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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 235 records · Page 13
All sourcesNASA NTRSDOE OSTI
DOE OSTI2025

Design, optimization, and validation of a triply periodic minimal surface based heat exchanger for extreme temperature applications

Heat exchanger (HX) innovation offers potential for significant improvements in energy efficiency for a host of applications including but not limited to aviation and power generation cycles. Triply Periodic Minimal Surfaces (TPMS) have received significant attention in recent years due to their incredibly high surface area density, which makes them very attractive from a heat transfer point of view. Recent efforts have largely focused on thermal-hydraulic characterization of the many available TPMS and the testing of small-scale HX prototypes. However, practical implementation remains largely unexplored, partially due to the extreme computational cost associated with accurately simulating these complex structures. In this work, we present the design, simulation, and optimization of a TPMS-HX for high temperature (900 °C) and pressure (25 MPa) applications. Detailed analysis of HX sub-sections is conducted to define the smallest repeatable section which may be used to characterize the thermal-hydraulic performance of the entire HX, enabling rapid design and iteration with significantly reduced computational cost. Compared to preliminary results for a water-to-water experiment, calibrated heat transfer and pressure drop predictions were within ±5 % and ±10 %, respectively. Optimization results show a 10x increase in volumetric power density over the initial design, which is verified against a parametric exhaustive search of the HX design space. Furthermore, it was found that reducing the unit cell hydraulic diameter cell plays the largest role in increasing heat transfer, increasing the surface area density and enabling a more compact and efficient HX.

42 ENGINEERING↗
DOE OSTI2023

A simple, validated approach for design of two-dimensional periodic particle patterns via acoustophoresis

Two-dimensional patterning of microparticles enables a wide range of functional materials, including patterned energy storage electrodes, flexible electronics, and sensor arrays. Particle patterning via acoustics offers an attractive path to generate a wide variety of 2D periodic patterns that introduce tailorable hierarchical porosity, useful for controlling surface area, transport distances, and other properties. This method is most effective with micron scale particles and patterns of tens to hundreds of microns. To enable systematic exploration of the broad design space for such patterns, this work develops a model of 2D and 3D assembly of particles at high loadings and validates the obtained patterns against both experiments and more computationally intensive modeling techniques. Using this simple model, connections are mapped between input parameters (like actuation conditions, particle volume fraction, material properties) and output geometrical features (like void size and shape, pattern connectivity, and surface area) so that they can be tailored to given applications. The utility of this simple model is illustrated by predicting and then experimentally demonstrating new hierarchical patterns resulting from multiple waves of different frequencies interacting. These multiscale patterns offer the potential to lift the limits on surface area, diffusion distances, and other features.

42 ENGINEERING↗
DOE OSTI2020

Rational Construction of Porous Metal–Organic Frameworks for Uranium(VI) Extraction: The Strong Periodic Tendency with a Metal Node

Although metal-organic frameworks (MOFs) have been reported as important porous materials for the potential utility in metal ion separation, coordinating the functionality, structure, and component of MOFs remains a great challenge. Herein, a series of anionic rare earth MOFs (RE-MOFs) were synthesized via a solvothermal template reaction and for the first time explored for uranium(VI) capture from an acidic medium. The unusually high extraction capacity of UO2 2 + (e.g., 538 mg U per g of Y-MOF) was achieved through ion-exchange with the concomitant release of Me 2 NH 2 + , during which the uranium(VI) extraction in the series of isostructural RE-MOFs was found to be highly sensitive to the ionic radii of the metal nodes. That is, the uranium(VI) adsorption capacities continuously increased as the ionic radii decreased. Finally, in-depth mechanism insight was obtained from molecular dynamics simulations, suggesting that both the accessible pore volume of the MOFs and hydrogen-bonding interactions contribute to the strong periodic tendency of uranium(VI) extraction.

36 MATERIALS SCIENCE↗
DOE OSTI2020

1.5 – 1.6 μm semiconductor lasers with an asymmetric periodic optically coupled waveguide

High-power 1.5 – 1.6-μm semiconductor lasers with an asymmetric periodic optically coupled waveguide are developed and their current – voltage, light – current, and spectral characteristics are experimentally studied. The characteristics of these lasers are compared with the characteristics of traditional lasers based on double separate-confinement heterostructures. It is shown that the developed lasers have lower divergence and almost the same threshold and power characteristics as conventional lasers with Fabry – Perot resonators. The developed lasers with a cavity length of 1.6 mm and a mesa-stripe contact width of 3 μm mounted in a housing 11 mm in diameter have a power no lower than 200 mW at a pump current not exceeding 700 mA with a divergence of 25 – 35° versus 45° typical for conventional lasers. (lasers)

