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High-performance eco-friendly all-polymer solar cells were realized by balancing the crystallinity and domain size via hot halogen-free solvent slot-die coating.
Empirical measurements of solution vapor pressure of ternary acetonitrile (MeCN) H 2 O–NaCl–MeCN mixtures were recorded, with NaCl concentrations ranging from zero to the saturation limit, and MeCN concentrations ranging from zero to an absolute mole fraction of 0.64. After accounting for speciation, the variability of the Henry's law coefficient at vapor–liquid equilibrium (VLE) of MeCN ternary mixtures decreased from 107% to 5.1%. Solute speciation was modeled using a mass action solution model that incorporates solute solvation and ion-pairing phenomena. Two empirically determined equilibrium constants corresponding to solute dissociation and ion pairing were utilized for each solute. When speciation effects were considered, the solid–liquid equilibrium of H 2 O–NaCl–MeCN mixtures appear to be governed by a simple saturation equilibrium constant that is consistent with the binary H 2 O–NaCl saturation coefficient. Further, our results indicate that the precipitation of NaCl in the MeCN ternary mixtures was not governed by changes in the dielectric constant. Our model indicates that the compositions of the salt-induced liquid–liquid equilibrium (LLE) boundary of the H 2 O–NaCl–MeCN mixture correspond to the binary plateau activity of MeCN, a range of concentrations over which the activity remains largely invariant in the binary water–MeCN system. Broader comparisons with other ternary miscible organic solvent (MOS) mixtures suggest that salt-induced liquid–liquid equilibrium exists if: (1) the solution displays a positive deviation from the ideal limits governed by Raoult's law; and (2) the minimum of the mixing free energy profile for the binary water-MOS system is organic-rich. Finally, this work is one of the first applications of speciation-based solution models to a ternary system, and the first that includes an organic solute.
Controlling the morphology of organic solar cells (OSCs) presents a significant challenge due to their complex structure and composition.
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Apollo 11 lunar rock K, Rb, Sr, Ba and rare earth element concentrations, examining relationship to terrestrial and chondritic levels
Apollo 12 lunar soils, rocks and core samples, determining rare earth, alkali and alkaline earth elements concentrations
In space, a replacement must be found for gravity to physically control and, in certain instances, contain cryogenic liquids. A program has been started at the Jet Propulsion Laboratory to study the use of electric field generated forces to establish the required orienting effects. Measurements which show that it is possible to apply strong enough electric fields to a liquid/vapor interface of He-4 to obtain an orienting force comparable to gravity are presented. Our measurements span the temperature range 1.7-4.2 K and demonstrate the applicability of Pashen's law for maximum attainable field before breakdown occurs. Some advantages of the electric field separator as opposed to passive surface tension devices are identified.
The results of molecular-dynamics studies of surface-tension-dominated spinodal decomposition of initially well-mixed binary fluids in the absence and presence of gravity are presented. The growth exponent for the domain size and the decay exponent of the potential energy of interaction between the two species with time are found to be 0.6 +/- 0.1, inconsistent with scaling arguments based on dimensional analysis.
The Crab and the Vela pulsars were observed to emit pulsed radiation in the radio, optical, X-ray and gamma ray windows of the electromagnetic spectrum. In all cases the emission appears in two peaks, except in the case of radio emission from the Vela pulsar which is single peaked. With accurate peak position determinations made possible by recent observations, it is interesting to see if the intra-peak separations at various wavelengths across the electromagnetic spectrum bear any relation to each other. We report here an emerging trend of a monotonic decrease of the intra-peak separation with energy. The rate of decrease is faster in the case of the Vela pulsar than in that of the Crab pulsar. Even the case of single peaked radio emission by the Vela pulsar can be viewed as being consistent with this trend. These trends provide both an opportunity and a challenge to realistic modelings of pulsed emissions by these objects.