Engineering Papers⌕ Search

SEARCH · Engineering Papers

Results for “Synthesis and processing”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 235 records · Page 13

Specification, Design, and Analysis of Advanced HUMS Architectures

During the two-year project period, we have worked on several aspects of domain-specific architectures for HUMS. In particular, we looked at using scenario-based approach for the design and designed a language for describing such architectures. The language is now being used in all aspects of our HUMS design. In particular, we have made contributions in the following areas. 1) We have employed scenarios in the development of HUMS in three main areas. They are: (a) To improve reusability by using scenarios as a library indexing tool and as a domain analysis tool; (b) To improve maintainability by recording design rationales from two perspectives - problem domain and solution domain; (c) To evaluate the software architecture. 2) We have defined a new architectural language called HADL or HUMS Architectural Definition Language. It is a customized version of xArch/xADL. It is based on XML and, hence, is easily portable from domain to domain, application to application, and machine to machine. Specifications written in HADL can be easily read and parsed using the currently available XML parsers. Thus, there is no need to develop a plethora of software to support HADL. 3) We have developed an automated design process that involves two main techniques: (a) Selection of solutions from a large space of designs; (b) Synthesis of designs. However, the automation process is not an absolute Artificial Intelligence (AI) approach though it uses a knowledge-based system that epitomizes a specific HUMS domain. The process uses a database of solutions as an aid to solve the problems rather than creating a new design in the literal sense. Since searching is adopted as the main technique, the challenges involved are: (a) To minimize the effort in searching the database where a very large number of possibilities exist; (b) To develop representations that could conveniently allow us to depict design knowledge evolved over many years; (c) To capture the required information that aid the automation process.

Mukkamala, Ravi↗

The Effect of Gravity on the Combustion Synthesis of Porous Biomaterials

Production of highly porous composite materials by traditional materials processing is limited by difficult processing techniques. This work investigates the use of self propagating high temperature (combustion) synthesis (SHS) to create porous tricalcium phosphate (Ca3(PO4)2), TiB-Ti, and NiTi in low and microgravity. Combustion synthesis provides the ability to use set processing parameters to engineer the required porous structure suitable for bone repair or replacement. The processing parameters include green density, particle size, gasifying agents, composition, and gravity. The advantage of the TiB-Ti system is the high level of porosity achieved together with a modulus that can be controlled by both composition (TiB-Ti) and porosity. At the same time, NiTi exhibits shape memory properties. SHS of biomaterials allows the engineering of required porosity coupled with resorbtion properties and specific mechanical properties into the composite materials to allow for a better biomaterial.

Castillo, M.↗

UH cosmic rays and solar system material - The elements just beyond iron

The nucleosynthesis of cosmic-ray elements between the iron peak and the rare-earth region is examined, and compositional changes introduced by propagation in interstellar space are calculated. Theories on the origin of elements heavier than iron are reviewed, a supernova model of explosive nucleosynthesis is adopted for the ultraheavy (UH) cosmic rays, and computational results for different source distributions are compared with experimental data. It is shown that both the cosmic-ray data and the nucleosynthesis calculations are not yet of sufficient precision to pinpoint the processes occurring in cosmic-ray source regions, that the available data do provide boundary conditions for cosmic-ray nucleosynthesis, and that these limits may apply to the origin of elements in the solar system. Specifically, it is concluded that solar-system abundances appear to be consistent with a superposition of the massive-star core-helium-burning s-process plus explosive-carbon-burning synthesis for the elements from Cu to As and are explained adequately by the s- and r-processes for heavier elements.

Wefel, J. P.↗

Antenna pattern control using impedence surfaces

During this research period, September 16, 1990 to March 15, 1991, a design method for selecting a low-loss impedance material coating for a horn antenna pattern control has been developed. This method and the stepped waveguide technique can be employed to accurately compute the electromagnetic wave phenomenon inside the transition region of the horn antenna, with or without the impedance surfaces, from the feed to the radiating aperture. For moment method solutions of the electric and magnetic current distributions on the radiating aperture and the outer surface of the horn antenna, triangular surface-patch modes are introduced to replace the sinusoidal surface-patch modes as expansion and testing functions to provide a more physical expansion of the current distributions. In the synthesis problem, a numerical optimization process is formulated to minimize the error function between the desired waveguide modes and the modes provided by the horn transition with impedance surfaces. Since the modes generated by the horn transition with impedance surface are computed by analytical techniques, the computational error involved in the synthesis of the antenna pattern is minimum. Therefore, the instability problem can be avoided. A preliminary implementation of the techniques has demonstrated that the developed theory of the horn antenna pattern control using the impedance surfaces is realizable.

