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At least 235 records · Page 13

The mechanisms, dynamics, and implications of self-sealing and CO 2 resistance in wellbore cements

Here, this study analyzes the dynamics and mechanisms of the interactions of carbonated brine with hydrated-Portland-cement; in particular, the study focuses on self-sealing, a process whereby hydrated-Portland cement reacts with carbonated brine to for silica and calcium carbonate in sufficient quantities to seal the flow pathway. The analysis is based on a comprehensive set of reactive-transport simulations that explore the complex coupled dynamics between the fluid flow and mineral reactions that underlie self-sealing, and it relies heavily on the synthesis of the extensive body of work on wellbore integrity that has been conducted over the past decade. The analysis explores a large chemical and mineralogical diversity and a wide range in physical conditions and flow regimes, attempting to assess the robustness of the analysis. Self-sealing conditions arise over a wide range in cement properties and reservoir conditions. Although some properties and conditions promote a stronger self-sealing response, self-sealing occurs for a wide range of Ca:Si ratios in cement and for various reservoir fluid compositions. Self-sealing conditions move along a wellbore proportional to the flux of the leaking carbonated brine, and the reaction zone spreads out proportional to the fluid velocity, where volumetric flux and velocity are related by porosity (flux = velocity * porosity). However, self-sealing conditions can be maintained in a specific section of a wellbore by controlling the pressure drive and/or effective wellbore permeability, which in turn can limit the flux and velocity of any leaking fluid. Finally, the phases produced by hydrating Portland cement represent a carbonic cement that will react with a carbonated brine to produce end products (calcium carbonate and silica) that can maintain integrity in the presence of carbonic acid. Lastly, the attributes that make hydrated Portland cement phases a carbonic cement are required for self-sealing.

58 GEOSCIENCES↗

NSTX-U Machine Core Vacuum Seals Upgrade Design

The vacuum in the National Spherical Torus Experiment Upgrade (NSTX-U) is in the range of 2.66x10⁻⁶ Pa (2x 10⁻⁸ torr). To enhance vacuum seals and lower gas permeation in the NSTX-U and therefore ensuring operation safety and quality, the machine core vacuum seal design has been upgraded using double elastomeric seals and pumped interspaces (guard channels). In NSTX-U machine core, there are six major vacuum seals, including upper and lower vacuum vessel main flanges, upper and lower bellows flanges, and two in the ceramic isolation ring assembly that are mounted to the upper vacuum vessel main flange. The elastomeric seals are commercially available and customized fluorocarbon (Viton) O-rings. To ensure appropriate O-ring compression ratios for the vacuum seal, the O-ring grooves are customized with appropriate tolerances considering specific situations for each seal. In this upgrade, the vacuum in each interspace is designed to reach 13.33 Pa (0.1 torr), thus the overall pressure difference crossing each double O-ring seal is expected to be reduced by at least three orders of magnitude, and accordingly the overall rates of leakage and permeation will be lowered by three orders of magnitude. The corresponding pump-down times for each seal, at room temperature, are estimated at about 60 s. Additionally, the vacuum pumped interspaces will be able to function as a real-time leak monitor.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Investigation of a Wedge Adhesion Test for Edge Seals

