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At least 235 records · Page 13

The effects of forced air flow and oxygen concentration on flammability, smoke density, and pyrolytic toxicity

The question is posed whether forced air flow should be incorporated into flammability tests as a relevant variable. A test apparatus is described which permits tests to be conducted on small test specimens in a forced flow which is (continuously) variable over flow velocities from zero to 300 feet per minute (1.52 m/s). The effects of air-flow rate and oxygen concentration on flame propagation rate, maximum smoke density, and pyrolytic product toxicity were measured for a single material and were statistically evaluated. Regression analysis was used to graph the resulting relationships. It is concluded that air velocity is an important variable for laboratory flammability testing.

Sauers, D. G.↗

Development of fire-resistant, low smoke generating, thermally stable end items for aircraft and spacecraft

Materials were developed to improve aircraft interior materials by modifying existing polymer structures, refining the process parameters, and by the use of mechanical configurations designed to overcome specific deficiencies. The optimization, selection, and fabrication of five fire resistant, low smoke emitting open cell foams are described for five different types of aircraft cabin structures. These include: resilient foams, laminate floor and wall paneling, thermal/acoustical insulation, molded shapes, and coated fabrics. All five have been produced from essentially the same polyimide precursor and have resulted in significant benefits from transfer of technology between the various tasks.

Gagliani, J.↗

Study of igniter design and applications to low smoke solid rockets

A simple analysis of igniter design is described which is sufficiently general to be applicable to any 'basket'-type housing containing one or more charges. The gas equation of state is used in conjunction with the experimentally determined propellant burning-rate law to predict the pressure-time histories in the igniter housing and the rocket motor. Typical numerical results are presented for three cases which represent three experimental conditions tested in a project on low-smoke motors where the requirements on the exhaust were sufficiently stringent to preclude condensible matter from the igniter. Pressure was measured continuously in time at two locations in the igniter housing and at the head end of the motor case. The agreement between theoretical and experimental results is felt to be encouraging considering the complexity of the problem and the many simplifications in the analysis.

Ramohalli, K.↗

Fire-and smoke-retardant polyesters and elastomers

Test results indicate that most effective fire-and smoke-retardant fillers are inorganic hydrates and carbonates that release water and/or carbon dioxide. Most effective filler tested was hydrated sodium silicate. Effectiveness is due to high water content and formation of viscous molten glass when heated. Glass tends to inhibit polymer combustion and to promote formation of char residue.

Chung, S. Y.↗

Development of lightweight, fire-retardant, low smoke, high strength, thermally stable aircraft floor paneling

Boeing's participation in a NASA funded program (FIREMEN) to develop materials for use as floor panels possessing flammability, smoke and toxicity characteristics superior to current materials is outlined. The objectives of the program are to develop an aircraft floor paneling suitable for high traffic areas, e.g., aisle or galley and to install and certify the panel in a commercial aircraft for service evaluation.

Anderson, R. A.↗

A spectroscopic study of intermediates in the condensation of refractory smokes: Matrix isolation experiments SiO

The infrared and Raman spectra of N2 matrix isolated silicon oxides are investigated. The vibrational frequencies of SiO, Si2O2, and Si3O3 were identified and assigned on the basis of normal coordinate analyses. Heating the solid to 50 K (evaporating the matrix) leaves a residue whose infrared spectrum is identical to that of a smoke condensed at ambient temperatures. Further heating of the sample to 500 K leads to significant changes in the band shapes. Investigations of the infrared spectra at several stages of the diffusion process result in the proposal of a mechanism for the transition from molecular properties to those of the residue (bulk) material, which is characterized as Si2O3.

Khanna, R. K.↗

Smoke and dust particles of meteoric origin in the mesosphere and stratosphere

A height profile of ablated mass from meteors is calculated, assuming an incoming mass of 10 to the -16th g/sq cm/s (44 metric tons per day) and the velocity distribution of Southworth and Sekanina, which has a mean of 14.5 km/s. The profile peaks at 84 km. The fluxes of micrometeorites and residual meteoroids are also calculated. The coagulation of the evaporated silicates into 'smoke' particles is then followed by means of a model adapted from a previous study of the stratospheric sulfate layer. Numerous sensitivity tests are made. Features of the results are a sharp cutoff of the particle distribution above 90 km, and a surface area close to 10 to the -9th sq cm/cu cm all the way from 30 to 85 km. Some confirmation is obtained from balloon studies of condensation nuclei, although the various measurements differ greatly. The optical scattering and extinction are shown to be undetectable. Several potential applications are suggested: nucleation of sulfate particles and noctilucent clouds, scavenging of metallic ions and atoms, and perhaps other aeronomical effects. The latter are limited to processes that can be influenced by a collision time of the order of a day.

