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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 235 records · Page 13
All sourcesNASA NTRSDOE OSTI
NASA NTRS1992

Comparison of methodologies for describing relaxation in nonequilibrium gaseous systems

The heat transfer process in hypervelocity vehicles is dominated by nonequilibrium gas dynamics. One model used in computational fluid dynamics (CFD) codes to predict hypervelocity heat transfer is the 'two-temperature' model. An analysis has been made to test the validity of the two-temperature model for predicting another nonequilibrium phenomenon, sound absorption and deviation of signal speed in a high temperature gas. It is found that the two temperature model's prediction capabilities degenerate with increasing temperature. These results are felt to have significance concerning the two-temperature's ability to predict heat transfer in hypervelocity flows.

Schreiber, Willard C.↗
NASA NTRS1994

Improvements to TOVS retrievals over sea ice and applications to estimating Arctic energy fluxes

Modeling studies suggest that polar regions play a major role in modulating the Earth's climate and that they may be more sensitive than lower latitudes to climate change. Until recently, however, data from meteorological stations poleward of 70 degs have been sparse, and consequently, our understanding of air-sea-ice interaction processes is relatively poor. Satellite-borne sensors now offer a promising opportunity to observe polar regions and ultimately to improve parameterizations of energy transfer processes in climate models. This study focuses on the application of the TIROS-N operational vertical sounder (TOVS) to sea-ice-covered regions in the nonmelt season. TOVS radiances are processed with the improved initialization inversion ('3I') algorithm, providng estimates of layer-average temperature and moisture, cloud conditions, and surface characteristics at a horizontal resolution of approximately 100 km x 100 km. Although TOVS has flown continuously on polar-orbiting satellites since 1978, its potential has not been realized in high latitudes because the quality of retrievals is often significantly lower over sea ice and snow than over the surfaces. The recent availability of three Arctic data sets has provided an opportunity to validate TOVS retrievals: the first from the Coordinated Eastern Arctic Experiment (CEAREX) in winter 1988/1989, the second from the LeadEx field program in spring 1992, and the third from Russian drifting ice stations. Comparisons with these data reveal deficiencies in TOVS retrievals over sea ice during the cold season; e.g., ice surface temperature is often 5 to 15 K too warm, microwave emissivity is approximately 15% too low at large view angles, clear/cloudy scenes are sometimes misidentified, and low-level inversions are often not captured. In this study, methods to reduce these errors are investigated. Improvements to the ice surface temperature retrieval have reduced rms errors from approximately 7 K to 3 K; correction of microwaves (50 GHz) brightness temperatures for view angle dependence now allows the surface type (open water versus sea ice) to be determined; modifications to the clear/cloud tests have improved cloud detection over sea ice, especially where it is inhomogeneous; and improved surface temperature estimates have resulted in more successful diagnoses of low-level stratification. Applications of improved retrievals to studies of the Arctic energy budget are encouraging. Preliminary calculations of air-ice stress vectors, 10-m wind speed, and horizontal advection of heat and moisture are presented.

Francis, Jennifer A.↗
DOE OSTI2021

Thermal conductivity modeling of monodispersed microspheres using discrete element method

Particle beds are widely used in various systems and processes, such as particle heat exchangers, granular flow reactors, and additive manufacturing. Accurate modeling of the thermal conductivity of particle beds and understanding of their heat transfer mechanisms are important. However, previous models were based on simple cubic packing of particles, which could not accurately represent the actual heat transfer processes under certain conditions. Here, we examine the effect of the packing structure on the thermal conductivity of particle beds. We use monodispersed silica microspheres with average particle sizes ranging from 23 to 330 μm as a model material. We employ a transient hot-wire technique to measure the thermal conductivity of the particle beds with packing density of 43%–57% within a temperature range of room temperature to 500 °C and under N2 gaseous pressures of 20–760 Torr. We then use a discrete element method (DEM) to obtain the realistic packing structure of the particles, which is then fed into a finite-element model (FEM) to calculate the thermal conductivity, with the consideration of solid conduction, gas conduction, and radiation heat transfer. Our results show that the thermal conductivity model based on the more realistic random packing structure derived from the DEM shows better agreement with the experimental data compared to that based on the simple cubic-packing structure. The combined DEM and FEM methodology can serve as a useful tool to predict the effective thermal conductivity of particle beds and to quantify different heat transfer mechanisms under various conditions.

