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PbBr2 is Rutile structured and crystallizes in the tetragonal P4_2/mnm space group. The structure is three-dimensional. Pb2+ is bonded to six equivalent Br1- atoms to form a mixture of edge and corner-sharing PbBr6 octahedra. The corner-sharing octahedral tilt angles are 49°. All Pb–Br bond lengths are 3.06 Å. Br1- is bonded in a distorted trigonal planar geometry to three equivalent Pb2+ atoms.
PbCl2 is Rutile structured and crystallizes in the tetragonal P4_2/mnm space group. The structure is three-dimensional. Pb2+ is bonded to six equivalent Cl1- atoms to form a mixture of corner and edge-sharing PbCl6 octahedra. The corner-sharing octahedral tilt angles are 50°. There are two shorter (2.92 Å) and four longer (2.94 Å) Pb–Cl bond lengths. Cl1- is bonded in a distorted trigonal planar geometry to three equivalent Pb2+ atoms.
ICl2 is Rutile structured and crystallizes in the tetragonal P4_2/mnm space group. The structure is one-dimensional and consists of two ICl2 ribbons oriented in the (0, 0, 1) direction. I is bonded in a distorted rectangular see-saw-like geometry to four equivalent Cl atoms. All I–Cl bond lengths are 2.71 Å. Cl is bonded in a water-like geometry to two equivalent I atoms.
Hf2N is Rutile structured and crystallizes in the tetragonal P4_2/mnm space group. The structure is three-dimensional. Hf is bonded in a distorted T-shaped geometry to three equivalent N atoms. There are one shorter (2.23 Å) and two longer (2.25 Å) Hf–N bond lengths. N is bonded to six equivalent Hf atoms to form a mixture of edge and corner-sharing NHf6 octahedra. The corner-sharing octahedral tilt angles are 46°.
YbCl2 is Rutile structured and crystallizes in the tetragonal P4_2/mnm space group. The structure is three-dimensional. Yb2+ is bonded to six equivalent Cl1- atoms to form a mixture of edge and corner-sharing YbCl6 octahedra. The corner-sharing octahedral tilt angles are 49°. All Yb–Cl bond lengths are 2.74 Å. Cl1- is bonded in a distorted trigonal planar geometry to three equivalent Yb2+ atoms.
YbF2 is Rutile structured and crystallizes in the tetragonal P4_2/mnm space group. The structure is three-dimensional. Yb2+ is bonded to six equivalent F1- atoms to form a mixture of edge and corner-sharing YbF6 octahedra. The corner-sharing octahedral tilt angles are 51°. There are two shorter (2.23 Å) and four longer (2.25 Å) Yb–F bond lengths. F1- is bonded in a trigonal planar geometry to three equivalent Yb2+ atoms.
RhCl2 is Rutile structured and crystallizes in the tetragonal P4_2/mnm space group. The structure is three-dimensional. Rh is bonded to six equivalent Cl atoms to form a mixture of edge and corner-sharing RhCl6 octahedra. The corner-sharing octahedral tilt angles are 50°. There are two shorter (2.44 Å) and four longer (2.45 Å) Rh–Cl bond lengths. Cl is bonded in a distorted trigonal planar geometry to three equivalent Rh atoms.
PuCl2 is Rutile structured and crystallizes in the tetragonal P4_2/mnm space group. The structure is three-dimensional. Pu is bonded to six equivalent Cl atoms to form a mixture of edge and corner-sharing PuCl6 octahedra. The corner-sharing octahedral tilt angles are 46°. There are four shorter (2.84 Å) and two longer (2.85 Å) Pu–Cl bond lengths. Cl is bonded in a distorted T-shaped geometry to three equivalent Pu atoms.
PuI2 is Rutile structured and crystallizes in the tetragonal P4_2/mnm space group. The structure is three-dimensional. Pu is bonded to six equivalent I atoms to form a mixture of corner and edge-sharing PuI6 octahedra. The corner-sharing octahedral tilt angles are 45°. There are four shorter (3.21 Å) and two longer (3.25 Å) Pu–I bond lengths. I is bonded in a distorted T-shaped geometry to three equivalent Pu atoms.
