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At least 235 records · Page 13

Synthesis of greigite (Fe 3 S 4 ) particles via a hydrothermal method

Greigite (Fe 3 S 4 ) particles, with strong ferrimagnetic behavior, have been found to have desirable uses in the areas of biomedical and environmental applications. Size-dependent magnetic properties of greigite can play a crucial role in efficiency of its applications. This study reviews two synthetic approaches to producing such particles. The methods tested within this study include a coprecipitation synthesis and a hydrothermal process. While the coprecipitation method proved to be ineffective at producing greigite, the hydrothermal process showed promise after consistently producing greigite. For the hydrothermal process, the effects of synthesis time, autoclave atmosphere, and polyvinylpyrrolidone (PVP) addition as a capping agent to control particle growth were investigated using X-ray diffractometry (XRD) with Rietveld refinement, vibrating sample magnetometry (VSM), and scanning electron microscopy (SEM). The results show that, while pyrite (FeS2) forms as an impurity phase, increasing the synthesis time up to 18 hours increases the greigite fraction up to 70 wt% and saturation magnetization up to ~ 35 emu/g for the powder synthesized in argon. The SEM micrographs of this sample reveal a mean greigite particle size of ~ 700 nm. It was found that adding PVP brings about a much more uniform microstructure of agglomerated plate-shape particles with nano-sized features.

36 MATERIALS SCIENCE↗

Assessing changes in US regional precipitation on multiple time scales

We estimate trends in US regional precipitation on multiple time spans and scales relevant to the detection of changes in climatic regimes. A large literature has shown that trend estimation in hydrological series may be affected by long-term persistence (LTP) and selection of sample length. We show that 2000-year proxy-based reconstructions of the Palmer Modified Drought Index for the US Southeast (SE) and Pacific Coast (PC) regions exhibit LTP and reveal post- 1900 changes to be within the range of longer-term natural fluctuations. We also use a new data base of daily precipitation records for 20 locations (10 PC and 10 SE) extending back in many cases to the 1870s. Over the 1901–2017 interval upward trends in some measures of average and extreme precipitation appear, but they are not consistently significant and in the full records back to 1872 they largely disappear. Furthermore, they also disappear or reverse in the post-1978 portion of the data set, which is inconsistent with them being responses to enhanced greenhouse gas forcing. We conclude that natural variability is likely the dominant driver of historical changes in precipitation and hence drought dynamics in the US SE and PC.

54 ENVIRONMENTAL SCIENCES↗

Microstructure and mechanical properties of high Mn-containing ferritic-martensitic alloys exposed to cyclical thermal treatment

Substantial residual tensile stress tends to accumulate in currently available high-Cr ferritic martensitic steels that are subjected to cyclical heat treatment, which leads to premature brittle fracture. By tailoring the alloy composition, this thermal cycling can be exploited to induce a high number density of nanoprecipitates and phase transformations countering residual tensile stresses. In this work, three new variants of ferritic-martensitic steels have been designed with computational thermodynamics to meet the goals of mitigating residual tensile stresses by lowering martensite start temperatures and of enhancing mechanical strength and irradiation sink strength by increasing the number density of nanoprecipitates. Furthermore, ctenast materials were subjected to cyclical heat treatment. The thermally cycled samples were evaluated with mechanical testing and microstructural analysis to identify the optimal composition in which figures of merit include low residual stress and a high density of nanoscale MX (M = metal, X = C/N) precipitates, leading to high yield strength with reasonable ductility. The noticeably higher density of nanoprecipitates in the optimal alloy favor its higher yield strength, which is supported by the microstructure-derived yield strength calculation and precipitation kinetics simulation.

36 MATERIALS SCIENCE↗

Evaluation of Modeled Precipitation in Oceanic Extratropical Cyclones Using IMERG

