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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 235 records · Page 13
All sourcesNASA NTRSDOE OSTI
DOE OSTI2018

Hybrid 0D–2D black phosphorus quantum dots–graphitic carbon nitride nanosheets for efficient hydrogen evolution

As an emerging post-graphene two-dimensional (2D) nanomaterial, black phosphorus (BP) is attracting a great deal of current attention for the direct conversion of solar energy into solar fuels on account of its unique tunable direct-bandgap and high charge-carrier mobility. Herein, for the first time, we immobilize BP quantum dots (BPQDs) onto graphitic carbon nitride (g-C 3 N 4 ) nanosheets to create a 0D-2D inorganic-organic hybrid via a conventional and cost–effective sonication approach. The as-prepared BPQDs/g-C 3 N 4 hybrids display BPQD content-dependent performance in visible-light-driven hydrogen generation. 5 wt% BPQDs/g-C 3 N 4 with cyclability exhibits the greatest hydrogen evolution rate of 271 μmol h-1 g-1 that is 5.6 and 4.2 times greater than that of pristine g-C 3 N 4 and BPQDs, respectively. We demonstrate that the type-II band alignment, the formation of phosphorus–carbon bonds and the efficient interfacial charge separation between well-dispersed BPQDs and g-C 3 N 4 synergetically enhance the photoactivity and photostability. In conclusion, this study opens possibilities to create viable BP-based heterostructures for energy conversion and storage.

36 MATERIALS SCIENCE↗
DOE OSTI2025

Soft X-ray Emission Spectroscopy of Phosphorus Compounds for Energy Conversion and Storage

Phosphorus (P) is a ubiquitous component of materials for energy conversion and storage. Despite the effectiveness of soft X-ray emission spectroscopy (XES) to characterize these complex materials, XES studies of P-containing compounds are still largely missing. In this investigation, the electronic structure and XES signatures from the P L 2,3 -edge are probed for nine solid-state P-containing compounds characterized by various oxidation states and chemical environments: GaP (3−) , InP (3−) , red-P (0) , H 3 P (3+) O 3 , Na 2 H 2 P 2 (4+) O 6 , H 3 P (5+) O 4 , KH 2 P (5+) O 4 , Na 2 HP (5+) O 4 , and InP (5+) O 4 . The XES spectrum of each material exhibits distinct spectral fingerprints, which provide a robust basis for the speciation of complex P-containing samples. Density functional theory calculations shed light on the electronic structure of selected materials and particularly on the effect of phosphorus-oxygen hybridization. This study provides a comprehensive understanding of P L 2,3 XES spectral fingerprints across a wide range of oxidation states and chemical environments. These data sets and insights pave the way for dedicated future work, such as in situ and operando investigations of P-containing compounds in energy-related applications, where speciation of P compounds is needed.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2024

Vibrational Fermi Resonance in Atomically Thin Black Phosphorus

Fermi resonance is a phenomenon involving the hybridization of two coincidentally quasi-degenerate states that is observed in the vibrational or electronic spectra of molecules. Despite numerous examples in molecular systems, vibrational Fermi resonances in dispersive semiconducting systems remain largely unexplored due to the rarity of occurrence. Here we report a vibrational Fermi resonance in atomically thin black phosphorus. The Fermi resonance arises via anharmonic mixing of a fundamental Raman mode and a Davydov component of an infrared mode, leading to a doublet with mixed character. The extent of Fermi coupling can be modulated by the application of external biaxial strain. The consequences of Fermi hybridization are revealed by electronic resonance effects in the thickness-dependent and excitation-wavelength-dependent Raman spectrum, which is predicted by ab initio hybrid functional simulations including excitonic interactions. This work reveals new insight into electron–phonon coupling in black phosphorus and demonstrates a novel method for modulating Fermi resonances in 2D semiconductors.

