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At least 235 records · Page 13
All sourcesNASA NTRSDOE OSTI
DOE OSTI2020

Braiding Majorana fermions and creating quantum logic gates with vortices on a periodic pinning structure

We show how vortices that support Majorana fermions when placed on a periodic pinning array can be used for vortex exchange and independent braiding by performing a series of specific moves with a probe tip. Using these braiding operations, we demonstrate realizations of a Hadamard and a CNOT gate. We specifically consider the first matching field at which there is one vortex per pinning site, and we show that there are two basic dynamic operations, move and exchange, from which basic braiding operations can be constructed in order to create specific logic gates. The periodic pinning array permits both control of the world lines of the vortices and freedom for vortex manipulation using a set of specific moves of the probe during which the probe tip strength and height remain unchanged. We measure the robustness of the different moves against thermal effects and show that the three different operations produce distinct force signatures on the moving tip.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
DOE OSTI2021

Effect of correlated oxide electrodes on disorder pinning and thermal roughening of ferroelectric domain walls in epitaxial PbZr 0.2 Ti 0.8 O 3 thin films

We report the competing effects of disorder pinning and thermal roughening on ferroelectric domain walls as a function of temperature in epitaxial PbZr 0.2 Ti 0.8 O 3 thin films deposited on (001) SrTiO 3 substrates buffered by three types of correlated oxide electrodes, La 0.67 Sr 0.33 MnO 3 , LaNiO 3 , and SrIrO 3 . Piezo-response force microscopy studies show that the 50 nm PbZr 0.2 Ti 0.8 O 3 films are uniformly polarized in the as-grown states, with the patterned domain structures persisting above 700 °C. For all three types of films, the domain wall roughness is dominated by 2D random bond disorder at room temperature, and transitions to 1D thermal roughening upon heating. The roughness exponent ζ increases progressively from 0.3 to 0.5 within a temperature window that depends on the bottom conducting oxide type, from which we extracted the distribution of disorder pinning energy. Lastly, we discuss the possible origins of the disorder pinning and the effect of the correlated oxide electrodes on the energy landscape of DW motion.

36 MATERIALS SCIENCE↗
DOE OSTI2021

Pinning Characteristics of Zr and Hf- Added REBCO Coated Conductors Made by Advanced MOCVD in Low-to-High Magnetic Fields

BaMO 3 (M=Zr, Hf) pinning centers introduced in REBa 2 Cu 3 O 7-x (REBCO and RE = rare earth) coated conductors yield superior performance in high magnetic fields. We present the critical current density J c over a temperature range of 4.2-77 K and magnetic fields of 0-14 T (B || c-axis), of 5-15 mol.% Zr- and Hf-added REBCO 4+ μm thick film tapes fabricated by advanced metal organic chemical vapor deposition (A-MOCVD). The morphology of self-assembled BMO nanorods aligned along c-axis is found to be dependent on the Zr/Hf content. We also observe a correlation between the density of RE 2 O 3 in-plane nano-precipitates and the continuity and concentration of BMO nanorods in films of different Ba content. It is found that the (Ba+M)/Cu (M=Zr, Hf) content in REBa 2 Cu 3 O 7-x affects the shape of pinning force density curves over a wide magnetic field range and temperatures below 20 K. Another remarkable observation is the similarity in the critical current properties of Hf and Zr -added REBCO films as function of (Ba+M)/Cu content at intermediate to high range of (Ba+M)/Cu content. As a result, a quantitative analysis of pinning efficiency and correlation with the microstructure of Zr and Hf- added REBCO coated conductors is discussed.

