{sup 3+} ions. The different concentration quenching behaviors were found while the related mechanism was investigated. The room temperature decay times and the related fluorescence dynamics process of Pr{sup 3+} ions in Ba{sub 3}ZrNb{sub 4}O{sub 15} were investigated. In addition, the optimal doping contents, CIE chromaticity coordinates as well as the color purity were determined. At last, the temperature sensitive emission quenching and decay behavior were discussed and the activation energy was calculated based on Arrhenius equation.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

DOE OSTI2021

Structure and dynamics of small polyimide oligomers with silicon as a function of aging

The effect of UV curing and shearing on the structure and behavior of a polyimide (PI) binder as it disperses silicon particles in a battery electrode slurry was investigated. PI dispersant effectiveness increases with UV curing time, which controls the overall binder molecular weight. Here, the shear force during electrode casting causes higher molecular weight PI to agglomerate, resulting in battery anodes with poorly dispersed Si particles that do not cycle well. It is hypothesized that when PI binder is added above a critical amount, it conformally coats the silicon particles and greatly impedes Li ion transport. There is an “interzonal region” for binder loading where it disperses silicon well and provides a coverage that facilitates Li transport through the anode material and into the silicon particles. These results have implications in ensuring reproducible electrode manufacturing and increasing cell performance by optimizing the PI structure and coordination with the silicon precursor.

36 MATERIALS SCIENCE↗

DOE OSTI2022

A Peer-to-Peer Market-Based Control Strategy for a Smart Residential Community with Behind-the-Meter Distributed Energy Resources

This paper presents a distributed peer-to-peer market control strategy to manage and to enable resource sharing of behind-the-meter distributed energy resources in a residential community. In the proposed strategy, each consumer or prosumer determines the flexibility of their point of connection to the power network such that the obtained flexibility is network-feasible. Based on the feasible flexibility, the consumers and the prosumers trade power among each other at each time instance to fulfill their preferred load requirements while maximizing their payoffs and helping to regulate node voltages inside the community. Because the problem to be solved is non-convex, a distributed particle swarm optimization algorithm is used to coordinate the consumers/prosumers in a fully autonomous manner without any centralized or hierarchical coordination. Numerical simulations performed on a community of 48 homes demonstrate the efficacy of the proposed approach.

behind-the-meter↗

DOE OSTI2022

Inference for Nonparanormal Partial Correlation via Regularized Rank-Based Nodewise Regression

Abstract Partial correlation is a common tool in studying conditional dependence for Gaussian distributed data. However, partial correlation being zero may not be equivalent to conditional independence under non-Gaussian distributions. In this paper, we propose a statistical inference procedure for partial correlations under the high-dimensional nonparanormal (NPN) model where the observed data are normally distributed after certain monotone transformations. The NPN partial correlation is the partial correlation of the normal transformed data under the NPN model, which is a more general measure of conditional dependence. We estimate the NPN partial correlations by regularized nodewise regression based on the empirical ranks of the original data. A multiple testing procedure is proposed to identify the nonzero NPN partial correlations. The proposed method can be carried out by a simple coordinate descent algorithm for lasso optimization. It is easy-to-implement and computationally more efficient compared to the existing methods for estimating NPN graphical models. Theoretical results are developed to show the asymptotic normality of the proposed estimator and to justify the proposed multiple testing procedure. Numerical simulations and a case study on brain imaging data demonstrate the utility of the proposed procedure and evaluate its performance compared to the existing methods. Data used in preparation of this article were obtained from the Alzheimer's Disease Neuroimaging Initiative (ADNI) database.

97 MATHEMATICS AND COMPUTING↗

DOE OSTI2020

2020 Transportation Research Board Workshop: Infrastructure Spatial Sensing at Intersections: The Potential to Enhance Safety and Enable Automation

The sensing technology that is enabling vehicle automation also can revolutionize traffic intersection safety, control, and efficiency. Infrastructure spatial sensing technology refers to the deployment of sensors that can detect and track all objects in the field of view - for example, mounting lidar sensors, radar, and video imaging at an intersection and fusing the data to produce a three-dimensional dynamic operational awareness. Combining such sensing capability with fail-safe vehicle communications can facilitate applications such as eco-approach and departure, optimizing efficient vehicle-signal coordination, and reducing traffic accidents through increasing safety. Furthermore, evidence is mounting suggesting that infrastructure-based sensing is needed in order to safely deploy automated public mobility alongside the normal vehicle and pedestrian traffic in our cities. Six speakers were invited to present their work from various aspects (safety, efficiency, and automation) addressing infrastructure-based sensing at the workshop on Infrastructure Spatial Sensing hosted in Washington DC as part of the Transportation Research Board Annual Meeting in January 12, 2019. A summary of the presentation are included herein.

