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At least 235 records · Page 13

Recent activities of National Synchrotron Light Source-II Insertion Device Group

Insertion Device (ID) Group at the National Synchrotron Light Source-II (NSLS-II) has been involved in the following activities: Installation and maintenance of the HEX-Superconducting Wiggler (SCW), Laboratory Directed Research and Development (LDRD) for SC adaptive gap undulator (AGU), NSLS-II Experimental Tools II & III (NEXT-II & III) project IDs. Improvement of in-vacuum flip coil bench, development of in-vacuum pulsed wire bench and upgrade of a regular flip coil bench. Development of rotating coil bench for the lattice magnets for future upgrade. This paper describes the specifics of each activity.

47 OTHER INSTRUMENTATION↗

Coronal manifestations of preflare activity

A variety of coronal manifestations of precursors or preheating for flares are discussed. Researchers found that almost everyone with a telescope sees something before flares. Whether an all-encompassing scenario will ever be developed is not at all clear at present. The clearest example of preflare activity appears to be activated filaments and their manifestations, which presumably are signatures of a changing magnetic field. But researchers have seen two similar eruptions, one without any evidence of emerging flux (Kundu et al., 1985) and the other with colliding poles (Simon et al., 1984). While the reconnection of flux is generally agreed to be required to energize a flare, the emergence of flux from below (at least on short timescales and in compact regions) does not appear to be a necessary condition. In some cases the cancelling of magnetic flux (Martin, 1984) by horizontal motions instead may provide the trigger (Priest, 1985) Researchers found similarities and some differences between these and previous observations. The similarities, besides the frequent involvement of filaments, include compact, multiple precursors which can occur both at and near (not at) the flare site, and the association between coronal sources and activity lower in the atmosphere (i.e., transition zone and chromosphere).

Schmahl, E. J.↗

Direct Top-down Estimates of Biomass Burning CO Emissions Using TES and MOPITT Versus Bottom-up GFED Inventory

In this study, we utilize near-simultaneous observations from two sets of multiple satellite sensors to segregate Tropospheric Emission Spectrometer (TES) and Measurements of Pollution in the Troposphere (MOPITT) CO observations over active fire sources from those made over clear background. Hence, we obtain direct estimates of biomass burning CO emissions without invoking inverse modeling as in traditional top-down methods. We find considerable differences between Global Fire Emissions Database (GFED) versions 2.1 and 3.1 and satellite-based emission estimates in many regions. Both inventories appear to greatly underestimate South and Southeast Asia emissions, for example. On global scales, however, CO emissions in both inventories and in the MOPITT-based analysis agree reasonably well, with the largest bias (30%) found in the Northern Hemisphere spring. In the Southern Hemisphere, there is a one-month shift between the GFED and MOPITT-based fire emissions peak. Afternoon tropical fire emissions retrieved from TES are about two times higher than the morning MOPITT retrievals. This appears to be both a real difference due to the diurnal fire activity variations, and a bias due to the scarcity of TES data.

bias↗

Cross-biome synthesis of source versus sink limits to tree growth

Uncertainties surrounding tree carbon allocation to growth are a major limitation to projections of forest carbon sequestration and response to climate change. The prevalence and extent to which carbon assimilation (source) or cambial activity (sink) mediate wood production are fundamentally important and remain elusive. We quantified source-sink relations across biomes by combining eddy-covariance gross primary production with extensive on-site and regional tree ring observations. We found widespread temporal decoupling between carbon assimilation and tree growth, underpinned by contrasting climatic sensitivities of these two processes. Substantial differences in assimilation-growth decoupling between angiosperms and gymnosperms were determined, as well as stronger decoupling with canopy closure, aridity, and decreasing temperatures. Our results reveal pervasive sink control over tree growth that is likely to be increasingly prominent under global climate change.

