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At least 235 records · Page 13

The dataset of in-situ measurements of chemically and radiatively important atmospheric gases from the AGAGE and affiliated stations (2022R2)

In the ALE/GAGE/AGAGE global network program, continuous high frequency gas chromatographic measurements of four biogenic/anthropogenic gases (methane, CH4; nitrous oxide, N2O; hydrogen, H2; and carbon monoxide, CO) and several anthropogenic gases that contribute to stratospheric ozone destruction and/or to the greenhouse effect have been carried out at five globally distributed sites for several years. The program, which began in 1978, is divided into three parts associated with three changes in instrumentation: the Atmospheric Lifetime Experiment (ALE), which used Hewlett Packard HP5840 gas chromatographs; the Global Atmospheric Gases Experiment (GAGE), which used HP5880 gas chromatographs; and the present Advanced GAGE (AGAGE). AGAGE uses two types of instruments: a gas chromatograph with multiple detectors (GC-MD), and a gas chromatograph with mass spectrometric analysis (GC-MS). Beginning in January 2004, an improved cryogenic preconcentration system (Medusa) replaced the absorption-desorption module in the GC-MS systems at Mace Head and Cape Grim; this provided improved capability to measure a broader range of volatile perfluorocarbons with high global warming potentials. The Medusa GC-MS systems were subsequently used at other AGAGE stations (Trinidad Head, Barbados, American Samoa, Zeppelin, Jungfraujoch, and Goan) after the initial setup at Mace Head and Cape Grim. More information may be found on the AGAGE home page: https://agage.mit.edu/instruments.Data from the AGAGE and affiliated stations (total of 9 sites) between August 1993 and December 2021 are provided in “Agage_gcmd_gcms_data_2022_11_15.tar.gz” (compressed tar file). The metadata file has information on each station and currently released species. The standard scales used in archived species are listed in "AGAGE_scale_2022_v2.pdf". Additional information such as the mission and scientific objectives of the ALE/GAGE/AGAGE program can be found on the AGAGE website (https://agage.mit.edu/about/our-mission).

54 ENVIRONMENTAL SCIENCES↗

The dataset of in-situ measurements of chemically and radiatively important atmospheric gases from the Advanced Global Atmospheric Gas Experiment (AGAGE) and affiliated stations (2023R1)

In the ALE/GAGE/AGAGE global network program, continuous high frequency gas chromatographic measurements of four biogenic/anthropogenic gases (methane, CH4; nitrous oxide, N2O; hydrogen, H2; and carbon monoxide, CO) and several anthropogenic gases that contribute to stratospheric ozone destruction and/or to the greenhouse effect have been carried out at five globally distributed sites for several years. The program, which began in 1978, is divided into three parts associated with three changes in instrumentation: the Atmospheric Lifetime Experiment (ALE), which used Hewlett Packard HP5840 gas chromatographs; the Global Atmospheric Gases Experiment (GAGE), which used HP5880 gas chromatographs; and the present Advanced GAGE (AGAGE). AGAGE uses two types of instruments: a gas chromatograph with multiple detectors (GC-MD), and a gas chromatograph with mass spectrometric analysis (GC-MS). Beginning in January 2004, an improved cryogenic preconcentration system (Medusa) replaced the absorption-desorption module in the GC-MS systems at Mace Head and Cape Grim; this provided improved capability to measure a broader range of volatile perfluorocarbons with high global warming potentials. The Medusa GC-MS systems were subsequently used at other AGAGE stations (Trinidad Head, Barbados, American Samoa, Zeppelin, Jungfraujoch, and Goan) after the initial setup at Mace Head and Cape Grim. More information may be found on the AGAGE home page: https://agage.mit.edu/instruments.Data from the AGAGE and affiliated stations (total of 10 sites) between August 1993 and June 2022 are provided in “Agage_gcmd_gcms_data_2023_07_24.tar.gz” (compressed tar file). The metadata file has information on each station and currently released species. The standard scales used in archived species are listed in "AGAGE_scale_2023_v1.pdf". Additional information can be found on the AGAGE website (https://agage.mit.edu).