47 OTHER INSTRUMENTATION↗

DOE OSTI2022

A Peer-to-Peer Market-Based Control Strategy for a Smart Residential Community with Behind-the-Meter Distributed Energy Resources: Preprint

behind-the-meter↗

DOE OSTI2023

A Peer-to-Peer Market-Based Control Strategy for a Smart Residential Community with Behind-the-Meter Distributed Energy Resources

This paper presents a distributed peer-to-peer market control strategy to manage and to enable resource sharing of behind-the-meter distributed energy resources in a residential community. In the proposed strategy, each consumer or prosumer determines the flexibility of their point of connection to the power network such that the obtained flexibility is network-feasible. Based on the feasible flexibility, the consumers and the prosumers trade power among each other at each time instance to fulfil their preferred load requirements while maximizing their payoffs and helping to regulate node voltages inside the community. Because the problem to be solved is non-convex, a distributed particle swarm optimization algorithm is used to coordinate the consumers/prosumers in a fully autonomous manner without any centralized or hierarchical coordination. Numerical simulations performed on a community of 48 homes demonstrate the efficacy of the proposed approach.

distributed energy resource↗

DOE OSTI2018

Development of a Waste Management Organization for the Whiteshell Laboratories Closure Project - 18317

Whiteshell Laboratories (WL) has been generating and managing radioactive waste for over fifty years in support of a wide variety of research and operational applications. The current mission of the WL site, located in Manitoba, Canada, is to fully decommission the site to an approved end-state criterion and to disposition the waste in compliance with national and provincial regulations. To expedite the decommissioning schedule from over thirty years to nine years, which was a contractual commitment for the site operating company, Canadian Nuclear Laboratories (CNL), it became apparent that a centralized and optimized organization be established to coordinate all waste management activities and to fulfill the mission to process, condition, transport and disposition all radioactive wastes, which include Low-Level Waste (LLW), Intermediate-Level Waste (ILW) and High-Level Waste (HLW). The WL Waste Management Division was effectively established as a two-person operation in 2016 and has rapidly expanded to fulfill the mandate of managing nearly 30,000 cubic meters of LLW, ILW and HLW. This paper outlines the early lessons learned from managing important organizational changes without disrupting ongoing work practices; developing executive-level waste management strategies based on options studies and cost-benefit analysis comparisons; selection of storage vs. disposal disposition strategies; evaluation and selection of transportation methods and packages for LLW, ILW and HLW; and the need to develop an entire suite of programmatic documentation and procedures to support and instill a strong conduct of operations culture. The waste management strategy, which now focuses on transporting the waste to another province (Ontario) in a disposal ready form, represents the first large-scale radioactive waste transportation campaign in Canada that includes all three classes of waste. This paper provides additional insight on the overall waste management strategies for the WL Closure Project. (authors)