Many photovoltaic (PV) technologies have been found to be sensitive to moisture that diffuses into a PV package. Even with the use of impermeable frontsheets and backsheets, moisture can penetrate from the edges of a module. To limit this moisture ingress pathway from occurring, manufacturers often use a low permeability polyisobutylene (PIB) based edge seal filled with desiccant to further restrict moisture ingress. Moisture ingress studies have shown that these materials are capable of blocking moisture for the 25-year life of a module; but to do so, they must remain well-adhered and free of cracks. This work focuses on adapting the Boeing Wedge test for use with edge seals laminated using glass substrates as part of a strategy to assess the long-term durability of edge seals. The advantage of this method is that it duplicates the residual stresses and strains that a glass/glass module may have when the lamination process results in some residual glass bending that puts the perimeter in tension. Additionally, this method allows one to simultaneously expose the material to thermal stress, humidity, mechanical stress, and ultraviolet radiation. The disadvantage of this method generally is that we are limited by the fracture toughness of the glass substrates that the edge seal is adhered to. However, the low toughness of typical uncrosslinked or sparsely crosslinked PIB makes them suitable for this technique. We present data obtained during the development of the wedge test for use with PV edge seal materials. This includes development of the measuring techniques and evaluation of the test method with relevant materials. We find consistent data within a given experiment, along with the theoretical independence of fracture toughness measurements with wedge thickness. This indicates that the test methodology is reproducible. However, even though individual experimental sets are consistent, the reproducibility between experimental sets is poor. We believe this may be due to inconsistencies in sample history, sample batch, or small changes in sample preparation/assembly from one month to the next. Because the fracture strength of typical edge seal materials is so low, they cannot be relied upon for mechanical strength. A small stress or strain on the edge seal is capable of promoting delamination or tearing causing the edge seal to fail. Because of this, edge seals are very dependent on the processing and construction parameters in the full size PV module such that any long term evaluation of their durability must be conducted on full size modules to be accurate.

14 SOLAR ENERGY↗

Large Eddy Simulation of Rotationally Induced Ingress and Egress around an Axial Seal between Rotor and Stator Disks

In gas turbines, the hot gas exiting the combustor can have temperatures as high as 2000 °C, and some of this hot gas enter into the space between the stator and rotor disks (wheelspace). Since the entering hot gas could damage the disks, its ingestion must be minimized. This is carried out by rim seals and by introducing a cooler flow from the compressor (sealing flow) into the wheelspace. Ingress and egress into rim seals are driven by the stator vanes, the rotor and its rotation, and the rotor blades. This study focuses on the ingress and egress driven by the rotor and its rotation. This is carried out by performing wall-resolved large eddy simulation (LES) around an axial seal in a rotor–stator configuration without vanes and blades. Results obtained show the mechanisms by which the rotor and its rotation induce ingress, egress, and flow trajectories. Kelvin–Helmholtz instability was found to create a wavy shear layer and displacement thickness that produces alternating regions of high and low pressures around the rotor side of the seal. Vortex shedding on the backward-facing side of the seal and its impingement on the rotor side of the seal also produces alternating regions of high and low pressures. The locations of the alternating regions of high and low pressures were found to be statistically stationary and to cause ingress to start on the rotor side of the seal. Vortex shedding and recirculating flow in the seal clearance also cause ingress by entrainment. With the effects of the rotor and its rotation on ingress and egress isolated, this study enables the effects of stator vanes and rotor blades to be assessed.

42 ENGINEERING↗

Dust Tolerance Characterization of Lunar Docking and Hatch Seals

Low-leakage seals are an enabling technology for future lunar surface systems, and they must be kept clean to ensure that crews have sufficient breathable air for extended lunar surface missions. Previous testing has shown that contamination and debris on seals can cause them to exhibit higher leak rates. However, seal performance in the presence of lunar dust has not been thoroughly characterized, and the size and concentration of dust particles that cause seal leak rates to become unacceptable have not been defined or well understood. To address this knowledge gap, researchers at the NASA Glenn Research Center have been executing a multiphase study to better understand and mitigate seal dust-exposure risks. The focus of this paper is on the first phase of that study, in which tests were conducted to develop a performance database for two representative state-of-the-art seal designs. Leak rates are presented for seals with varying levels of dust contamination, and breakthrough points are identified at which seal leak rates exceeded equivalent leak rate requirements. This phase of the study also investigated the effects of temperature on the seals’ ability to hold pressure when contaminated with dust.