Using a high-spatial- and high-temporal-resolution precipitation dataset, Integrated Multi-satellite Retrievals for GPM (IMERG), extratropical cyclone precipitation is evaluated in two reanalyses and two climate models. Based on cyclone-centered composites, all four models overestimate precipitation in the western subsiding and dry side of the cyclones, and underestimate the precipitation in the eastern ascending and moist side. By decomposing the composites into frequency of occurrence and intensity (mean precipitation rate when precipitating), the analysis reveals a tendency for all four models to overestimate frequency and underestimate intensity, with the former issue dominating in the western half and the latter in the eastern half of the cyclones. Differences in frequency are strongly dependent on cyclone environmental moisture, while the differences in intensity are strongly impacted by the strength of ascent within the cyclone. There are some uncertainties associated with the observations: IMERG might underreport frozen precipitation and possibly exaggerate rates in vigorously ascending regions. Nevertheless, the analysis suggests that all models produce extratropical cyclone precipitation too often and too lightly. These biases have consequences when evaluating the changes in precipitation characteristics with changes in cyclone properties: the models disagree on the magnitude of the change in precipitation intensity with a change in environmental moisture and in precipitation frequency with a change in cyclone strength. This complicates accurate predictions of precipitation changes in a changing climate.

54 ENVIRONMENTAL SCIENCES↗

Estimation of Surface Sensible Heat Flux due to Precipitation over CONUS and Its Impact on Urban Extreme Precipitation Modeling

The surface sensible heat flux induced by precipitation (Q P ) is a consequence of the temperature difference between the surface and the rain droplets. Despite its seemingly negligible nature, Q P is frequently omitted from both meteorological and climatological models. Nevertheless, it is important to acknowledge the numerous occasions in which the instantaneous values of Q P can be significant, particularly during extreme precipitation events. This study undertakes a comprehensive assessment of Q P across the contiguous United States (CONUS) utilizing high-resolution reanalysis, observational data, and numerical modeling to examine the influence of Q P on precipitation and the surface energy budget. The findings indicate that the spatial distribution of Q P climatology is analogous to that of precipitation, with magnitudes ranging from 2 to 3 W m -2 predominantly over the Midwest and Southeast regions. A seasonal analysis of QP reveals that the highest values occurring during the June–August (JJA) period, averaging 3.18 W m -2 . Peak Q P values of approximately 4 W m -2 are observed during JJA over the Great Plains region. We hypothesize that the Q P during an extreme precipitation event would be nonnegligible and have a significant impact on the local weather. To test this conjecture, we perform high-resolution simulations with and without Q P during an extreme precipitation event over the Chicago Metropolitan Area (CMA). The results show that the Q P may be a dominant factor compared to other components of surface heat flux during the zenith of precipitation hours. Also, Q P has the potential to not only diminish precipitation but also alter and reconfigure the remaining surface energy budget components.

54 ENVIRONMENTAL SCIENCES↗

Design studies of large aperture, high-resolution Earth science microwave radiometers compatible with small launch vehicles

High-spatial-resolution microwave radiometer sensing from space with reasonable swath widths and revisit times favors large aperture systems. However, with traditional precision antenna design, the size and weight requirements for such systems are in conflict with the need to emphasize small launch vehicles. This paper describes tradeoffs between the science requirements, basic operational parameters, and expected sensor performance for selected satellite radiometer concepts utilizing novel lightweight compactly packaged real apertures. Antenna, feed, and radiometer subsystem design and calibration are presented. Preliminary results show that novel lightweight real aperture coupled with state-of-the-art radiometer designs are compatible with small launch systems, and hold promise for high-resolution earth science measurements of sea ice, precipitation, soil moisture, sea surface temperature, and ocean wind speeds.

Schroeder, Lyle C.↗

Successes with the Global Precipitation Measurement (GPM) Mission

Water is essential to our planet Earth. Knowing when, where and how precipitation falls is crucial for understanding the linkages between the Earth's water and energy cycles and is extraordinarily important for sustaining life on our planet during climate change. The Global Precipitation Measurement (GPM) Core Observatory spacecraft launched February 27, 2014, is the anchor to the GPM international satellite mission to unify and advance precipitation measurements from a constellation of research and operational sensors to provide "next-generation" precipitation products. GPM is currently a partnership between NASA and the Japan Aerospace Exploration Agency (JAXA). Status and successes in terms of spacecraft, instruments, retrieval products, validation, and impacts for science and society will be presented. Precipitation, microwave, satellite