36 MATERIALS SCIENCE↗
DOE OSTI2020

Skyrmion dynamics and topological sorting on periodic obstacle arrays

Abstract We examine skyrmions under a dc drive interacting with a square array of obstacles for varied obstacle size and damping. When the drive is applied in a fixed direction, we find that the skyrmions are initially guided in the drive direction but also move transverse to the drive due to the Magnus force. The skyrmion Hall angle, which indicates the difference between the skyrmion direction of motion and the drive direction, increases with drive in a series of quantized steps as a result of the locking of the skyrmion motion to specific symmetry directions of the obstacle array. On these steps, the skyrmions collide with an integer number of obstacles to create a periodic motion. The transitions between the different locking steps are associated with jumps or dips in the velocity–force curves. In some regimes, the skyrmion Hall angle is actually higher than the intrinsic skyrmion Hall angle that would appear in the absence of obstacles. In the limit of zero damping, the skyrmion Hall angle is 90°, and we find that it decreases as the damping increases. For multiple interacting skyrmion species in the collective regime, we find jammed behavior at low drives where the different skyrmion species are strongly coupled and move in the same direction. As the drive increases, the species decouple and each can lock to a different symmetry direction of the obstacle lattice, making it possible to perform topological sorting in analogy to the particle sorting methods used to fractionate different species of colloidal particles moving over two-dimensional obstacle arrays.

36 MATERIALS SCIENCE↗
DOE OSTI2022

Temporally quasiperiodic data, propagating in the laboratory frame, can be rendered periodic by Galilean transformation

For a broad class of distributions of temperature, concentration, or another quantity propagating rectilinearly, we show that temporally quasiperiodic behavior in the laboratory frame can be rendered periodic by Galilean transformation. The approach is illustrated analytically and numerically using as an example a closed-form model distribution generated from a one-dimensional partial differential equation, and a detailed process is developed to determine frame speed from more general quasiperiodic, one-dimensional, temporally- and spatially-discretized data. Furthermore, the approach is extended to two- and three-dimensional rectilinear propagation, and its application to nonrectilinear propagation, along with implications for interpreting noise-corrupted data, are also discussed.

97 MATHEMATICS AND COMPUTING↗
DOE OSTI2023

Triply Periodic Minimal Surfaces Lattice Neutronics Scoping Studies

Triply Periodic Minimal Surfaces (TPMS) have seen extensive research in heat exchanger development due to their enhanced heat transfer performance. When applied to nuclear reactor cores, TPMS can more efficiently dissipate heat to the coolant, permitting increased power densities. The increased power density can be used to develop smaller reactors while retaining power output. Although TPMS core geometries promise enhanced heat transfer, the neutronic behavior of such geometries require further inquiry. In this study, the neutron multiplication and buckling are compared between variations of TPMS and traditional pincell core designs.

22 GENERAL STUDIES OF NUCLEAR REACTORS↗
DOE OSTI2025

Preliminary modeling of triply periodic minimal surface (TPMS) structures using RELAP5-3D

With the United States Department of Energy (DOE)’s goal of quadrupling the nation’s nuclear energy supply by 2050, and with the Advanced Fuels Campaign pushing for new types of advanced reactor fuels and geometries, the need has arisen for new nuclear fuel designs. One such design is to swap out current nuclear fuel geometries in exchange for another type of geometry, called a Triply Periodic Minimal Surface (TPMS). TPMSs are self-supporting, infinitely repeating lattices—attributes that lend themselves well to additive manufacturing. These surfaces also possess enhanced heat transfer properties thanks to their internal area changes and large surface-area-to-volume ratios. Their drawback, however, is an increased pressure drop. Given the small amount of correlations and data (Reynolds numbers in the 2,000–8,000 range), and the minimal amount of experience so far obtained by modeling TPMS structures using 1D systems codes such as the Reactor Excursion and Leak Analysis Program (RELAP5-3D), further research into this topic was needed. Using data from the University of Wisconsin - Madison (UW), curve fits were created for both a Heat Transfer Coefficient (HTC) correlation and a Darcy friction factor empirical coefficient correlation. The curves’ coefficients and multipliers were then output and utilized in RELAP5-3D models of two upcoming experiments—Flow Loop for INFLUX Pressure drop (FLIP) and Microreactor Agile Non-nuclear Experimental Test (MAGNET)—aimed at increasing the available data for Reynolds numbers to the 16,000–36,000 range for TPMS structures. The models were run under the conditions utilized by a Computational Fluid Dynamics (CFD) analysis performed by another group at Idaho National Laboratory. Only CFD pressure drop values were obtained from the FLIP test, and those values showed that the RELAP5-3D models had a lower rate of pressure increase in comparison to the CFD values. In addition, there seemed to be a vertical shift upward in the pressure drop for both models whenever the TPMS porosity decreased, and the RELAP5-3D models showed a higher vertical shift in comparison to the CFD values. The MAGNET results did not correspond to any CFD or experimental results against which they could be compared, so they were instead compared against the proposed CFD input conditions. These values were then compared with each other to make sure the model seemed to be performing as expected, paving the way for future tests that can be run for the purpose of further analyses and comparisons. The pressure drop increased with temperature and mass flow rate independently. The temperature change would decrease with increasing mass flow rate and temperature, which was just as we expected based on the fact that the lower viscosity and decreased density would result in higher friction and churning losses. The last metric that was assessed was the enthalpy flow change, which increased with increasing mass flow rate and decreasing temperature.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗
DOE OSTI2024

