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At least 235 records · Page 13
All sourcesNASA NTRSDOE OSTI
DOE OSTI2017

Free energy models for ice VII and liquid water derived from pressure, entropy, and heat capacity relations

Here, we present equations of state relevant to conditions encountered in ramp and multiple-shock compression experiments of water. These experiments compress water from ambient conditions to pressures as high as about 14 GPa and temperatures of up to several hundreds of Kelvin. Water may freeze into ice VII during this process. Although there are several studies on the thermodynamic properties of ice VII, an accurate and analytic free energy model from which all other properties may be derived in a thermodynamically consistent manner has not been previously determined. We have developed such a free energy model for ice VII that is calibrated with pressure-volume-temperature measurements and melt curve data. Furthermore, we show that liquid water in the pressure and temperature range of interest is well-represented by a simple Mie-Grüneisen equation of state. Our liquid water and ice VII equations of state are validated by comparing to sound speed and Hugoniot data. Although they are targeted towards ramp and multiple-shock compression experiments, we demonstrate that our equations of state also behave reasonably well at pressures and temperatures that lie somewhat beyond those found in the experiments.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2021

Economic risk analysis for the capture of a distributed energy resource using modular chemical process intensification

Recent advances in the chemical process industry have allowed for the intensification of reactors and unit operations, by enhancing heat and mass transfer or combining multiple unit operations. Process intensification can enable chemical plants to be constructed in a more compact, modular fashion, offering improvements over conventional on-site approaches to capital construction, operations and maintenance. This modular chemical process intensification (MCPI) offers several benefits over conventional stick-built (CSB) plant construction in terms of reduced footprint, reduced energy consumption, lower cost, less waste and improved safety and quality control. However, acceptance of MCPI over CSB construction practices within the chemical industry can be impeded by the uncertain risks associated with investing in new technology. Furthermore, the work here documents a case study during the development of a modular chemical plant for capturing distributed energy resources within chemical production. This MCPI approach to plant construction is contrasted with a CSB approach for producing the same chemical product. Data collection tools were developed, based on a literature review, and data was collected from the technology developer to understand the process technology. Sensitivity analysis was then conducted to analyze the business rationale for the application of MCPI over CSB across several market scenarios. It was found that MCPI would be better suited for capacities up to 150 000 metric tons per year, but that improvement in payback period was needed. Additionally, for MCPI approach to achieve acceptable payback periods, efforts are needed to reduce the cost of capital equipment and compress the schedule for ramping up modular production.

42 ENGINEERING↗
DOE OSTI2015

Probing iron at Super-Earth core conditions

In this paper, we report on the quasi-isentropic compression of an iron sample using ramp shaped laser irradiation. This technique allows us to quasi-isentropically compress iron up to 700 GPa and 8500 K. To our knowledge, these data are the highest pressures reached on iron in off-Hugoniot conditions and the closest to the thermodynamic states thought to exist in Earth-like planetary cores. The experiment was performed on the Ligne d'Intégration laser facility at CESTA, Bordeaux, France.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗
NASA NTRS1985

The relationship of extensional and compressional tectonics to a Precambrian fracture system in the eastern overthrust belt, USA

The central and southern Appalachians have a long history of interrelated extensional and compressional tectonics. It is proposed that each episode was controlled by a reactivation of a fracture system in the Precambrian basement. Proprietary seismic-reflection profiles show a system of down-to-the-east Precambrian extensional faults. When under renewed extension, these faults produce features such as the western border faults of Mesozoic basins, and when under compression, probably produce tectonic ramps in the overlying sedimentary cover rocks as well as the spatially and genetically related Alleghenian folds. This system, which parallels the Appalachian trend, is cut by a system of cross-strike hinge or scissors faults that have probable strike-slip movements. Reactivation of this cross-strike system appears to have produced lateral ramps that connect decollements at different stratigraphic levels and caused abrupt changes in fold wavelength along strikes. Continued reactivation of this cross-strike system is suggested by east-west border faults and Precambrian highs between Mesozoic basins. The present activity of this system is suggested by the fact that more than 35% of recent earthquakes are coincident with cross-strike faults and lateral ramps.