Balanis, Constantine A.↗

Mechanical Alloying for Making Thermoelectric Compounds

An economical room-temperature mechanical alloying process has been shown to be an effective means of making a homogeneous powder that can be hot-pressed to synthesize a thermoelectric material having reproducible chemical composition. The synthesis of a given material consists of the room temperature thermomechanical-alloying process followed b y a hot-pressing process. Relative to synthesis of nominally the same material by a traditional process that includes hot melting, this s ynthesis is simpler and yields a material having superior thermoelect ric properties.

Huang, Chen-Kuo↗

Discrete-Time Demodulator Architectures for Free-Space Broadband Optical Pulse-Position Modulation

The objective of this work is to develop discrete-time demodulator architectures for broadband optical pulse-position modulation (PPM) that are capable of processing Nyquist or near-Nyquist data rates. These architectures are motivated by the numerous advantages of realizing communications demodulators in digital very large scale integrated (VLSI) circuits. The architectures are developed within a framework that encompasses a large body of work in optical communications, synchronization, and multirate discrete-time signal processing and are constrained by the limitations of the state of the art in digital hardware. This work attempts to create a bridge between theoretical communication algorithms and analysis for deep-space optical PPM and modern digital VLSI. The primary focus of this work is on the synthesis of discrete-time processing architectures for accomplishing the most fundamental functions required in PPM demodulators, post-detection filtering, synchronization, and decision processing. The architectures derived are capable of closely approximating the theoretical performance of the continuous-time algorithms from which they are derived. The work concludes with an outline of the development path that leads to hardware.

Gray, A. A.↗

AGB stars as a source of short-lived radioactive nuclei in the solar nebula

The purpose is to estimate the possible contribution of some short-lived nuclei to the early solar nebula from asymptotic giant branch (AGB) sources. Low mass (1 to 3 solar mass) AGB stars appear to provide a site for synthesis of the main s process component for solar system material with an exponential distribution of neutron irradiations varies as exp(-tau/tau(sub 0)) (where tau is the time integrated neutron flux with a mean neutron exposure tau(sub 0)) for solar abundances with tau(sub 0) = 0.28 mb(sup -1). Previous workers estimated the synthesis of key short-lived nuclei which might be produced in AGB stars. While these calculations exhibit the basic characteristics of nuclei production by neutron exposure, there is need for a self-consistent calculation that follows AGB evolution and takes into account the net production from a star and dilution with the cloud medium. Many of the general approaches and the conclusions arrived at were presented earlier by Cameron. The production of nuclei for a star of 1.5 solar mass during the thermal pulsing of the AGB phase was evaluated. Calculations were done for a series of thermal pulses with tau(sub 0) = 0.12 and 0.28 mb(sup -1). These pulses involve s nucleosynthesis in the burning shell at the base of the He zone followed by the ignition of the H burning shell at the top of the He zone. After about 10-15 cycles the abundances of the various nuclei in the He zone become constant. Computations of the abundances of all nuclei in the He zone were made following Gallino. The mass of the solar nebula was considered to consist of some initial material of approximately solar composition plus some contributions from AGB stars. The ratios of the masses required from the AGB He burning zone to the ISM necessary to produce the observed value of Pd-107/Pd-108 in the early solar system were calculated and this dilution factor was applied to all other relevant nuclei.

Wasserburg, G. J.↗

Polymer precursors for ceramic matrix composites

The synthesis and characterization of a polycyclohexasilane is reported. Because of its cyclic structure, it is anticipated that this polymer might serve as a precursor to SIC having a high char yield with little rearrangement to form small, volatile cyclic silanes, and, as such, would be of interest as a precursor to SiC composite matrices and fibers, or as a binder in ceramic processing. Several approaches to the synthesis of a bifunctional cyclic monomer were attempted; the most successful of these was metal coupling of PhMeSiCl2 and Me2SiCl2. The procedure gives six-membered ring compounds with all degrees of phenyl substitution, from none to hexaphenyl. The compounds with from 0-2 groups were isolated and characterized. The fraction with degree of phenyl substitution equal to 2, a mixture of cis and trans 1,2-; 1,3-; and 1,4 isomers, was isolated in 32 percent yield. Pure 1,4 diphenyldecamethylcyclohexasilane was isolated from the mixed diphenyl compounds and characterized. Diphenyldecamethylcyclohexasilanes were dephenylated to dichlorodecamethylcyclohexasilanes by treating with H2SO4.NH4Cl in benzene. The latter were purified and polymerized by reacting with sodium in toluene. The polymers were characterized by HPGPC, elemental analysis, proton NMR, and IR. Thermogravimetric analyses were carried out on the polymers. As the yield of residual SiC was low, polymers were heat treated to increase the residual char yield. As high as 51.52 percent residual char yield was obtained in one case.