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

DOE OSTI2018

Warm white light emission of apatite-type compound Ca4Y6O(SiO4)6 doped with Dy3+

Highlights: • Single-phase phosphor Ca{sub 4}Y{sub 6}O(SiO{sub 4}){sub 6}: Dy{sup 3+} for WLEDs were synthesized. • The CIE coordinates are (0.330, 0.339) for the optimal doping sample. • The CCT (5600 K) is close to that of the midday sunlight. • The emission intensity at 400 K keeps 82% with respect to that at RT. • The CIE coordinates maintain in the white light area in the range of RT-300 °C. - Abstract: A series of Ca{sub 4}Y{sub 6}O(SiO{sub 4}){sub 6}: x%Dy{sup 3+} (x = 1, 3, 5, 7, 9) phosphors were synthesized successfully via a conventional solid-state method at high temperature. The X-ray diffraction results show that all obtained samples are the pure hexagonal crystal structure of the space group P6{sub 3}/m (No.176). The blue ({sup 4}F{sub 9/2} → {sup 6}H{sub 15/2}) and yellow ({sup 4}F{sub 9/2} → {sup 6}H{sub 13/2}) emissions of Ca{sub 4}Y{sub 6}O(SiO{sub 4}){sub 6}:7% Dy{sup 3+} phosphors are of such a ratio to produce almost perfect white light with CIE coordinates of (0.330, 0.339). The correlated color temperature is about 5600 K, close to that of the midday sunlight (5500 K). In addition, both the emission intensity and the CIE coordinates exhibit an excellent thermal stability in the temperature range of RT ∼ 300 °C. Our study illustrates that Ca{sub 4}Y{sub 6}O(SiO{sub 4}){sub 6}:7%Dy{sup 3+} may serve as potential warm white lighting phosphors in NUV-based solid state lighting and optical display applications.

36 MATERIALS SCIENCE↗

DOE OSTI2021

Controlling the Co–S coordination environment in Co-doped WS 2 nanosheets for electrochemical oxygen reduction

The impact of Co–S coordination environment in pH 7 ORR catalysis is evaluated using dilute Co atoms adsorbed on WS 2 nanosheets. Optimal reactivity is achieved when Co is coordinated to both sulfur atoms on WS 2 and labile solvent ligands.

Hong, Wei↗

DOE OSTI2021

Market-based Co-optimization of Energy and Ancillary Services with Distributed Energy Resource Flexibilities

Energy storage systems and flexible loads have attracted significant interests due to their capabilities to provide various grid services. In this paper, the flexibilities are optimally allocated among multiple distributed energy resource aggregators with energy storage systems and flexible buildings by the utility coordinator through market-based co-optimization. An iterative market clearing algorithm is developed to determine the optimal energy and ancillary service prices, with consideration of both local dynamics and network constraints. Simulation results demonstrate the effectiveness of the proposed algorithm and the benefits of co-optimizing the energy and ancillary service markets.

Ma, Ke↗

DOE OSTI2023

Controlling circuitry underlies the growth optimization of Saccharomyces cerevisiae

Microbial growth emerges from coordinated synthesis of various cellular components from limited resources. In Saccharomyces cerevisiae, cyclic AMP (cAMP)-mediated signaling is shown to orchestrate cellular metabolism; however, it remains unclear quantitatively how the controlling circuit drives resource partition and subsequently shapes biomass growth. Here we combined experiment with mathematical modeling to dissect the signaling-mediated growth optimization of S. cerevisiae. We showed that, through cAMP-mediated control, the organism achieves maximal or nearly maximal steady-state growth during the utilization of multiple tested substrates as well as under perturbations impairing glucose uptake. However, the optimal cAMP concentration varies across cases, suggesting that different modes of resource allocation are adopted for varied conditions. Under settings with nutrient alterations, S. cerevisiae tunes its cAMP level to dynamically reprogram itself to realize rapid adaptation. Moreover, to achieve growth maximization, cells employ additional regulatory systems such as the GCN2-mediated amino acid control. This study establishes a systematic understanding of global resource allocation in S. cerevisiae, providing insights into quantitative yeast physiology as well as metabolic strain engineering for biotechnological applications.

59 BASIC BIOLOGICAL SCIENCES↗

DOE OSTI2023

Data for Controlling Circuitry Underlies the Growth Optimization of Saccharomyces cerevisiae

Microbial growth emerges from coordinated synthesis of various cellular components from limited resources. In Saccharomyces cerevisiae , cyclic AMP (cAMP)-mediated signaling is shown to orchestrate cellular metabolism; however, it remains unclear quantitatively how the controlling circuit drives resource partition and subsequently shapes biomass growth. Here we combined experiment with mathematical modeling to dissect the signaling-mediated growth optimization of S. cerevisiae . We showed that, through cAMP-mediated control, the organism achieves maximal or nearly maximal steady-state growth during the utilization of multiple tested substrates as well as under perturbations impairing glucose uptake. However, the optimal cAMP concentration varies across cases, suggesting that different modes of resource allocation are adopted for varied conditions. Under settings with nutrient alterations, S. cerevisiae tunes its cAMP level to dynamically reprogram itself to realize rapid adaptation. Moreover, to achieve growth maximization, cells employ additional regulatory systems such as the GCN2-mediated amino acid control. This study establishes a systematic understanding of global resource allocation in S. cerevisiae , providing insights into quantitative yeast physiology as well as metabolic strain engineering for biotechnological applications.