74 ATOMIC AND MOLECULAR PHYSICS↗
DOE OSTI2020

Structural and Thermoelectric Properties of Black Arsenic–Phosphorus

Here, we report the structural and temperature dependent transport properties of As x P 1-x (x = 0, 0.2, 0.5, 0.83, 1) alloys. It is observed that black phosphorous (BP)-related phonon modes in the alloy samples are red-shifted with increasing arsenic concentration, while black arsenic-related modes in these samples are blue-shifted with increasing phosphorus concertation. As the arsenic concentration, x increases from 0 to 1, the 4-probe resistance of the As x P 1-x alloys is found to decrease by more than 3 orders of magnitude. The transport studies reveal that samples with the highest arsenic concentration (x = 1 and 0.83) show metallic behavior in the temperature dependence of resistance with a small thermopower at room temperature with an anomalous temperature dependence. In contrast, the samples with high phosphorus concentration (x = 0, 0.2, and 0.5) show very large thermopower values at room temperature reaching a value as high as 803 μV/k for x = 0.2. The temperature dependence of the thermopower of these samples can be well described by the variable range hopping (VRH) mechanism in two-dimensions (2-d), S ~ T 1/3 . Similarly, their 4-probe resistance (R) values can be fitted with 2-d VRH mechanism, R ~ exp(T -1/3 ).

36 MATERIALS SCIENCE↗
DOE OSTI2017

Mid-Wave Infrared Photoconductors Based on Black Phosphorus-Arsenic Alloys

Black phosphorus (b-P) and more recently black phosphorus-arsenic alloys (b-PAs) are candidate 2D materials for the detection of mid-wave and potentially long-wave infrared radiation. However, studies to date have utilized laser-based measurements to extract device performance and the responsivity of these detectors. As such, their performance under thermal radiation and spectral response has not been fully characterized. In this work, we perform a systematic investigation of gated-photoconductors based on b-PAs alloys as a function of thickness over the composition range of 0-91% As. Infrared transmission and reflection measurements are performed to determine the bandgap of the various compositions. The spectrally resolved photoresponse for various compositions in this material system is investigated to confirm absorption measurements, and we find that the cutoff wavelength can be tuned from 3.9 to 4.6 μm over the studied compositional range. In addition, we investigated the temperature-dependent photoresponse and performed calibrated responsivity measurements using blackbody flood illumination. Notably, we find that the specific detectivity (D*) can be optimized by adjusting the thickness of the b-P/b-PAs layer to maximize absorption and minimize dark current. We obtain a peak D* of 6 × 10 10 cm Hz 1/2 W -1 and 2.4 × 1010 cm Hz 1/2 W -1 for pure b-P and b-PAs (91% As), respectively, at room temperature, which is an order of magnitude higher than commercially available mid-wave infrared detectors operating at room temperature.

2D materials↗
DOE OSTI2019

Ternary Palladium–Boron–Phosphorus Alloy Mesoporous Nanospheres for Highly Efficient Electrocatalysis

Alloying palladium (Pd) catalysts with various metalloid and nonmetal elements can improve their catalytic performance in different chemical reactions. However, current nanosynthesis methods can only generate Pd alloys containing one metalloid or nonmetal, which limits the types of element combinations that may be used to improve Pd-based nanocatalysts. Here, we report a simple soft-templating synthetic strategy to co-alloy Pd with the metalloid boron (B) and the nonmetal phosphorus (P) to generate ternary PdBP mesoporous nanospheres (MSs) with three-dimensional dendritic frameworks. We use a one-step aqueous synthesis method where dimethylamine borane and sodium hypophosphite serve as the B and P sources, respectively, as well as the co-reducing agents to drive the nucleation and growth of ternary PdBP alloy on a sacrificial dioctadecyldimethylammonium chloride template. The concentration of metalloid to nonmetal and the diameters of dendritic MSs can be tailored. The synthetic protocol is also extended to other multicomponent PdMBP alloy MSs to generate different types of dendritic mesoporous frameworks. Boron and phosphorus are known to accelerate the kinetics of the electrochemical oxygen reduction reaction (ORR) and alcohol oxidation reactions (AORs), because their alloys promote the decomposition of oxygen-containing intermediates on Pd surfaces. The dendritic mesoporous morphology of the ternary PdBP MSs also accelerates electron/mass transfer and exposes numerous active sites, enabling better performance in the ORR and AORs. Extending the surfactant-templating synthetic route to multiple types of elements will enable the generation of libraries of multicomponent metal–metalloid-nonmetal alloy nanostructures with functions that are suitable for various targeted applications.

