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At least 235 records · Page 13

Elemental profiling and genomewide association studies reveal genomic variants modulating ionomic composition in Populus trichocarpa leaves

Samples were collected from a population of 1,089 black cottonwood genotypes (P. trichocarpa) assembled from native stands to encompass the central portion of the natural range of the species, stretching from 38.8° to 54.3° N Q13 latitude from California, USA, to British Columbia, Canada. Establishment of the common garden, growth conditions, and site maintenance have been described by Muchero et al (2015). In this study, leaf samples for ionomic profiling were collected from 4-year-old trees, during the growing season, in July 2012, from a field located in Clatskanie, Oregon, USA (46°6′11″N 123°12′13″W). The field site was located in a protected alluvial floodplain containing a uniform Wauna-Locoda silt loam soil area characterized by an acidic pH, in Columbia County, Oregon. A subset of 584 out of the 1,089 P. trichocarpa genotypes were represented in this sampling. These genotypes were randomly selected to represent the geographical distribution of the population. A single fully mature (LPI 7-9) leaf on the south side of the tree exposed to full sunlight conditions was removed from the tree within a 6-hour window centering on solar noon and immediately frozen under dry ice before processing. Leaf samples of 584 P. trichocarpa genotypes were finely ground to 40 mm particle size using a mortar and pestle, and ionomic composition was analyzed using ICP-MS. In total, 20 elements were profiled, including aluminum (Al27), arsenic (As75), boron (B11), cadmium (Cd111), calcium (Ca43), cobalt (Co), copper (Cu), iron (Fe57), magnesium (Mg25), manganese (Mn55), molybdenum (Mo), nickel (Ni60), phosphorus (P31), potassium (K39), rubidium (Rb85), selenium (Se82), sodium (Na23), strontium (Sr88), sulfur (S34), and zinc (Zn66), following a protocol established by Ziegler et al. (2013). For each sample, 75mg of powder was digested overnight in 2.5 mL HNO3 containing 20 parts per billion (ppb) indium as an internal standard, following the protocol described in Ziegler et al. (2013). Following a dilution, concentration of the 20 elements was measured using an Elan 6000 DRC-e mass spectrometer (Perkin-Elmer SCIEX) connected to a PFA microflow nebulizer (Elemental Scientific) and Apex HF desolvator (Elemental Scientific). One measurement per sample per genotype was done. For subsequent analyses, the quantifications were converted to total element concentration.

CBI ionomics, GWAS, plasma-mass spectrometry, neut↗

Trace element studies of rocks and soils from Oceanus Procellarum and Mare Tranquillitatis

Neutron activation data on Zn, Ga, Ge, Cd, In and Ir are reported for six rocks and two soils from the Apollo 12 mission. Comparison of these and similar data for Apollo 11 samples indicates extralunar components in the 12070 and 10084 soils of about 1.0 and 1.1% expressed in terms of an assumed composition which is the same as the water-free portion of C1 chondrites. A relationship between the integrated flux of extralunar material and the increase in concentration of such material in the fines of the lunar regolith is derived. Apollo 12 rocks have concentrations of Zn, Ge, Cd, In and possibly Ir which are lower by factors of 60 or more, relative to terrestrial basalts. A mechanism is proposed for the late accretion of volatile-rich materials, including comets, in which a primitive terrestrial atmosphere is invoked to explain the significantly higher concentrations of such substances on the earth.

Baedecker, P. A.↗

A lunar differentiation model in light of new chemical data on Luna 20 and Apollo 16 soils.

Fines from a Luna 20 soil sample and from three Apollo 16 deep drill core samples have been analyzed for major-minor element abundances by a combined, semi-micro atomic absorption spectrophotometric and colorimetric method. Both the major element and large ion lithophile trace element abundances in these soils, the first from interior highland sites, are greatly influenced by the very high normative plagioclase content, being distinctly richer in Al and Ca, and poorer in K, P, Cr, Mn, Fe, and Ti, than most bulk soil samples from previous lunar missions. The relatively large compositional variations in the Apollo 16 core can be ascribed almost entirely to decreasing plagioclase with increasing depth. The chemical composition of the Luna 20 soil indicates less plagioclase and less KREEP than in the Apollo 16 soils. A lunar differentiation model is presented in which is made the suggestion that KREEP is the result of a second fusion event in a lunar crust consisting of early feldspathic cumulates and primary aluminous 'liquid.'