SnBr2 is Rutile structured and crystallizes in the tetragonal P4_2/mnm space group. The structure is three-dimensional. Sn2+ is bonded to six equivalent Br1- atoms to form a mixture of corner and edge-sharing SnBr6 octahedra. The corner-sharing octahedral tilt angles are 48°. There are two shorter (3.00 Å) and four longer (3.02 Å) Sn–Br bond lengths. Br1- is bonded in a distorted trigonal planar geometry to three equivalent Sn2+ atoms.
WN2 is Rutile structured and crystallizes in the tetragonal P4_2/mnm space group. The structure is three-dimensional. W6+ is bonded to six equivalent N3- atoms to form a mixture of edge and corner-sharing WN6 octahedra. The corner-sharing octahedral tilt angles are 48°. There are four shorter (2.01 Å) and two longer (2.08 Å) W–N bond lengths. N3- is bonded in a distorted trigonal planar geometry to three equivalent W6+ atoms.
NiO2 is Rutile-like structured and crystallizes in the monoclinic Cm space group. The structure is three-dimensional. there are four inequivalent Ni4+ sites. In the first Ni4+ site, Ni4+ is bonded to six O2- atoms to form a mixture of corner and edge-sharing NiO6 octahedra. The corner-sharing octahedral tilt angles are 51°. There are a spread of Ni–O bond distances ranging from 1.86–1.89 Å. In the second Ni4+ site, Ni4+ is bonded to six O2- atoms to form a mixture of corner and edge-sharing NiO6 octahedra. The corner-sharing octahedral tilt angles are 51°. There are a spread of Ni–O bond distances ranging from 1.85–1.88 Å. In the third Ni4+ site, Ni4+ is bonded to six O2- atoms to form a mixture of corner and edge-sharing NiO6 octahedra. The corner-sharing octahedral tilt angles are 51°. There are a spread of Ni–O bond distances ranging from 1.85–1.88 Å. In the fourth Ni4+ site, Ni4+ is bonded to six O2- atoms to form a mixture of corner and edge-sharing NiO6 octahedra. The corner-sharing octahedral tilt angles are 51°. There are a spread of Ni–O bond distances ranging from 1.85–1.89 Å. There are eight inequivalent O2- sites. In the first O2- site, O2- is bonded in a distorted trigonal planar geometry to three Ni4+ atoms. In the second O2- site, O2- is bonded in a distorted trigonal planar geometry to three Ni4+ atoms. In the third O2- site, O2- is bonded in a distorted trigonal planar geometry to three Ni4+ atoms. In the fourth O2- site, O2- is bonded in a distorted trigonal planar geometry to three Ni4+ atoms. In the fifth O2- site, O2- is bonded in a 3-coordinate geometry to three Ni4+ atoms. In the sixth O2- site, O2- is bonded in a 3-coordinate geometry to three Ni4+ atoms. In the seventh O2- site, O2- is bonded in a 3-coordinate geometry to three Ni4+ atoms. In the eighth O2- site, O2- is bonded in a 3-coordinate geometry to three Ni4+ atoms.
FeO2 is Rutile-like structured and crystallizes in the triclinic P1 space group. The structure is three-dimensional. there are four inequivalent Fe sites. In the first Fe site, Fe is bonded to six O atoms to form a mixture of corner and edge-sharing FeO6 octahedra. The corner-sharing octahedral tilt angles are 50°. There are a spread of Fe–O bond distances ranging from 1.95–2.04 Å. In the second Fe site, Fe is bonded to six O atoms to form a mixture of corner and edge-sharing FeO6 octahedra. The corner-sharing octahedral tilt angles are 50°. There are a spread of Fe–O bond distances ranging from 1.94–2.04 Å. In the third Fe site, Fe is bonded to six O atoms to form a mixture of corner and edge-sharing FeO6 octahedra. The corner-sharing octahedral tilt angles are 50°. There are a spread of Fe–O bond distances ranging from 1.94–2.05 Å. In the fourth Fe site, Fe is bonded to six O atoms to form a mixture of corner and edge-sharing FeO6 octahedra. The corner-sharing octahedral tilt angles are 50°. There are a spread of Fe–O bond distances ranging from 1.95–2.04 Å. There are eight inequivalent O sites. In the first O site, O is bonded in a distorted trigonal planar geometry to three Fe atoms. In the second O site, O is bonded in a trigonal planar geometry to three Fe atoms. In the third O site, O is bonded in a distorted trigonal planar geometry to three Fe atoms. In the fourth O site, O is bonded in a distorted trigonal planar geometry to three Fe atoms. In the fifth O site, O is bonded in a distorted trigonal non-coplanar geometry to three Fe atoms. In the sixth O site, O is bonded in a distorted trigonal non-coplanar geometry to three Fe atoms. In the seventh O site, O is bonded in a distorted trigonal non-coplanar geometry to three Fe atoms. In the eighth O site, O is bonded in a distorted trigonal non-coplanar geometry to three Fe atoms.