Optimization of Triply Periodic Minimal Surface Heat Exchanger to Achieve Compactness, High Efficiency, and Low-Pressure Drop

With advancements in additive manufacturing (AM) techniques, high-quality triply periodic minimal surface (TPMS) structures can now be produced. TPMS walled heat exchangers (HX) hold significant potential for industrial applications and are receiving increasing attention. This paper explores the impact of various TPMS design variables on flow and thermal performance to optimize TPMS heat exchangers for compactness, high efficiency, and low pressure drop. The design variables examined include the type of TPMS lattice, unit cell size, wall thickness, aspect ratio, TPMS orientation, and equivalent thickness. The study reveals that the flow and heat transfer performance of TPMS structures are significantly affected by these design variables. For the Gyroid, Diamond, and SplitP lattices, performance is nearly identical when the surface-to-volume ratio is kept constant. The average velocity of the fluid in the TPMS HX should be 0.3 m/s. The corresponding Re is between 300~800. Thin wall thickness, small equivalent thickness, and flat lattice configurations can significantly reduce pressure drop while maintaining the overall heat transfer coefficient. Additionally, the angle between the flow direction and TPMS orientation can increase pressure drop. Three aluminum heat exchangers were successfully printed using an AM machine, and testing results are comparable with theoretical prediction.

42 ENGINEERING↗
DOE OSTI2020

Periodic Narrowband Radio Wave Emissions and Inward Plasma Transport at Saturn's Magnetosphere

The abrupt brightening of an Energetic Neutral Atom (ENA) blob or cloud has been interpreted as plasma injection in the Kronian magnetosphere (termed ENA injection herein). Morphologically, there appears to be two types of abrupt ENA cloud brightening: (1) the brightening of a large cloud usually seen at distances >10–12 R {sub s} (R {sub s} ∼ 60,268 km) in the midnight or postmidnight region; (2) the brightening of a smaller cloud usually seen at distances <10–12 R {sub s} around 21–03 magnetic local time. Among many radio waves observed at Saturn, type 2 ENA injections correlate best with the 5 kHz narrowband (NB) waves. Using Cassini Ion and Neutral Camera (INCA) and Radio and Plasma Wave Science (RPWS) data, we examine the periodicities of the type 2 ENA injections and the 5 kHz NB emissions as well as their cross-correlations, which have been previously used to measure the lag times or phase differences. Because correlational analysis can only establish linear relationships, we also use mutual information to establish linear and nonlinear relationships. On average, the peak of the 5 kHz NB emission lags those of the type 2 ENA injection by about a few minutes to 2 hr. The injection of hot plasma to the inner magnetosphere can lead to temperature anisotropy, which can generate electrostatic upper hybrid waves, which upon encountering the high-density gradient at the outer edge of the Enceladus density torus, can mode convert to Z mode and then to O mode. The 5 kHz NB waves commonly propagate in the O mode.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2020

Dynamical Instabilities in Systems of Multiple Short-period Planets Are Likely Driven by Secular Chaos: A Case Study of Kepler-102