54 ENVIRONMENTAL SCIENCES↗

The dataset of in-situ measurements of chemically and radiatively important atmospheric gases from the Advanced Global Atmospheric Gas Experiment (AGAGE) and affiliated stations (2023R2)

In the ALE/GAGE/AGAGE global network program, continuous high frequency gas chromatographic measurements of four biogenic/anthropogenic gases (methane, CH4; nitrous oxide, N2O; hydrogen, H2; and carbon monoxide, CO) and several anthropogenic gases that contribute to stratospheric ozone destruction and/or to the greenhouse effect have been carried out at five globally distributed sites for several years. The program, which began in 1978, is divided into three parts associated with three changes in instrumentation: the Atmospheric Lifetime Experiment (ALE), which used Hewlett Packard HP5840 gas chromatographs; the Global Atmospheric Gases Experiment (GAGE), which used HP5880 gas chromatographs; and the present Advanced GAGE (AGAGE). AGAGE uses two types of instruments: a gas chromatograph with multiple detectors (GC-MD), and a gas chromatograph with mass spectrometric analysis (GC-MS). Beginning in January 2004, an improved cryogenic preconcentration system (Medusa) replaced the absorption-desorption module in the GC-MS systems at Mace Head and Cape Grim; this provided improved capability to measure a broader range of volatile perfluorocarbons with high global warming potentials. The Medusa GC-MS systems were subsequently used at other AGAGE stations (Trinidad Head, Barbados, American Samoa, Zeppelin, Jungfraujoch, and Goan) after the initial setup at Mace Head and Cape Grim. More information may be found on the AGAGE home page: https://agage.mit.edu/instruments.Data from the AGAGE and affiliated stations (total of 10 sites) between August 1993 and December 2022 are provided in “Agage_gcmd_gcms_data_2023_11_15.tar.gz” (compressed tar file). The metadata file has information on each station and currently released species. The standard scales used in archived species are listed in "AGAGE_scale_2023_v2.pdf". Additional information can be found on the AGAGE website (https://agage.mit.edu).

54 ENVIRONMENTAL SCIENCES↗

The dataset of in-situ measurements of chemically and radiatively important atmospheric gases from the Advanced Global Atmospheric Gas Experiment (AGAGE) and affiliated stations (2024R1)

In the ALE/GAGE/AGAGE global network program, continuous high frequency gas chromatographic measurements of four biogenic/anthropogenic gases (methane, CH4; nitrous oxide, N2O; hydrogen, H2; and carbon monoxide, CO) and several anthropogenic gases that contribute to stratospheric ozone destruction and/or to the greenhouse effect have been carried out at five globally distributed sites for several years. The program, which began in 1978, is divided into three parts associated with three changes in instrumentation: the Atmospheric Lifetime Experiment (ALE), which used Hewlett Packard HP5840 gas chromatographs; the Global Atmospheric Gases Experiment (GAGE), which used HP5880 gas chromatographs; and the present Advanced GAGE (AGAGE). AGAGE uses two types of instruments: a gas chromatograph with multiple detectors (GC-MD), and a gas chromatograph with mass spectrometric analysis (GC-MS). Beginning in January 2004, an improved cryogenic preconcentration system (Medusa) replaced the absorption-desorption module in the GC-MS systems at Mace Head and Cape Grim; this provided improved capability to measure a broader range of volatile perfluorocarbons with high global warming potentials. The Medusa GC-MS systems were subsequently used at other AGAGE stations (Trinidad Head, Barbados, American Samoa, Zeppelin, Jungfraujoch, and Goan) after the initial setup at Mace Head and Cape Grim. More information may be found on the AGAGE home page: https://agage.mit.edu/instruments.Data from the AGAGE and affiliated stations (total of 10 sites) between August 1993 and June 2023 are provided in “Agage_gcmd_gcms_data_2024_07_11.tar.gz” (compressed tar file). The metadata file has information on each station and currently released species. The standard scales used in archived species are listed in "AGAGE_scale_2024_v1.pdf". Additional information can be found on the AGAGE website (https://agage.mit.edu).Update: Dec. 4, 20241. The Cape Grim H2_PDD data are updated in this release ((H2_PDD values in previous release are wrong due to coding error). All other data in this release are the same as previous version ("Agage_gcmd_gcms.data.2024_07_11.tar.gz")2. The latest data are saved in "Agage_gcmd_gcms.data.2024_12_04.tar.gz"

54 ENVIRONMENTAL SCIENCES↗

AmeriFlux US-xKZ NEON Konza Prairie Biological Station (KONZ)

This is the AmeriFlux version of the carbon flux data for the site US-xKZ NEON Konza Prairie Biological Station (KONZ). Site Description - Konza Prairie Biological Station (KPBS) was established to provide a "natural laboratory" to conduct ecological research and is located on a 3,487 hectare native tallgrass prairie preserve. KPBS is a field research station dedicated to conservation, education and long-term ecological research. Over 1,580 scientific papers have been published by scientists conducting studies at KPBS. The study of ecological patterns and processes in native tallgrass prairie ecosystems is the primary subject of research.