microwave↗

IMERG V06: Changes to the Morphing Algorithm

As the US Science Team’s globally gridded precipitation product from the NASA/JAXA Global Precipitation Measurement (GPM) mission, the Integrated Multi-satellitE Retrievals for GPM (IMERG) estimates the surface precipitation rates at 0.1° every half-hour using spaceborne sensors for various scientific and societal applications. One key component of IMERG is the morphing algorithm, which uses motion vectors to perform quasi-Lagrangian interpolation to fill in gaps in the passive microwave precipitation field using motion vectors. Up to IMERG V05, the motion vectors were derived from the large-scale motions of infrared observations of cloud tops. This study details the changes introduced in IMERG V06 to derive motion vectors from large-scale motions of selected atmospheric variables in numerical models, which allow IMERG estimates to be extended from the 60°N/S latitude band to the entire globe. Evaluation against both instantaneous passive microwave retrievals and ground measurements demonstrates the general improvement in the precipitation field of the new approach. Most of the model variables tested exhibited similar performance, but total precipitable water vapor was chosen as the source of the motion vectors for IMERG V06 due to its competitive performance and global completeness. Continuing assessments will provide further insights into possible refinements of this revised morphing scheme in future versions of IMERG.

Jackson Tan↗

GPM Constellation Reconfiguration and Mission Status

The Global Precipitation Measurement (GPM) Mission is an international satellite mission that uses combined active and passive remote sensing techniques to improve global precipitation measurements derived from dedicated and operational passive microwave sensors. GPM is a science mission with integrated applications goals to (1) advance the knowledge of precipitation physics and the global water cycle variability, and (2) improve weather, climate, and hydrological prediction capabilities through more accurate and frequent measurements of global precipitation and innovative application methods. The GPM Mission is currently a partnership between NASA and the Japan Aerospace Exploration Agency (JAXA), with opportunities for additional domestic and international partners in satellite constellation buildup and ground validation activities. The GPM concept is centered on employing a dualfrequency precipitation radar and a microwave radiometer with high-frequency capabilities on a core satellite to serve as a physics observatory and calibration standard to provide a consistent framework for unifying precipitation measurements from a heterogeneous constellation of passive microwave sensors. Building on the siccess of TRMM, GPM extends combined radadradiometer precipitation measurements into the mid and high latitudes, with new science foci on improved capabilities for light-rain and snowfall measurements, as well as more accurate precipitation retrievals over land. With recent studies indicating that AMSU-B rainfall estimates are comparable in quality to those derived from conically-scanning radiometers over land, it is envisioned that cross-track microwave sounders with high-frequency channels on operational satellites such as the National Polar-orbiting Operational Environmental Satellite System (NPOESS), NPOESS Preparatory Project (NPP), NOAA-N', and MetOp satellites can play a significant role in augmenting conically-scanning microwave radiometers to achieve better sampling and coverage over land. Plans to reconfigure the baseline GPM constellation to include cross-track microwave sounders over land and the status of other GPM mission elements such as snowfall algorithm development and ground validation plans will be presented

Hou, Arthur Y.↗

The Atmosphere Observing System (AOS): Synergistic Aerosol, Cloud, Convection and Precipitation Measurement and Modeling Systems

The 2017 Decadal Survey (DS) highlighted Earth System Science themes, science and application questions, and several high priority objectives that have led to the inclusion of Aerosols (A) and Clouds-Convection-Precipitation (CCP) as Designated Observables (DOs). On June 1, 2018, several NASA centers (GSFC, LaRC, JPL, MSFC, GRC and ARC) submitted a joint Study Plan to the NASA Earth Science Division for the Aerosol (A) and Cloud, Convection, and Precipitation (CCP) Pre-formulation Study (ACCP), with the ACCP Study concluding in early 2021. The new mission now in pre-phase A is being referred to as the Atmosphere Observing System (AOS), an integral part of NASA’s Earth System Observatory (ESO) strategy. The DS and the ACCP team recognized the science merit in combining the A and CCP DOs for both enhancing the ability to address a number of science objectives and also to provide an expanded capability to address additional objectives beyond those of the individual DOs. A critical element of the ACCP observing strategy is to make extensive use of new passive and active sensors as well as of the so-called Program-of-Record (PoR), complemented by a fully integrated sub-orbital component. In order to achieve maximum benefit, all these observations need to be integrated into comprehensive observing and modeling/data assimilation systems. Such an approach requires comprehensive model-data synthesis capabilities that needs to be conceived in conjunction with the space-based and suborbital components of AOS. In this presentation we will summarize the major science goals of AOS including cloud feedbacks, atmospheric convection, emphasizing aerosol processes and aerosol radiative effects, and the synergistic aspects of clouds-precipitation-aerosol interactions. We will describe examples of how AOS data will be used across space and time to better initialize forecasts and train modeling systems, and to infuse models and data assimilation systems with AOS data for advancing operational predictions and to generate expanded hindcasts and reconstruction of the climate record.