Hunten, D. M.↗

A spectroscopic study of intermediates in the condensation of refractory smokes - Matrix isolation experiments of SiO

The infrared and Raman spectra of N2 matrix-isolated silicon oxides were investigated. The vibrational frequencies of SiO, Si2O2, and Si3O3 were identified and assigned on the basis of normal coordinate analyses. Heating the solid to approximately 50 K (evaporating the matrix) leaves a residue whose infrared spectrum is identical to that of a smoke condensed at ambient temperatures. Further heating of the sample to approximately 500 K leads to significant changes in the band shapes. Investigations of the infrared spectra at several stages of the diffusion process enable a mechanism to be proposed for the transition from molecular properties to those of the residue (bulk) material, which has been characterized as Si2O3.

Khanna, R. K.↗

Laboratory studies of the condensation and properties of amorphous silicate smokes

The results of experiments intended for defining the vapor phase condensation of refractory materials are reported, and the usefulness of applying laboratory data to astrophysical conditions is assessed. The testing apparatus used produced Mg-SiO smokes by boiling powders in an evaporator. Critical temperatures for the onset of nucleation were measured for SiO-H2 and Mg-SiO-H2 systems. Spectroscopic examination of the grains produced were determined to be similar to the spectra obtained from both carbonaceous chondrites and several stratospheric micrometeorites. The experiments demonstrated that direct nucleation of refractory silicates from the vapor phase yielded amorphous, metastable particles, resembling more circumstellar grains than a chondritic matrix. It is suggested that the formation of SiO(x) may control nucleation in oxygen-rich stars.

Nuth, J. A.↗

A smoke-wire study of low Reynolds number flow over a NASA LRN(1) - 1007 airfoil section

Smoke-filament visualization photographs are presented for two-dimensional flow over a NASA LRN(1) - 1007 airfoil section designed specifically for high-efficiency operation at low chord Reynolds numbers. Results are included for chord Reynolds numbers of 60,000, 100,000, and 220,000 and for angles of attack ranging from 0 to 16 degrees. Two kinds of laminar separation bubble are found to develop in the flow over the airfoil. The sites and characteristics of formation of these bubbles are described, and their dimensional properties are estimated. The transition-to-turbulence Reynolds numbers, surface pressure coefficient distributions, and lift coefficients deduced from the measured coefficients are compared with those obtained by other authors.

Fisher, S. S.↗

Method of cold smoke generation for vortex core tagging

Attention is given to the flow-visualization problem posed by the 'dark-core' region of the vortices formed on the upper side of a delta wing; the low particle density in the core region minimizes the density of tracing particles whose presence is essential in LDV measurements. An effort is presently undertaken using TiCl4 smoke in subsonic wind tunnel tests of a 70-deg sweep delta wing model.

Nelson, R. C.↗

Oxygen isotopic fractionation in the condensation of refractory smokes

This paper reports preliminary measurements of the oxygen isotopic fractionation that occurs during the condensation of refractory metal oxide smokes. Fractionation occurred at temperatures in excess of 500 K during and/or subsequent to reaction of SiH4, Fe(CO)5, Al(CH3)3, and O2 in a H2 carrier gas. Observed isotopic fractionation was as high as -15 per mil/amu. The magnitude of the isotopic fractionation suggests that the process is kinetically controlled since the effect is greatly in excess of that expected for equilibrium isotopic exchange.

