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At least 235 records · Page 13
All sourcesNASA NTRSDOE OSTI
NASA NTRSDate not supplied

Overview of Predictive Simulation Capability Development for Crater Evolution and Ejecta in Continuum/Rarefied Flows

As part of the Game Changing Development (GCD) Program, funded by NASA’s Space Technology Mission Directorate (STMD), the development of simulation capability for the prediction of extra-terrestrial Plume Surface Interaction (PSI) environments has been undertaken by the Fluid Dynamics Branch at NASA/MSFC. The Predictive Simulation Capability (PSC) Element is focused on creating simulation capability for the reliable and accurate prediction of PSI in Martian (~650 Pa) and Lunar (vacuum) ambient environments. In addition to the predictive simulation capability, the GCD Program also contains a companion Ground Testing Element for development of focused datasets for validation of predictive capability as well as a Flight-focused Instrumentation Element. The focus of this paper is to provide an overview and a brief status on one area of capability development through this GCD PSI project - capturing the effects of mixed continuum/rarefied flow on crater development and ejecta sheets. This includes both capability enhancements and maturation of the predictive tool, Loci/GGFS, into a production capable tool as well as validation of the tool against PSI data in Martian and Lunar environments. There are six newly developed capabilities that will be production ready by the end of the fiscal year. Newly developed capabilities must first be verified prior to being production ready, and this process includes capability demonstration, solution verification, and performance evaluation. An overview of the newly developed capabilities with respect to several test cases, including cratering simulations of the Apollo Lunar Module, will be presented. Several validation analyses have been performed to validate in Martian and more Lunar-like environments, including simulations of cratering from a subsonic flow test at Planetary Aeolian Lab (PAL) conducted in a Martian-like environment and pre-test cratering predictions of Physics Focused Ground Test (PFGT) tests planned to be performed in Martian-like and more Lunar-like environments. An overview of these validation analyses as it pertains to the capability development will be presented.

Andrew Weaver↗
NASA NTRSDate not supplied

TIME-SERIES SOIL MOISTURE RETRIEVAL USING S-BAND BACKSCATTER MEASUREMENTS FROM THE SMEX02 CAMPAIGN

S-band observations from NASA’s Passive/Active L/S Band (PALS) radar from theSMEX02 campaign were used to estimate soil moisture. The “alpha”method is applied for this process, in which a time series of ratios of normalized radar cross section values at successive measurements is used to infer the corresponding soil moisture time series given ancillary information on the minimum and maximum soil moisture values expected over the time series. Results are examined as a function of the polarization and crop type. The results show reasonable retrieval performance, indicating the potential of usingS-band observations from the future NASA/ISRO SAR(NISAR)mission.

Dustin Horton↗
NASA NTRS2021

SMAP Validation Experiment 2019-2021 (SMAPVEX19-21): Detection of Soil Moisture Under Temperate Forest Canopy

The retrieval of soil moisture under forest canopy has long been an important goal for low frequency remote sensing. The NASA mission started a dedicated field experiment in May 2019 by deploying two temporary soil moisture networks in northeast US that cover two separate SMAP pixels with variable degree of forest cover. The measurements will be augmented with two intensive observation periods (IOP). The first IOP is planned for July and the other one for October. The IOPs will see deployment of the airborne PALS (Passive Active L-band sensor) instrument, which is similar to the SMAP instrument, and intensive manual measurements of soil moisture and vegetation. The measurements also include tower-based radiometer observations with ground truth measurements within the instrument footprint. The early results have shown that the SMAP measurement signal at L-band is sensitive to soil moisture changes observed on the ground.

Yueh, Simon H.↗
NASA NTRSDate not supplied

A Structurally-Adaptive Framework for Distributed Airborne Sensing over Real-time Collaborative Information Sharing Networks

The emergence and maturation of wireless communication technologies continue to transform the aviation industry and are enabling new solutions to challenges faced by NASA’s Advanced Air Mobility (AAM) initiative. AAM is leading towards high-density autonomous aircraft operations in areas underserved by traditional aviation, such as over densely populated urban centers. In this paper, we build on concepts from Smart Spaces - where sensing, processing, and communication are embedded in an environment, and agents are operating within the space can exploit these capabilities in real-time through collaborative information sharing networks. Building from these concepts, we propose a framework to enable a dynamic, topologically-adaptive, and distributed estimation system for man-rated aviation to address challenges faced by autonomous AAM operations. This paper presents the initial concept of operations and system design for this framework, presents a mathematical formulation for abstraction of the problem, identifies requirements and constraints for operation, and presents algorithmic constructs and mathematical formalisms to demonstrate operation. The proposed framework will be evaluated on a regional AAM flight scenario and will focus on two initial applications: (1) GPS-free navigation supporting precision approach and landing (PAL), and (2) surveillance and conformance monitoring of aircraft in vertiport airspaces. Such approaches show promise in addressing gaps in current technologies needed to enable future AAM concepts, while promising greater capabilities, performance, robustness, and safety over current aviation systems and operations.