14 SOLAR ENERGY↗
NASA NTRS1971

High density electronic packaging module with improved cooling assembly

Cold plate increases heat transfer within high density electronic module. Tapered pins improve heat transfer process by providing larger surface pressure with increased planar area. Cooling technique increases thermal contact where planar area is limited, interface pressure increases the heat transfer coefficient.

Martin, J. H.↗
DOE OSTI2020

Efficient Hot Electron Transfer from Small Au Nanoparticles

Many important chemical transformations enabled by plasmonic hot carrier photocatalysis have been reported, although their efficiencies are often too low for practical applications. Here, we examine how the efficiency of plasmon-induced hot electron transfer depends on the Au particle size in Au-tipped CdS nanorods. We show that with decreasing Au size, the plasmon width increases due to enhanced surface damping contributions. The excitation of Au nanoparticles leads to an instrument response time-limited ultrafast hot electron transfer process to CdS ($\ll$140 fs). The quantum efficiency of this process increases from ~1% to ~18% as the particle size decreases from 5.5 ± 1.1 to 1.6 ± 0.5 nm due to both enhanced hot electron generation and transfer efficiencies in small Au particles. Our finding suggests that decreasing plasmonic particle size is an effective approach for improving plasmon-induced hot carrier transfer efficiency and provides important insight for the rational improvement of plasmonic hot carrier-based devices.

77 NANOSCIENCE AND NANOTECHNOLOGY↗
NASA NTRS1984

Measurements of energy distribution in microwave plasmas of N2 and He and comparisons with results for H2

An electrothermal propulsion concept utilizing a microwave plasma system as the mechanism to convert electromagnetic energy into translational energy of the flowing gas is being investigated. Specifically, this study compares the energy transfer characteristics of three different gases, H2, N2, and He, to gain some insight as to the dominant energy transfer processes present in a microwave plasma. A calorimetric experimental system has been designed and built enclosing the microwave plasma system to accurately determine the net energy transferred to the flowing gas. Results are obtained for N2 and He discharges and compared with previously reported experimental results for H2.

Chapman, R.↗
NASA NTRS1991

Precision metering of microliter volumes of biological fluids in micro-gravity

Concepts were demonstrated and investigated for transferring accurately known and reproducible microliter volumes of biological fluids from sample container onto dry chemistry slides in microgravity environment. Specific liquid transfer tip designs were compared. Information was obtained for design of a liquid sample handling system to enable clinical chemical analysis in microgravity. Disposable pipet tips and pipet devices that were designed to transfer microliter volumes of biological fluid from a (test tube) sample container in 1-G environment were used during microgravity periods of parabolic trajectories of the KC-135 aircraft. The transfer process was recorded using charge coupled device camera and video cassette equipment. Metering behavior of water, a synthetic aqueous protein solution, and anticoagulated human blood was compared. Transfer of these liquids to 2 substrate materials representative of rapidly wettable and slowly wettable dry chemistry slide surface was compared.