Litt, M. H.↗

A Web Centric Architecture for Deploying Multi-Disciplinary Engineering Design Processes

There are continuous needs for engineering organizations to improve their design process. Current state of the art techniques use computational simulations to predict design performance, and optimize it through advanced design methods. These tools have been used mostly by individual engineers. This paper presents an architecture for achieving results at an organization level beyond individual level. The next set of gains in process improvement will come from improving the effective use of computers and software within a whole organization, not just for an individual. The architecture takes advantage of state of the art capabilities to produce a Web based system to carry engineering design into the future. To illustrate deployment of the architecture, a case study for implementing advanced multidisciplinary design optimization processes such as Bi-Level Integrated System Synthesis is discussed. Another example for rolling-out a design process for Design for Six Sigma is also described. Each example explains how an organization can effectively infuse engineering practice with new design methods and retain the knowledge over time.

Woyak, Scott↗

Synthesis algorithm of VLSI multipliers for ASIC

Multipliers are critical sub-blocks in ASIC design, especially for digital signal processing and communications applications. A flexible multiplier synthesis tool is developed which is capable of generating multiplier blocks for word size in the range of 4 to 256 bits. A comparison of existing multiplier algorithms is made in terms of speed, silicon area, and suitability for automated synthesis and verification of its VLSI implementation. The algorithm divides the range of supported word sizes into sub-ranges and provides each sub-range with a specific multiplier architecture for optimal speed and area. The algorithm of the synthesis tool and the multiplier architectures are presented. Circuit implementation and the automated synthesis methodology are discussed.

Chua, O. H.↗

Materials for Heated Head Automated Thermoplastic Tape Placement

NASA Langley Research Center (LaRC) is currently pursuing multiple paths to develop out of autoclave (OOA) polymeric composite materials and processes. Polymeric composite materials development includes the synthesis of new and/or modified thermosetting and thermoplastic matrix resins designed for specific OOA processes. OOA processes currently under investigation include vacuum bag only (VBO) prepreg/composite fabrication, resin transfer molding (RTM), vacuum assisted resin transfer molding (VARTM) and heated head automated thermoplastic tape placement (HHATP). This paper will discuss the NASA Langley HHATP facility and capabilities and recent work on characterizing thermoplastic tape quality and requirements for quality part production. Samples of three distinct versions of APC-2 (AS4/PEEK) thermoplastic dry tape were obtained from two materials vendors, TENCATE, Inc. and CYTEC Engineered Materials** (standard grade and an experimental batch). Random specimens were taken from each of these samples and subjected to photo-microscopy and surface profilometry. The CYTEC standard grade of APC-2 tape had the most voids and splits and the highest surface roughness and/or waviness. Since the APC-2 tape is composed of a thermoplastic matrix, it offers the flexibility of reprocessing to improve quality, and thereby improve final quality of HHATP laminates. Discussions will also include potential research areas and future work that is required to advance the state of the art in the HHATP process for composite fabrication.

Jensen, Brian J.↗

Advantages of barium peroxide in the powder synthesis of perovskite superconductors

This paper compares reaction chemistry, material processing, and material characteristics for the solid state reaction using BaCO3 or BaO2 in the synthesis of perovskite superconductors. Results are presented for weight loss and X-ray diffraction, sample morphology and homogeneity as monitored by SEM and EDS, and the superconductivity critical temperature and ac susceptibility. Greater mass density, increased sample homogeneity, lower resistance, and improved reproducibility for material are found when BaO32 is used.

Hepp, A. F.↗

Processable Polyimides Containing ATBN Elastomers

Void-free moldings obtained without serious sacrifice in other properties. New synthesis produces high-temperture linear aromatic polyimide processed in imide form to yield tough, void-free components without serious sacrifice in other properties. Linear aromatic condensation polyimides are materials of prime choice for use as adhesives, composite matrix resins, films, coatings, and/or moldings where durability at temperatures as high as 200 to 300oC needed. Finding increasing use in aircraft and spacecraft applications.