Dust Mitigation↗

Tamper-indicating quantum optical seals

Confidence in the means for identifying when tampering occurs is critical for containment and surveillance technologies. Fiber-optic seals have proven especially useful for actively surveying large areas or inventories due to the extended transmission range and flexible layout of fiber. However, it is reasonable to suspect that an intruder could tamper with a fiber-optic sensor by accurately replicating the light transmitted through the fiber. In this contribution, we demonstrate a novel approach to using fiber-optic seals for safeguarding large-scale inventories with increased confidence in the state of the seal. Our approach is based on the use of quantum mechanical phenomena to offer unprecedented surety in the authentication of the seal state. In particular, we show how quantum entangled photons can be used to monitor the integrity of a fiber-optic cable - the entangled photons serve as active sensing elements whose non-local correlations indicate normal seal operation. Moreover, we prove using the quantum no-cloning theorem that attacks against the quantum seal necessarily disturb its state and that these disturbances are immediately detected. Our quantum approach to seal authentication is based on physical principles alone and does not require the use of secret or proprietary information to ensure proper operation. We demonstrate an implementation of the quantum seal using a pair of entangled photons and we summarize our experimental results including the probability of detecting intrusions and the overall stability of the system design. We conclude by discussing the use of both free-space and fiber-based quantum seals for surveying large areas and inventories.

quantum information↗

Field Test and Evaluation of Engineered Biomineralization Technology for Sealing Existing Wells

This research project addresses one of the goals of the U.S. Department of Energy (DOE) Carbon Storage Program (CSP) aimed at developing Advanced Wellbore Integrity Technologies to Ensure Permanent Geologic Carbon Storage. The technology field-tested in this research project is referred to as microbially induced calcite precipitation (MICP), which utilizes a biologically-based process to precipitate calcium carbonate. If properly controlled MICP can successfully seal fractures, high permeability zones, and compromised wellbore cement in the vicinity of wellbores and in nearby caprock, thereby improving the storage security of geologically-stored carbon dioxide. This report describes an MICP sealing field test performed on a 24.4 cm (9.625 inch) diameter well located on the Gorgas Steam Generation facility near Jasper, Alabama. The research was aimed at (1) developing methods for delivering MICP promoting fluids downhole using conventional oil field technologies and (2) assessing the ability of MICP to seal cement and formation fractures in the near wellbore region in a sandstone formation. Both objectives were accomplished successfully during a field test performed during the period April 1-11, 2014. The test resulted in complete biomineralization sealing of a horizontal fracture located 340.7 m (1118 feet) below ground surface. A total of 24 calcium injections and six microbial inoculation injections were required over a three day period in order to achieve complete sealing. The fractured region was considered completely sealed when it was no longer possible to inject fluids into the formation without exceeding the initial formation fracture pressure. The test was accomplished using conventional oil field technology including an 11.4 L (3.0 gallon) wireline dump bailer for injecting the biomineralization materials downhole. Metrics indicating successful MICP sealing included reduced injectivity during seal formation, reduction in pressure falloff, and demonstration of MICP by-products including calcium carbonate (CaCO 3 ) in treated regions of side wall cores. This project successfully integrated mesoscale laboratory experiments at the Center for Biofilm Engineering (CBE) together with simulation modeling conducted at the University of Stuttgart to develop the protocol for conducting the biomineralization sealing test in the field well.

54 ENVIRONMENTAL SCIENCES↗

Development of a self-lubricating high-efficiency hybrid seal composed of carbon nanotube-coated metal meshes for CSP turbomachinery (SETO CPS #36333 Final Report)

In turbomachinery, internal leakage flow accounts for up to 3% of the total thermodynamic cycle energy loss. Tradeoff must be made between the sealing efficiency (smaller clearance) and the friction and wear issues for interfering with the shaft (larger clearance). This ORNL-Danfoss joint effort developed a novel hybrid seal composed of carbon nanotube (CNT)-coated metal meshes. The CNT growth process was based on a self-catalyzing chemical vapor deposition and these multiwall CNTs were well aligned with high crystallinity. This hybrid material structure takes advantage of the CNT’s low-friction nature and uses the metal mesh as an extendable backbone. Full-scale experimental seals were designed, fabricated, and optimized for sealing performance and durability. The CNT-coated metal mesh seal demonstrated superior gas sealing efficiency to the baseline labyrinth seal and significantly improved shaft surface protection compared with the state-of-the-art superalloy brush seal on the static rig and full-scale compressor dynamometer tests. The CNT-metal mesh seal is low-cost and scalable and can potentially benefit wide applications, including CSP and other power generation, marine, automotive, and HVAC.