Science & Technology - Other Topics↗

Measurement report: Comparison of wintertime individual particles at ground level and above the mixed layer in urban Beijing

Beijing has been suffering from frequent severe air pollution events, with concentrations affected significantly by the mixed-layer height. Major efforts have been made to study the physico-chemical properties, compositions, and sources of aerosol particles at ground level. However, little is known about the morphology, elemental composition, and mixing state of aerosol particles above the mixed layer. In this work, we collected individual aerosol particles simultaneously at ground level (2 m above ground) and above the mixed layer in urban Beijing (within the Atmospheric Pollution and Human Health in a Chinese Megacity, APHH-Beijing, 2016 winter campaign). The particles were analyzed offline by transmission electron microscopy coupled with energy dispersive X-ray spectroscopy. Our results showed that the relative number contribution of mineral particles to all measured particles was much higher during non-haze periods (42.5 %) than haze periods (18.1 %); in contrast, internally mixed particles contributed more during haze periods (21.9 %) than non-haze periods (7.2 %) at ground level. In addition, more mineral particles were found at ground level than above the mixed-layer height. Around 20 % of individual particles showed core–shell structures during haze periods, whereas only a few core–shell particles were observed during non-haze periods (2 %). The results showed that the particles above the mixed layer were more aged, with a larger proportion of organic particles originating from coal combustion. Our results indicate that a large fraction of the airborne particles above the mixed layer come from surrounding areas influenced by coal combustion activities. This source contributes to the surface particle concentrations in Beijing when polluted air is mixed down to the ground level.

54 ENVIRONMENTAL SCIENCES↗

Rotating cylinder electrode in reactive CO 2 capture: Identifying active C species via transport, VLE models and kinetics

Here, this article explores technical challenges and potential methodologies for understanding electrochemical Reactive CO 2 Capture (RCC) mechanisms. RCC offers potential energy cost advantages by directly converting captured CO 2 into fuels and chemicals, unlike traditional carbon capture and utilization (CCU) processes that require sequential capture, concentration, and compression. However, direct conversion of captured CO 2 introduces complexity due to additional equilibrium buffer reactions, making it challenging to identify active species for reduction in electrochemical studies. This article discusses methods to integrate transport, thermodynamics, and kinetics concepts to identify active carbon sources in RCC. Vapor‐Liquid Equilibrium (VLE) and transport models are validated against experimental results obtained in a gastight rotating cylinder electrode reactor and are shown as useful tools for studying RCC in heterogeneous electrocatalysts across different capture agents, solvents, and temperatures. This article establishes an experimental framework for advancing research in electrochemical RCC.

Electrocatalysis↗

Local Structure Analysis and Modelling of Lignin‐Based Carbon Composites through the Hierarchical Decomposition of the Radial Distribution Function

Abstract Carbonized lignin has been proposed as a sustainable and domestic source of activated, amorphous, graphitic, and nanostructured carbon for many industrial applications as the structure can be tuned through processing conditions. However, the inherent variability of lignin and its complex physicochemical structure resulting from feedstock and pulping selection make the Process‐Structure‐Property‐Performance (PSPP) relationships hard to define. In this work, radial distribution functions (RDFs) from synchrotron X‐ray and neutron scattering of lignin‐based carbon composites (LBCCs) are investigated using the Hierarchical Decomposition of the Radial Distribution Function (HDRDF) modelling method to characterize the local atomic environment and develop quantitative PSPP relationships. PSPP relationships for LBCCs defined by this work include crystallite size dependence on lignin feedstock as well as increasing crystalline volume fraction, nanoscale composite density, and crystallite size with increasing reduction temperature.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Implications of Underground Nuclear Explosion Cavity Evolution for Radioxenon Isotopic Composition

Abstract Isotopic ratios of radioxenons sampled in the atmosphere or subsurface can be used to verify the occurrence of an underground nuclear explosion (UNE). Differences in the half-lives of radioactive xenon precursors and their decay-chain networks produce different time-dependent concentration profiles of xenon isotopes allowing isotopic ratios to be used for tracking UNE histories including estimating the time of detonation. In this study, we explore the potential effects of post-detonation cavity processes: precipitation of iodine precursors, gas seepage, and prompt venting on radioxenon isotopic evolution which influences UNE histories. Simplified analytical models and closed-form solutions yielding a potentially idealized radioactive decay/ingrowth chain in a closed and well-mixed system typically have limited application by not including the partitioning of the radionuclide inventory between a gas phase and rock melt created by the detonation and by ignoring gas transport from the cavity to host rock or ground surface. In reality, either subsurface transport or prompt release that is principally responsible for gas signatures violates the closed-system (or batch-mode) assumption. A closed-form solution representing time-dependent source-term activities is extended by considering the cavity partitioning process, slow seepage, and/or prompt release of gases from the cavity and applied to realistic systems.