2G high-temperature superconductor (2G-HTS)↗
DOE OSTI2019

Crystal Structure of VapBC-1 from Nontypeable Haemophilus influenzae and the Effect of PIN Domain Mutations on Survival during Infection

Toxin-antitoxin (TA) gene pairs have been identified in nearly all bacterial genomes sequenced to date and are thought to facilitate persistence and antibiotic tolerance. TA loci are classified into various types based upon the characteristics of their antitoxins, with those in type II expressing proteic antitoxins. Many toxins from type II modules are ribonucleases that maintain a PilT N-terminal (PIN) domain containing conserved amino acids considered essential for activity. The vapBC ( v irulence- a ssociated p rotein) TA system is the largest subfamily in this class and has been linked to pathogenesis of nontypeable Haemophilus influenzae (NTHi). In this study reported here, the crystal structure of the VapBC-1 complex from NTHi was determined to 2.20 Å resolution. Based on this structure, aspartate-to-asparagine and glutamate-to-glutamine mutations of four conserved residues in the PIN domain of the VapC-1 toxin were constructed and the effects of the mutations on protein-protein interactions, growth of Escherichia coli , and pathogenesis ex vivo were tested. Finally, a novel model system was designed and utilized that consists of an NTHi Δ vapBC-1 strain complemented in cis with the TA module containing a mutated or wild-type toxin at an ectopic site on the chromosome. This enabled the analysis of the effect of PIN domain toxin mutants in tandem with their wild-type antitoxin under the control of the vapBC-1 native promoter and in single copy. This is the first report of a system facilitating the study of TA mutant operons in the background of NTHi during infections of primary human tissues ex vivo .

59 BASIC BIOLOGICAL SCIENCES↗
DOE OSTI2016

The application of MAMMOTH for a detailed tightly coupled fuel pin simulation with a station blackout

The accurate calculation of desired quantities to predict fuel behavior in a nuclear reactor requires the solution of inter linked equations representing different physics phenomena. Traditional fuels performance codes often rely on internal empirical models for the pin power density and a simplified boundary condition on the cladding outer surface. These simplifications are performed because of the difficulty of coupling applications or codes on differing domains and mapping the required data. In this work the MAMMOTH application is employed in the demonstration of an approach that more consistent with first principles, in a simulation that couples the neutronics application Rattlesnake, the thermal fluids application RELAP-7 and the fuels performance application BISON. A single fuel pin was modeled based on the dimensions of a fuel rod from a Westinghouse 17*17 optimized PWR fuel assembly. The simulation consisted of a depletion period of 1343 days, representing three full operating cycles, followed by a station blackout (SBO) event. The fuel rod was depleted with a total pin power of 65.81 kW. After 1343 days the fission power was reduced to zero (simulating a reactor shutdown). Decay heat calculations provided the time-varying energy source after this time. For this problem, Rattlesnake, BISON, and RELAP-7 are coupled under MAMMOTH in a tightly coupled approach. Each system solves its physics on a separate mesh and, for RELAP-7 and BISON, on only a subset of the full problem domain. Rattlesnake solves the neutronics over the whole domain, which includes the fuel, cladding, gaps, water, and top and bottom rod holders. Here BISON is applied to the fuel and cladding with a 2-D axisymmetric domain, and RELAP-7 is applied to the flow of the circular outer water channel with a set of 1-D flow equations. For this work, the mesh on the Rattlesnake side is either be 3-D (for low order PN transport or diffusion) or 2-D axisymmetric (for diffusion). BISON has a matching ring structure mesh for the fuel so both the power density and local burnup are transferred accurately from Rattlesnake. At each depletion time step, Rattlesnake calculates a power density, fission density rate, burnup distribution and fast flux based on the current water density and fuel temperature. These are then mapped to the BISON mesh to perform a fuels performance solution. BISON calculates the fuel temperature and cladding surface temperature based upon the current power density and bulk fluid temperature. RELAP-7 then calculates the fluid temperature, water density fraction and water phase velocity based upon the cladding surface temperature. The fuel temperature and the fluid density are then passed back to Rattlesnake for another neutronics calculation. For this paper, sets of results from the detailed calculation are provided for both depletion and the SBO event. We demonstrate that a detailed simulation akin to first principles can be achieved using MAMMOTH and the various MOOSE application on differing domains. (authors)

21 SPECIFIC NUCLEAR REACTORS AND ASSOCIATED PLANTS↗
DOE OSTI2016

Comparison of Subdivided Versus Full-Length Fuel Pin Burnup in the ATF-2 Safety Analysis