36 MATERIALS SCIENCE↗

Feasibility of liquid-metal vacuum seals

A basic component of any ultrahigh-vacuum system is a seal capable of isolating a test chamber from its higher pressure surroundings. Two of the most common vacuum seals now in use are the elastomer O-ring seal and the metallic shear seal. The former has the problem of outgassing and gas permeation; the latter requires a large force per unit seal-length to maintain the sealing action. The search for a seal which would provide minimal virtual and real leak rates in a chamber, without requiring a large force to consummate the seal, led to investigation of a liquid-metal seal.

SEALANT↗

Sealing technology for aircraft gas turbine engines

Experimental evaluation under simulated engine conditions revealed that conventional mainshaft seals have disadvantages of high gas leakage rates and wear. An advanced seal concept, the self-acting face seal, has a much lower gas leakage rate and greater pressure and speed capability. In endurance tests (150 hr) to 43 200 rpm the self-acting seal wear was not measurable, indicating noncontact sealing operation was maintained even at this high rotative speed. A review of published data revealed that the leakage through gas path seals has a significant effect on TSFC, stall margin and engine maintenance. Reducing leakages by reducing seal clearances results in rubbing contact, and then the seal thermal response and wear determines the final seal clearances. The control of clearances requires a material with the proper combination of rub tolerance (abradability) and erosion resistance. Increased rub tolerance is usually gained at the expense of reduced erosion resistance and vice versa.

Ludwig, L. P.↗

High speed, self-acting shaft seal

A high-speed, self-acting circumferential type shaft seal for use in turbine engines is disclosed. One or more conventional circumferential ring seals having a central aperture are mounted in a housing. In three of the four embodiments of the invention, a helical groove and one or more dam seals are cut in the inner cylindrical surface of the one or more ring seals. In a fourth embodiment, two or more lift pads are disposed in surface contact with the inner cylindrical surface of the seal rings. To the outside of the lift pads, two dam seals are cut in the inner cylindrical surface of two of the ring seals. In each of the embodiments, a net outward radial force was produced during rotation of the turbine causing the ring seals to lift out of contact with the turbine shaft to minimize wear of the ring seals.

Ludwig, L. P.↗

Sealing technology for aircraft gas turbine engines

Experimental evaluation under simulated engine conditions revealed that conventional mainshaft seals have disadvantages of high gas leakage rates and wear. An advanced seal concept, the self-acting face seal, has a much lower gas leakage rate and greater pressure and speed capability. In endurance tests (150 hr) to 43,200 rpm the self-acting seal wear was not measurable, indicating that noncontact sealing operation was maintained even at this high rotative speed. A review of published data revealed that the leakage through gas path seals has a significant effect on thrust specific fuel consumption, stall margin, and engine maintenance. Reducing leakages by reducing seal clearances results in rubbing contact, and then the seal thermal response and wear determines the final seal clearances.

Ludwig, L. P.↗

Mainshaft seals for small gas turbine engines

An experimental evaluation of mainshaft seals for small gas turbine engines was conducted with shaft speeds to 213 m/sec, air pressures to 215 psia, and air temperatures to 412 K. A radial face seal incorporating self-acting geometry for lift augmentation was evaluated. In addition, three conventional carbon seal types (face, circumferential segmented, and rotating ring) were run for comparison. Test results indicated that the conventional seals used in this evaluation may not be satisfactory in future advanced engines because of excessive air leakage. On the other hand, the self-acting face seal was shown to have the potential capability of limiting leakages to one-half that of the conventional face seals and one-fifth that of conventional ring seals. A 150 hour endurance test of the self-action face seal was conducted at speeds to 145 m/sec, air pressures to 180 psia, and air temperatures to 408 K. The seal wear was not measurable.

Ludwig, L. P.↗

Self-acting seals for helicopter engines

An experimental evaluation was conducted with NASA-designed self-acting face and circumferential seals for use in the main shaft positions of advanced gas turbine engines. The seals featured Rayleigh step pads (self-acting geometry) for lift augmentation. The tested seals incorporated design improvements over previous self-acting configurations. Self-acting face seals were tested to speeds of 214 m/s (700 ft/sec, 63700 rpm), air pressures of 216.8 N/sq cm abs (314.7 psia), and air temperatures of 688K (778 F). Self-acting circumferential seals were tested to speeds of 183 m/s (600 ft/sec, 47700 rpm), air pressures of 61.8 N/sq cm abs (89.7 psia), and air temperatures of 711 K (820 F). Self-acting face-seals are capable of operating at conditions exceeding conventional seal capability. The limit on speed capability was found to be the flatness of the seal-seat. The self-acting circumferential seal design tested requires further development for use in advanced engines.