36 MATERIALS SCIENCE↗
DOE OSTI2025

Reducing Coke and Increasing Bio-Oil Yield during Catalytic Fast Pyrolysis of Biomass Using Phosphorus-Modified Zeolite Catalysts

Catalytic fast pyrolysis (CFP) is a promising strategy for producing hydrocarbon transportation fuels from biomass feedstocks. However, catalyst development is needed to increase bio-oil yields and enhance process economics. In this work, we demonstrate how post synthetic modification of formed ZSM-5 with phosphorus shifts CFP selectivity from coke and light gases toward the desired bio-oil product. Microscale experiments demonstrated reduced coke production relative to unmodified ZSM-5 and identified an optimal P loading. Extensive catalyst characterization revealed that P interacted with Al sites to reduce the acid site density, with preferential binding to the strongest acid sites. Insights from the microscale experiments were leveraged to produce kilogram quantities of formed P-ZSM-5 for evaluation in a larger semi-integrated process. These experiments generated liters of bio-oil that was hydrotreated and fractionated into gasoline, diesel, and jet cuts. The phosphorus-modified ZSM-5 improved CFP bio-oil yield, resulting in an 11% relative increase in the carbon yield from biomass to aviation fuel and a 14% decrease in the minimum fuel selling price. These results highlight the impact targeted changes in catalyst acidity, achieved by adding 2.5 wt % P, can have on the carbon efficiency and feasibility of fuel production from biomass feedstocks.

09 BIOMASS FUELS↗
DOE OSTI2019

Representing Nitrogen, Phosphorus, and Carbon Interactions in the E3SM Land Model: Development and Global Benchmarking

Over the past several decades, the land modeling community has recognized the importance of nutrient regulation on the global terrestrial carbon cycle. Implementations of nutrient limitation in land models are diverse, varying from applying simple empirical down–regulation of potential gross primary productivity under nutrient deficit conditions to more mechanistic treatments. In this study, we introduce a new approach to model multinutrient (nitrogen [N] and phosphorus [P]) limitations in the Energy Exascale Earth System Model (E3SM) Land Model version 1 (ELMv1–ECA). The development is grounded on (1) advances in representing multiple–consumer, multiple–nutrient competition; (2) a generic dynamic allocation scheme based on water, N, P, and light availability; (3) flexible plant CNP stoichiometry; (4) prognostic treatment of N and P constraints on several carbon cycle processes; and (5) global data sets of plant physiological traits. Through benchmarking the model against best knowledge of global plant and soil carbon pools and fluxes, we show that our implementation of nutrient constraints on the present–day carbon cycle is robust at the global scale. Compared with predecessor versions, ELMv1–ECA better predicts global–scale gross primary productivity, ecosystem respiration, leaf area index, vegetation biomass, soil carbon stocks, evapotranspiration, N2O emissions, and NO3– leaching. Factorial experiments imply that representing the phosphorus cycle improves modeled carbon fluxes, while considering dynamic allocation improves modeled carbon stock density. We also illustrate the value of using the International Land Model Benchmarking (ILAMB) package to evaluate and document performance during model development.

58 GEOSCIENCES↗
DOE OSTI2026

First principles band structure of interacting phosphorus and boron/aluminum δ -doped layers in silicon

Silicon can be heavily doped with phosphorus in a single atomic layer (a δ layer), significantly altering the electronic structure of the conduction bands within the material. Recent progress has also made it possible to further dope silicon with acceptor-based δ layers using either boron or aluminum, making it feasible to create devices with interacting δ layers with opposite polarity. Using density functional theory, we calculate the electronic structure of a phosphorus-based δ layer interacting with a boron or aluminum δ layer, varying the distances between the δ layers. At separations 1 nm and smaller, the dopant potentials overlap and largely cancel each other out, leading to an electronic structure closely mimicking intrinsic silicon. At separations greater than 1 nm, the two δ layers behave independently of one another, with an equivalent electronic structure to a p–n diode with an intrinsic layer taking the place of the depletion region. One mechanism for charge transfer between δ layers at larger distances could be tunneling, where we see a tunneling probability exceeding what would be seen for a standard silicon 1.1 eV triangular barrier, indicating that the interaction between delta layers may enhance tunneling compared to a traditional junction.