Network), NEON (National Ecological Observatory↗

AmeriFlux US-xML NEON Mountain Lake Biological Station (MLBS)

This is the AmeriFlux version of the carbon flux data for the site US-xML NEON Mountain Lake Biological Station (MLBS). Site Description - Mountain Lake Biological Station (MLBS) is a remote, but accessible research station and is a unit of the College of Arts & Sciences at University of Virginia. It sits at 1160 meters on the top of Salt Pond Mountain in the southern Appalachian mountains in southwestern Virginia. It consists of 259 hectares of forested reserve.

Network), NEON (National Ecological Observatory↗

AmeriFlux FLUXNET-1F US-KFS Kansas Field Station

This is the AmeriFlux Management Project (AMP) created FLUXNET-1F version of the carbon flux data for the site US-KFS Kansas Field Station. This is the FLUXNET version of the carbon flux data for the site US-KFS Kansas Field Station produced by applying the standard ONEFlux (1F) software. Site Description - The study is an abandoned grassland at the Kansas Field Station and Ecological Reserves. The site is located within the tallgrass prairie-deciduous forest ecotonal area. The site was subjected to intensive agriculture from the 1940s through the late 1960s. In the mid-1970s, the site was planted with the cool-season grass Bromus inermis and used as a hay meadow until 1987. Then, mowing and burning approximately every five years maintained it as a grassland until 2007, when the eddy flux tower was installed.

Brunsell, Nathaniel↗

AmeriFlux FLUXNET-1F US-xAE NEON Klemme Range Research Station (OAES)

This is the AmeriFlux Management Project (AMP) created FLUXNET-1F version of the carbon flux data for the site US-xAE NEON Klemme Range Research Station (OAES). This is the FLUXNET version of the carbon flux data for the site US-xAE NEON Klemme Range Research Station (OAES) produced by applying the standard ONEFlux (1F) software. Site Description - The 1,560-acre Klemme Range Research Station is a grassland site managed for livestock grazing and pasture, located in the middle of the Rolling Red Plains Resource Area. The Rolling Red Plains extends from south of the Red River to north of the Oklahoma/Kansas border consisting of approximately 9.4 million acres, which occupies a significant portion of Western Oklahoma excluding the Oklahoma Panhandle.

Network), NEON (National Ecological Observatory↗

AmeriFlux FLUXNET-1F US-xKA NEON Konza Prairie Biological Station - Relocatable (KONA)

This is the AmeriFlux Management Project (AMP) created FLUXNET-1F version of the carbon flux data for the site US-xKA NEON Konza Prairie Biological Station - Relocatable (KONA). This is the FLUXNET version of the carbon flux data for the site US-xKA NEON Konza Prairie Biological Station - Relocatable (KONA) produced by applying the standard ONEFlux (1F) software. Site Description - Konza Prairie Biological Station (KPBS) was established to provide a "natural laboratory" to conduct ecological research and is located on a 3,487 hectare native tallgrass prairie preserve.

Network), NEON (National Ecological Observatory↗

AmeriFlux FLUXNET-1F US-xUK NEON The University of Kansas Field Station (UKFS)

This is the AmeriFlux Management Project (AMP) created FLUXNET-1F version of the carbon flux data for the site US-xUK NEON The University of Kansas Field Station (UKFS). This is the FLUXNET version of the carbon flux data for the site US-xUK NEON The University of Kansas Field Station (UKFS) produced by applying the standard ONEFlux (1F) software. Site Description - Along an eastern deciduous forest and tallgrass prairie transition zone just north of Lawrence, Kansas, this 6 km2 terrestrial field site is located at the University of Kansas Field Station. A 116' tall flux tower rises out of a mixed hardwood forest dominated by white ash trees. Field obdservations of plants, animals, soils and microbes are collected around the tower and in the nearby tallgrass prairie.

Network), NEON (National Ecological Observatory↗

AmeriFlux US-SHC Sagehen Creek Field Station

This is the AmeriFlux version of the carbon flux data for the site US-SHC Sagehen Creek Field Station. Site Description - This tower is located at the Sagehen Creek Field Station of UC Berkeley. The 30m tower near the station has been used for meteorological measurements since at least 2006 and EC flux measurements were started in late June 2017. The area is dominated by coniferous forest with patches of grassland in between.