Lynwander, P.↗

Testing of molded high temperature plastic actuator road seals for use in advanced aircraft hydraulic systems

Molded high temperature plastic first and second stage rod seal elements were evaluated in seal assemblies to determine performance characteristics. These characteristics were compared with the performance of machined seal elements. The 6.35 cm second stage Chevron seal assembly was tested using molded Chevrons fabricated from five molding materials. Impulse screening tests conducted over a range of 311 K to 478 K revealed thermal setting deficiencies in the aromatic polyimide molding materials. Seal elements fabricated from aromatic copolyester materials structurally failed during impulse cycle calibration. Endurance testing of 3.85 million cycles at 450 K using MIL-H-83283 fluid showed poorer seal performance with the unfilled aromatic polyimide material than had been attained with seals machined from Vespel SP-21 material. The 6.35 cm first stage step-cut compression loaded seal ring fabricated from copolyester injection molding material failed structurally during impulse cycle calibration. Molding of complex shape rod seals was shown to be a potentially controllable technique, but additional molding material property testing is recommended.

Waterman, A. W.↗

Development of improved high pressure turbine outer gas path seal components

A plasma sprayed graded layered ceramic/metallic (ZrO2/CoCrAlY) seal was evaluated for JT9D turbine application by rig and engine tests. Four cyclic thermal shock rig tests were conducted during the program. Three completed 1000 simulated engine thermal cycle tests and the fourth completed 500 cycles without severe cracking or spalling. Three ceramic seals were installed in a JT9D experimental engine to evaluate the effect of the engine thermal environment on the seals. All three seals completed the test successfully without severe cracking or spalling. The three seals did have slight laminar cracks at the 85/15-40/60 ZrO2/CoCrAlY interface. The second engine test evaluated the rub capabilities of the seal. Six ceramic seals were installed in the engine with fourteen abrasive tip blades. Three of the six seals rubbed to a depth of 24 mils. Eight of the fourteen abrasive tip blades showed evidence of wear. Three of the eight blades wore a maximum of five mils. Engine rub test results demonstrated the potential of reducing turbine clearances and thereby improving engine performance by use of sprayed ceramic seals.

Shiembob, L. T.↗

Variable-Friction Secondary Face Seals

Feedback-controlled friction or damping suppresses vibrations. Variable-friction secondary seal conceived to control vibration and stability of primary seal ring over wide range of conditions. By varying friction force or damping applied to primary seal ring, vibration controlled to provide stable operation. Advantages of "variablefriction secondary seal": face-seal stability controlled as function of primary-ring vibration amplitudes, and also friction remotely changed to achieve acceptable vibration amplitudes for large range of seal-operating conditions without compromising secondary-seal performance. Concept also useful in seal testing in which dynamic stability of face seals is under evaluation.

Dirusso, E.↗

Development of gas-to-gas lift pad dynamic seals, volumes 1 and 2

Dynamic tests were performed on self acting (hydrodynamic) carbon face rotary shaft seals to assess their potential, relative to presently used labyrinth seals, for improving performance of aircraft gas turbine engines by reducing air leakage flow rate at compressor end seal locations. Three self acting bearing configurations, designed to supply load support at the interface of the stationary carbon seal and rotating seal race, were tested. Two configurations, the shrouded taper and shrouded flat step, were incorporated on the face of the stationary carbon seal element. The third configuration, inward pumping spiral grooves, was incorporated on the hard faced surface of the rotating seal race. Test results demonstrated seal leakage air flow rates from 75 to 95% lower that can be achieved with best state-of-the-art labyrinth designs and led to identification of the need for a more geometrically stable seal design configuration which is presently being manufactured for subsequent test evaluation.

Pope, A. N.↗