Sun, Yunwei (ORCID:0000000194801439)↗

High-resolution lithospheric structure of continental China from joint inversion of surface wave and gravity data

The lithospheric structure of continental China has been previously determined by seismic travel time tomography, surface wave tomography, and joint inversion of body wave and surface wave data. However, due to the inherent limitations of seismic data, the lithospheric structure of continental China is still not well resolved in the shallow part and in some regions where the station coverage is relatively sparse. In this study, we aim at improving the lithospheric structure by joint inversion of seismic surface wave data and satellite gravity data to take advantage of the uniform distribution and complementary strength of the gravity data. Here, the empirical relationship between velocity and density is used as a bridge for joint inversion of surface wave and gravity data. The joint inversion shear-wave velocity Vs (density) model, named as USTClitho1.0g, can fit both surface wave and gravity data well. This high-resolution Vs model can better fit the active airgun source seismic arrival times and better delineate some features in continental China, such as the velocity contrast across the north–south gravity lineament (NSGL), the lithosphere thinning in eastern China, the crustal footprint of the Hainan mantle plume, the likely magma chamber beneath volcanos in northeast China, the middle-lower crust low velocity layer beneath the Tibetan plateau, and the tearing of subducted Indian mantle lithosphere. Our joint inversion Vs model can provide a reference model for geosciences in continental China and surrounding areas.

58 GEOSCIENCES↗

Secure Command Line Solution for Token-based Authentication

The WLCG is modernizing its security infrastructure, replacing X.509 client authentication with the newer industry standard of JSON Web Tokens (JWTs) obtained through the Open ID Connect (OIDC) protocol. There is a wide variety of software available using the standards, but most of it is for Web browser-based applications and doesn’t adapt well to the command line-based software used heavily in High Throughput Computing (HTC). OIDC command line client software did exist, but it did not meet our requirements for security and convenience. This paper discusses a command line solution we have made based on the popular existing secrets management software from Hashicorp called vault. We made a package called htvault-config to easily configure a vault service and another called htgettoken to be the vault client. In addition, we have integrated use of the tools into the HTCondor workload management system, although they also work well independent of HTCondor. All of the software is open source, under active development, and ready for use.

Dykstra, Dave↗

Alternatives to NIST Cf-252 Iirradiations for Transfer Calibration of S-32 Neutron Monitors

Gas-flow proportional counting systems are used by the Radiation Metrology Laboratory (RML) at Sandia National Laboratories for reactor fluence monitoring with the 32 S(n,p) 32 P reaction. Calibration of these systems has traditionally been accomplished by fluence-transfer irradiations at the NIST 252 Cf facility. Such calibrations have become increasingly difficult as the NIST 252 Cf source decayed to unusable levels. To minimize the risk to the testing programs from an inability to properly calibrate these systems, the RML has developed two alternative calibration techniques: 1) development and implementation of certified 32 P sources for activity calibrations and subsequent calculation of neutron fluence, and 2) direct counting of non-certified reactor-irradiated sulfur pellets by liquid scintillation counting to determine 32 P activity for the subsequent calibration of gas-flow proportional counters. Preliminary comparisons show that the several calibration methods are capable of overall uncertainties within about 5 percent.

Vehar, David W.↗

Tuning nonequilibrium phase transitions with inertia

In striking contrast to equilibrium systems, inertia can profoundly alter the structure of active systems. Here, we demonstrate that driven systems can exhibit effective equilibrium-like states with increasing particle inertia, despite rigorously violating the fluctuation–dissipation theorem. Increasing inertia progressively eliminates motility-induced phase separation and restores equilibrium crystallization for active Brownian spheres. This effect appears to be general for a wide class of active systems, including those driven by deterministic time-dependent external fields, whose nonequilibrium patterns ultimately disappear with increasing inertia. The path to this effective equilibrium limit can be complex, with finite inertia sometimes acting to accentuate nonequilibrium transitions. The restoration of near equilibrium statistics can be understood through the conversion of active momentum sources to passive-like stresses. Unlike truly equilibrium systems, the effective temperature is now density dependent, the only remnant of the nonequilibrium dynamics. Further, this density-dependent temperature can in principle introduce departures from equilibrium expectations, particularly in response to strong gradients. Our results provide additional insight into the effective temperature ansatz while revealing a mechanism to tune nonequilibrium phase transitions.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Coupled 2D MHD and runaway electron fluid simulations of SPARC disruptions