Nava, D. F.↗

Ancient meteoritic component in Apollo 17 boulders

The reported investigation is concerned with the resolution of a number of questions related to the ancient meteoritic component in Apollo 17 boulders. Numerical taxonomic methods have been adopted to objectively group the components. Only the nonvolatile siderophile elements have been used for the classification. Efforts were made to obtain data on the metal composition of breccias analyzed for trace elements, to determine if metal homogeneity was reflected in siderophile ratios. Thirty-one samples were analyzed of which twenty-eight have significant siderophile contents. It is concluded that highland breccias are largely the product of large basin-forming impacts. Highland soils are then produced by comminution of the breccias by small local impacts and micrometeorite bombardment. The long-lived component of bulk soils considered by Baedecker et al. (1974) is thought to contain a substantial micrometeorite contribution, plus assorted debris.

Higuchi, H.↗

Composition and Formation of the "Paso Robles" Class Soils at Gusev Crater

Light-toned, subsurface soil deposits have been excavated by the Mars Exploration Rover (MER) Spirit in six distinct locations along its traverse across the Columbia Hills of Gusev Crater. Samples at two of these sites have been analyzed in detail by the M ssbauer (MB) and Alpha Particle X-ray Spectrometers (APXS), providing information on iron mineralogy and elemental chemistry, respectively. These soils are referred to as "Paso Robles" class deposits.

Yen, A. S.↗

Soft Soil Impact Testing and Simulation of Aerospace Structures

In June 2007, a 38-ft/s vertical drop test of a 5-ft-diameter, 5-ft-long composite fuselage section that was retrofitted with a novel composite honeycomb Deployable Energy Absorber (DEA) was conducted onto unpacked sand. This test was one of a series of tests to evaluate the multi-terrain capabilities of the DEA and to generate test data for model validation. During the test, the DEA crushed approximately 6-in. and left craters in the sand of depths ranging from 7.5- to 9-in. A finite element model of the fuselage section with DEA was developed for execution in LS-DYNA, a commercial nonlinear explicit transient dynamic code. Pre-test predictions were generated in which the sand was represented initially as a crushable foam material MAT_CRUSHABLE_FOAM (Mat 63). Following the drop test, a series of hemispherical penetrometer tests were conducted to assist in soil characterization. The penetrometer weighed 20-lb and was instrumented with a tri-axial accelerometer. Drop tests were performed at 16-ft/s and crater depths were measured. The penetrometer drop tests were simulated as a means for developing a more representative soil model based on a soil and foam material definition MAT_SOIL_AND FOAM (Mat 5) in LS-DYNA. The model of the fuselage with DEA was reexecuted using the updated soil model and test-analysis correlations are presented.

Fasanella, Edwin L.↗

The Mars Environmental Compatibility Assessment (MECA) Wet Chemistry Experiment on the Mars 2001 Lander

The Mars Environmental Compatibility Assessment (MECA) is an instrument suite that will fly on the Mars Surveyor 2001 Lander Spacecraft. MECA is sponsored by the Human Exploration and Development of Space (HEDS) program and will evaluate potential hazards that the dust and soil of Mars might present to astronauts and their equipment on a future human mission to Mars. Four elements constitute the integrated MECA payload: a microscopy station, patch plates, an electrometer, and the wet chemistry experiment (WCE). The WCE is the first application of electrochemical sensors to study soil chemistry on another planetary body, in addition to being the first measurement of soil/water solution properties on Mars. The chemical composition and properties of the watersoluble materials present in the Martian soil are of considerable interest to the planetary science community because characteristic salts are formed by the water-based weathering of rocks, the action of volcanic gases, and biological activity. Thus the characterization of water-soluble soil materials on Mars can provide information on the geochemical history of the planet surface. Additional information is contained in the original extended abstract.

Grannan, S. M.↗

Geochemistry of 2-4-mm particles from Apollo 14 soil (14161) and implications regarding igneous components and soil-forming processes

The present paper describes the compositional systematics of 381 particles analyzed from 14161, which was taken near the lunar module as part of the bulk sample. Attention is given to the distribution of lithologies, based on petrographic examination and compositions determined by INAA, and to implications of the compositions of polymict particles regarding igneous precursors and soil-forming processes. It was found that the most abundant particles are the impact-melt lithologies and regolith and fragmental breccias. The mean composition of the entire suite of 2-4-mm particles differs from that of the associated less-than-1-mm fines by having higher concentrations of incompatible trace elements and Na2O, and a lower concentration of CaO. There is a subset of regolith breccia particles and agglutinates in the 2-4-mm particles that have nearly identical compositions and Is/FeO similar to those of the less-than-1-mm fines. It is suggested that these particles are constructional products formed from the local regolith rather than comminuted fragments of ancient regolith breccias.