Nelson, R.↗

Climate and smoke - An appraisal of nuclear winter

A reevaluation is presented of the 'nuclear winter' scenario of Turco et al. (1983). New pertinent data have emerged from laboratory studies, field experiments, and numerical models on the smoke-plume, mesoscale, and global scales. A full-scale nuclear exchange's probable soot injections lead, in three-dimensional climate simulations, to midsummer land temperature decreases averaging 10-20 C in northern midlatitudes, with local cooling of as much as 35 C. Anomalous circulation patterns due to solar heating of the soot could stabilize the upper atmosphere against overturning, thereby prolonging the soot's residence time in the atmosphere. Monsoon disruptions and severe ozone layer depletion are also foreseen.

Turco, R. P.↗

Tridymite and maghemite formation in an Fe-SiO smoke

Grains produced in porous Fe-SiO smoke are analyzed by means of electron microscopy to determine their crystallographical, morphological, and chemical properties. The nucleation of metal oxide condensates takes place as the vapor evolves in a condensation-flow apparatus, initially producing simple crystalline phases. Fe nucleation follows, and the subsequent heterogeneous nucleation of quenched mixed high-Fe silica grains exhibits associated Fe-depletion, eventually producing pure silica grains. The coalescence exhibited by the pure silica grains is compatible with the higher surface energy found in the pure silica phase. During coagulation the grains melt and anneal to a chemically pure mixture of alpha- and beta-tridymite, and the precipitation of amorphous silica material is observed. The settling of grains in evolving solar nebula is theorized to be related to the stickiness of this material, and maghemite is suggested to contribute to the Fe/Si fractionation in solar nebula.

Rietmeijer, F. J. M.↗

Smoke palls induced by Kuwaiti oilfield fires mapped from Space Shuttle imagery

Consideration is given to initial observations on the Kuwaiti oilfield fires and the spatial and areal extent of these smoke palls as viewed from the Space Shuttle flights during April/May 1991. It is concluded that one of the early lessons learned from Kuwaiti oilfield fires is that the presence of intelligent observers on orbit is of great value for acquiring data and confirm/deny events.

Lulla, Kamlesh P.↗

Aerosol characterization in smoke plumes from a wetlands fire

Results are presented from airborne measurements of aerosol mass loading, size distribution, and elemental composition obtained in a smoke plume from a fire at a Florida wildlife refuge. It is found that there was a high concentration of carbon-containing aerosols and salt crystals in the 0.1-0.2 micron size range; the composition and morphology of the aerosols differed with size. Aerosol mass concentrations are used in conjunction with those obtained for CO2 in order to calculate ratios of aerosol and CO2. The ratios are noted to be higher for the smoldering phase of the fire than for its flaming phase.

Woods, David C.↗

Smoke Study of Nozzle Secondary Flows in a Low-speed Turbine

Still and motion pictures were made of boundary-layer and wake secondary-flow phenomena visualized by smoke. Two annular cascades of turbine nozzles were used, both designed for constant discharge angle but differing in blade shape and suction-surface velocity distribution. Flows were similar to those obtained with pressure and angle measurements at near-sonic airspeeds. Boundary-layer cross-channel and trailing-edge radial flows caused vortices and an accumulation of low-momentum air at the hub, which may affect flow in following blade rows. Motion of a downstream rotor blade row produced pulsations in trailing-edge radial flow. The motion-picture supplement may be obtained on loan from NACA Headquarters, Washington, D.C.

Kofskey, Milton G↗

Smoke Studies of Secondary Flows in Bends, Tandem Cascades, and High-turning Configurations

Flow-visualization studies, using smoke, were made of the secondary flows in rectangular bends, tandem cascades, and high-turning configurations. The roll-up of the wall boundary layer of a rectangular bend forms a passage vortex near the suction surface similar to that previously observed for cascades. The vortex so formed then shifts out into the main stream. Because of leading-edge effects, the boundary-layer flows in bends were found to be sufficiently different from the flows in blade rows to make direct application of bend results to blade rows inadvisable. Passage vortices are shown, in the tandem-cascade study, to resist turning with the main stream through which they pass and to disturb the flow in subsequent blade rows. This disturbance may explain in part the appreciable size of the losses sometimes attributed to secondary flows in turbomachines despite the fact that the energy involvement in vortex formation is slight. Tip-flow studies of high-turning blades with relative motion between blades and end wall indicated that if the relative sizes of the passage vortex forces, the tip clearance forces, and the blade-scraping effects are properly controlled, it may be possible to improve the blade-tip loading characteristics in turbomachine.

CASCADES↗