delta layers↗
DOE OSTI2018

Band Structure of the IV-VI Black Phosphorus Analog and Thermoelectric SnSe

Here, the success of black phosphorus in fast electronic and photonic devices is hindered by its rapid degradation in the presence of oxygen. Orthorhombic tin selenide is a representative of group IV-VI binary compounds that are robust and isoelectronic and share the same structure with black phosphorus. We measure the band structure of SnSe and find highly anisotropic valence bands that form several valleys having fast dispersion within the layers and negligible dispersion across. This is exactly the band structure desired for efficient thermoelectric generation where SnSe has shown great promise.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
DOE OSTI2017

Surface buckling of black phosphorus: Determination, origin, and influence on electronic structure

The surface structure of black phosphorus materials is determined using surface-sensitive dynamical microspot low energy electron diffraction ( μ LEED ) analysis using a high spatial resolution low energy electron microscopy (LEEM) system. Samples of (i) crystalline cleaved black phosphorus (BP) at 300 K and (ii) exfoliated few-layer phosphorene (FLP) of about 10 nm thickness which were annealed at 573 K in vacuum were studied. In both samples, a significant surface buckling of 0.22 Å and 0.30 Å, respectively, is measured, which is one order of magnitude larger than previously reported. As direct evidence for large buckling, we observe a set of (for the flat surface forbidden) diffraction spots. Using first-principles calculations, we find that the presence of surface vacancies is responsible for the surface buckling in both BP and FLP, and is related to the intrinsic hole doping of phosphoresce materials previously reported.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
DOE OSTI2021

Comparative Studies of Optoelectronic Properties, Structures, and Surface Morphologies for Phosphorus-Doped Poly-Si/SiOx Passivating Contacts

We investigated and compared optoelectronic properties, crystallographic structures, and nanoscale surface morphologies of ex-situ phosphorus-doped polycrystalline silicon (poly-Si)/SiO x passivating contacts, formed by different deposition methods (sputtering, plasma-enhanced chemical vapour deposition (PECVD), and low-pressure chemical vapour deposition (LPCVD)). Across all these deposition technologies, a similar trend is observed: higher diffusion temperatures yield films that are more crystalline but have rougher surface morphologies due to bigger surface crystal grains. Also, the recrystallization process of the as-deposited Si films starts from the SiO x interface, rather than from the film surface and bulk. However, there are some distinct differences among these technologies. Firstly, the LPCVD method yields the roughest surface and smallest degree of crystallinity on finished poly-Si films. In contrast, the PECVD method has the smoothest surface for both as-deposited Si and annealed poly-Si films. Secondly, as-deposited sputtered and PECVD Si films contain only an amorphous phase whereas as-deposited LPCVD films has already had some crystalline phase. Thirdly, the LPCVD phosphorus in-diffusion into the substrate depends strongly on the initial film thickness, whereas for the other two methods it is weakly dependent on thickness.

crystallographic structures↗
DOE OSTI2021

Deforestation strengthens atmospheric transport of mineral dust and phosphorus from North Africa to the Amazon

Phosphorus contained in atmospheric mineral dust aerosol originating from Africa fertilizes tropical forests in Amazonia. However, the mechanisms influencing this nutrient transport pathway remain poorly understood. Here we use the Community Earth System Model to investigate how large-scale deforestation affects mineral dust aerosol transport and deposition in the tropics. We find that the surface biophysical changes that accompany deforestation produce a warmer, drier and windier surface environment that perturbs atmospheric circulation and enhances long-range dust transport from North Africa to the Amazon. Tropics-wide deforestation weakens the Hadley circulation, which in turn, leads to a northward expansion of the Hadley cell and increases surface air pressure over the Sahara Desert. Additionally, the high pressure anomaly over the Sahara, in turn, increases northeasterly winds across North Africa and the tropical North Atlantic Ocean, which subsequently increases dust transport to the South America continent. We estimate that the annual atmospheric phosphorus deposition from dust significantly increases by 27% (P < 0.01) in the Amazon under a scenario of complete deforestation. These interactions exemplify how land surface changes can modify tropical nutrient cycling, which in turn, may have consequences for long-term changes in tropical ecosystem productivity and biodiversity.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2017

The ultimate mineral processing challenge: Recovery of rare earths, phosphorus and uranium from Florida phosphatic clay

