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At least 235 records · Page 13

A Versatile Remediation Module for Remote Repair of Spent Nuclear Fuel and High-Level Waste Storage Containers

Oak Ridge National Laboratory (ORNL) successfully demonstrated the Versatile Remediation Module (VRM), a prototype module designed and built by ORNL for on-site remote repair of welded stainless steel storage containers for spent nuclear fuel and high-level radioactive waste. This paper describes the VRM prototype and its design features and components to support continued long-term storage or off-site transportation of spent nuclear fuel and high-level radioactive waste currently stored in storage containers. A remote (100 ft away from the simulated radiative environment) demonstration of the VRM was successfully performed on a full-scale mock-up welded stainless steel canister. The VRM is designed with features to accommodate remediation techniques beyond those currently selected and described in this paper. Therefore, many of the VRM’s features may benefit other remote nuclear or nonnuclear applications. The VRM is envisioned to serve as a development center to facilitate and enhance further development of new remediation technologies.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

Remediation strategy, capping construction and ongoing monitoring for the mill tailings pond, Ningyo-Toge uranium mine, Japan

Ningyo-toge Uranium Mine is subject to the environmental remediation. The main purposes are to take measures to ensure the radiation protection from the exposure pathways to humans in future, and to prevent the occurrence of mining pollution. The Yotsugi Mill Tailings Pond in the Ningyo-toge Uranium Mine has deposited mining waste and impounded water as a buffer reservoir before it is transferred to the Water Treatment Facility. It is located at the upstream of the water-source river and as the impact on its environment in case of earthquake is estimated significant, the highest priority has been put to it among mine-related facilities in the Mine. So far, basic concept has been examined and a great number of data has been acquired, and using the data, some remediation activities have already done, including capping construction for the upstream part of the Mill Tailings Pond. The capping is to reduce rainwater penetration to lower the burden of water treatment, and to reduce radon exhalation and dose rates. Only natural materials are used to alleviate the future maintenance. Data, including settlement amount and underground temperature is now being acquired and accumulated to verify the effectiveness of the capping, and used for the future remediation of the Downstream with revision of its specifications if necessary. (authors)

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

Brennilis decommissioning - the case of the treatment station and the discharge channel remediation

The site of the Monts d'Arree located in Brennilis in the area of Brittany in France is a former 70 MWe heavy water reactor, that was jointly operated by CEA and EDF from 1967 until 1985. It was an industrial prototype. EDF is now in charge of its decommissioning. This paper presents the management plan and the remediation objectives that were approved by the French Nuclear Authority for the channel remediation and the first studies carried out for the future Treatment Station remediation. (authors)

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Foam Delivery of Amendments for Vadose Zone Remediation – Propagation Performance in Unsaturated Sediments

Foam delivery of remedial amendments is potentially useful for vadose zone remediation because aqueous amendments are delivered while maintaining a low water content. The transport behavior of foam in the vadose zone is not well studied. Bench top scale column tests were conducted to investigate the foam transport, foaming gas and liquid propagation, pressure build up and distribution, influence of foam quality and sediment permeability on foam injection pressure, and liquid up-taking and distribution in sediments during foam flow in unsaturated sediments. Results indicated that under the unsaturated conditions, foaming gas front traveled much faster than the foam front where bubbles rupture was significant. A liquid front was formed ahead of the foam flow front. The accumulated liquid in this front was mainly composed of the water injected with foam. The foam injection pressure was mostly attributed to the resistance to foam flow from the sediment, but not to the movement of the water ahead of the foam front. Foam had a high effective viscosity compare to water. A near linear pressure distribution within the foam-occupied column section was observed. At fixed injection rate, higher foam quality resulted lower injection pressure. Higher permeability sediments did not necessarily have a lower foam injection pressure, as other factors such as the foam injection rate, foam bubble diameter, and sediment pore size also influenced the pressure. In the foam flushed region, the liquid uptake and the water content distribution in sediment was barely affected by the initial water content and the foam injection rate. The implications of these findings in field remediation application were discussed.