We investigated the dynamical stability of high-multiplicity Kepler and K2 planetary systems. Our numerical simulations find instabilities in ∼20% of the cases on a wide range of timescales (up to 5 × 10{sup 9} orbits) and over an unexpectedly wide range of initial dynamical spacings. To identify the triggers of long-term instability in multiplanet systems, we investigated in detail the five-planet Kepler-102 system. Despite having several near-resonant period ratios, we find that mean-motion resonances are unlikely to directly cause instability for plausible planet masses in this system. Instead, we find strong evidence that slow inward transfer of angular momentum deficit (AMD) via secular chaos excites the eccentricity of the innermost planet, Kepler-102 b, eventually leading to planet–planet collisions in ∼80% of Kepler-102 simulations. Kepler-102 b likely needs a mass ≳0.1 M {sub ⊕}, hence a bulk density exceeding about half Earth’s, in order to avoid dynamical instability. To investigate the role of secular chaos in our wider set of simulations, we characterize each planetary system’s AMD evolution with a “spectral fraction” calculated from the power spectrum of short integrations (∼5 × 10{sup 6} orbits). We find that small spectral fractions (≲0.01) are strongly associated with dynamical stability on long timescales (5 × 10{sup 9} orbits) and that the median time to instability decreases with increasing spectral fraction. Our results support the hypothesis that secular chaos is the driver of instabilities in many nonresonant multiplanet systems and also demonstrate that the spectral analysis method is an efficient numerical tool to diagnose long-term (in)stability of multiplanet systems from short simulations.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2021

Quasi-periodic Oscillations in the TESS Light Curve of TX Col, a Diskless Intermediate Polar on the Precipice of Forming an Accretion Disk

One of the fundamental properties of an intermediate polar is the dynamical nature of the accretion flow as it encounters the white dwarf’s (WD’s) magnetosphere. Many works have presumed a dichotomy between disk-fed accretion, in which the WD accretes from a Keplerian disk, and stream-fed accretion, in which the matter stream from the donor star directly impacts the WD’s magnetosphere without forming a disk. However, there is also a third, poorly understood regime in which the accretion flow consists of a torus of diamagnetic blobs that encircles the WD. This mode of accretion is expected to exist at mass-transfer rates below those observed during disk-fed accretion, but above those observed during pure stream-fed accretion. We invoke the diamagnetic-blob regime to explain the exceptional Transiting Exoplanet Survey Satellite light curve of the intermediate polar TX Col, which transitioned into and out of states of enhanced accretion during Cycles 1 and 3. Power-spectral analysis reveals that the accretion was principally stream fed. However, when the mass-transfer rate spiked, large-amplitude quasi-periodic oscillations (QPOs) abruptly appeared and dominated the light curve for weeks. The QPOs have two striking properties: they appear in a stream-fed geometry at elevated accretion rates, and they occur preferentially within a well-defined range of frequencies (∼10–25 cycle day{sup −1}). We propose that during episodes of enhanced accretion, a torus of diamagnetic blobs forms near the binary’s circularization radius and that the QPOs are beats between the white dwarf’s spin frequency and unstable blob orbits within the WD’s magnetosphere. We discuss how such a torus could be a critical step in producing an accretion disk in a formerly diskless system.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2025

Preliminary Modeling of Triply Periodic Minimal Surface (TPMS) Structures with RELAP5-3D

This poster goes over preliminary work performed on modeling triply periodic minimal surfaces (TPMS) with RELAP5-3D. The poster starts off with the need for advanced nuclear fuel designs for future reactors, and how TPMS are being researched for this purpose. There is then a focus on what a TPMS is and then moves onto the motivation for why this geometry is being modeled and looked into. The methodology is then shown for how data from different experiments will be used for pre-test predictions and eventual creation of empirical coefficients and multipliers to be used in models. Then there is a show of how data would be compared between the experimental tests, CFD, and RELAP5-3D values. The results from the simulations and comparisons are then presented to show how the CFD and RELAP5-3D compare to each other currently, with no experimental data to compare to for one test model. Results from the second test model are also presented to show that there is stability in the solving of that model.

42 - ENGINEERING↗
DOE OSTI2026

Validation of OpenPronghorn for Periodic Hill Flow Separation

OpenPronghorn is an open-source, MOOSE-based thermal-hydraulics simulation tool used for advanced reactor analysis. As an open-source code, it offers a transparent framework for validating governing equations, assumptions, and numerical methods against established benchmarks. This study evaluates OpenPronghorn's RANS turbulence model against the ERCOFTAC Case 81 periodic hill benchmark, a standard test case for separated turbulent flow featuring curved-wall separation, recirculation, shear-layer development, and reattachment. Streamwise velocity profiles predicted by OpenPronghorn were compared to reference LES data at multiple x/h locations. Results show that OpenPronghorn captures the overall trend of the velocity profiles, but the largest discrepancies occur in the separated-flow region, where turbulence is highly anisotropic and strongly affected by adverse pressure gradients and wall curvature—conditions that are inherently difficult for standard RANS models to resolve. Future work will test alternative k-e model variants and correction terms to improve prediction accuracy in this region.