Arlindo da Silva↗

Irradiation-induced nano-voids in strained tin precipitates in silicon

We report on self-assembling of spherically shaped voids in nanometer size strained Sn precipitates after irradiation with He{sup +} ions in different conditions. It is found that high-temperature irradiation induces vacancies which are collected by compressively strained Sn precipitates enhancing of out-diffusion of Sn atoms from the precipitates. Nano-voids formation takes place simultaneously with a β- to α-phase transformation in the Sn precipitates. Post-irradiation thermal treatment leads to the removal of voids and a backward transformation of the Sn phase to β-phase. Strain-enhanced separation of point defects along with vacancy assisted Sn out-diffusion and precipitate dissolution are discussed.

36 MATERIALS SCIENCE↗

An Update on Global Satellite-Based Precipitation Products and Services at NASA GES DISC

The NASA Goddard Earth Sciences Data and Information Services Center (GES DISC) is home to major NASA satellite precipitation measurement missions including the Tropical Rainfall Measuring Mission (TRMM) and the Global Precipitation Measurement (GPM) as well as other NASA projects. Accurate and timely available global and regional precipitation products play an important role in research and applications around the world. The GES DISC provides near-real-time, near-global precipitation products (e.g.IMERG) to support a wide variety of interdisciplinary research and operational activities including flood modeling, landslides, crop monitoring and assessment, vector-borne diseases, etc. Climate data record products (e.g.GPCP3) are essential for climate research, assessment, model evaluation and applications. To facilitate data access and exploration, the GES DISC has developed data services such asGiovanni, an online visualization and analysis tool for easy access to over 2000 satellite- and model-based variables. Established in the mid 1980s, the GES DISC also distributes data in other disciplines including hydrology, atmospheric chemistry, atmospheric dynamics, etc. In this presentation, we will present an update on global precipitation products and data services including the new IMERG V06B suite, the latest version of GPCP (Version 3) and value-added data subsetting services (L34RS, L2S).

Liu, Zhong↗

GPM Data Products, Their Availability, and Production Status

On February 28, 2014, Japan Standard Time, the Global Precipitation Measurement (GPM) mission was launched in a picture-perfect launch activity. On March 4, 2014, the GPM Microwave Imager (GMI) was put into science observation mode. The Dual-Frequency Radar (DPR) was put in science observation mode on March 8, 2014. The Precipitation Processing System (PPS) produced products immediately upon receiving the data. Both regular science products and Near-realtime (NRT) products were produced. These were made immediately available to a group of early adopters. In mid-June 2014, GMI level-1 brightness temperature products were made publicly available. In mid-July 2014, GMI and partner-radiometer precipitation retrievals were made public. GMI public availability was several months ahead of the planned release. The DPR products became publicly available on the planned release date of September 2, 2014. Data continues to be available to any user desiring it.

Data Products↗

Deep Neural Network High Spatiotemporal Resolution Precipitation Estimation (Deep-STEP) Using Passive Microwave and Infrared Data

Recent developments in “headline-making” deep neural networks (DNNs), specifically convolutional neural networks (CNNs), along with advancements in computational power, open great opportunities to integrate massive amounts of real-time observations to characterize spatiotemporal structures of surface precipitation. This study aims to develop a CNN algorithm, named Deep Neural Network High Spatiotemporal Resolution Precipitation Estimation (Deep-STEP), that ingests direct satellite passive microwave (PMW) brightness temperatures (Tbs) at emission and scattering frequencies combined with infrared (IR) Tbs from geostationary satellites and surface information to automatically extract geospatial features related to the precipitable clouds. These features allow the end-to-end Deep-STEP algorithm to instantaneously map surface precipitation intensities with a spatial resolution of 4 km. The main advantages of Deep-STEP, as compared to current state-of-the-art techniques, are 1) it learns and estimates complex precipitation systems directly from raw measurements in near–real time, 2) it uses the automatic spatial neighborhood feature extraction approach, and 3) it fuses coarse-resolution PMW footprints with IR images to reliably retrieve surface precipitation at a high spatial resolution. We anticipate our proposed DNN algorithm to be a starting point for more sophisticated and efficient precipitation retrieval systems in terms of accuracy, fine spatial pattern detection skills, and computational costs.

54 ENVIRONMENTAL SCIENCES↗