The Accident Tolerant Fuels (ATF) campaign, under the Fuel Cycle Research and Development (FCRD) Advanced Fuels program, was developed after the Fukushima Daiichi Nuclear Power Plant disaster in 2011. Under ATF, fuel and cladding concepts are to be developed and tested that may more readily withstand an accident similar to the one that occurred at Fukushima Daiichi. ATF is a combination of industry, universities, and national laboratories in an effort to develop advanced accident tolerant cladding and fuel concepts. The end goal of the ATF program is to insert a lead test rod (LTR) or lead test assembly (LTA) into an operating commercial power light water reactor by 2022. In order to meet this 2022 insertion goal, ATF is split into three separate phases: ATF-1, ATF-2, and ATF-3. The first phase of the ATF program, ATF-1, is the concept feasibility study and early irradiation testing. Feasibility, fabrication, and out-of-pile testing are happening at universities and laboratories all over the United States. Irradiation testing of these concepts is happening at the Advanced Test Reactor (ATR) at the Idaho National Laboratory (INL). Early irradiation testing involves testing clad and/or fuel in drop-in capsules in the ATR. Currently, these capsules are in the relatively low-flux positions in the ATR, but some newer concepts and concepts that require higher burnup will be moved to the higher-flux positions later on during irradiation. Currently, Oak Ridge National Laboratory (ORNL), Westinghouse Electric Company, Areva, and General Electric (GE) have inserted capsules for ATF-1, although more concepts are planned. The second phase of ATF, ATF-2, is the focus of this paper. ATF-2 is the loop testing of fuel pins with new cladding and fuel concepts to simulate pressurized water reactor (PWR) and boiling water reactor (BWR) environments. ATF-2 will concurrently be happening at the ATR and at the Halden Reactor in Norway. The ATF-2 irradiation at the ATR will only simulate a PWR environment. ATF-2 will be inserted into the ATR pressurized water loop, Loop 2A, in the Center Flux Trap (CFT), where chemistry, temperature, and pressure can all be controlled separately from the primary coolant system and other loops in ATR. Loop 2A will be borated, pressurized to 2200 psi nominal, and have an average water temperature of 300 deg. C. A borated loop with fueled rodlets is extremely rare for Nuclear Energy experiments in the ATR, so ATF-2 will demonstrate new and unique capabilities for INL. ATF-3 is the testing of fresh and irradiated ATF concepts at the Transient Reactor Test (TREAT) Facility. The TREAT Reactor is planned for restart, re-establishing U.S. transient testing capabilities after nearly 20 years of non-operations. TREAT will test ATF concepts under transient conditions, such as a reactivity insertion accident. In addition to fresh fuel pins, TREAT will use from ATF2 and do transient testing on those irradiated pins. The information TREAT will provide to the vendors to support fuel licensing will be valuable, showing that these concepts do enhance the accident tolerance of the fuel in commercial reactors. (author)

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗
DOE OSTI2014

Capillary pinning and blunting of immiscible gravity currents in porous media

Gravity-driven flows in the subsurface have attracted recent interest in the context of geological carbon dioxide (CO 2 ) storage, where supercritical CO 2 is captured from the flue gas of power plants and injected underground into deep saline aquifers. After injection, the CO 2 will spread and migrate as a buoyant gravity current relative to the denser, ambient brine. Although the CO 2 and the brine are immiscible, the impact of capillarity on CO 2 spreading and migration is poorly understood. We previously studied the early time evolution of an immiscible gravity current, showing that capillary pressure hysteresis pins a portion of the macroscopic fluid–fluid interface and that this can eventually stop the flow. Here we study the full lifetime of such a gravity current. Using tabletop experiments in packings of glass beads, we show that the horizontal extent of the pinned region grows with time and that this is ultimately responsible for limiting the migration of the current to a finite distance. We also find that capillarity blunts the leading edge of the current, which contributes to further limiting the migration distance. Using experiments in etched micromodels, we show that the thickness of the blunted nose is controlled by the distribution of pore–throat sizes and the strength of capillarity relative to buoyancy. We develop a theoretical model that captures the evolution of immiscible gravity currents and predicts the maximum migration distance. By applying this model to representative aquifers, we show that capillary pinning and blunting can exert an important control on gravity currents in the context of geological CO 2 storage.