Pohn, H.↗
NASA NTRS2019

Principal Component Analysis of Up-The-Ramp Sampled Infrared Array Data

We describe the results of principal component analysis (PCA) of up-the-ramp sampled infrared (IR) array data from the Hubble Space Telescope wide field camera 3 (WFC3 IR), James Webb Space Telescope NIRSpec, and prototype Wide Field Infrared Survey Telescope’s wide field instrument detectors. These systems use, respectively, Teledyne H1R, H2RG, and H4RG-10 near-IR detector arrays with a variety of IR array controllers. The PCA shows that the Legendre polynomials approximate the principal components of these systems (i.e., they roughly diagonalize the covariance matrix). In contrast to the monomial basis that is widely used for polynomial fitting and linearization today, the Legendre polynomials are an orthonormal basis. They provide a quantifiable, compact, and (nearly) linearly uncorrelated representation of the information content of the data. By fitting a few Legendre polynomials, nearly all of the meaningful information in representative WFC3 astronomical datacubes can be condensed from 15 up-the-ramp samples down to 6 compressible Legendre coefficients per pixel. The higher order coefficients contain time domain information that is lost when one projects up-the-ramp sampled datacubes onto two-dimensional images by fitting a straight line, even if the data are linearized before fitting the line. Going forward, we believe that this time domain information is potentially important for disentangling the various nonlinearities that can affect IR array observations, i.e., inherent pixel nonlinearity, persistence, burn in, brighter-fatter effect, (potentially) nonlinear interpixel capacitance, and perhaps others.

Rauscher, Bernard J.↗
NASA NTRS1993

Experimental and numerical study of swept ramp injection into a supersonic flowfield

Time-averaged measurements of pressure, temperature, velocity, and injectant mole fraction are presented using the planar laser-induced iodine fluorescence (PLIIF) techniques in the complex 3D compressible flowfield around a swept ramp fuel injector. Within the range of thermodynamic conditions present in the test case studied, the technique's accuracy is estimated to be 4 percent for pressure, 4 percent for temperature, 4 percent for velocity, and 3 percent for injectant mole fraction. Comparisons to numerical simulations using the SPARK 3D Navier-Stokes computer code with an algebraic turbulence model are made at the centerplane of the flowfield as well as on three crossflow planes downstream of the injector, and good agreement is found. A weak asymmetry in the incoming flowfield appears to be amplified by boundary layer separation occuring when the the ramp generated shock reflects off the tunnel walls. In the near field of the injector, laminar calculations show better agreement to the measurements than turbulent calculations.

Donohue, James M.↗
NASA NTRS1994

Experimental and numerical study of swept ramp injection into a supersonic flowfield

Time-averaged measurements of pressure, temperature, velocity, and injectant mole fraction are presented using the planar laser-induced iodine fluorescence technique in the complex three-dimensional compressible flowfield around a swept ramp fuel injector. Within the range of thermodynamic conditions present in the test case studied, the technique's accuracy is estimated to be 4% for pressure, temperature, and velocity and 3% for injectant mole fraction. Comparisons with numerical simulations using the SPARK three-dimensional Navier-Stokes computer code with an algebraic turbulence model are made at the centerplane of the flowfield as well as on three crossflow planes downstream of the injector. Calculations and measurements are in good agreement throughout the flowfield, with deviations on the order of 5%; however, in specific regions, such as in the base of the ramp, deviations are larger. A weak asymmetry in the incoming flowfield appears to be amplified by boundary-layer separation occurring when the ramp-generated shock reflects off the tunnel walls. Ramp-generated vortices are weaker in the calculated results due to the effects of numerical viscosity in the vortex cores. This leads to less turning and mixing of the jet plume than observed in the experiments. The rate of decay of the maximum injectant mole fraction with streamwise distance is greater for the present ramp injection scheme than for previously measured transverse injection schemes. In this recirculation region at the base of the injector, laminar calculations show better agreement with the measurements than turbulent calculations.