Structurally-Adaptive↗
NASA NTRSDate not supplied

Predicted Performance Effects of Blade Elasticity on Testing of Rotors for Mars

The Rotor Optimization for the Advancement of Mars Exploration project (ROAMX) has designed and manufactured a set of rotor blades optimized for hover on Mars. These blades will soon be tested for hover performance in the NASA Ames Research Center Planetary Aeolian Laboratory, a large vacuum chamber capable of rotor testing at reduced pressures. To match the tip Mach numbers during this testing with the tip Mach numbers that would be experienced in the Martian atmosphere, the rotor will be spun faster in the vacuum chamber than it would be spun on Mars. While this accomplishes the goal of simulating the tip Mach numbers of Mars operations, the elevated RPM may have undesired consequences for performance, due to elastic deflections of the blades. The purpose of this paper is to use CAMRAD II, a rotorcraft comprehensive analysis code, to predict the effect on performance of blade elasticity at elevated RPM in the vacuum chamber environment. Results are presented for different thrust conditions and different rotor speeds, and comparisons are made between rigid and elastic blade predictions. Overall, the CAMRAD II analysis suggests that blade elasticity does influence rotor performance in the operating conditions of interest, although the effect is moderate enough to conclude that the PAL testing will be a good simulation of Mars operation.

Blade elasticity↗
NASA NTRS2023

Comparison Between Ozone Column Depths and Methane Lifetimes Computed By One- and Three-Dimensional Models at Different Atmospheric O(2) Levels

The calculation of ozone column depth as a function of atmospheric O2concentration has been performed multiple times over the past 40 years using one-dimensional (1-D) photochemical models. Several of these calculations [1–3] have been done by the Kasting group. We refer to the current version of that model as the‘standard’1-D model (see §2). Recently, Cooke et al., henceforth C22 ,performed a similar calculation using a three-dimensional (3-D) coupled chemistry-climate model (WACCM6). They found substantially lower ozone column depths at lower pO2levels. For example, at0.01 times the present atmospheric level (PAL) of O(2), Segura et al. calculated 124 Dobson units(DU), whereas C22 calculated a mean column depth of just 66 DU—almost a factor of two lower. This comparison is shown in figure 1. C22 argued, correctly, that 3-D models should be able to do a better job on this problem than 1-D models because ozone column depths are affected by atmospheric transport, e.g. the Brewer–Dobson circulation in the stratosphere that blows ozone from the tropics towards the poles, as well as vertical transport that carries ozone downward from the stratosphere to the troposphere. Meridional transport is absent in 1-D models, and vertical transport is fixed, so model geometry almost certainly contributes to the observed discrepancies in ozone column depth. The 3-D model also has a variable tropopause height (higher at the equator, lower towards the poles), which is difficult to simulate in one dimension.

Atmospheric chemistry↗
NASA NTRSDate not supplied

Contrails Measurement and Testing Capabilities in NASA's Particulate Aerosol Laboratory

The NASA Glenn Research Center Particulate Aerosol Laboratory (PAL) is a ground test facility for studying emissions and contrails at upper atmospheric conditions. The facility consists of a small-scale combustor that generates hot combustion gases and soot nanoparticles, which flow through a transition pipe into a jet nozzle, which exhausts into an altitude chamber. Thermodynamic conditions experienced in flight are matched in the altitude chamber, allowing the study of ice particle formation of simulated aircraft engine exhaust plumes. A non-intrusive optical diagnostic technique based on Mie scattering provides ice particle size, number density, and mass density. A suite of commercial extractive particle measurement instruments provides estimates of soot number density, size, and black carbon mass distributions. Measurements are presented for various fuels at chamber conditions covering an altitude range of 20,000 ft (6 km) to 45,000 ft (14 km) altitude and ambient temperatures from -48°C to -68°C. The data presented demonstrate the effect of soot number density, altitude, and fuel-to-air equivalence ratio on the contrail ice particle formation. Ice mass density measurements are compared to values predicted by a thermodynamic plume similarity solution.