Columbus, Richard L.↗
NASA NTRS2003

Microphysics of Waves and Instabilities in the Solar Wind and their Macro Manifestations in the Corona and Interplanetary Space

Investigations of the physical processes responsible for the acceleration of the solar wind were pursued with the development of two new solar wind codes: a hybrid code and a 2-D MHD code. Hybrid simulations were performed to investigate the interaction between ions and parallel propagating low frequency ion cyclotron waves in a homogeneous plasma. In a low-beta plasma such as the solar wind plasma in the inner corona, the proton thermal speed is much smaller than the Alfven speed. Vlasov linear theory predicts that protons are not in resonance with low frequency ion cyclotron waves. However, non-linear effect makes it possible that these waves can strongly heat and accelerate protons. This study has important implications for study of the corona and the solar wind. Low frequency ion cyclotron waves or Alfven waves are commonly observed in the solar wind. Until now, it is believed that these waves are not able to heat the solar wind plasma unless some cascading processes transfer the energy of these waves to high frequency part. However, this study shows that these waves may directly heat and accelerate protons non-linearly. This process may play an important role in the coronal heating and the solar wind acceleration, at least in some parameter space.

Habbal, Shadia R.↗
NASA NTRS1988

The Flight Telerobotic Servicer Program

The Flight Telerobotic Servicer (FTS) Program, initiated by NASA to provide new capabilities for task accomplishment in the space environment, is described. The FTS Program includes the following: a series of test flights, a ground-based supporting infrastructure, and a technology utilization and transfer process. The FTS Program strives to reduce Space Station dependence on crew EVA, improve crew safety, enhance crew utilization, provide remote servicing capabilities for platforms, and accelerate technology transfer from research to U.S. industry.

Townsend, John W., Jr.↗
NASA NTRS1972

Radiative transfer effects behind reflected shock waves

Theoretical studies are reported which were largely centered on the nonequilibrium coupling of collisional, ionization, and radiative transfer processes behind reflected shock waves in nitrogen. Experimental studies included broad-band photomultiplier radiative intensity measurements, luminosity photographs of the reflected shock wave front, end-wall heat transfer measurements, and reflected shock velocity time-history measurements. The results of these activities are summarized, and comparisons between the theoretical and experimental results are discussed.

Nerem, R. M.↗
DOE OSTI2020

Energy Migration Processes in Re(I) MLCT Complexes Featuring a Chromophoric Ancillary Ligand

We present herein the synthesis, structural characterization, electronic structure calculations, and ultrafast and supra-nanosecond photophysical properties of a series of five Re(I) bichromophores exhibiting metal to ligand charge transfer (MLCT) excited states based on the general formula fac -[Re(N ^ N)(CO) 3 (PNI-py)]PF 6, where PNI-py is 4-piperidinyl-1,8-naphthalimidepyridine and N ^ N is a diimine ligand ( Re1 – 5 ), along with their corresponding model chromophores where 4-ethylpyridine was substituted for PNI-py ( Mod1 – 5 ). The diimine ligands used include 1,10-phenanthroline (phen, 1 ), 2,9-dimethyl-4,7-diphenyl-1,10-phenanthroline (bcp, 2 ), 4,4'-di- tert -butyl-2,2'-bipyridine (dtbb, 3 ), 4,4'-diethyl ester-2,2'-bipyridine (deeb, 4 ), and 2,2'-biquinoline (biq, 5 ). In these metal–organic bichromophores, structural modification of the diimine ligand resulted in substantial changes to the observed energy transfer efficiencies between the two chromophores as a result of the variation in 3 MLCT excited-state energies. The photophysical properties and energetic pathways of the model chromophores were explored in parallel to accurately track the changes that arose from introduction of the organic chromophore pendant on the ancillary ligand. All relevant photophysical and energy transfer processes were probed and characterized using time-resolved photoluminescence spectroscopy, ultrafast and nanosecond transient absorption spectroscopy, and time-dependent density functional theory calculations. Of the five bichromophores in this study, four ( Re1 – 4 ) exhibited a thermal equilibrium between the 3 PNI-py and the 3 MLCT excited state, drastically extending the lifetimes of the parent model chromophores.

