Coherent anti-Stokes Raman scattering thermometry and concentration measurements in Plasmatron X
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A computer program is described for simulating the vibration-rotation and pure rotational spectrum of a combustion system consisting of various diatomic molecules and CO2 as a function of temperature and number density. Two kinds of spectra are generated: a pure rotational spectrum for any mixture of diatomic and linear triatomic molecules, and a vibrational spectrum for diatomic molecules. The program is designed to accept independent rotational and vibrational temperatures for each molecule, as well as number densities.
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A type of high resolution XUV radiation source is described which is based upon spontaneous anti-Stokes scattering of tunable incident laser radiation from atoms excited to metastable levels. The theory of the source is summarized and two sets of experiments using He (1s2s)(1)S atoms, produced in a cw hollow cathode and in a pulsed high power microwave discharge, are discussed. The radiation source is used to examine transitions originating from the 3p(6) shell of potassium. The observed features include four previously unreported absorption lines and several sharp interferences of closely spaced autoionizing lines. A source linewidth of about 1.9 cm(-1) at 185,000 cm(-1) is demonstrated.
A type of high resolution XUV radiation source is described which is based upon spontaneous anti-Stokes scattering of tunable incident laser radiation from atoms excited to metastable levels. The theory of the source is summarized and two sets of experiments using He (1s2s)(1)S atoms, produced in a CW hollow cathode and in a pulsed high power microwave discharge, are discussed. The radiation source is used to examine transitions originating from the 3p(6) shell of potassium. The observed features include four previously unreported absorption lines and several sharp interferences of closely spaced autoionizing lines. A source linewidth of about 1.9 cm(-1) at 185,000 cm(-1) is demonstrated. Previously announced in STAR as N83-18422
A nonintrusive diagnostic system is described which permits simultaneous measurement of temperature, nitrogen number density, and oxygen number density in hostile combustion environments. This system is pumped by a 10-Hz neodymium YAG laser, and signals are detected with an intensified photodiode array and dual photomultipliers. The system utilizes a folded BOXCARS beam arrangement, two probe dye lasers, dynamic range expansion, polarization rejection of nonresonant background, and multiplexing of the signal beams.
The theory for third and higher harmonic plasma emission by the weak turbulence (or random phase) process L + T prime to T (where L denotes a Langmuir wave, and T and T prime denote transverse waves) is developed. Kinematic constraints on the characteristics and growth lengths of waves participating in the wave processes are identified. The cases of L waves produced either directly by a streaming instability, or by the decay L to L prime + S (S is an ion sound wave) of L waves generated by a streaming instability, are considered. Limits on the brightness temperature of the radiation are determined, and expressions for the growth rate and path-integrated wave temperatures are derived.
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The model describing three coupled quantum oscillators with decay of Rayleigh mode into the Stokes and vibration (phonon) modes is examined. Due to the Manley-Rowe relations the problem of exact eigenvalues and eigenstates is reduced to the calculation of new orthogonal polynomials defined both by the difference and differential equations. The quantum statistical properties are examined in the case when initially: the Stokes mode is in the vacuum state; the Rayleigh mode is in the number state; and the vibration mode is in the number of or squeezed states. The collapses and revivals are obtained for different initial conditions as well as the change in time the sub-Poisson distribution by the super-Poisson distribution and vice versa.
A method of examining a sample comprises exposing the sample to a pump pulse of electromagnetic radiation for a first period of time, exposing the sample to a stimulant pulse of electromagnetic radiation for a second period of time which overlaps in time with at least a portion of the first exposing, to produce a signal pulse of electromagnetic radiation for a third period of time, and interfering the signal pulse with a reference pulse of electromagnetic radiation, to determine which portions of the signal pulse were produced during the exposing of the sample to the stimulant pulse. The first and third periods of time are each greater than the second period of time.
Global mapping of terrestrial vegetation fluorescence from space has recently been accomplished with high spectral resolution measurements from the Japanese Greenhouse gases Observing SATellite (GOSAT). These data are of interest because they can potentially provide global information on the functional status of vegetation including light use efficiency and global primary productivity that can be used for global carbon cycle modeling. Quantifying the impact of fluorescence on the O2-A band is important as this band is used for cloud- and aerosol-characterization for other trace-gas retrievals including CO2. Here, we demonstrate that fluorescence information can be derived from space using potentially lower-cost hyperspectral instrumentation, i.e., more than an order of magnitude less spectral resolution than GOSAT, with a relatively simple algorithm. As a demonstration, we use the filling-in of one of the few wide and deep solar Fraunhofer lines in the red and far-red chlorophylla fluorescence bands, the calcium II line near 866 nm, to retrieve fluorescence with the SCanning Imaging Absorption spectroMeter for Atmospheric CHartographY (SCIAMACHY) satellite instrument. Although the signal from vegetation fluorescence is extremely weak at 866 nm, our results suggest that useful information may be obtained after adjustments are made to the observed spectra to correct for instrumental artifacts. We compare fluorescence from SCIAMACHY with that retrieved at 758 and 770 nm from similarly-corrected GOSAT data as well with the Enhanced Vegetation Index (EVI) from the MODerate-resolution Imaging Spectroradiometer (MODIS). We also show that filling-in occurs at 866 nm over barren areas, possibly originating from luminescent minerals in rock and soil.
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