Analysis of variation of the diffusion constant of carbon in austenite with concentration
Variation of diffusion constant of carbon in austenite
CARBON↗
SEARCH · Engineering Papers
Results for “concentric carbon”
Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.
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From Minutes to Seasons: An Overview of Predictions of Carbon Flux and Concentrations over North America
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Carbon Flux↗
SPRUCE Redox-Active Subsurface Organic Matter, Marcell Experimental Forest, Minnesota, 2023
This dataset contains measurements that report on the effects of the SPRUCE experimental treatments on redox-active organic matter (RAOM) reduction (Valenzuela and Cervantes, 2021). Measurements occurred at the SPRUCE Experiment site in the Marcell Experimental Forest in northern Minnesota, USA. This work is also a follow-up to Rush et al. (2021a) which investigated effects of temperature on RAOM reduction after two years of experimental warming (Rush et al. 2021b). This follow-up dataset addresses two main questions; (i) How does warming and elevated carbon dioxide (CO2) directly affect in situ RAOM reduction, and subsequent methane (CH4) and CO2 production, across the peat depth profile? and (ii) How has long-term warming and elevated CO2 changed the total RAOM pool, and subsequent CH4 and CO2 production, across the peat depth profile? This dataset reports electron shuttling capacity (a proxy for RAOM reduction; Keller, and Takagi, 2013) and carbon dioxide (CO2) and methane (CH4) concentrations both in one-week in situ incubations (2023-05-31 to 2023-08-01) and 42-day laboratory incubations from peat collected in 2023 (2023-05-31 to 2023-06-26). Laboratory incubations also measured acetate concentrations. The 2023 laboratory incubations were also compared with laboratory incubations conducted on peat collected in 2016 (Rush et al. 2021b). This dataset contains three data files in comma-separate (.csv) format. Additional metadata are provided: three data dictionaries and a file-level metadata file in comma separate (.csv) format and a user guide in PDF (*.pdf) format.
54 ENVIRONMENTAL SCIENCES↗
Validation of Regional CO2 Concentrations in the ECMWF Real-Time Analysis and Carbon-Tracker Reanalysis with Airborne Observations from ACT-A Field Campaign
Through verifying against hundreds of hours of airborne in-situ measurements from the NASA-sponsored Atmospheric Carbon and Transport – America (ACT-A) field campaign, this study systematically examines the regional uncertainties and biases of the carbon dioxide (CO2) concentrations from two of the state-of-the-art global analysis products, namely the real-time analysis from the European Center (EC) for Medium Range Forecasting and NOAA’s near real-time Carbon Tracker (CT) reanalysis. It is found that both the EC and CT-NRT analyses agree reasonably well with the independent ACT-A flight-level CO2 measurements in the free troposphere but the uncertainties are considerably larger in the boundary layer during both the summer months of 2016 and the winter months of 2017. There are also strong variabilities in accuracy and bias between seasons, and across three different subregions in the United States (Mid-Atlantic, Midwest and South). Overall, the analysis uncertainties of the EC and CT-NRT analyses in terms of root-mean square deviations against airborne data are comparable to each other, both of which are between 1-2 ppm in the free troposphere but can be as large as 10 ppm near the surface, which are grossly consistent with the difference between the two analyses. The current study not only provides systematic uncertainty estimates for both analysis products over North America but also demonstrated that these two independent estimates can be used to approximate the overall regional CO2 analysis uncertainties. Both statistics are important in future studies in quantifying the uncertainties of regional carbon concentration and flux estimates, as well as in assessing the impact of regional transport through more refined regional modeling and analysis systems.
Chen, Hans W.↗
Spacecraft oxygen recovery system
Recovery system is comprised of three integrated subsystems: electrochemical carbon dioxide concentrator which removes carbon dioxide from atmosphere, Sabatier reactor in which carbon dioxide is reduced with hydrogen to form methane and water, and static-feed water electrolysis cell to recover oxygen from water.