We report phosphate beneficiation in Florida generates more than one tonne of phosphatic clay, or slime, per tonne of phosphate rock produced. Since the start of the practice of large-scale washing and desliming for phosphate beneficiation, more than 2 Gt of slime has accumulated, containing approximately 600 Mt of phosphate rock, 600 kt of rare earth elements (REEs) and 80 million kilograms of uranium. The recovery of these valuable elements from the phosphatic clay is one of the most challenging endeavors in mineral processing, because the clay is extremely dilute, with an average solids concentration of 3 percent, and fine in size, with more than 50 percent having particle size smaller than 2 μm, and it contains nearly 50 percent clay minerals as well as large amounts of magnesium, iron and aluminum. With industry support and under funding from the Critical Materials Institute, the Florida Industrial and Phosphate Research Institute in conjunction with the Oak Ridge National Laboratory undertook the task to recover phosphorus, rare earths and uranium from Florida phosphatic clay. This paper presents the results from the preliminary testing of two approaches. The first approach involves three-stage cycloning using cyclones with diameters of 12.4 cm (5 in.), 5.08 cm (2 in.) and 2.54 cm (1 in.), respectively, to remove clay minerals followed by flotation and leaching. The second approach is a two-step leaching process. In the first step, selective leaching was conducted to remove magnesium, thus allowing the production of phosphoric acid suitable for the manufacture of diammonium phosphate (DAP) in the second leaching step. The results showed that multistage cycloning with small cyclones is necessary to remove clay minerals. Finally, selective leaching at about pH 3.2 using sulfuric acid was found to be effective for removing more than 80 percent of magnesium from the feed with minimal loss of phosphorus.

36 MATERIALS SCIENCE↗
DOE OSTI2019

Mechanisms Responsible for Soil Phosphorus Availability Differences between Sprinkler and Furrow Irrigation

From a historical perspective, human‐induced soil erosion and resulting soil phosphorus (P) losses have likely occurred for thousands of years. In modern times, erosion risk and off‐site P transport can be decreased if producers convert from furrow to sprinkler irrigation, but conversion may alter nutrient dynamics. Our study goal was to determine soil P dynamics in furrow‐ (in place since the early 1900s) versus sprinkler‐irrigated (installed within the last decade) soils from four paired producer fields in Idaho. Furrow‐ and sprinkler‐irrigated soils (0–5 cm; Aridisols) contained on average 38 and 20 mg kg −1 of Olsen‐extractable P (i.e., plant‐available P), respectively; extractable P values over 40 mg kg −1 limit Idaho producers to P application based on crop uptake only. Soil samples were also analyzed using a modified Hedley extraction. Furrow‐irrigated soils contained greater inorganic P concentrations in the soluble+aluminum (Al)‐bound+iron (Fe)‐bound, occluded, and amorphous Fe‐bound pools. Phosphorus K ‐edge X‐ray absorption near‐edge structure (XANES) spectroscopy was unable to detect Fe‐associated P but indicated greater amounts of apatite‐like or octacalcium phosphate‐like P in furrow‐irrigated producer soils, while sprinkler‐irrigated fields had lower amounts of apatite‐like P and greater proportions of P bound to calcite. Findings from a controlled USDA‐ARS sprinkler‐ versus furrow‐irrigation study suggested that changes in P dynamics occur slowly over time, as few differences were observed. Overall findings suggest that Fe redox chemistry or changes in calcium (Ca)‐associated P in flooded conditions altered P availability under furrow irrigation, even in aridic, calcareous soils, contributing to greater Olsen‐extractable P concentrations in long‐term furrow‐irrigated fields. Core Ideas Irrigation type may greatly affect soil P dynamics in calcareous systems. Furrow irrigated fields contained more plant‐available P than sprinkler irrigated fields. Furrow irrigation leads to Fe chemistry alterations, release of P, and increases available P. Available P increases under furrow irrigation could limit amendment application based on P, not N, crop needs. We still do not fully understand P dynamics in irrigated calcareous systems.