14 SOLAR ENERGY↗
NASA NTRSDate not supplied

Single and Multi-Node Modeling of Direct, Submerged, and Self-Pressurization of A Cryogenic Propellant Tank Using Nodal Tools

The pressurization of cryogenic propellant tanks will always be an important process so long as cryogenic liquids are being considered as fuel sources or used for other in-space applications. Pressure control of the tank ullage is necessary for managing propellant flowrates to an engine or a receiver tank, and modeling of the process is used to predict the pressurant requirements and the amount of propellant boiloff. Direct ullage pressurization is the more traditional approach to tank pressurization, as the physics are straight-forward, and ample test (flight) data have been collected and analyzed over the past several decades. Submerged injection pressurization is an alternate method for tank pressurization and has been shown to reduce pressurant requirements, subcool the propellant, and reduce the risk of ullage collapse. Additionally, the pressurant gas entering the ullage is usually much colder when using the submerged pressurization approach, resulting in reduced propellant boiloff. These benefits are at the expense of vaporizing a small percentage of the propellent. Both tank pressurization methods are viable options for current and future space missions, and it is important to have the capability of analyzing the tank ullage conditions for both approaches. Our previous work has demonstrated the development of a Generalized Fluid System Simulation Program (GFSSP) model, which contains a thermodynamic equilibrium heat and mass transfer subroutine capable of effectively analyzing both direct and submerged pressurization systems [1-2]. This subroutine has most recently been enhanced to include the non-equilibrium effect of pressurant dissolution into the propellant. To date the ullage has always been represented as a single node, and although the simulated single-node temperatures have good comparison with the volume-averaged ullage temperatures computed from test data, the physics of the thermal stratification in the ullage were never captured, and adjustment factors in the model were required. The purpose of this paper is to introduce the development of a multi-node ullage model using GFSSP and to discuss the improvements of the simulated ullage temperature distribution and its resulting effects on ullage heat transfer processes. Test data from the Cryogenic Propellant Storage and Transfer Engineering Developmental Unit (CPST EDU) was used for model validation. For additional comparison, a Thermal Desktop (TD) model was also developed to analyze the CPST EDU direct ullage pressurization tests using both a single node and multi-node approach. The model includes the direct pressurant line, vent line, fill/drain line, and a TD FloCAD Compartment. The TD FloCAD Compartment is employed to represent the liquid and ullage as single volumes inside the tank, to include a liquid/vapor interface, and to generate network level objects such as lumps (analogous to nodes in GFSSP), paths, and ties between the fluid and thermal elements. An established heat load on the model tank was leveraged from a pre-existing higher-fidelity model correlated to CPST EDU test data.

pressurization↗
DOE OSTI2024

First-principles investigation of near-field energy transfer between localized quantum emitters in solids

We present a predictive and general approach to investigate near-field energy transfer processes between localized defects in semiconductors, which couples first-principles electronic structure calculations and a nonrelativistic quantum electrodynamics description of photons in the weak-coupling regime. The approach is general and can be readily applied to investigate broad classes of defects in solids. We apply our approach to investigate an exemplar point defect in an oxide, the F center in MgO, and we show that the energy transfer from a magnetic source, e.g., a rare-earth impurity, to the vacancy can lead to spin nonconserving long-lived excitations that are dominant processes in the near field, at distances relevant to the design of photonic devices and ultrahigh dense memories. We also define a descriptor for coherent energy transfer to predict geometrical configurations of emitters to enable long-lived excitations, that are useful to design optical memories in semiconductor and insulators. Published by the American Physical Society 2024

Chattaraj, Swarnabha (ORCID:0000000329333581)↗
DOE OSTI2020

Efficient Intermolecular Energy Exchange and Soft-ionization of Water at Nanoplatelet Interfaces