54 ENVIRONMENTAL SCIENCES↗

Summary Report of Laboratory Testing to Establish the Effectiveness of Proposed Treatment Methods for Unremediated and Remediated Nitrate Salt Waste Streams

The inadvertent creation of transuranic waste carrying hazardous waste codes D001 and D002 requires the treatment of the material to eliminate the hazardous characteristics and allow its eventual shipment and disposal at the Waste Isolation Pilot Plant (WIPP). This report documents the effectiveness of two treatment methods proposed to stabilize both the unremediated and remediated nitrate salt waste streams (UNS and RNS, respectively). The two technologies include the addition of zeolite (with and without the addition of water as a processing aid) and cementation. Surrogates were developed to evaluate both the solid and liquid fractions expected from parent waste containers, and both the solid and liquid fractions were tested. Both technologies are shown to be effective at eliminating the characteristic of ignitability (D001), and the addition of zeolite was determined to be effective at eliminating corrosivity (D002), with the preferred option1 of zeolite addition currently planned for implementation at the Waste Characterization, Reduction, and Repackaging Facility. During the course of this work, we established the need to evaluate and demonstrate the effectiveness of the proposed remedy for debris material, if required. The evaluation determined that Wypalls absorbed with saturated nitrate salt solutions exhibit the ignitability characteristic (all other expected debris is not classified as ignitable). Follow-on studies will be developed to demonstrate the effectiveness of stabilization for ignitable Wypall debris. Finally, liquid surrogates containing saturated nitrate salts did not exhibit the characteristic of ignitability in their pure form (those neutralized with Kolorsafe and mixed with sWheat did exhibit D001). As a result, additional nitrate salt solutions (those exhibiting the oxidizer characteristic) will be tested to demonstrate the effectiveness of the remedy.

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Mercury Remediation Technology Development for Lower East Fork Poplar Creek - FY 2015 Progress Report

Mercury remediation is a high priority for the US Department of Energy (DOE) Oak Ridge Office of Environmental Management (OREM) because of large historical losses of mercury within buildings and to soils and surface waters at the Y-12 National Security Complex (Y-12). Because of the extent of mercury losses and the complexities of mercury transport and fate in the downstream environment, the success of conventional options for mercury remediation in lower East Fork Poplar Creek (EFPC) is uncertain. A phased, adaptive management approach to remediation of surface water includes mercury treatment actions at Y-12 in the short-term and research and technology development (TD) to evaluate longer-term solutions in the downstream environment (US Department of Energy 2014b).

54 ENVIRONMENTAL SCIENCES↗

Emerging Technologies and Techniques for Wide Area Radiological Survey and Remediation

Technologies to survey and decontaminate wide-area contamination and process the subsequent radioactive waste have been developed and implemented following the Chernobyl nuclear power plant release and the breach of a radiological source resulting in contamination in Goiania, Brazil. These civilian examples of radioactive material releases provided some of the first examples of urban radiological remediation. Many emerging technologies have recently been developed and demonstrated in Japan following the release of radioactive cesium isotopes (Cs-134 and Cs-137) from the Fukushima Dai-ichi nuclear power plant in 2011. Information on technologies reported by several Japanese government agencies, such as the Japan Atomic Energy Agency (JAEA), the Ministry of the Environment (MOE) and the National Institute for Environmental Science (NIES), together with academic institutions and industry are summarized and compared to recently developed, deployed and available technologies in the United States. The technologies and techniques presented in this report may be deployed in response to a wide area contamination event in the United States. In some cases, additional research and testing is needed to adequately validate the technology effectiveness over wide areas. Survey techniques can be deployed on the ground or from the air, allowing a range of coverage rates and sensitivities. Survey technologies also include those useful in measuring decontamination progress and mapping contamination. Decontamination technologies and techniques range from non-destructive (e.g., high pressure washing) and minimally destructive (plowing), to fully destructive (surface removal or demolition). Waste minimization techniques can greatly impact the long-term environmental consequences and cost following remediation efforts. Recommendations on technical improvements to address technology gaps are presented together with observations on remediation in Japan.