Wolf, Sebastian [ETH Zurich]↗

AmeriFlux US-BFS Robert J. Bernard Biological Field Station

This is the AmeriFlux version of the carbon flux data for the site US-BFS Robert J. Bernard Biological Field Station. Site Description - The Bernard Field Station (BFS), an 86-acre academic resource of the Claremont University Consortium, is situated within the campus of The Claremont Colleges in Claremont, CA. Its principal habitats comprise coastal sage scrub, Riversidian alluvial fan scrub, live oak forest, and grassland. The eddy covariance tower is located in the 'neck' of the field station, home to a protected area of Coastal Sage Scrub, dominated by Artemisia californica. BFS is within walking distance of Harvey Mudd College, serving as an invaluable outdoor laboratory resource for the students. With extensive flora and fauna, including over 170 species of birds, 27 species of mammals, and more than 700 species of insects, it embodies a significant ecological haven in the region that is otherwise Southern California suburbs.

Kavassalis, Sarah [Harvey Mudd College]↗

AmeriFlux FLUXNET-1F PR-xLA NEON Lajas Experimental Station (LAJA)

This is the AmeriFlux Management Project (AMP) created FLUXNET-1F version of the carbon flux data for the site PR-xLA NEON Lajas Experimental Station (LAJA). This is the FLUXNET version of the carbon flux data for the site PR-xLA NEON Lajas Experimental Station (LAJA) produced by applying the standard ONEFlux (1F) software. Site Description - The NEON Lajas Experimental Station (LAJA) site is located on the southwest corner of the main island of Puerto Rico in a experimental range. This is a grassland site that is periodically grazed by cattle.

Network), NEON (National Ecological Observatory [N↗

AmeriFlux FLUXNET-1F US-RC3 WSU Lind Dryland Research Station

This is the AmeriFlux Management Project (AMP) created FLUXNET-1F version of the carbon flux data for the site US-RC3 WSU Lind Dryland Research Station. This is the FLUXNET version of the carbon flux data for the site US-RC3 WSU Lind Dryland Research Station produced by applying the standard ONEFlux (1F) software. Site Description - RC3 operated from 2011-2016 at the Washington State University Lind Dryland Experimental Station, as part of a cluster of 5 towers (RC1 to RC5) operated for the Regional Approaches to Climate Change (REACCH) USDA-supported research project. Lind is in the low precipitation region of the Columbia Plateau dryland cropping region. The area is characterized as a stable crop-fallow agroecological zone, with crops typically grown every second year to allow soil water to accumulate during intervening fallow years. Winter wheat was grown August 2012-August 2013, and August 2014-July 2015. The growing seasons of 2012 and 2014 were fallow years. Soils at Lind are predominantly silt loam texture Mollisols in the Shano and Ritzville series. Site topography is flat.

Chi, Jinshu [The Hong Kong University of Science a↗

Hydrogen Station Compression, Storage, and Dispensing Technical Status and Costs

The Independent Review Panel found that for a high-pressure tube-trailer delivery scenario, an 850-kg/d dispensing station resulted in the lowest cost of dispensed hydrogen based on the delivery technologies most likely to be available and thus represented the best approach toward achieving the U.S. Department of Energy’s 2020 dispensed hydrogen cost target for centrally produced hydrogen. The costs reviewed in this report include only those costs contributing to the selling price of hydrogen by the forecourt CSD portion of the hydrogen station and do not include the costs of production or delivery to the station.

08 HYDROGEN↗

Design and Demonstration of a Material-Plasma Exposure Target Station for Neutron Irradiated Samples