58 GEOSCIENCES↗
DOE OSTI2018

Comparison of the Microstructure and Flux Pinning Properties of Polycrystalline YBa{sub 2}Cu{sub 3}O{sub 7-d} Containing Zn{sub 0.95}Mn{sub 0.05}O or Al{sub 2}O{sub 3} Nanoparticles

Here we compare the microstructure and flux pinning properties of polycrystalline YBa{sub 2}Cu{sub 3}O{sub 7-d} (Y-123 or YBCO) containing either Al{sub 2}O{sub 3} or Zn{sub 0.95}Mn{sub 0.05}O nanoparticles. Samples were prepared using a standard solid-state reaction process, and nanoparticles were added up to a concentration of 0.1 wt%. The crystal structure, microstructure, electrical and magnetic properties were analyzed using X-ray diffraction, scanning electron microscopy and transmission electron microscopy (TEM), and electrical resistivity and DC magnetization measurements, respectively. TEM observations showed that the addition of Zn{sub 0.95}Mn{sub 0.05}O resulted in a high density of fine twins and a variety of interacting microstructures, while Al{sub 2}O{sub 3} addition resulted in a high density of Al-rich nanoscale inhomogeneities embedded in the Y-123 matrix. Flux pinning forces were determined, and predominant pinning mechanisms in the prepared samples were proposed. We evaluated the superconducting properties of YBCO considering the effects of adding insulating or magnetic nanoparticles.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
DOE OSTI2018

Angular-Dependent Vortex Pinning Properties of YBa{sub 2}Cu{sub 3}O{sub 7−δ}/Y{sub 2}O{sub 3} Quasi-Multilayers

A series of quasi-multilayers of YBa{sub 2}Cu{sub 3}O{sub 7−δ} (YBCO)/Y{sub 2}O{sub 3} specifically 70 × (m YBCO/n Y{sub 2}O{sub 3}) were prepared on SrTiO{sub 3} single crystal using pulsed-laser deposition (PLD) with a controlled deposition pulses of m = 40 and n = 2, 5, and 10 for YBCO and Y{sub 2}O{sub 3}, respectively. The x-ray diffraction patterns indicate that all the present quasi-multilayers exhibit good c-axis orientation. The angular dependence of critical current density (J{sub c}) on applied magnetic field directions are systemically measured to study the anisotropic vortex pinning performances for those quasi-multilayers. It is revealed that compared with the pure YBCO films, the quasi-multilayers with n = 2, i.e., a proper constituent pulse of Y{sub 2}O{sub 3}, exhibits the enhanced vortex pinning abilities in all angles between c-axis orientation and the applied magnetic field direction. As well, such a quasi-multilayer film (n = 2) shows the higher lift factor J{sub c}(Θ)/ J{sub c}(90°) and much better vortex pinning properties at high fields and high temperatures, showing promising potential for coated conductor application.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
DOE OSTI2018

Solving macroscopic and microscopic pin-fin heat sink problems by adapted spectral method

In this paper, simulation of heat transfer in a heat sink with macroscopic and microscopic scales when one pin-fin is added to the system is investigated by the proposed spectral method. In the microscopic problems, heat transfer model uses dual-phase lag formulas in contrast with macroscopic problems when Fourier law is used to formulate the governing equation. In macroscopic problem, the results are compared with COMSOL multiphysics software results and a good agreement between the results are shown. In microscopic problems, 3D Gaussian heat source is used and boundary conditions obey the Newton law. Comparisons show the efficiency of the current method, while the results are compared with existed literature. It is shown that: by adding one pin fin to the heat sink problem, temperature of the system will decrease. Numerical results are given and graphs of the temperature for various kinds of pin-fin heat sink problems are depicted.