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Effect of Co-Contaminants Uranium and Nitrate on Iodine Remediation

The objective of this study is to evaluate the significance of co-contaminants on the migration and transformation of iodine species in the Hanford subsurface environment. These impacts are relevant because remedies that target individual contaminants like iodine, may not only impact the fate and transport of other contaminants in the subsurface, but also inhibit the effectiveness of a targeted remedy. For example, iodine (as iodate) co-precipitates with calcite, and has been identified as a potential remedy because it immobilizes iodine. Since uranium also co-precipitates with calcite in field sediments, the presence of uranium may also inhibit iodine co-precipitation. Another potentially significant impact from co-existing contaminants is iodine and nitrate. The presence of nitrate has been shown to promote biogeochemical reduction of iodate to iodide, thereby increasing iodine species subsurface mobility (as iodide exhibits less sorption). Hence, this study reports on both laboratory batch and column experiments that investigated a) the change in iodate uptake mass and rate of uptake into precipitating calcite due to the presence of differing amounts of uranium, b) the amount of change of the iodate bio-reduction rate due to the presence of differing nitrate concentrations, and c) whether nitrite can reduce iodate in the presence of microbes and/or minerals acting as catalysts.

38 RADIATION CHEMISTRY, RADIOCHEMISTRY, AND NUCLEA↗

FIU Project 2: Environmental Remediation Science & Technology [Slides]

FIU’s research under this project involves conducting basic and applied science to fill knowledge gaps and validate potential remediation technologies for contaminated soil and groundwater and the assessment of the fate and transport of contaminants in the environment. The aim of FIU’s research is to reduce the potential for contaminant mobility or toxicity in the surface and subsurface through the development and application of state-of-the-art scientific and environmental remediation technologies at the Hanford Site, Savannah River Site (SRS), and the Waste Isolation Pilot Plant (WIPP), which is the Nation’s only mined geologic repository for permanent disposal of transuranic waste. FIU collaborates with scientists from Pacific Northwest National Laboratory (PNNL), Savannah River National Laboratory (SRNL), Savannah River Ecology Laboratory (SREL), Los Alamos National Laboratory (LANL) and the DOE Carlsbad Field Office (CBFO) in order to plan and execute research that is synergistic with the work being conducted at the sites, and that supports the resolution of critical science and engineering needs which leads to a better understanding of the long-term behavior of subsurface contaminants. The knowledge gained through this research will be used to transform experimental and modeling innovations into practical applications deployed at the sites to support EM’s primary goal of expediting the closure of major contaminated soil and groundwater sites and waste units. Collaborative relationships between FIU and the national laboratories have provided large benefits over the years to FIU, the national laboratories, the DOE complex, and the DOE EM mission. By working closely with the national laboratories, FIU’s research is not only closely aligned with the cleanup mission priorities at the DOE sites, but complements and supports ongoing work at the national laboratories for screening of new remedial technologies. This coordination and leveraging of research efforts results in time- and cost-savings, and will accelerate progress of the DOE EM environmental restoration mission.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Determining Appropriate Risk Remediation Thresholds from Empirical Conjunction Data Using Survival Probability Methods

Satellites sometimes maneuver before conjunctions to remediate the risk of an on-orbit collision. Many missions use probability of collision (P(sub c)) thresholds to decide when such maneuvers should be performed. These thresholds tend to be conservative because of policies that require satellites survive their lifetimes without collision with high confidence (e.g., 99.9%). This study presents a semi-empirical method to estimate remediation P(sub c) thresholds that satisfy such lifetime risk requirements. The formulation combines survival probability analysis with empirical conjunction histories to estimate remediation thresholds as a function of satellite size, remaining on-orbit duration, lifetime collision probability limit, collision consequence, and other parameters.

Risk remediation thresholds↗

Determining Appropriate Risk Remediation Thresholds from Empirical Conjunction Data Using Survival Probability Methods

Satellites sometimes maneuver before conjunctions to remediate the risk of an on-orbit collision. Many missions use probability of collision (P_c) thresholds to decide when such maneuvers should be performed. These thresholds tend to be conservative because of policies that require satellites survive their lifetimes without collision with high confidence (e.g., 99.9%). This study presents a semi-empirical method to estimate remediation P_c thresholds that satisfy such lifetime risk requirements. The formulation combines survival probability analysis with empirical conjunction histories to estimate remediation thresholds as a function of satellite size, remaining on-orbit duration, lifetime collision probability limit, collision consequence, and other parameters.