Jolliff, B. L.↗

APXS of First Rocks Encountered by Curiosity in Gale Crater: Geochemical Diversity and Volatile Element (K and ZN) Enrichment

The Alpha Particle X-ray spectrometer (APXS) on the Curiosity rover in Gale Crater [1] is the 4th such instrument to have landed on Mars [2]. Along the rover's traverse down-section toward Glenelg (through sol 102), the APXS has examined four rocks and one soil [3]. Gale rocks are geochemically diverse and expand the range of Martian rock compositions to include high volatile and alkali contents (up to 3.0 wt% K2O) with high Fe and Mn (up to 29.2% FeO*).

Schmidt, M. E.↗

Pb loss from Apollo 17 glassy samples and Apollo 16 revisited

U-Th-Pb analyses of bulk samples of soil breccia 70019, when compared to KREEP data, indicate that different lunar samples are sometimes characterized by distinctly different initial Pb isotopic compositions. U-Th-Pb analyses on nonglassy samples and a glassy separate of soil breccia 70019, and bulk and agglutinate samples of soil 72701 showed that the glassy samples did lose considerable Pb relative to U less than 200 million years ago. These data support the contention of other investigators that vaporization of volatile elements owing to impact events significantly alters the chemistry of the lunar regolith. Metaclastic rock 60315 was reanalyzed and was found to be concordant at 3.93 billion years rather than slightly discordant, as was previously reported.

Nunes, P. D.↗

Composition and Maturity of Apollo 16 Regolith Core 60013/14

Samples from every half-centimeter dissection interval of double drive tube 60013/14 (sections 60013 and 60014) were analyzed by magnetic techniques for Fe concentration and surface maturity parameter I(sub s)/ Fe(O), and by neutron activation for concentrations of 25 lithophile and siderophile elements. Core 60013/14 is one of three regolith cores taken in a triangular array 40-50 m apart on the Cayley plains during Apollo 16 mission to the Moon. The core can be divided into three zones based both on I(sub s)/FeO and composition. Unit A (0-44 cm depth) is compositionally similar to other soils from the surface of the central region of the site and is mature throughout, although maturity decreases with depth. Unit B (44-59 cm) is submature and compositionally more feldspathic than Unit A. Regions of lowest maturity in Unit B are characterized by lower Sm/Sc ratios than any soil obtained from the Cayley plains as a result of some unidentified lithologic component with low surface maturity. The component is probably some type of mafic anorthosite that does not occur in such high abundance in any of the other returned soils. Unit C (59-62 cm) is more mature than Unit B and compositionally equivalent to an 87: 13 mixture of soil such as that from Unit A and plagioclase such as found in ferroan anorthosite. Similar soils, but containing greater abundances of anorthosite (plagioclase), are found at depth in the other two cores of the array. These units of immature to submature soil enriched to varying degrees (compared to the mature surface soil) in ferroan anorthosite consisting of approx. 99% plagioclase are the only compositionally distinct subsurface similarities among the three cores. Each of the cores contains other units that are compositionally dissimilar to any soil unit in the other two cores. These compositionally distinct units probably derive from local subsurface blocks deposited by the event(s) that formed the Cayley plains. The ferroan anorthosite with approx. 99% plagioclase, however, must represent some subsurface lithology that is significant on the scale of tens of meters. The compositional uniformity of the surface soil (0-10 cm depth) over distances of kilometers reflects the large-scale uniformity of the plains deposits; the fine- structure reflects small-scale nonuniformity and the inefficiency of the impact-mixing process at depths as shallow as even one meter.

Korotev, Randy T.↗

Lunar resource surveys from orbit

The chemical composition of lunar soil and rocks is known now for nine surface sites, by analysis of returned samples. Three classes of silicate material, mare basalt, KREEP, and highland material (sometimes called ANT) have been identified as major components. Gamma-ray and X-ray instruments have mapped the Apollo 15 and 16 ground tracks for major elements, K, and Th. It is hoped that the Lunar Polar Orbiter will carry instruments capable of producing a chemical map of the entire moon. The most exciting possibility is that ice may exist in shadowed regions near the lunar pole.

Arnold, J. R.↗

A geochemical and petrographic study of 1-2-mm fines from Apollo 17

Samples of fines less than 1-mm and 155 1-2 mm particles from several Apollo 17 sites were analyzed for Na, Sc, Cr, Mn, Fe, Co, Ni, Hf, Ta, Th, and REE. Products of comminution and construction are present in the 1-2 mm particles, and the compositions of the rock fragments clearly indicate the general chemical characteristics of their parent rock types. The likely sources of materials for the glassy particles are considered. Glasses are enriched over their parent soils in Fe, Sc, Mn, and Cr, and are relatively enriched in light REE, so that some chemical fractionation accompanies glass-forming processes. Elements were determined by instrumental neutron activation analysis.