X-ray, energetic photon and electron irradiation can ionize and electronically excite target atoms and molecules. These excitations undergo complicated relaxation and energy transfer processes that ultimately determine the manifold of system responses to the deposited excess energy. In weakly bound gas- and solution-phase samples, intermolecular Coulomb decay (ICD) and electron-transfer mediated decay (ETMD) can occur with neighboring atoms or molecules leading to efficient transfer of the excess energy to the surroundings. In ionic solids such as metal-oxides, intra- and inter-atomic Auger decay produces localized final states that lead to lattice damage and typically removal of cations from the substrate. The relative importance of Auger stimulated damage (ASD) versus ICD and ETMD in micro-solvated nanoparticle interfaces is not known. Though ASD is generally expected, essentially no lattice damage and very efficient ICD and ETMD resulting from ionization and electronic excitation of micro-solvated boehmite (AlOOH) nanoplatelets has been observed. Efficient energy transfer and soft ionization of interfacial molecules is likely a general phenomenon at gas-oxyhydroxide nanoparticle interfaces where the density of states of the ionized chemisorbed species significantly overlap the core hole states of the solid.

Jones, Brant M.↗
NASA NTRS1984

A review of NASA combustor and turbine heat transfer research

The thermal design of the combustor and turbine of a gas turbine engine poses a number of difficult heat transfer problems. The importance of improved prediction techniques becomes more critical in anticipation of future generations of gas turbine engines which will operate at higher cycle pressure and temperatures. Research which addresses many of the complex heat transfer processes holds promise for yielding significant improvements in prediction of metal temperatures. Such research involves several kinds of program including: (1) basic experiments which delineate the fundamental flow and heat transfer phenomena that occur in the hot sections of the gas turbine but at low enthalpy conditions; (2) analytical modeling of these flow and heat transfer phenomena which results from the physical insights gained in experimental research; and (3) verification of advanced prediction techniques in facilities which operate near the real engine thermodynamic conditions. In this paper, key elements of the NASA program which involves turbine and combustor heat transfer research will be described and discussed.

Rudey, R. A.↗
NASA NTRS1982

Electronic levels and charge distribution near the interface of nickel

The energy levels in clusters of nickel atoms were investigated by means of a series of cluster calculations using both the multiple scattering and computational techniques (designated SSO) which avoids the muffin-tin approximation. The point group symmetry of the cluster has significant effect on the energy of levels nominally not occupied. This influences the electron transfer process during chemisorption. The SSO technique permits the approaching atom or molecule plus a small number of nickel atoms to be treated as a cluster. Specifically, molecular levels become more negative in the O atom, as well as in a CO molecule, as the metal atoms are approached. Thus, electron transfer from the nickel and bond formation is facilitated. This result is of importance in understanding chemisorption and catalytic processes.

Waber, J. T.↗
DOE OSTI2020

Timescales and Processes of Methane Hydrate Formation and Breakdown, With Application to Geologic Systems

Abstract Gas hydrate is an ice‐like form of water and low molecular weight gas stable at temperatures of roughly −10°C to 25°C and pressures of ~3 to 30 MPa in geologic systems. Natural gas hydrates sequester an estimated one sixth of Earth's methane and are found primarily in deepwater marine sediments on continental margins, but also in permafrost areas and under continental ice sheets. When gas hydrate is removed from its stability field, its breakdown has implications for the global carbon cycle, ocean chemistry, marine geohazards, and interactions between the geosphere and the ocean‐atmosphere system. Gas hydrate breakdown can also be artificially driven as a component of studies assessing the resource potential of these deposits. Furthermore, geologic processes and perturbations to the ocean‐atmosphere system (e.g., warming temperatures) can cause not only dissociation, but also more widespread dissolution of hydrate or even formation of new hydrate in reservoirs. Linkages between gas hydrate and disparate aspects of Earth's near‐surface physical, chemical, and biological systems render an assessment of the rates and processes affecting the persistence of gas hydrate an appropriate Centennial Grand Challenge. This paper reviews the thermodynamic controls on methane hydrate stability and then describes the relative importance of kinetic, mass transfer, and heat transfer processes in the formation and breakdown (dissociation and dissolution) of gas hydrate. Results from numerical modeling, laboratory, and some field studies are used to summarize the rates of hydrate formation and breakdown, followed by an extensive treatment of hydrate dynamics in marine and cryospheric gas hydrate systems.

58 GEOSCIENCES↗