Zr2N is Rutile structured and crystallizes in the tetragonal P4_2/mnm space group. The structure is three-dimensional. Zr is bonded in a distorted T-shaped geometry to three equivalent N atoms. There are one shorter (2.27 Å) and two longer (2.29 Å) Zr–N bond lengths. N is bonded to six equivalent Zr atoms to form a mixture of corner and edge-sharing NZr6 octahedra. The corner-sharing octahedral tilt angles are 47°.
CeSe2 is Rutile-like structured and crystallizes in the monoclinic C2/c space group. The structure is three-dimensional. there are two inequivalent Ce4+ sites. In the first Ce4+ site, Ce4+ is bonded to six Se2- atoms to form a mixture of corner and edge-sharing CeSe6 octahedra. The corner-sharing octahedra tilt angles range from 21–55°. There are a spread of Ce–Se bond distances ranging from 2.84–2.90 Å. In the second Ce4+ site, Ce4+ is bonded to six Se2- atoms to form a mixture of corner and edge-sharing CeSe6 octahedra. The corner-sharing octahedra tilt angles range from 48–55°. There are a spread of Ce–Se bond distances ranging from 2.85–2.89 Å. There are three inequivalent Se2- sites. In the first Se2- site, Se2- is bonded in a distorted trigonal planar geometry to three Ce4+ atoms. In the second Se2- site, Se2- is bonded in a distorted trigonal planar geometry to three Ce4+ atoms. In the third Se2- site, Se2- is bonded in a T-shaped geometry to three equivalent Ce4+ atoms.
EuBr2 is Rutile structured and crystallizes in the tetragonal P4_2/mnm space group. The structure is three-dimensional. Eu2+ is bonded to six equivalent Br1- atoms to form a mixture of edge and corner-sharing EuBr6 octahedra. The corner-sharing octahedral tilt angles are 49°. There are four shorter (3.05 Å) and two longer (3.06 Å) Eu–Br bond lengths. Br1- is bonded in a distorted trigonal planar geometry to three equivalent Eu2+ atoms.
Fe3TeO8 is Rutile-derived structured and crystallizes in the hexagonal P6_3mc space group. The structure is three-dimensional. Fe is bonded to six O atoms to form FeO6 octahedra that share corners with two equivalent TeO6 octahedra, an edgeedge with one TeO6 octahedra, and edges with four equivalent FeO6 octahedra. The corner-sharing octahedral tilt angles are 49°. There are a spread of Fe–O bond distances ranging from 1.91–2.07 Å. Te is bonded to six O atoms to form TeO6 octahedra that share corners with six equivalent FeO6 octahedra and edges with three equivalent FeO6 octahedra. The corner-sharing octahedral tilt angles are 49°. There is three shorter (1.95 Å) and three longer (1.98 Å) Te–O bond length. There are four inequivalent O sites. In the first O site, O is bonded in a distorted trigonal planar geometry to two equivalent Fe and one Te atom. In the second O site, O is bonded in a distorted T-shaped geometry to two equivalent Fe and one Te atom. In the third O site, O is bonded in a trigonal non-coplanar geometry to three equivalent Fe atoms. In the fourth O site, O is bonded in a trigonal non-coplanar geometry to three equivalent Fe atoms.
MgCd2 is Rutile structured and crystallizes in the tetragonal P4_2/mnm space group. The structure is three-dimensional. Mg is bonded to six equivalent Cd atoms to form a mixture of corner and edge-sharing MgCd6 octahedra. The corner-sharing octahedral tilt angles are 50°. There are two shorter (2.83 Å) and four longer (2.91 Å) Mg–Cd bond lengths. Cd is bonded in a distorted trigonal planar geometry to three equivalent Mg atoms.