Risk Remediation↗

The Office of Groundwater & Soil Remediation Fiscal Year 2011 Research & Development Program

The U.S. Department of Energy's (DOE) Office of Groundwater and Soil Remediation supports technology development and technical assistance for the remediation of environments contaminated by legacy nuclear waste. The core of the program is centered on delivering proactive, responsive expertise and technologies with highly-leveraged, carefully selected investments that maximum impact on life-cycle cleanup costs and risks across the DOE complex. The program currently focuses on four main priorities: improved sampling and characterization strategies, advanced predictive capabilities, enhanced remediation methods, and improved long-term performance evaluation and monitoring. In FY 2010, the program developed a detailed research and development (R and D) plan in support of a larger initiative to integrate R and D efforts across EM. This paper provides an overview of the priority action areas and the program's near-term technical direction.

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Treatment of Bottled Liquid Waste During Remediation of the Hanford 618-10 Burial Ground - 13001

A problematic waste form encountered during remediation of the Hanford Site 618-10 burial ground consists of bottled aqueous waste potentially contaminated with regulated metals. The liquid waste requires stabilization prior to landfill disposal. Prior remediation activities at other Hanford burial grounds resulted in a standard process for sampling and analyzing liquid waste using manual methods. Due to the highly dispersible characteristics of alpha contamination, and the potential for shock sensitive chemicals, a different method for bottle processing was needed for the 618-10 burial ground. Discussions with the United States Department of Energy (DOE) and United States Environmental Protection Agency (EPA) led to development of a modified approach. The modified approach involves treatment of liquid waste in bottles, up to one gallon per bottle, in a tray or box within the excavation of the remediation site. Bottles are placed in the box, covered with soil and fixative, crushed, and mixed with a Portland cement grout. The potential hazards of the liquid waste preclude sampling prior to treatment. Post treatment verification sampling is performed to demonstrate compliance with land disposal restrictions and disposal facility acceptance criteria. (authors)

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Protecting Lake Ontario - Treating Wastewater from the Remediated Low-Level Radioactive Waste Management Facility - 13227

The Port Granby Project is part of the larger Port Hope Area Initiative, a community-based program for the development and implementation of a safe, local, long-term management solution for historic low level radioactive waste (LLRW) and marginally contaminated soils (MCS). The Port Granby Project involves the relocation and remediation of up to 0.45 million cubic metres of such waste from the current Port Granby Waste Management Facility located in the Municipality of Clarington, Ontario, adjacent to the shoreline of Lake Ontario. The waste material will be transferred to a new suitably engineered Long-Term Waste Management Facility (LTWMF) to be located inland approximately 700 m from the existing site. The development of the LTWMF will include construction and commissioning of a new Wastewater Treatment Plant (WWTP) designed to treat wastewater consisting of contaminated surface run off and leachate generated during the site remediation process at the Port Granby Waste Management Facility as well as long-term leachate generated at the new LTWMF. Numerous factors will influence the variable wastewater flow rates and influent loads to the new WWTP during remediation. The treatment processes will be comprised of equalization to minimize impacts from hydraulic peaks, fine screening, membrane bioreactor technology, and reverse osmosis. The residuals treatment will comprise of lime precipitation, thickening, dewatering, evaporation and drying. The distribution of the concentration of uranium and radium - 226 over the various process streams in the WWTP was estimated. This information was used to assess potential worker exposure to radioactivity in the various process areas. A mass balance approach was used to assess the distribution of uranium and radium - 226, by applying individual contaminant removal rates for each process element of the WTP, based on pilot scale results and experience-based assumptions. The mass balance calculations were repeated for various flow and load scenarios. (authors)

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Maximizing Operational Efficiencies in Waste Management on the Hanford Plateau Remediation Contract in a Down-turned Market - 13484