Fusion energy is the most promising energy source for the future, and one of the most important problems to be solved progressing to a commercial fusion reactor is the identification of plasma-facing materials compatible with the extreme conditions in the fusion reactor environment. The development of plasma–material interaction (PMI) science and the technology of plasma-facing components are key elements in the development of the next step fusion device in the United States, the so-called Fusion Nuclear Science Facility (FNSF). All of these PMI issues and the uncertain impact of the 14-MeV neutron irradiation have been identified in numerous expert panel reports to the fusion community. The 2007 Greenwald report classifies reactor plasma-facing materials (PFCs) and materials as the only Tier 1 issues, requiring a “. . . major extrapolation from the current state of knowledge, need for qualitative improvements and substantial development for both the short and long term.” The Greenwald report goes on to list 19 gaps in understanding and performance related to the plasma–material interface for the technology facilities needed for DEMO-oriented R&D and DEMO itself. Of the 15 major gaps, six (G7, G9, G10, G12, G13) can possibly be addressed with ORNL’s proposal of an advanced Material Plasma Exposure eXperiment. Establishing this mid-scale plasma materials test facility at ORNL is a key element in ORNL’s strategy to secure a leadership role for decades of fusion R&D. That is to say, our end goal is to bring the “signature facility” FNSF home to ORNL. This project is related to the pre-conceptual design of an innovative target station for a future Material–Plasma Exposure eXperiment (MPEX). The target station will be designed to expose candidate fusion reactor plasma-facing materials and components (PFMs and PFCs) to conditions anticipated in fusion reactors, where PFCs will be exposed to dense high-temperature hydrogen plasmas providing steady-state heat fluxes of 5–20 MW/m 2 and ion fluxes up to 10 24 m -2 s -1 . Since PFCs will have to withstand neutron irradiation displacement damage up to 50 dpa, the target station design must accommodate radioactive specimens (materials to be irradiated in HFIR or at SNS) to enable investigations of the impact of neutron damage on materials. Therefore, the system will have to be able to install and extract irradiated specimens using equipment and methods to avoid sample modification, control contamination, and minimize worker dose. Included in the design considerations will be an assessment of all the steps between neutron irradiation and post-exposure materials examination/characterization, as well as an evaluation of the facility hazard categorization. In particular, the factors associated with the acquisition of radioactive specimens and their preparation, transportation, experimental configuration at the plasma-specimen interface, post-plasma-exposure sample handling, and specimen preparation will be evaluated. Neutronics calculations to determine the dose rates of the samples were carried out for a large number of potential plasma-facing materials.

42 ENGINEERING↗

Filtration testing for enhanced performance of Radionuclide Monitoring Stations for Nuclear Treaty Verification

A study of aerosol filtration was conducted to improve U.S. Radionuclide Monitoring Station (RMS) performance for Nuclear Treaty Verification. The primary objectives of this study were to improve system operability and maintainability, reduce power consumption and operational cost, and reduce baseline radionuclide sensitivity. To meet these goals, Sandia National Laboratories (SNL) studied the performance of alternate filter materials and aerosol collection technologies that could be engineered into U.S. Radionuclide Monitoring Stations. Laboratory-scale filtration experiments were conducted with Filter Material 1, FM1 (current filter), Filter Material 2, FM2, and Filter Material 3, FM3. All three materials employ electrostatically charged filter fibers to enhance nanoparticle collection. FM2 and FM3 both had higher air permeability with respect to FM1 which is advantageous for high volume collection and power savings. Particle pre-charging, a well-established industrial technique used in electrostatic precipitators, was tested to see if electrostatically charging particles prior to filtration could enhance filter performance. We found that particle-pre-charging did enhance aerosol collection efficiencies for materials which would not have otherwise satisfied RMS performance requirements. Laboratory-scale testing indicated it may be possible to reduce the baseline radionuclide sensitivity to approximately 60% of its current value by increasing the volume of air sampled in 24 hours to 2.5 times the current air volume. Improvements to geolocation may also be possible with shorter air samples (e.g., 12 hours). A new methodology was developed at SNL to assess filter performance using established RMS certification procedures. We coined these tests “mid-scale” since they bridged the gap between laboratory-scale and full-scale RMS testing. Four filter specimens were drawn from the exact same atmospheric aerosol. Gamma spectroscopy was used to assess radiological backgrounds due to radon progeny and other naturally occurring radionuclides. Direct comparisons between the four filters allowed SNL to quantify the relative change in baseline sensitivity by altering air flow rate, filter material, and particle-pre charging. Mid-scale results agreed with laboratory-scale results: alterations to RMS configuration (filter, flow, and particle charge) may result in baseline sensitivities approximately 55-60% of their current values. Finally, an assessment of scalability was performed to determine if technical approaches used in laboratory-scale and mid-scale testing could be engineered into full-scale Radionuclide Monitoring Stations. Results suggested that particle-pre-charging is a viable technical approach if reductions in baseline sensitivity or power consumption are desired.

54 ENVIRONMENTAL SCIENCES↗

GMS Station SOH Monitoring Users Guide (V.1.2)

The Geophysical Monitoring System (GMS) State-of-Health User Interface (SOH UI) is a web-based application that allows a user to view and acknowledge the SOH status of stations in the GMS system. The SOH UI will primarily be used by the System Controller, who monitors and controls the system and external data connections. The System Controller uses the station SOH UIs to monitor, detect, and troubleshoot problems with station data availability and quality.

58 GEOSCIENCES↗