Optical Instrumentation↗
NASA NTRSDate not supplied

Rotor Performance Predictions of a Next Generation Mars Science Helicopter

Since Ingenuity took flight and proved aerial capabilities on Mars, the horizon for rotorcraft on the Red Planet has only expanded. One proposed future Martian rotorcraft is the Mars Science Helicopter (MSH). The MSH is a hexacopter capable of carrying scientific payloads. As a part of its joint development by NASA Ames Research Center (ARC) and the Jet Propulsion Laboratory (JPL), key MSH rotor components will be tested inside the in-development Reduced Atmospheric Pressure Testing Of Rotors (RAPTOR) wind tunnel in the Planetary Aeolian Laboratory (PAL) at NASA ARC. In preparation for the test, the Comprehensive Hierarchical Aeromechanics Rotorcraft Model (CHARM) analysis was utilized to predict the aerodynamic performance for one MSH hexacopter isolated rotor. This paper provides an overview of the planned experiments involving the MSH reference blades, as well as CHARM pretest predictions of rotor performance in hover and forward flight. Additionally, the interference effects of wind tunnel walls on rotor performance will be evaluated to inform the test matrix of the upcoming test in the RAPTOR tunnel.

MHS↗
DOE OSTI2020

Synthesis and Characterization of Pd-based Nanomaterials

Bimetallic nanoparticles (BNPs) consist of two different types of metals or alloys that are bonded together. Unique properties such as optical, electronic, thermal, and catalytic effects differ for each type of BNP. Important BNPs range from Au-Pd, Ag- Pt, Au-Pt, and Ag-Ni. Pd bimetallic nanoparticles are of interest due to their many applications such as catalysis and sensing. Bimetallic catalysts have increase reaction rates and have improved catalyst stability through the geometry and ligand distribution. Pd nanoparticles are considered to be a strong catalyst due to their high activity at low temperatures and high tolerance to moisture. The catalytic properties of bimetallic nanoparticles depend on the structural properties such as size and shape. Core-shell, hollow structure, and multi-shell alloy are three possible structures nanoparticles can form as bimetallic catalysts. BNPs can be synthesized through different methods to control the size, shape, and structure. To obtain different morphologies, a variety of methods can be performed. Different methods can range from the usage of the glancing angle deposition (GLAD) to the galvanic replacement reaction, but the methods all depend on the properties of the metals. The galvanic displacement reaction was the method used to obtain Pd-based nanoparticles. This reaction is best know for obtaining hollow shaped NPs. To determine what redox process was preformed, the activity series of metals was used. From the activity series of metals, silver (Ag) was selected to preform Pd-based nanoparticles. Objectives: Synthesize Ag nanoparticles and Ag-Pd nanoparticles to understand the morphology. Characterize the synthesized nanoparticles using scanning electron microscopy (SEM), phase analysis light scattering (PALS), dynamic light scattering (DLS), energy dispersive X-ray spectroscopy (EDS), and UV-Vis spectroscopy. Results: In the UV-Vis spectrum, the Ag-Pd bimetallic NP's plasmon band decreased as the volume of palladium increased. The surface charge increases as the concentration of palladium increases. The Pd{sup 2+} ions interact with the sodium citrate surface, and decrease the negative charge. Conclusion: Ag-Pd nanoparticles were successfully created and stabilized with sodium citrate. The addition of Pd decreased the prominent plasmon band of the Ag nanoparticles. The SEM analysis showed that Ag nanoparticles had a well-defined structure, while the Ag-Pd nanoparticles showed hollow and rough structure. The EDX analysis confirmed the presence of silver and palladium. This material can be used in many industrial and research fields such as organic synthesis, fuel cells, and environmental sensing and remediation.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗
DOE OSTI2020

Functionalized Magnetic Nanoparticles for Technetium Sequestration from Groundwater