Runaway electrons (REs) generated during disruption events in tokamaks can carry mega-Ampère level currents, potentially causing damage to plasma-facing components. Understanding RE evolution during disruption events is important for evaluating strategies to mitigate RE damage. Using two-dimensional toroidally symmetric magnetohydrodynamic (MHD) simulations in M3D-C1, which incorporates a fluid RE model evolved self-consistently with the bulk MHD fluid, we examine the seeding and avalanching of REs during disruptions in the SPARC tokamak – a compact, high-field, high-current device designed to achieve a fusion gain Q > 2 in deuterium–tritium plasmas. The M3D-C1 simulations of unmitigated disruptions demonstrate RE plateau formation and peaking of the final current density, which agree well with the results of lower-fidelity reduced RE fluid models. This work provides the first systematic comparison and benchmarking of different primary sources, including activated tritium beta decay and Compton scattering, in SPARC disruption simulations with self-consistent MHD and RE coupling.

Compton scattering↗

Comparison and calibration of dose delivered by 137 Cs and x-ray irradiators in mice

Objective. The Office of Radiological Security, U.S. Department of Energy's National Nuclear Security Administration, is implementing a radiological risk reduction program which seeks to minimize or eliminate the use of high activity radiological sources, including 137 Cs, by replacing them with non-radioisotopic technologies, such as x-ray irradiators. The main goal of this paper is to evaluate the equivalence of the dose delivered by gamma- and x-ray irradiators in mice using experimental measurements and Monte Carlo simulations. We also propose a novel biophantom as an in situ dose calibration method. Approach. We irradiated mouse carcasses and 3D-printed mouse biophantoms in a 137 Cs irradiator (Mark I-68) and an x-ray irradiator (X-Rad320) at three voltages (160 kVp, 225 kVp and 320 kVp) and measured the delivered radiation dose. A Geant4-based Monte Carlo model was developed and validated to provide a comprehensive picture of gamma- and x-ray irradiation in mice. Main Results. Our Monte Carlo model predicts a uniform dose delivered in soft-tissue for all the explored irradiation programs and in agreement with the absolute dose measurements. Our Monte Carlo model shows an energy-dependent difference between dose in bone and in soft tissue that decreases as photon energy increases. Dose rate depends on irradiator and photon energy. We observed a deviation of the measured dose from the target value of up to –9% for the Mark I-68, and up to 35% for the X-Rad320. The dose measured in the 3D-printed phantoms are equivalent to that in the carcasses within 6% uncertainty. Significance. Our results suggest that 320 kVp irradiation is a good candidate to substitute 137 Cs irradiation barring a few caveats. There is a significant difference between measured and targeted doses for x-ray irradiation that suggests a strong need for in situ calibration, which can be achieved with 3D-printed mouse biophantoms. A dose correction is necessary for bone doses, which can be provided by a Monte Carlo calculation. Lastly, the biological implications of the differences in dose rates and dose per photon for the different irradiation methods should be carefully assessed for each small-animal irradiation experiment.

62 RADIOLOGY AND NUCLEAR MEDICINE↗

Distribution Substation Planning Toolkit (dsp-toolkit) v1.0

The Distribution Substation Planning Toolkit (DSP Toolkit) is a software suite designed to streamline the planning and optimization of distribution substations. This toolkit offers a comprehensive set of tools and APIs for data curation, short-term electric load forecasting, and weather-sensitive load adjustment, making it an essential resource for utility companies, engineers, and researchers. Features • Data Preprocessing and Curation: Efficiently manage and preprocess large datasets to ensure high-quality input for analysis. • Short-Term Load Forecasting: Utilize data-driven models to predict short-term electric loads accurately. • Weather-Sensitive Modeling: Automatically adjust load forecasts based on weather data to predict future peak demands more precisely. Uses The DSP Toolkit is ideal for planning and optimizing distribution substations, providing a user-friendly interface and comprehensive documentation. It is suitable for both novice and experienced users, facilitating efficient and accurate planning processes. Advantages • Efficiency: Automates complex planning tasks, reducing manual effort and minimizing errors. • Scalability: Handles large datasets and complex models, making it suitable for large-scale projects. • Community and Support: Open-source with active community contributions, ensuring continuous improvement and support. • Extensibility: Easily extendable with custom modules and plugins, allowing users to tailor the toolkit to their specific needs. The DSP Toolkit stands out by offering a robust, flexible, and user-friendly solution for distribution substation planning. Public Abstract