Recent changes in DOE priorities and funding have pressed DOE and its contractors to look for innovative methods to sustain critical operations at sites across the Complex. At the Hanford Site, DOE Richland Operations and its prime contractor, CH2M Hill Plateau Remediation Company (CHPRC), have completed in-depth assessments of the Plateau Remediation Contract (PRC) operations that compared available funding to mission and operational objectives in an effort to maintain requisite safety and compliance margins while realizing cost savings that meet funding profiles. These assessments included confirmation of current baseline activities, identification of potential efficiencies, barriers to implementation, and potential increased risks associated with implementation. Six operating PRC waste management facilities were evaluated against three possible end-states: complete facility closure, maintaining base operations, and performing minimum safe surveillance and maintenance activities. The costs to completely close evaluated facilities were determined to be prohibitively high and this end-state was quickly dropped from consideration. A summary of the analysis of remaining options by facility, efficiencies identified, impact to risk profiles, and expected cost savings is provided in Table I. The expected cost savings are a result of: - right-sizing and cross-training work crews to address maintenance activities across facilities; - combining and sequencing 'like-moded' operational processes; - cross-cutting emergency planning and preparedness staffing; - resource redistribution and optimization; - reducing areas requiring routine surveillance and inspection. For the efficiencies identified, there are corresponding increases in risk, including a loss of breadth and depth of available resources; lengthened response time to emergent issues; inability to invest in opportunities for improvement (OFIs); potential single-point failures or non-compliancies due to resource scarcity; limited cross-training capability; and reduced capability to respond to changes in DOE priorities. Finally, there are many challenges to achieving these cost savings. With a workforce nearing retirement effective succession planning becomes critical to success and requires establishing a balance between the cost of hiring and training and cost-saving activities. With six active waste management facilities spread across nearly 15 square miles, scheduling and deploying cross-trained surveillance and maintenance teams is a logistical challenge, particularly as the loss of funding has not diminished emphasis by regulatory agencies placed on the safe and compliant performance of DOE and its contractors. As reflected in Table I, efficiencies are currently being implemented on the Hanford Plateau Remediation Contract (PRC) that deliver cost savings that align with the current site budget while maintaining critical capabilities. It is currently estimated that these efficiencies will result in a cost savings of approximately $9 million for FY13 in base and minimum safe operations on the PRC - a cost reduction of more than 13 percent over FY12 and nearly 30 percent over FY09 levels. (authors)

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Facility Utilization and Risk Analysis for Remediation of Legacy Transuranic Waste at the Savannah River Site - 13572

Savannah River Nuclear Solutions (SRNS) completed the Accelerated TRU Project for remediating legacy waste at the Savannah River Site with significant cost and schedule efficiencies due to early identification of resources and utilization of risk matrices. Initial project planning included identification of existing facilities that could be modified to meet the technical requirements needed for repackaging and remediating the waste. The project schedule was then optimized by utilization of risk matrices that identified alternate strategies and parallel processing paths which drove the overall success of the project. Early completion of the Accelerated TRU Project allowed SRNS to pursue stretch goals associated with remediating very difficult TRU waste such as concrete casks from the hot cells in the Savannah River National Laboratory. Project planning for stretch goals also utilized existing facilities and the risk matrices. The Accelerated TRU project and stretch goals were funded under the American Recovery and Reinvestment Act (ARRA). (authors)

