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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 235 records · Page 13
All sourcesNASA NTRSDOE OSTI
NASA NTRS1975

Porous matrix structures for alkaline electrolyte fuel cells

A number of advancements have been realized by a continuing research program to develop higher chemically stable porous matrix structures with high bubble pressure (crossover resistance) for use as separators in potassium hydroxide electrolyte fuel cells. More uniform, higher-bubble-pressure asbestos matrices were produced by reconstituting Johns-Manville asbestos paper; Fybex potassium titanate which was found compatible with 42% KOH at 250 F for up to 3000 hr; good agreement was found between bubble pressures predicted by an analytical study and those measured with filtered structures; Teflon-bonded Fybex matrices with bubble pressures greater than 30 psi were obtained by filtering a water slurry of the mixture directly onto fuel cell electrodes; and PBI fibers have satisfactory compatibility with 42% KOH at 250 F.

Vine, R. W.↗
NASA NTRS1975

Coal refuse site inventories

Small-scale color-infrared aerial photography at 1:120,000 scale is used to carry out an operational survey of coal refuse sites. Site analyses and reclamation cost estimates are completed in less than 90 days by using remote sensing techniques. Analysis of photographs provided dependable and accurate data for the location and environmental assessment of nearly 200 coal refuse banks and slurry ponds. The inventory constitutes a comprehensive reference for establishing priorities for coal refuse site reclamation and for complementing future field surveys.

Wobber, F. J.↗
NASA NTRS1976

Repair of fused silica platens

Refill/leveling technique, which consists of spreading slurry refill material to affected areas and then sanding until surfaces are flat, extends service life of platen up to 50 production cycles between downtime.

Heisman, R. M.↗
NASA NTRS1977

Extracting lignins from mill wastes

Addition of quaternary ammonium compound and activated charcoal to pulp and mill wastes precipitates lignins in sludge mixture. Methanol dissolves lignins for separation from resulting slurry. Mineral acid reprecipitates lignins in filtered solution. Quaternary ammonium compound, activated charcoal, as well as water may be recovered and recycled from this process.

Humphrey, M. F.↗
NASA NTRS1976

Large area Czochralski silicon for solar cells

A detailed model of a typical Czochralski silicon crystal puller is utilized to predict maximum crystal growth rate as a function of various furnace parameters. Results of this analysis, when combined with multiblade slurry sawing, indicate that the Czochralski process is highly attractive for achieving near-term cost reduction of solar cell silicon.

Rea, S. N.↗
NASA NTRS1978

Microbial desulfurization of coal

Experiments indicate that several sulfur-oxidizing bacteria strains have been very efficient in desulfurizing coal. Process occurs at room temperature and does not require large capital investments of high energy inputs. Process may expand use of abundant reserves of high-sulfur bituminous coal, which is currently restricted due to environmental pollution. On practical scale, process may be integrated with modern coal-slurry transportation lines.

Dastoor, M. N.↗
NASA NTRS1977

Research on graphite reinforced glass matrix composites

The results of research for the origination of graphite-fiber reinforced glass matrix composites are presented. The method selected to form the composites consisted of pulling the graphite fiber through a slurry containing powdered glass, winding up the graphite fiber and the glass it picks up on a drum, drying, cutting into segments, loading the tape segment into a graphite die, and hot pressing. During the course of the work, composites were made with a variety of graphite fibers in a glass matrix.

Bacon, J. F.↗
NASA NTRS1977

Lock hopper values for coal gasification plant service

Although the operating principle of the lock hopper system is extremely simple, valve applications involving this service for coal gasification plants are likewise extremely difficult. The difficulties center on the requirement of handling highly erosive pulverized coal or char (either in dry or slurry form) combined with the requirement of providing tight sealing against high-pressure (possibly very hot) gas. Operating pressures and temperatures in these applications typically range up to 1600 psi (110bar) and 600F (316C), with certain process requirements going even higher. In addition, and of primary concern, is the need for reliable operation over long service periods with the provision for practical and economical maintenance. Currently available data indicate the requirement for something in the order of 20,000 to 30,000 open-close cycles per year and a desire to operate at least that long without valve failure.

Schoeneweis, E. F.↗
NASA NTRS1977

Anion exchange membranes for electrochemical oxidation-reduction energy storage system

Oxidation-reduction couples in concentrated solutions separated by appropriate ion selective membranes were considered as an attractive approach to bulk electrical energy storage. A key problem is the development of the membrane. Several promising types of anionic membranes are discussed which were developed and evaluated for redox energy storage systems. The copolymers of ethyleneglycoldimethacrylate with either 2-vinylpyridine or vinylbenzl chloride gave stable resistance values compared to the copolymer of vinylbenzlchloride and divinylbenzene which served as the baseline membrane. A polyvinylchloride film aminated with tetraethylenepentamine had a low resistance but a high ion transfer rate. A slurry coated vinylpyridine had the lowest ion transfer rate. All these membranes functioned well in laboratory cells at ambient temperatures with the acidic chloride oxidant/reductant system, Fe 3, Fe 2/Ti 3, Ti 4.