Donohue, James M.↗
DOE OSTI2020

Investigating off-Hugoniot states using multi-layer ring-up targets

Abstract Laser compression has long been used as a method to study solids at high pressure. This is commonly achieved by sandwiching a sample between two diamond anvils and using a ramped laser pulse to slowly compress the sample, while keeping it cool enough to stay below the melt curve. We demonstrate a different approach, using a multilayer ‘ring-up’ target whereby laser-ablation pressure compresses Pb up to 150 GPa while keeping it solid, over two times as high in pressure than where it would shock melt on the Hugoniot. We find that the efficiency of this approach compares favourably with the commonly used diamond sandwich technique and could be important for new facilities located at XFELs and synchrotrons which often have higher repetition rate, lower energy lasers which limits the achievable pressures that can be reached.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
DOE OSTI2016

Estimates of crystalline LiF thermal conductivity at high temperature and pressure by a Green-Kubo method

Here, given the unique optical properties of LiF, it is often used as an observation window in high-temperature and -pressure experiments; hence, estimates of its transmission properties are necessary to interpret observations. Since direct measurements of the thermal conductivity of LiF at the appropriate conditions are difficult, we resort to molecular simulation methods. Using an empirical potential validated against ab initio phonon density of states, we estimate the thermal conductivity of LiF at high temperatures (1000–4000 K) and pressures (100–400 GPa) with the Green-Kubo method. We also compare these estimates to those derived directly from ab initio data. To ascertain the correct phase of LiF at these extreme conditions, we calculate the (relative) phase stability of the B1 and B2 structures using a quasiharmonic ab initio model of the free energy. We also estimate the thermal conductivity of LiF in an uniaxial loading state that emulates initial stages of compression in high-stress ramp loading experiments and show the degree of anisotropy induced in the conductivity due to deformation.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
NASA NTRS1989

Euler and Navier-Stokes solutions for hypersonic flows

An upwind finite-element technique that uses cell-centered quantities and implicit and/or explicit time marching has been developed for computing hypersonic laminar viscous flows using adaptive unstructured grids in two and three dimensions. A perfect gas model as well as an equilibrium air model is implemented for solving high-speed flows. A first-order basic scheme and a higher-order flux-corrected transport (FCT) scheme have been implemented. This technique has been used to predict 'Type III and IV' shock interactions on a cylinder in two dimensions and a swept cylinder in three dimensions, with a view to determine the pressure and heating rate augmentation caused by an impinging shock on the leading edge of a cowl lip of an engine inlet. The predictions of wall pressure and heating rates compare very well with experimental data. The flow features are very distinctly captured with a sequence of adaptively-generated grids. Three-dimensional corner flow, typically encountered in engine inlets due to compression of the flow by ramps in the walls, is also modeled. This procedure is the first step in developing an integrated fluid, thermal, structural analysis capability for hypersonic flight vehicles like the National Aero-Space Plane.

Thareja, Rajiv R.↗
DOE OSTI2025

High-compression implosions based on high density carbon ablator using modified drive and capsule dopant profiles

Laser-driven inertial fusion experiments have, for the first time, achieved a target gain greater than unity in a laboratory setting [Abu-Shawareb et al., Phys. Rev. Lett. 132, 065102 (2024)]. Despite this breakthrough, the burn-up fraction remains limited to about one-fourth of ideal estimates due to insufficient areal density, highlighting the potential for greater gains through enhanced compression. In our previous work, we demonstrated record-high compression of stagnated fuel in indirectly driven implosions using high-density carbon ablators. This was achieved by combining a continuous ramped pulse drive with a modified ablator dopant profile, which reduced mixing at the fuel–ablator interface and improved stability [Tommasini et al., Phys. Rev. Res. 5, L042034 (2023)]. Based on this foundation, the study presented here investigates the limits of compression achievable by combining the continuous ramped pulse drive with different dopant profiles to further minimize unstable interfaces and gradient discontinuities, thereby reducing fuel–ablator mixing. Our results demonstrate that the continuous ramped pulse consistently outperforms designs based on 3-shock drive pulses across all ablator profiles studied, with compression showing only a relatively modest dependence on dopant configurations that reduce the number of interfaces or eliminate discontinuities in the dopant gradient profile. Sub-scale experiments using the continuous ramped pulse achieved compression levels exceeding those of full-scale “HyE” implosions [Kritcher et al., Phys. Plasmas 28, 072706 (2021)] at similar adiabat, anticipating significant performance gains with increased scale, as supported by models and simulations. These findings underscore the critical role of the continuous ramped pulse in reducing mix and achieving improved compression. They also provide a foundation for future large-scale experiments to test the continuous ramped pulse design on deuterium–tritium fuel in the burn-wave propagation regime, leveraging the most effective combinations of continuous ramped pulse and dopant profiles identified in this study.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗
NASA NTRS1991