97 MATHEMATICS AND COMPUTING↗
DOE OSTI2024

Optimization-Inspired Pin-Fin Array for Supercritical Carbon Dioxide Recuperator

Additively manufactured heat exchangers are one possible route to cost-effective sCO 2 power cycles. In this paper, experimental results are obtained for two helical pin fin tubes that were designed following parametric optimization of the fin array. Neither the numerical optimization nor the experimental testing have been previously reported in the literature. The two tube designs were, (1) the optimization inspired design, and (2) the optimization-inspired design with a fin diameter increased by a factor of 2. To characterize the print, the designs were scanned using X-ray computed tomography to measure feature sizes and heat transfer area. The optimization was conducted in a commercial, computational fluid dynamics code. The code solved the Reynolds Averaged Navier-Stokes (RANS) and energy equations with turbulence closure provided by the shear stress transport (SST) k-ω model. In the experiments, the Nusselt number augmentation was measured using the Wilson plot technique and the friction factor was determined with mass flow and pressure drop measurements. The experimental testing indicated that the optimization-inspired design had a friction factor that was four times less than the baseline tube design at equal Nusselt number. Additionally, the optimization-inspired design had a 14% improvement in Nusselt number, at equal friction factor, relative to the best performing computational fluid dynamics (CFD) trial points. Tube design (2), with the larger diameter pin fins, had similar performance, within experimental error, as the tube with the smaller diameter pin fins (1). Both tubes achieved overall fin array efficiencies near 1. A performance factor, V/V 0 , equal to the volume of the enhanced heat exchanger divided by the volume of the baseline (no-fins) heat exchanger, is recommended to quantify internal cooling performance. In conclusion, the experimental shell and tube heat exchanger, using the additively manufactured tube, is competitive with printed circuit heat exchangers in its pressure drop class and could be further improved by optimizing a shell-and-tube heat exchanger utilizing this heat transfer enhancement feature.

42 ENGINEERING↗
DOE OSTI2026

Ultra-low thermal resistance and pressure drop copper and copper-tungsten diamond-shaped pin fin cold plates for liquid cooling of electronics

Modern and future data centers face increasing cooling challenges due to increasing chip thermal design power and die size, along with the need to reduce energy consumption used for cooling. High performance cooling solutions that maintain a low chip junction temperature are needed to ensure electronics reliability. This work develops an ultra-low thermal resistance and low pressure drop 75 mm × 75 mm cold plate, intended for next-generation electronics cooling. The cold plate features an array of diamond-shaped pin fins and integrated copper tungsten heat spreader, selected for its low coefficient of thermal expansion which reduces thermomechanical deformation and allows for closer integration of the cold plate with silicon dies. Starting with 300 candidate designs, three-dimensional computational fluid dynamics simulations predict the thermal-hydraulic performance of cold plate subsections. The highest performing geometries are evaluated with high fidelity simulations. Four cold plates are manufactured for experiments: three with diamond-shaped pin fins and one with straights fins for comparison purposes. The cold plates are fabricated from copper-tungsten (CuW), copper (Cu), or aluminum-silicon-magnesium alloy (AlSi10Mg). The diamond-shaped pin fins achieve a roughly 15 % lower thermal resistance compared to the conventional straight fin microchannel. The highest performing design achieves a chip-to-coolant (including thermal interface material) thermal resistance of 9.0 K/kW in CuW and 6.9 K/kW in Cu under a 1 kW heat load with an inlet-to-outlet pressure drop of 9.0 kPa and water as the working fluid. This work demonstrates ultra-low thermal resistance and pressure drop cold plates for large die, high heat load applications, and shows that CuW is an attractive cold plate material for improved reliability in next generation data center cooling.