Quattrone, P. D.↗
Effects of carbon and hafnium concentrations in wrought powder-metallurgy superalloys based on NASA 2B-11 alloy
A candidate alloy for advanced-temperature turbine engine disks, and four modifications of that alloy with various C and Hf concentrations were produced as cross-rolled disks from prealloyed powder that was hot isostatically compacted. The mechanical properties, microstructures, and phase relations of the alloys are discussed in terms of their C and Hf concentrations. A low-C and high-Hf modification of IIB-11 had the best balance of mechanical properties for service below about 750 C. Because of their finer grain sizes, none of the powder-metallurgy alloys produced had the high-temperature rupture strength of conventionally cast and wrought IIB-11.
Miner, R. V., Jr.↗
Ex Situ Tailings Leaching and Lateritization with Electrolytic Acid Recycling for Critical Metal Concentration and Mineral Carbon Sequestration
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37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
Zinc depolarized electrochemical CO2 concentration
Two zinc depolarized electrochemical carbon dioxide concentrator concepts were analytically and experimentally evaluated for portable life support system carbon dioxide (CO2) removal application. The first concept, referred to as the zinc hydrogen generator electrochemical depolarized CO2 concentrator, uses a ZHG to generate hydrogen for direct use in an EDC. The second concept, referred to as the zinc/electrochemical depolarized concentrator, uses a standard EDC cell construction modified for use with the Zn anode. The Zn anode is consumed and subsequently regenerated, thereby eliminating the need to supply H2 to the EDC for the CO2 removal process. The evaluation was based primarily on an analytical evaluation of the two ZnDCs at projected end item performance and hardware design levels. Both ZnDC concepts for PLSS CO2 removal application were found to be noncompetitive in both total equivalent launch weight and individual extravehicular activity mission volume when compared to other candidate regenerable PLSS CO2 scrubbers.
Woods, R. R.↗
Techno-economic analysis of carbon dioxide capture from low concentration sources using membranes
Rising carbon dioxide (CO 2 ) levels in the atmosphere lead to global warming, causing climate change. As such, carbon capture has become necessary to slow the increase and reduce CO 2 levels in the atmosphere. Point source emissions have a wide range of CO 2 concentrations, but emissions below 3% CO 2 have mostly been ignored because Carbon capture from these sources has been viewed as costly and economically unsustainable. Membrane technologies are considered the most viable solution by virtue of more energy-efficient operation. Our group at Idaho National Laboratory (INL) has developed poly[bis((2-methoxyethoxy)ethoxy)phosphazene] (MEEP)-based carbon dioxide selective membranes with CO 2 /N 2 selectivity greater than 40 and CO 2 permeability greater than 450 Barrer. To understand the economics of carbon capture, a spreadsheet-based techno-economic analysis (TEA) model was developed to consider multiple parameters, including selectivity and permeability of the membranes, performance conditions such as the number of stages, module material, electricity price, membrane price, and capital financing. The cost of carbon capture in US $\$$/metric ton was calculated at various purities and compared with other membrane processes, cryogenic capture, solvent-based capture, and pressure swing adsorption-based capture. It was determined that a MEEP-based three-stage process had a capture cost of US $\$$ 50.1/metric ton for 99.8% purity CO 2 from a 1% CO 2 feed source in nitrogen (N 2 ). In conclusion, the capture cost using the best performing Pebax-based membrane was 464% higher, cryogenic capture was 60%–140% higher, pressure swing adsorption was 55%–165% higher, and chemical absorption was -10%–110% higher than MEEP-based membrane capture, respectively.
32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗
GEOS-Carb III: Delivering a Mature, Physically Consistent Set of Flux and Concentration Products o in Support of Carbon Monitoring
This iposter presents work completed under the CMS supported GEOS-Carb project, which seeks to provide an advanced and physically consistent set of carbon flux and concentration data products in support of carbon monitoring. We focus here on reviewing the overall goals and project structure and highlighting recent work on COVID-19 impacts.