Blanchard, D. P.↗

The source of sublimates on the Apollo 15 green and Apollo 17 orange glass samples

Elemental analyses of the thin film of micromounds which coat the surfaces of Apollo 15 green glass and Apollo 17 orange glass are reported. It is thought that Zn, Ga, Pb, Cu, Tl, S, F, and Cl condensed as a sublimate on the outside surface of these glass particles in lava fountains about 3.4 and 3.6 b.y. ago (Apollos 15 and 17, respectively). The heavy metals enriched in these samples may have been mobilized in a halide- and sulfide-rich vapor, while the source of these elements and of the glass may be a sulfide- and halide-rich pyroxenite inside the moon. The isotopic composition of lead on the surface of individual particles was determined, and the composition is considered with respect to the evolution of the source region. The lead on the surfaces is similar to lead that has been mixed into other soils and breccias at nearby sites.

Meyer, C., Jr.↗

Lunar Meteorites and Implications for Compositional Remote Sensing of the Lunar Surface

Lunar meteorites (LMs) are rocks found on Earth that were ejected from the Moon by impact of an asteroidal meteoroid. Three factors make the LMs important to remote-sensing studies: (1) Most are breccias composed of regolith or fragmental material; (2) all are rocks that resided (or breccias composed of material that resided) in the upper few meters of the Moon prior to launch and (3) most apparently come from areas distant from the Apollo sites. How Many Lunar Locations? At this writing (June 1999), there are 18 known lunar meteorite specimens. When unambiguous cases of terrestrial pairing are considered, the number of actual LMs reduces to 13. (Terrestrial pairing is when a single piece of lunar rock entered Earth's atmosphere, but multiple fragments were produced because the meteoroid broke apart on entry, upon hitting the ground or ice, or while being transported through the ice.) We have no reason to believe that LMs preferentially derive from any specific region(s) of the Moon; i.e., we believe that they are samples from random locations. However, we do not know how many different locations are represented by the LMs; mathematically, it could be as few as 1 or as many as 13. The actual maximum is < 13 because in some cases a single impact appears to have yielded more than one LM. Yamato 793169 and Asuka 881757 are considered "source-crater paired" or "launch paired" because they are compositionally and petrographically similar to each other and distinct from the others, and both have similar cosmic-ray exposure (CRE) histories. The same can be said of QUE 94281 and Y 793274. Thus the 13 meteorites probably represent a maximum of 11 locations on the Moon. The minimum number of likely source craters is debated and in flux as new data for different isotopic systems are obtained. Conservatively, considering CRE data only, a minimum of about 5 impacts is required. Compositional and petrographic data offer only probabilistic constraints. An extreme, but not unreasonable viewpoint, is that such data offer no constraint. For example, if one were to cut up the Apollo 17 landing site (which was selected for its diversity) into softball-sized pieces, some of those pieces (e.g., sample 70135) would be crystalline mare basalts like Y 793169 whereas others (e.g., sample 73131 would be feldspathic regolith breccias like MAC 88104/ 88105. However, nature is not so devious. Warren argues that LMs come from craters of only a few kilometers in diameter. If so, even though CRE data allow, for example, that ALHA 81005 and Y 791197) were launched simultaneously from the same crater, the probability is nevertheless low because the two meteorites are compositionally and mineralogically distinct. Thus, within the allowed range (5-11) for the number of locations represented by the LMs, values at the high end of the range are probably more likely. Mare Meteorites: Three LMs consist almost entirely of mare basalt. Two, Y 793169 and Asuka 881757, are unbrecciated, low-Ti, crystalline rocks that are compositionally and mineralogically similar (but not identical) to each other; they probably derive from a single lunar-mare location. The third, EET 87521/96008, is a fragmental breccia consisting predominantly of VLT mare basalt. Thus, these LMs probably represent only two lunar mare locations. The basaltic LMs have mineral and bulk compositions distinct from Apollo mare basalts. The petrography of Calcalong Creek has not been described in detail, but compositionally it is unique in that it corresponds to a mixture (breccia) of about one-half feldspathic material (i.e., the mean composition of the feldspathic lunar meteorites, below), one-fourth KREEP norite, one-fourth VLT mare basalt (like EET 87521), and 1% CI chondrite. With 4 micro g/g Th and correspondingly high concentrations of other incompatible elements, it is the only lunar meteorite that is likely to have come from within the Procellarum KREEP Terrane (PKT). Yamato 793274 and QUE 94281 are together distinct in being fragmental breccias containing subequal parts of feldspathic highland material and VLT mare basalt. Jolliff et al. estimate a mare to highland ratio of 54:46 for QUE 94281 and 62:38 for Y 793274; this difference is well within the range observed for soils collected only centimeters apart (in cores) at interface site like Apollo 15 and 17 [11]. Although the two meteorites were found on opposite sides of Antarctica, they are probably launch-paired. The strongest evidence is that the pyroclastic glass spherules that occur in both are of two compositional groups and the two groups are essentially the same in both meteorites. Yamato 791197 is nominally a feldspathic lunar meteorite (below), but among FLMs, it probably contains the highest abundance of clasts and glasses of mare derivation. As a consequence, its composition is at the high-Fe, low-Mg end of the range for FLMs and is not included in the FLM average of Table 1. Its composition is consistent with about 10% mare-derived material. Similarly, the two small (Y 82) pieces of Y 82192/82193186032 are more mafic than the large (Y 86) piece, probably as a result of about 7% mare-derived material. All Apollo missions went to areas in or near the PKT, and, consequently, all Apollo regolith samples are contaminated with Th-rich material from the PKT. At the nominally "typical" highland site, Apollo 16, about 30% of the regolith (<1-mm fines) is Th-rich ejecta from the Imbrium impact and about 6% is mare material probably derived from mare basins. Thus Apollo 16 regolith is not typical of the highlands. Among Apollo rocks, the compositions of the FLMs correspond most closely to the feldspathic granulitic breccias of Apollo 16 and 17. (Additional information is contained in original)