42 - ENGINEERING↗
DOE OSTI2020

Periodic Porous 3D Electrodes Mitigate Gas Bubble Traffic during Alkaline Water Electrolysis at High Current Densities

We report alkaline water electrolysis at high current densities is plagued by gas bubble generation and trapping in stochastic porous electrodes (e.g., Ni foams), which causes a significant reduction in the number of electrolyte accessible catalyst active sites. Here, 3D printed Ni (3DPNi) electrodes with highly controlled, periodic structures are reported that suppress gas bubble coalescence, jamming, and trapping and, hence, result in rapid bubble release. The 3DPNi electrodes decorated with carbon-doped NiO achieve a high current density of 1000 mA cm -2 in 1.0 m KOH electrolyte at hydrogen evolution reaction and oxygen evolution reaction overpotentials of 245 and 425 mV, respectively. This work demonstrates a new approach to the deterministic design of 3D electrodes to facilitate rapid bubble transport and release to enhance the total electrode catalytic activity at commercially relevant current densities.

08 HYDROGEN↗
DOE OSTI2020

Heterotrimetallic Mixed‐Valent Molecular Precursors Containing Periodic Table Neighbors: Assignment of Metal Positions and Oxidation States

Abstract A known trinuclear structure was used to design the heterobimetallic mixed‐valent, mixed‐ligand molecule [Co II (hfac) 3 −Na−Co III (acac) 3 ] ( 1 ). This was used as a template structure to develop heterotrimetallic molecules [Co II (hfac) 3 −Na−Fe III (acac) 3 ] ( 2 ) and [Ni II (hfac) 3 −Na−Co III (acac) 3 ] ( 3 ) via isovalent site‐specific substitution at either of the cobalt positions. Diffraction methods, synchrotron resonant diffraction, and multiple‐wavelength anomalous diffraction were applied beyond simple structural investigation to provide an unambiguous assignment of the positions and oxidation states for the periodic table neighbors in the heterometallic assemblies. Molecules of 2 and 3 are true heterotrimetallic rather than a statistical mixture of two heterobimetallic counterparts. Trinuclear platform 1 exhibits flexibility in accommodating a variety of di‐ and trivalent metals, which can be further utilized in the design of molecular precursors for the NaMM′O 4 functional oxide materials.

Han, Haixiang↗
DOE OSTI2020

Catchment storage and residence time in a periodically irrigated watershed

Understanding anthropogenic impacts on water storage and water flow pathways in catchments is an ongoing challenge in hydrology. Here, we study the dynamics of subsurface storage and residence time of water in a catchment in Berkeley, California, that is within a regional park but contains diverse land use within its perimeter, including a periodically irrigated golf course. Our study combines several isotopic tracers with water budget data to examine sources of water in a stream draining the site. Irrigation water, applied to a small area of the watershed, is a minor component of the water budget. However, geochemical tracers reveal that irrigation water is a significant fraction of stream flow downstream of the golf course during baseflow and during precipitation events. Isotopic tracers indicate that the watershed has a preference to release young water for stream flow generation, resulting in contrasting tritium ages for stream water and groundwater of 1.3 ± 0.5 year and 8.2 ± 1.7 year, respectively. We determined that the older water is a very small component (0.7%) of the stream water in the tail of an assumed exponential distribution. We used the seasonal variation of stable water isotopes in precipitation and stream water over two water years to explain the damping of the isotopic signature of stream water, which yields information about the catchment's response to the input signal. In conclusion, the methods described here may be applicable to other urban or suburban headwater catchments in areas with a component of non-natural recharge from, for example, leaky infrastructure, storm water routing or dry season irrigation.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2021

Periodic trends in gas–phase oxidation and hydrogenation reactions of lanthanides and 5d transition metal cations

Of the many publications coming from the laboratory of Diethard K. Bohme, among the most valuable were the surveys of reactivity throughout the periodic table as studied using selected ion flow tube (SIFT) mass spectrometry. In all cases, quantitative rate constants at 295 K and 0.35 Torr of He were obtained for metal cations generated by an inductively coupled plasma (ICP). This source creates ions at a temperature characterized as 5500 K. Here, it was believed that radiative relaxation and interactions with the flow gases would rapidly deplete most excited electronic states of the metal cations, although this is unknown

transition metals↗