Carbon↗
A review of carbon monoxide sources, sinks, and concentrations in the earth's atmosphere
Carbon monoxide is a toxic pollutant which is continually introduced into the earth's atmosphere in significant quantities. There are apparently some mechanisms operating which destroy most of the CO in the atmosphere, i.e., a carbon monoxide sink. These mechanisms have not as yet been established in a quantitative sense. This report discusses the various possible removal mechanisms which warrant serious consideration. Particular emphasis is given to chemical reactions (especially that with OH), soil bacteria and other biological action, and transport effects. The sources of carbon monoxide, both natural and anthropogenic, are reviewed and it is noted that there is quite possibly a significant undefined natural source. Atmospheric CO concentrations are discussed and their implications on carbon monoxide lifetime, sinks and sources are considered.
Bortner, M. H.↗
Measurements of concentrations of chlorofluoromethanes (CFMs) carbon dioxide and carbon isotope ratio in stratospheric and tropospheric air by grab-sampling systems
Measurements of concentrations of chlorofluoromethanes (CFMs), carbon dioxide and carbon isotope ratio in stratospheric and tropospheric air by grab-sampling systems are reported. The balloon-borne grab-sampling system has been launched from Sanriku Balloon Center three times since 1981. It consists of: (1) six sampling cylinders, (2) eight motor driven values, (3) control and monitor circuits, and (4) pressurized housing. Particular consideration is paid to the problem of contamination. Strict requirements are placed on the choice of materials and components, construction methods, cleaning techniques, vacuum integrity, and sampling procedures. An aluminum pressurized housing and a 4-m long inlet line are employed to prevent the sampling air from contamination by outgassing of sampling and control devices. The sampling is performed during the descent of the system. Vertical profiles of mixing ratios of CF2Cl2, CFCl3 and CH4 are given. Mixing ratios of CF2Cl2 and CFCl3 in the stratosphere do not show the discernible effect of the increase of those in the ground level background, and decrease with altitude. Decreasing rate of CFCl3 is larger than that of CF2Cl2. CH4 mixing ratio, on the other hand, shows diffusive equilibrium, as the photodissociation cross section of CH4 is small and concentrations of OH radical and 0(sup I D) are low.
Itoh, T.↗
Adaptational readjustments in the organism of mice during and after exposure to elevated CO2 concentrations
Adaptational rearrangements in mice exposed to elevated carbon dioxide concentrations
ADAPTATION↗
BSEC Air Quality: Stationary Black and Brown Carbon Properties and Mass Concentration
Data is 1-min absorption/attenuation of aerosol collected on filter and sampled at seven wavelengths (950, 880, 660, 590, 520, 470, and 370 nm) with a Magee AE-33 dual spot aethalometer. The wavelength value for black carbon, as recommended by the manufacturer, is the 880 nm channel. The derived mass concentrations, using the factory default mass absorption cross-sections, are reported for all seven wavelengths. The absorption at all seven wavelengths are reported by dividing the derived mass concentrations by the factory default mass absorption cross-sections. The estimated mass concentration contribution from biomass burning and fossil fuel black carbon, using factory default values, are reported. The estimated brown carbon mass concentration is derived by finding the difference between the recommended black carbon wavelength (880 nm) and the ultra violet wavelength (370 nm), assuming that brown carbon absorption is strongest at 370 nm and minimal at 880 nm. Finally, the estimated absorption Angstrom exponent for black and brown carbon is derived. For black carbon, the slope between each minute log(AbsXXX), where XXX is the wavelength used versus log(XXX) is used, and the wavelengths are 590, 660, 880, and 950 nm. For brown carbon, the slope between each minute log(AbsXXX), where XXX is the wavelength used versus log(XXX) is used, and the wavelengths are 370, 470, and 520 nm.