Korotev, R. L.↗

Rb-Sr systematics for chemically defined Apollo 14 breccias.

The Rb and Sr systematics were determined for eight lithic fragments from the coarse fines of Apollo 11, Apollo 12, and Apollo 14; for bulk soils from Luna 16, Apollo 14, and Apollo 15 and for 'whole rocks' from Apollo 14 and the Apollo 15 anorthosite 15415. The objective of the studies was to identify important lunar rock types by their major and trace element chemistry and utilize Rb and Sr systematics to obtain a chronology for events which establish or modify rock chemical composition.

Nyquist, L. E.↗

NASA’s Satellite Needs Working Group Management Office: Developing Solutions in an Agile, Open Science Environment

Every two years, the National Aeronautics and Space Administration (NASA) leads an assessment of U.S. Federal civilian agency Earth observation needs submitted through the Satellite Needs Working Group (SNWG) survey. In four survey cycles beginning in 2016, nearly 400 high-priority satellite needs have been identified, spanning Earth Science and representing a wide variety of potential applications for Earth observation data. During each assessment cycle, new data products and services (i.e., solutions) that meet the needs of multiple agencies are identified and proposed for funding. The majority of solutions being developed or currently operational are global in scope, including harmonized land surface reflectance data from Landsat and Sentinel-2; composites of cloud properties derived from MODIS, VIIRS, and five geostationary satellites; dynamic surface water extent and land surface disturbance products derived from multiple optical and radar missions; a suite of low-latency products from the ICESat-2 mission; and a soil moisture product derived from the upcoming NISAR mission. The SNWG Management Office, within the Earth Action element of NASA’s Earth Science Division, manages both the biennial SNWG survey assessment and the development of solutions starting at full capacity with the 2020 cycle. Each solution project is required to align with NASA’s open science policy, including developing source code in an open code repository, having an open-source software license, and making all data freely available via NASA’s Earthdata website. The presentation will include an overview of the SNWG process, its emphasis on open science, and highlight several operational solutions freely available to the global research and applications communities.

Katrina Virts↗

Compositional characteristics of some Apollo 14 clastic materials.

Eighty-two subsamples of Apollo 14 materials have been analyzed by instrumental neutron activation analysis techniques for as many as 25 elements. In many cases, it was necessary to develop new procedures to allow analyses of small specimens. Compositional relationships among Apollo 14 materials indicate that there are small but systematic differences between regolith from the valley terrain and that from Cone Crater ejecta. Fragments from 1-2 mm size fractions of regolith samples may be divided into compositional classes, and the 'soil breccias' among them are very similar to valley soils. Multicomponent linear mixing models have been used as interpretive tools in dealing with data on regolith fractions and subsamples from breccia 14321. These mixing models show systematic compositional variations with inferred age for Apollo 14 clastic materials.

Lindstrom, M. M.↗