A parametric study of scramjet combustors for Mach 8 to Mach 20 flight

Performance trends for a combustor with ramp and slot fuel injectors are investigated through a three-dimensional parametric study at flight Mach numbers of 8, 10, 12, 16, and 20. Focus is placed on the mixing (combustion) efficiency, combustor loads, and thrust over the Mach number range. It is observed that the mixing efficiency decreases by 0.2 when a flight Mach number is increased from 8 to 12 but changes little for higher Mach numbers; the lower mixing is attributed more to a large decrease in the fuel-to-air velocity ratio and residence time over the Mach number range than to compressibility. It is pointed out that the ramp generates a shock impinging on the cowl, while a combined ramp and slot injection produces better mixing, both because of the action of this shock on the slot fuel and because of better fuel distribution in the duct.

Kamath, Pradeep S.↗
NASA NTRS1989

Viscous analysis of high speed flows using an upwind finite volume technique

A numerical study using an upwind finite volume technique to analyze high speed viscous flows is described. Two test cases were considered: a Mach 4.0 shock wave/laminar-boundary-layer interaction, and Mach 14.1 compression corners (15-deg and 24-deg ramp angle). PNS, TLNS, and NS equation results were obtained on each test case. As expected, PNS solutions are not adequate to resolve the flow physics. For the grids used in this study, there is no noticeable difference between the TLNS and full NS solutions. Both the TLNS and full NS solutions compared favorably with experimental data.

Ng, W. F.↗
NASA NTRSDate not supplied

Experimental Methods Using Force Application of A Single Boom for A 500-M²-Class Solar Sail

Solar sailing missions rely on deployable systems for large area-to-mass ratios once in space, while still being small enough for launcher envelopes in the stowed configuration. Many of these deployable systems feature booms that are flattened and subsequently coiled onto a spool / hub. As part of a collaborative deployable space structures research effort between the National Aeronautics and Space Administration (NASA) and German Aerospace Center (DLR), a boom deployment system for a future 500 m² solar sail has been developed. To achieve the respective solar sail size goal, 16.5-m-long booms produced by NASA were integrated into a DLR-designed deployer mechanism. This considerable size, as well as the lightweight construction of the booms and respective deployable systems makes testing on the ground a significant challenge. Some systems for gravity compensation as well as vertical testing to minimize the influence of gravity have been used in the past. However, an uncertainty factor remains towards the behaviour in the space environment. The focus of this paper is the load application testing of the integrated boom-deployment mechanism system under microgravity condition, as well as a comparison to vertical testing under gravity. Testing in microgravity was performed during a parabolic flight test inside an aircraft and it included stowage and full deployment of a single boom along the longitudinal axis of the aircraft. The load application was split into two categories: static testing, which induced a linear force ramp to the static boom for either compression or compression-bending; and dynamic testing, which applied a constant force to a boom during extension provided by the deployer mechanism. Both types of tests were performed multiple times at two distinct lengths of the boom, fully deployed (12.76 m) and ~28.6 % deployed (3.65 m). More parameters that are vital to the test philosophy are the angles of attack in the force application and the highest force applied. The data acquisition used for the applied load and deflection measurements of the boom is also presented.