Coefficient of thermal expansion↗
DOE OSTI2020

Characterization of a minor actinides bearing metallic fuel pin irradiated in EBR-II

The X501 transmutation experiment irradiated in Experimental Breeder Reactor II (EBR-II) was intended to evaluate the safety and performance of the addition of minor actinides (Am, Np) into the metallic nuclear fuel system. The irradiation of this experiment is also of paramount importance for comparisons between true fast spectrum irradiations (e.g. EBR-II) and shrouded irradiation capsules performed at the thermal neutron spectrum Idaho National Laboratory Advanced Test Reactor. The X501 experimental fuel pins were irradiated to a peak measured burnup of 6.2% fission per initial heavy metal atom. This paper reports and discusses Postirradiation Examination results for one of two minor actinide bearing pins from the EBR-II X-501 experiment (X501-G591) with a focus on fuel microstructure evolution. Additionally, fuel swelling, fission product distribution, cladding strain, fission gas release, fuel microstructure and fuel cladding chemical interaction were all evaluated. The fission gas release was 79.9% and the microstructure along the fuel pin presented several characteristics very similar to other EBR-II U-Pu-Zr ternary metallic fuel experience. Minor actinides seem to not dramatically affect the overall performance of this candidate transmutation fuel. Scanning Electron Microscopy was also performed and an in-depth characterization of the different regions and phases is presented. Performance data from these irradiations can be used to inform the feasibility of minor actinide transmutation in future reactor systems.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗
DOE OSTI2014

Local structure around the flux pinning centers in superconducting niobium silicon oxynitride (Nb{sub 0.87}Si{sub 0.09}□{sub 0.04})(N{sub 0.87}O{sub 0.13})

The superconducting transition temperature of niobium silicon oxynitride (Nb{sub 0.87}Si{sub 0.09}□{sub 0.04})(N{sub 0.87}O{sub 0.13}) exhibits a gradual reduction from 16.8 K to around 11 K under an increasing applied magnetic field of up to 14 T. This relatively small T{sub c} reduction under an applied magnetic field suggests a robustness of its superconducting behavior in comparison to that in the parent niobium oxynitride. It was similar to the flux pinning effect observed in the large magnetic hysteresis of the niobium-silicon oxynitrides in our previous study. Both Si K-edge XANES and {sup 29}Si MAS-NMR indicated that the local structure of pinning centers around the silicon atoms close to cationic vacancies was similar to that of Si in amorphous SiO{sub 2} in the rock-salt structure of niobium oxynitride. - Graphical abstract: Potential energy scan of the Si atom in the most stable Si{sub 3}□O{sub 3}N cube around the vacancy in our preliminary simulation on niobium silicon oxynitride (Nb{sub 0.87}Si{sub 0.09}□{sub 0.04})(N{sub 0.87}O{sub 0.13}). A possible distortion of the Si atom was suggested from its octahedral towards tetrahedral position forming the local structure similar to that in amorphous SiO{sub 2}. Display Omitted - Highlights: • Critical current density was enhanced in superconducting niobium oxynitride. • The robustness was introduced by forming rock-salt type niobium silicon oxynitride. • The silicon atom had a local structure similar to that in amorphous SiO{sub 2} in the rock-salt type lattice. • The local structure was formed together with its neighboring cationic vacancy. • It contributed as the flux pinning center in the NbSiNO.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2021

Initial demonstration of automated fuel performance modeling with 1977 EBR-II metallic fuel pins using BISON code with FIPD and IMIS databases