Li, Han [Lawrence Berkeley National Laboratory (LB↗

Report of the Sixth Regional Review Meeting of the Radiological Security Partnership.

The Sri Lanka Atomic Energy Regulatory Commission (AERC) and the United States Department of Energy (U.S. DOE) co-hosted the 6th Regional Review Meeting on Radiological Security involving representatives from over 20 countries, the International Atomic Energy Agency (IAEA), the International Criminal Police Organization (INTERPOL), and the World Institute for Nuclear Security. The purpose of the event was to discuss the implementation of, and plans for, high-activity radioactive source security (RSS). The U.S. DOE’s National Nuclear Security Administration (NNSA) Office of Radiological Security (ORS) fully sponsored this review meeting. Participants were welcomed to Colombo, Sri Lanka, and the meeting was formally opened by Nirmali Karunarathna of the Sri Lanka Atomic Energy Regulator Council who emphasized the strong partnerships among the participants. The opening Ceremony and Lamp Lighting included dignitaries from the sponsoring countries. Robert Hilton, Deputy Chief of Mission at the U.S. Embassy in Colombo, and Kristin Hirsch of the ORS gave other opening remarks that highlighted the social benefit from radiological sources in medicine, industry, and agriculture, while stressing the importance of addressing the risks associated with the malicious use of radiological sources. Emphasis was placed on the importance of partnerships among all the participants to help ensure the success of securing radiological materials throughout the world and the opportunity to share information and experiences. AERC was acknowledged with special thanks for hosting this event. A participant list is included as Attachment A, and the meeting agenda is provided as Attachment B. All presentations were made available to participants. The following sections summarize the meeting’s presentations, discussions, issues, suggestions, and recommendations.

61 RADIATION PROTECTION AND DOSIMETRY↗

Oak Ridge National Laboratory Shutdown Dose Rate Code Suite

The Oak Ridge National Laboratory (ORNL) shutdown dose rate (SDDR) code suite calculates gamma dose rates at a location of interest due to activation of materials. The code suite is based on the rigorous two-step (R2S) method that involves two radiation transport calculations: (1) neutron radiation transport to determine neutron fluxes in the material for which activation calculations will be performed and (2) gamma radiation transport to determine dose rates at a location of interest, due to material activation. The ORNL SDDR code suite is used to determine an importance function that characterizes the neutron’s importance to the final SDDR when the Monte Carlo radiation transport method is used. This report demonstrates how the ORNL SDDR code suite is implemented through the following codes: Monte Carlo N-Particle (MCNP) code Version 5-1.60, Oak Ridge Isotope Generator (ORIGEN), MSX suite of utilities, Neutron Activation Gamma Source Sampler (NAGSS), and Automated Variance Reduction Generator (ADVANTG). For this demonstration, the International Thermonuclear Experimental Reactor (ITER) SDDR benchmark problem is used and the dose rate result is compared to previously published work.

61 RADIATION PROTECTION AND DOSIMETRY↗

United States Nuclear Data Program Annual Report for FY2021

The US Nuclear Data Program (USNDP) Annual Report for Fiscal Year 2021 (FY21) summarizes the work of USNDP for the period of October 1, 2020 through September 30, 2021, with respect to the Work Plan for FY21 that was prepared in 2019. The Work Plan and Final Report for USNDP are prepared for the DOE Office of Science, Office of Nuclear Physics. The support for the nuclear data activity from sources outside the nuclear data program is described in the staffing table and in Appendix A. This leverage amounts to about 3.24 FTE scientific, to be compared with 25.095 FTEs at USNDP units funded by the DOE Office of Science, Office of Nuclear Physics. Since it is often difficult to separate accomplishments funded by various sources, some of the work reported in the present report was accomplished with nuclear data program support leveraged by other funding.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