aerosol↗
One-man electrochemical air revitalization system evaluation
A program to evaluate the performance of a one man capacity, self contained electrochemical air revitalization system was successfully completed. The technology readiness of this concept was demonstrated by characterizing the performance of this one man system over wide ranges in cabin atmospheric conditions. The electrochemical air revitalization system consists of a water vapor electrolysis module to generate oxygen from water vapor in the cabin air, and an electrochemical depolarized carbon dioxide concentrator module to remove carbon dioxide from the cabin air. A control/monitor instrumentation package that uses the electrochemical depolarized concentrator module power generated to partially offset the water vapor electrolysis module power requirements and various structural fluid routing components are also part of the system. The system was designed to meet the one man metabolic oxygen generation and carbon dioxide removal requirements, thereby controlling cabin partial pressure of oxygen at 22 kN/sq m and cabin pressure of carbon dioxide at 400 N/sq m over a wide range in cabin air relative humidity conditions.
Schbert, F. H.↗
Mossbauer effect in the ion-implanted iron-carbon alloys
The concentration dependence of Mossbauer effect in four carbon ion-implanted iron absorbers, which contain carbon as the solute atoms, has been investigated over the range of concentration 0.05 through 1 atomic percent. The specimens were prepared by implanting carbon atoms on each reference iron foil with four different bombarding energies of 250 keV, 160 keV, 140 keV and 80 keV, respectively. Thus, the specimen contains a uniform dosage of carbon atoms which penetrated up to 3,000 A depth of the reference iron. In the measurement of Mossbauer spectra, the backscattering conversion electron counting geometry was used. Typical results of Mossbauer parameters of iron-carbon alloys show that the isomer shift, quadrupole shift, the effective hyperfine splitting of Fe-57, and the intensity ratio exhibit a large variation with the increase of carbon concentration in the environment of iron atoms.
Han, K. S.↗
Climate Sensitivity and the Direct Effect of Carbon Dioxide in a Limited-Area Cloud-Resolving Model
Even in a small domain, it can be prohibitively expensive to run cloud-resolving greenhouse gas warming experiments due to the long equilibration time. Here, a technique is introduced that reduces the computational cost of these experiments by an order of magnitude: instead of fixing the carbon dioxide concentration and equilibrating the sea surface temperature (SST), this technique fixes the SST and equilibrates the carbon dioxide concentration. Using this approach in a cloud-resolving model of radiative–convective equilibrium (RCE), the equilibrated SST is obtained as a continuous function of carbon dioxide concentrations spanning 1 ppmv to nearly 10 000 ppmv, revealing a dramatic increase in equilibrium climate sensitivity (ECS) at higher temperatures. This increase in ECS is due to both an increase in forcing and a decrease in the feedback parameter. In addition, the technique is used to obtain the direct effects of carbon dioxide (i.e., the rapid adjustments) over a wide range of SSTs. Overall, the direct effect of carbon dioxide offsets a quarter of the increase in precipitation from warming, reduces the shallow cloud fraction by a small amount, and has no impact on convective available potential energy (CAPE).
Romps, David M.↗
Editorial: Selective Controls on Microbial Energy Metabolisms: From the Microscale to the Macroscale
A mechanistic and predictive understanding of the genotypic and phenotypic controls on microbial element cycling remains a grand challenge in microbiology. While the composition and concentration of carbon sources, electron donors, and electron acceptors are known to influence microbial community structure by selecting for microbial sub-populations with distinct catabolic and respiratory pathways, selective inhibitors and trace nutrient availability modulate the activity of metabolic enzymes. This in turn influences the distribution of microbial sub-populations with distinct metabolic and respiratory traits, which are then structured by complex multi-dimensional environmental gradients that influence the composition, gene content and element cycling activity of microbiomes. While some parameters are known to select for different respiratory activities (e.g., lanthanides as essential nutrients for methanotrophs, molybdate as a specific inhibitor of sulfate reduction, carbon:nitrogen ratio and concentration as a control on the end-products of nitrate respiration), there are others to discover, and demonstrating how selective parameters operate and mediate element cycling across scales requires multi-disciplinary research in both the lab and field.
59 BASIC BIOLOGICAL SCIENCES↗