Using the BISON fuel performance code, simulations were conducted using an automated process to read initial and operating conditions from the Fuels Irradiation and Physics Database (FIPD) and Integral Fast Reactor materials information system (IMIS) database, which contains metallic fuel data from the Experimental Breeder Reactor-II (EBR-II). This work demonstrates use of an integrated framework to access the vast majority of EBR-II experimental fuel pin data to support rapid development of fuel performance models for next-generation metallic fuel systems. With this capability, validation for fuel qualification can be performed rapidly. Between IMIS and FIPD, there is enough information to conduct 1977 unique EBR-II metallic fuel pin histories from 24 different experiments, at varying levels of detail between the two databases. Each of these histories includes a high-resolution power history, flux history, coolant channel flow rates, and coolant channel temperatures. Fission gas release (FGR), cumulative damage fraction (CDF), fuel axial swelling, cladding profilometry, and burnup were all simulated in BISON. The results were compared to post-irradiation examination (PIE) results for the initial demonstration of automated BISON modeling. BISON simulations conducted with IMIS and FIPD were in rough agreement with PIE measurements and calculations. Cladding profilometry, FGR, and fuel axial swelling were found to be in rough agreement with PIE measurements, depending on the physics used within the BISON input files. Here, the mechanical contact solver chosen was found to significantly impact axial fuel swelling and cladding strain predictions. CDF values were assessed to see whether pin failure may have been predicted (CDF ≥ 1). This work suggests that continued development of an automated tool for BISON should focus on inclusion of the Fast Flux Test Facility (FFTF) experimental data for a larger database for metallic fuel, improved physical models to better capture fuel performance, such as fuel-cladding interactions, and a more detailed comparison with available PIE data to further the BISON model development.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗
DOE OSTI2021

Spin pinning effect to reconstructed oxyhydroxide layer on ferromagnetic oxides for enhanced water oxidation

Producing hydrogen by water electrolysis suffers from the kinetic barriers in the oxygen evolution reaction (OER) that limits the overall efficiency. With spin-dependent kinetics in OER, to manipulate the spin ordering of ferromagnetic OER catalysts (e.g., by magnetization) can reduce the kinetic barrier. However, most active OER catalysts are not ferromagnetic, which makes the spin manipulation challenging. In this work, we report a strategy with spin pinning effect to make the spins in paramagnetic oxyhydroxides more aligned for higher intrinsic OER activity. The spin pinning effect is established in oxideFM/oxyhydroxide interface which is realized by a controlled surface reconstruction of ferromagnetic oxides. Under spin pinning, simple magnetization further increases the spin alignment and thus the OER activity, which validates the spin effect in rate-limiting OER step. The spin polarization in OER highly relies on oxyl radicals (O∙) created by 1 st dehydrogenation to reduce the barrier for subsequent O-O coupling.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2019

Edge effect pinning in mesoscopic superconducting strips with non-uniform distribution of defects

Transport characteristics of nano-sized superconducting strips and bridges are determined by an intricate interplay of surface and bulk pinning. In the limiting case of a very narrow bridge, the critical current is mostly defined by its surface barrier, while in the opposite case of very wide strips it is dominated by its bulk pinning properties. Here we present a detailed study of the intermediate regime, where the critical current is determined, both, by randomly placed pinning centres and by the Bean-Livingston barrier at the edge of the superconducting strip in an external magnetic field. We use the time-dependent Ginzburg-Landau equations to describe the vortex dynamics and current distribution in the critical regime. Our studies reveal that while the bulk defects arrest vortex motion away from the edges, defects in their close vicinity promote vortex penetration, thus suppressing the critical current. We determine the spatial distribution of the defects optimizing the critical current and find that it is in general non-uniform and asymmetric: the barrier at the vortex-exit edge influence the critical current much stronger than the vortex-entrance edge. Furthermore, this optimized defect distribution has a more than 30% higher critical current density than a homogeneously disorder superconducting film.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
DOE OSTI2014

Simple physics of the partly pinned fluid systems

In this paper, we consider some aspects of the physics of the partly pinned (PP) systems obtained by freezing in place particles in equilibrium bulk fluid configurations in the normal (nonglassy) state. We first discuss the configurational overlap and the disconnected density correlation functions, both in the homogeneous and heterogeneous cases, using the tools of the theory of adsorption in disordered porous solids. The relevant Ornstein-Zernike equations are derived, and asymptotic results valid in the regime where the perturbation due to the pinning process is small are obtained. Second, we consider the homogeneous PP lattice gas as a means to make contact between pinning processes in particle and spin systems and show that it can be straightforwardly mapped onto a random field Ising model with a strongly asymmetric bimodal distribution of the field. Possible implications of these results for studies of the glass transition based on PP systems are also discussed.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