St. Clair, Anne K.↗

Collaborative Research: Atlantic Ocean Tropical/Subtropical Processes from Seasonal to Decadal Time Scales: Model/Data, Model/Model Comparison and Model/Data Synthesis Through Assimilation

The effort of this first year of research has been focused on the assimilation of TOPEX/Poseidon altimetric data into a primitive equation model of the Atlantic tropical/subtropical circulation. A reduced-rank, stationary Kalman filter has been constructed to assimilate the altimetric sea surface height anomaly (SHA) into the model. The goal is to assess how the inter-hemispheric transports between the Atlantic subtropics and tropics are affected by the assimilation and how the subsurface thermocline structure , and its variability ,is dynamically constrained by the SHA. The model is a reduced-gravity primitive equation GCM of the upper Atlantic Ocean between 30 S and 30 N. The assimilation scheme is an approximation to the extended Kalman filter in which the error covariances of the state estimates are calculated only in a reduced- dimension subspace. The subspace is defined by the leading empirical orthogonal functions calculated from an unconstrained model calculation. Both an identical twin experiment using simulated SHA observations and assimilation of the real TOPEX data were performed. Results from the twin experiments demonstrate the ability of the method to constrain the ocean circulation and the subsurface temperature structure. The impact on the subsurface temperature structure of TOPEX assimilation was assessed using data from expandable bathythermographs. This showed a substantial improvement in the estimated temperature variability only within 13 degrees in latitude around the equator. The impact of TOPEX SHA assimilation on zonally integrated meridional transport across different latitudes was also estimated. Again within 13 degrees from the equator both the mean amplitude and interannual variability of the surface and subsurface transports were significantly enhanced, while the transports were insensitive to the assimilation in the subtropics.

Malannotte-Rizzoli, Paola↗

A Recording-Based Method for Auralization of Rotorcraft Flyover Noise

Rotorcraft noise is an active field of study as the sound produced by these vehicles is often found to be annoying. A means to auralize rotorcraft flyover noise is sought to help understand the factors leading to annoyance. Previous work by the authors focused on auralization of rotorcraft fly-in noise, in which a simplification was made that enabled the source noise synthesis to be based on a single emission angle. Here, the goal is to auralize a complete flyover event, so the source noise synthesis must be capable of traversing a range of emission angles. The synthesis uses a source noise definition process that yields periodic and aperiodic (modulation) components at a set of discrete emission angles. In this work, only the periodic components are used for the source noise synthesis for the flyover; the inclusion of modulation components is the subject of ongoing research. Propagation of the synthesized source noise to a ground observer is performed using the NASA Auralization Framework. The method is demonstrated using ground recordings from a flight test of the AS350 helicopter for the source noise definition.

Pera, Nicholas M.↗

M-ary Laguerre detection.

In a communication system using optical devices, the receiver is modeled as a counter of electrons which are emitted from a photodetector when a modulated optical wave is incident on it. The synthesis of the optimal receiver processing and its resulting performance depend upon the statistics associated with this counting. In an M-ary system, the transmitter selects one of a set of M intensities for the optical process. Questions of error probability are investigated.

Mohanty, N. C.↗

A new readily processable polyimide

As part of an effort to develop tough solvent resistance thermoplastics for potential use as structural resins on aerospace vehicles, a new processable polyimide was evaluated. The synthesis involved the reaction of a new diamine, 1,3-bis 2-(3-aminophenoxy)ethyl ether, with 3,3',4,4'-benzophenonetetracarboxylic dianhydride to form the polyamic acid and subsequent conversion of it to the polyimide. Various physical properties such as thermal stability, solvent resistance, glass transition temperature, crystalline melt temperature, melt viscosity and mechanical properties such as fracture toughness, adhesive, film and composite properties are reported. Of particular interest is the extremely high titanium to titanium tensile shear strength obtained for this polyimide.

Harris, F. W.↗

A new readily processable polyimide

As part of an effort to develop tough solvent resistance thermoplastics for potential use as structural resins on aerospace vehicles, a new processable polyimide was evaluated. The synthesis involved the reaction of a new diamine, 1,3-bis 2-(3-aminophenoxy)ethyl ether, with 3,3',4,4'-benzophenonetetracarboxylic dianhydride to form the polyamic acid and subsequent conversion of it to the polyimide. Various physical properties such as thermal stability, solvent resistance, glass transition temperature, crystalline melt temperature, melt viscosity and mechanical properties such as fracture toughness, adhesive, film and composite properties are reported. Of particular interest is the extremely high titanium to titanium tensile shear strength obtained for this polyimide.

Harris, F. W.↗