Ippolito, James A.↗
DOE OSTI2022

The Galactic Distribution of Phosphorus: A Survey of 163 Disk and Halo Stars*

Phosphorus (P) is a critical element for life on Earth, yet the cosmic production sites of P are relatively uncertain. To understand how P has evolved in the solar neighborhood, we measured abundances for 163 FGK stars over a range of –1.09 < [Fe/H] < 0.47 using observations from the Habitable-zone Planet Finder instrument on the Hobby–Eberly Telescope. Atmospheric parameters were calculated by fitting a combination of astrometry, photometry, and Fe I line equivalent widths. Phosphorus abundances were measured by matching synthetic spectra to a P I feature at 10529.52 Å. Our [P/Fe] ratios show that chemical evolution models generally underpredict P over the observed metallicity range. Additionally, we find that the [P/Fe] differs by ~0.1 dex between thin disk and thick disk stars that were identified with kinematics. The P abundances were compared with α-elements, iron-peak, odd-Z, and s-process elements, and we found that the evolution of P in the disk most strongly resembles that of the α-elements. We also find that molar P/C and N/C ratios for our sample match the scatter seen from other abundance studies. Finally, we measure a [P/Fe] = 0.09 ± 0.1 ratio in one low-α halo star and probable Gaia–Sausage–Enceladus member, an abundance ratio ~0.3–0.5 dex lower than the other Milky Way disk and halo stars at similar metallicities. Overall, we find that P is likely most significantly produced by massive stars in core-collapse supernovae, based on the largest P abundance survey to date.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2018

Influence of climate variability, fire and phosphorus limitation on vegetation structure and dynamics of the Amazon–Cerrado border

Abstract. Climate, fire and soil nutrient limitation are important elements that affect vegetation dynamics in areas of the forest–savanna transition. In this paper, we use the dynamic vegetation model INLAND to evaluate the influence of interannual climate variability, fire and phosphorus (P) limitation on Amazon–Cerrado transitional vegetation structure and dynamics. We assess how each environmental factor affects net primary production, leaf area index and aboveground biomass (AGB), and compare the AGB simulations to an observed AGB map. We used two climate data sets (monthly average climate for 1961–1990 and interannual climate variability for 1948–2008), two data sets of total soil P content (one based on regional field measurements and one based on global data), and the INLAND fire module. Our results show that the inclusion of interannual climate variability, P limitation and fire occurrence each contribute to simulating vegetation types that more closely match observations. These effects are spatially heterogeneous and synergistic. In terms of magnitude, the effect of fire is strongest and is the main driver of vegetation changes along the transition. Phosphorus limitation, in turn, has a stronger effect on transitional ecosystem dynamics than interannual climate variability does. Overall, INLAND typically simulates more than 80 % of the AGB variability in the transition zone. Furthermore, the AGB in many places is clearly not well simulated, indicating that important soil and physiological factors in the Amazon–Cerrado border region, such as lithology, water table depth, carbon allocation strategies and mortality rates, still need to be included in the model.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2025

Burn severity and vegetation type control phosphorus concentration, molecular composition, and mobilization

Shifting phosphorus (P) dynamics after wildfires can have cascading impacts from terrestrial to aquatic environments. However, it is unclear whether shifts in P composition or P concentration are responsible for changes in P dynamics post-fire. We used laboratory leaching experiments of Douglas fir forest and sagebrush shrubland chars to examine how the potential mobility of P compounds is influenced by different burn severities. Burning produced a 6.9- and 29-fold increase in particulate P mobilization but a 3.8- and 30.5-fold decrease in aqueous P released for Douglas fir forest and sagebrush shrubland, respectively. The mechanisms driving particulate- and dissolved-phase P compound mobilization were contrasting. Phosphorus compound mobilization in the particulate phase was controlled by solid char total P concentrations, while the aqueous phase was driven by solubility changes of molecular species. Nuclear magnetic resonance (NMR) and X-ray absorption near-edge structure (XANES) on the solid chars indicated that organic orthophosphate monoester and diester species were thermally mineralized to inorganic P moieties with burning in both vegetation types, which decreases P solubility. This coincided with the production of calcium- and magnesium-bound inorganic P compounds. With increasing burn severity there were systematic shifts in P concentration and composition – higher-severity chars mobilized P compounds in the particulate phase, although the magnitude of change was vegetation-specific. Our results indicate a post-fire transformation to both the composition of the solid charred material and how P compounds are mobilized, which may influence its environmental cycling and fate.

31P solution-state NMR↗