Odonnell, P. M.↗
NASA NTRS1977

Assessment of present state-of-the-art sawing technology of large diameter ingots for solar sheet material

The objective of this program is to assess the present state-of-the-art sawing technology of large diameter silicon ingots (3 inch and 4 inch diameter) for solar sheet materials. During this period, work has progressed in three areas: (1) slicing of the ingots with the multiblade slurry saw and the I.D. saw, (2) characterization of the sliced wafers, and (3) analysis of direct labor, expendable material costs, and wafer productivity.

Yoo, H. I.↗
NASA NTRS1978

Array automated assembly, phase 2

An analysis was made of cost tradeoffs for shaping modified square wafers from cylindrical crystals. Tests were conducted of the effectiveness of texture etching for removal of surface damage on sawed wafers. A single step texturing etch appeared adequate for removal of surface damage on wafers cut with multiple blade reciprocating slurry saws.

Taylor, W. E.↗
NASA NTRS1978

Low density bismaleimide-carbon microballoon composites

A process is described for constructing for a composite laminate structure which exhibits a high resistance to heat and flame provides safer interior structures for aircraft and submarine compartments. Composite laminate structures are prepared by the bismaleimide resin preimpregnation of a fiberglass cloth to form a face sheet which is bonded with a bismaleimide hot melt adhesive to a porous core structure selected from the group consisting of polyamide paper and bismaleimide-glass fabric which is filled with carbon microballoons. The carbon microballoons are prepared by pyrolyzing phenolic micro-balloons in the presence of nitrogen. A slurry of the carbon microballoons is prepared to fill the porous core structure. The porous core structure and face sheet are bonded to provide panel structures exhibiting increased mechanical capacities and lower oxygen limit values and smoke density values.

Kourtides, D. A.↗
NASA NTRS1978

Coal desulfurization process

A method for chlorinolysis of coal is an organic solvent at a moderate temperautre and atmospheric pressure has been proven to be effective in removing sulfur, particularly the organic sulfur, from coal. Chlorine gas is bubbled through a slurry of moist coal in chlorinated solvent. The chlorinated coal is separated, hydrolyzed and the dechlorinated. Preliminary results of treating a high sulfutr (4.77%S) bituminous coal show that up to 70% organic sulfur, 90% hyritic sulfur and 76% total sulfur can be removed. The treated coal is dechlorinated by heating at 500 C. The presence of moisture helps to remove organic sulfur.

Hsu, G. C.↗
NASA NTRS1976

Economic analysis of low cost silicon sheet produced from Czochralski grown material

This study shows that the lower limits for manufacturing add-on costs to convert polysilicon to wafers is in the range of $22 to $26/sq m with the cost about equally divided between the crystal growth and wafering processes. However, the $22 to $26/sq m cost limit should be viewed as an asymptote since it is based on multicharge or continuous growth configurations, solidification rates in excess of 2 Kg/hr, multiblade wafering and a slice plus kerf of .045 cm. It should also be emphasized that the results of this study are based on as-sawn wafers, 100% yields (growth and slicing) and no profit. To the first approximation, the limiting cost factors are crucible material and furnace parts for growth and blade material and slurry for slicing.

Koliwad, K. M.↗
NASA NTRS1978

Catalytic hydrosolvation process converts coal to low-sulfur liquid fuel

Development of the catalytic hydrosolvation process for converting coal to low-sulfur fuel oil is described in this paper. Coal impregnated with catalyst was slurried with oil, and the mixture was hydrogenated at a temperature of 475 C, and 30 min residence time under 3600 psi pressure. A ton of coal yielded 3.5 bbl of fuel oil containing 0.2% sulfur, with naphtha and C1-C4 hydrocarbon gases as byproducts. A preliminary economic evaluation of the process indicated potential for further development.

Qader, S. A.↗
NASA NTRS1978

Surfactant-assisted liquefaction of particulate carbonaceous substances

A slurry of carbonaceous particles such as coal containing an oil soluble polar substituted oleophilic surfactant, suitably an amine substituted long chain hydrocarbon, is liquefied at high temperature and high hydrogen presence. The pressure of surfactant results in an increase in yield and the conversion product contains a higher proportion of light and heavy oils and less asphaltene than products from other liquefaction processes.

Hsu, G. C.↗
NASA NTRS1979

Bonding of sapphire to sapphire by eutectic mixture of aluminum oxide and zirconium oxide

An element comprising sapphire, ruby or blue sapphire can be bonded to another element of such material with a eutectic mixture of aluminum oxide and zirconium oxide. The bonding mixture may be applied in the form of a distilled water slurry or by electron beam vapor deposition. In one embodiment the eutectic is formed in situ by applying a layer of zirconium oxide and then heating the assembly to a temperature above the eutectic temperature and below the melting point of the material from which the elements are formed. The formation of a sapphire rubidium maser cell utilizing eutectic bonding is shown.

Deluca, J. J.↗