54 ENVIRONMENTAL SCIENCES↗

Remedial Investigation of Hanford Site Releases to the Columbia River - 13603

In south-central Washington State, the Columbia River flows through the U.S. Department of Energy Hanford Site. A primary objective of the Hanford Site cleanup mission is protection of the Columbia River, through remediation of contaminated soil and groundwater that resulted from its weapons production mission. Within the Columbia River system, surface water, sediment, and biota samples related to potential Hanford Site hazardous substance releases have been collected since the start of Hanford operations. The impacts from release of Hanford Site radioactive substances to the Columbia River in areas upstream, within, and downstream of the Hanford Site boundary have been previously investigated as mandated by the U.S. Department of Energy requirements under the Atomic Energy Act. The Remedial Investigation Work Plan for Hanford Site Releases to the Columbia River [1] was issued in 2008 to initiate assessment of the impacts under the Comprehensive Environmental Response, Compensation, and Liability Act of 1980 [2]. The work plan established a phased approach to characterize contaminants, assess current risks, and determine whether or not there is a need for any cleanup actions. Field investigation activities over a 120-mile stretch of the Columbia River began in October 2008 and were completed in 2010. Sampled media included surface water, pore water, surface and core sediment, island soil, and fish (carp, walleye, whitefish, sucker, small-mouth bass, and sturgeon). Information and sample results from the field investigation were used to characterize current conditions within the Columbia River and assess whether current conditions posed a risk to ecological or human receptors that would merit additional study or response actions under CERCLA. The human health and ecological risk assessments are documented in reports that were published in 2012 [3, 4]. Conclusions from the risk assessment reports are being summarized and integrated with remedial investigation/feasibility study (RI/FS) reports developed for upland areas, riparian areas, and groundwater in the Hanford Site River Corridor. The RI/FS reports will evaluate the impacts to soil, groundwater, and river sediments and lead to proposed cleanup actions and records of decision to address releases from the Hanford Site reactor operations. (authors)

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Development of Preliminary Remediation Goals for Indoor Dust at the Colonie FUSRAP Site - 12273

The Colonie FUSRAP Site is located in the Town of Colonie, Albany County, New York. The U.S. Army Corps of Engineers is currently addressing environmental contamination associated with the Site under the Comprehensive Environmental Response, Compensation and Liability Act (CERCLA) process as part of the Formerly Utilized Sites Remedial Action Program (FUSRAP). Soil remediation activities have been substantially completed at the Colonie FUSRAP Site and its vicinity properties under the FUSRAP. A study unrelated to FUSRAP was recently performed by an independent party to establish the distribution of DU contamination in various media in the environs of the Site. As part of this study, dust samples were collected in residencies and businesses in the immediate vicinity of the Site. These samples were collected in non-living areas such as basement window sills and garages. Many of these samples tested positive for DU. An assessment was performed to establish preliminary remediation goals (PRGs) for indoor dust in non-living areas of residential homes and businesses in the vicinity of the Site. The results of this assessment provide estimates of dose-based, carcinogenic risk-based, and noncarcinogenic-based PRGs derived from a hypothetical exposure scenario with reasonable levels of conservatism. Ultimately, the PRGs will be compared to results of dust sampling and analyses in residences and businesses in proximity of the Site to determine whether a response action is appropriate. This assessment estimates PRGs for DU contaminated dust in non-living areas of residences in the vicinity of the Colonie FUSRAP site based on a reasonably conservative exposure scenario. Estimated PRGs based on residential receptors are considered to be conservatively representative of workers in nearby businesses based on the considerably longer exposure duration of residents relative to workers. This assessment provides reasonably conservative estimates of PRGs for DU contaminated dust in non-living areas within residences in the vicinity of the Site. It should be noted that the PRGs include hypothetical exposures resulting from activities in both the living areas and non-living areas of a residence. The PRGs are derived and presented in terms of DU dust concentration in non-living areas to facilitate comparison to results of a planned Site Investigation that will characterize concentrations of DU in dust in non-living areas. It is important to recognize that the exposure assumptions used to derive these PRGs are based on average dust DU concentrations in non-living areas. It is inappropriate to compare these PRGs to the dust DU concentration in an isolated small area. The ongoing Site Investigation addresses this consideration and is designed to provide reasonable estimates of average dust DU concentrations in non-living areas of vicinity properties. In order to accomplish this, sampling is conducted in accordance with EPA Guidance for the Sampling and Analysis of Lead in Indoor Residential Dust for Use in the Integrated Exposure Uptake Biokinetic (IEUBK) Model, (EPA 2008), which specifically addresses estimating average contaminant concentrations in dust. Four (4) large-area samples are collected from each VP in accordance with this guidance. It is anticipated that the results of the Site Investigation will be used in conjunction with the results of this assessment, and/or subsequent assessments, to establish whether or not a response action is appropriate. (authors)

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