Martin Richter↗
NASA NTRSDate not supplied

Experimental Methods Using Force Application of A Single Boom for A 500-M²-Class Solar Sail

Solar sailing missions rely on deployable systems for large area-to-mass ratios once in space, while still being small enough for launcher envelopes in the stowed configuration. Many of these deployable systems feature booms that are flattened and subsequently coiled onto a spool / hub. As part of a collaborative deployable space structures research effort between the National Aeronautics and Space Administration (NASA) and German Aerospace Center (DLR), a boom deployment system for a future 500 m² solar sail has been developed. To achieve the respective solar sail size goal, 16.5-m-long booms produced by NASA were integrated into a DLR-designed deployer mechanism. This considerable size, as well as the lightweight construction of the booms and respective deployable systems makes testing on the ground a significant challenge. Some systems for gravity compensation as well as vertical testing to minimize the influence of gravity have been used in the past. However, an uncertainty factor remains towards the behaviour in the space environment. The focus of this paper is the load application testing of the integrated boom-deployment mechanism system under microgravity condition, as well as a comparison to vertical testing under gravity. Testing in microgravity was performed during a parabolic flight test inside an aircraft and it included stowage and full deployment of a single boom along the longitudinal axis of the aircraft. The load application was split into two categories: static testing, which induced a linear force ramp to the static boom for either compression or compression-bending; and dynamic testing, which applied a constant force to a boom during extension provided by the deployer mechanism. Both types of tests were performed multiple times at two distinct lengths of the boom, fully deployed (12.76 m) and ~28.6 % deployed (3.65 m). More parameters that are vital to the test philosophy are the angles of attack in the force application and the highest force applied. The data acquisition used for the applied load and deflection measurements of the boom is also presented.

Martin Richter↗
DOE OSTI2021

Simultaneous inference of the compressibility and inelastic response of tantalum under extreme loading

We study the deformation of tantalum under extreme loading conditions. Experimental velocity data are drawn from both ramp loading experiments on Sandia’s Z-machine and gas gun compression experiments. The drive conditions enable the study of materials under pressures greater than 100 GPa. We provide a detailed forward model of the experiments including a model of the magnetic drive for the Z-machine. Utilizing these experiments, we simultaneously infer several different types of physically motivated parameters describing equation of state, plasticity, and anelasticity via the computational device of Bayesian model calibration. Characteristics of the resulting calculated posterior distributions illustrate relationships among the parameters of interest via the degree of cross correlation. The calibrated velocity traces display good agreement with the experiments up to experimental uncertainty as well as improvement over previous calibrations. Examining the Z-shots and gun-shots together and separately reveals a trade-off between accuracy and transferability across different experimental conditions. Implications for model calibration, limitations from model form, and suggestions for improvements are discussed.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗
DOE OSTI2024

A platform for planar dynamic compression of crystalline hydrogen toward the terapascal regime

Here we describe a method for laser-driven planar compression of crystalline hydrogen that starts with a sample of solid para-hydrogen (even-valued rotational quantum number j) having an entropy of 0.06 k B /molecule at 10 K and 2 atm, with Boltzmann constant k B . Starting with this low-entropy state, the sample is compressed using a small initial shock (<0.2 GPa), followed by a pressure ramp that approaches isentropic loading as the sample is taken to hundreds of GPa. Planar loading allows for quantitative compression measurements; the objective of our low-entropy compression is to keep the sample cold enough to characterize crystalline hydrogen toward the terapascal range.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
NASA NTRS1991

The 3D computation of single-expansion-ramp and scramjet nozzles

A description of the computations for three-dimensional nonaxisymmetric nozzles and an analysis of the flowfields are presented. Two different types of nozzles are investigated for compressible flows at high Reynolds numbers. These are the single-expansion-ramp and scramjet nozzles. The computation for the single-expansion-ramp nozzle focuses on the condition of low pressure ratio, which requires the simulation for turbulent flow that is not needed at high pressure ratios. The flowfield contains the external quiescent air, and the internal regions of subsonic and low supersonic flows. The second type is the scramjet nozzle, which typically has a very large area ratio and is designed to operate at high speeds and pressure ratios. The freestream external flow has a Mach number of 6, and the internal flow leaving the combustion chamber is at a Mach number of 1.62. The flowfield is mostly supersonic except in the viscous region near walls. The computed results from both cases are compared with experimental data for the surface pressure distributions.

Lai, H. T.↗