Conversion↗

DOE OSTI2020

COHORT: Coordination of Heterogeneous Thermostatically Controlled Loads for Demand Flexibility

Demand flexibility is increasingly important for power grids. Careful coordination of thermostatically controlled loads (TCLs) can modulate energy demand, decrease operating costs, and increase grid resiliency. We propose a novel distributed control framework for the Coordination Of HeterOgeneous Residential Thermostatically controlled loads (COHORT). COHORT is a practical, scalable, and versatile solution that coordinates a population of TCLs to jointly optimize a grid-level objective, while satisfying each TCL’s end-use requirements and operational constraints. To achieve that, we decompose the grid-scale problem into subproblems and coordi- nate their solutions to find the global optimum using the alternating direction method of multipliers (ADMM). The TCLs’ local problems are distributed to and computed in parallel at each TCL, making COHORT highly scalable and privacy-preserving. While each TCL poses combinatorial and non-convex constraints, we characterize these constraints as a convex set through relaxation, thereby making COHORT computationally viable over long planning horizons. After coordination, each TCL is responsible for its own control and tracks the agreed-upon power trajectory with its preferred strategy. In this work, we translate continuous power back to discrete on/off actuation, using pulse width modulation. COHORT is generalizable to a wide range of grid objectives, which we demonstrate through three distinct use cases: generation following, minimizing ramping, and peak load curtailment. In a notable experiment, we validated our approach through a hardware-in-the-loop simulation, including a real-world air conditioner (AC) controlled via a smart thermostat, and simulated instances of ACs modeled after real-world data traces. During the 15-day experimental period, COHORT reduced daily peak loads by an average of 12.5% and maintained comfortable temperatures.

demand response↗

DOE OSTI2026

Uncertainty quantification and reliability assessment for intermodal freight transportation

Intermodal freight optimization models support cost-effective, low-emission, and timely goods movement by coordinating trucks, rail, and barges. These models determine optimal flows, routing, and modal switches while respecting infrastructure and operational constraints. However, their real-world utility is often undermined by pervasive uncertainties-such as fluctuating transportation costs and emissions, variable terminal capacities, and uncertain freight demand-that distort key performance outcomes, including total system cost, carbon footprint, and transit time reliability. This study presents a structured framework for quantifying uncertainty in intermodal freight transportation (IFT) optimization. The framework evaluates how input uncertainty affects system performance and reliability, a critical need for ensuring that model-based decisions remain robust under real-world variability, especially amid volatile fuel prices, shifting demand, and growing disruptions. It integrates three complementary methods: (1) Sobol-based global sensitivity analysis to identify influential parameters affecting cost, emissions, and transit time, (2) Monte Carlo-based capacity perturbation analysis to assess robustness under probabilistic facility disruptions, and (3) Monte Carlo filtering with Bayesian inference to detect threshold-based performance vulnerabilities. The results highlight diesel truck unit cost as the dominant driver of variability. To improve system resilience, planners should prioritize uncertainty in fuel-related parameters when designing intermodal strategies.

Intermodal freight transportation↗

DOE OSTI2017

A Hierarchical Modeling for Reactive Power Optimization With Joint Transmission and Distribution Networks by Curve Fitting

Here, in order to solve the reactive power optimization with joint transmission and distribution networks, a hierarchical modeling method is proposed in this paper. It allows the reactive power optimization of transmission and distribution networks to be performed separately, leading to a master–slave structure and improves traditional centralized modeling methods by alleviating the big data problem in a control center. Specifically, the transmission-distribution-network coordination issue of the hierarchical modeling method is investigated. First, a curve-fitting approach is developed to provide a cost function of the slave model for the master model, which reflects the impacts of each slave model. Second, the transmission and distribution networks are decoupled at feeder buses, and all the distribution networks are coordinated by the master reactive power optimization model to achieve the global optimality. Finally, numerical results on two test systems verify the effectiveness of the proposed hierarchical modeling and curve-fitting methods.

24 POWER TRANSMISSION AND DISTRIBUTION↗