Technetium 99 (Tc) is among the most common environmental contaminants at DOE sites and one of the most common risk drivers in low- and high-level waste disposal sites. The majority of Tc is generated from anthropogenic sources, such as nuclear power plants, global weapons, nuclear storage facilities and medical applications. Through these sources, Tc contamination has been unintentionally introduced in to the environment. The most common chemical form of Tc is Tc(VII)O{sub 4}{sup -}. Due to its high solubility and mobility, Tc can enter the food chain and cause adverse health effects to humans. Currently, ion exchange resins and reduction processes are the most common approaches for Tc immobilization. Although these techniques have shown to be effective, they also possess major drawbacks, such as high cost, low adsorption capacity, and complex creation and maintenance. Therefore, development of more efficient and simple technologies for the remediation of Tc-contaminated systems are needed. Functionalized magnetic nanoparticles have been used to remove organic and inorganic contaminants from water resources. These nanoparticles have attracted extensive attention as an adsorbent material due to their large surface area, high efficiency, low-cost, easy functionalization and separation with a magnet. This study seek to develop functionalized magnetic iron oxide nanoparticles for the efficient removal of Tc and other heavy metal contaminants from water resources under ambient conditions. Objectives: Synthesize magnetic iron oxide nanoparticles and functionalize their surface with Cetyltrimethylammonium Bromide (CTAB) and tetraethyl-orthosilicate (TEOS). Characterize the synthesized nanoparticles using scanning electron microscopy (SEM) coupled with energy dispersive X-ray spectroscopy (EDS), Dynamic Light Scattering (DLS) and Zeta PALS. Perform adsorption studies to evaluate their adsorption behavior and capacity for (a) Technetium using Rhenium (ReO{sub 4}{sup -}) as a surrogate and (b) heavy metals, e.g. Cu{sup 2+}. Conclusions: Magnetic iron oxide nanoparticles were successfully functionalized with CTAB and TEOS. The functionalization of the iron oxide nanoparticles affects their surface charge and their hydrodynamic diameter. The addition of CTAB or TEOS decreased the hydrodynamic diameter of the nanoparticles due to repulsive and steric forces. The SEM micrographs show spherical nanoparticles of different sizes. The EDX analysis shows the presence of iron and oxygen from the iron oxide crystalline structure, and the different constituents of the CTAB and TEOS molecules. Proof-of-concept shows the successful adsorption of rhenium (ReO{sub 4}{sup -}) and copper Cu{sup 2+}) onto CTAB-Fe{sub 2}O{sub 3} and TEOS-Fe{sub 2}O{sub 3} respectively.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗
DOE OSTI2026

Cooperative Charge Ordering Signature of Trimer Molecules in Infinite-Layer CaCoO 2

The infinite-layer compound CaCoO 2 provides a compelling platform to explore how local orbital distortions evolve into collective electronic order. Using resonant soft x-ray scattering (RSXS) and its time-resolved counterpart (tr-RSXS), we reveal a cooperative coupling between two intertwined orders at the same in-plane wave vector, 𝑞 ≈ (1/4, 1/4, 0), comprising a quasi-two-dimensional orbital order associated with the distorted Co (1) sites and a quasi-three-dimensional trimerlike charge order stabilized through Co-O-Ca hybridization. The charge-sensitive component exhibits a uniform relaxation time of ∼400 fs (391 ± 5 fs) across multiple Co resonances, evidencing a collective charge response. A comparable timescale observed in the orbital order associated with the highly distorted Co (1) sites indicates that this collective behavior naturally originates from the same orbital framework that mediates both charge and orbital degrees of freedom. Together, these findings establish CaCoO 2 as a model system in which Jahn-Teller distortions, orbital hybridization, and geometric frustration cooperate to form molecular trimer units that dictate the macroscopic electronic behavior.

Lee, J.-S. [SLAC National Accelerator Laboratory (↗
DOE OSTI2018

Equivalence of Einstein and Jordan frames in quantized anisotropic cosmological models

The present work shows that the mathematical equivalence of the Jordan frame and its conformally transformed version, the Einstein frame, so as far as Brans–Dicke theory is concerned, survives a quantization of cosmological models, arising as solutions to the Brans–Dicke theory. We work with the Wheeler–deWitt quantization scheme and take up quite a few anisotropic cosmological models as examples. We effectively show that the transformation from the Jordan to the Einstein frame is a canonical one and hence two frames furnish equivalent description of same physical scenario.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗
DOE OSTI2013

Heavily doped n-type PbSe and PbS nanocrystals using ground-state charge transfer from cobaltocene

Colloidal nanocrystals (NCs) of lead chalcogenides are a promising class of tunable infrared materials for applications in devices such as photodetectors and solar cells. Such devices typically employ electronic materials in which charge carrier concentrations are manipulated through “doping;” however, persistent electronic doping of these NCs remains a challenge. Here, we demonstrate that heavily doped n-type PbSe and PbS NCs can be realized utilizing ground-state electron transfer from cobaltocene. This allows injecting up to eight electrons per NC into the band-edge state and maintaining the doping level for at least a month at room temperature. Doping is confirmed by inter- and intra-band optical absorption, as well as by carrier dynamics. Finally, FET measurements of doped NC films and the demonstration of a p-n diode provide additional evidence that the developed doping procedure allows for persistent incorporation of electrons into the quantum-confined NC states.

36 MATERIALS SCIENCE↗
DOE OSTI2025

Bidirectional Ultrafast Control of Charge Density Waves via Phase Competition

The intricate competition between coexisting charge density waves (CDWs) can lead to rich phenomena, offering unique opportunities for phase manipulation through electromagnetic stimuli. Here, leveraging time-resolved x-ray diffraction, we demonstrate ultrafast control of a CDW in EuTe 4 upon optical excitation. At low excitation intensities, the amplitude of one of the coexisting CDW orders increases at the expense of the competing CDW, whereas at high intensities, it exhibits a nonmonotonic temporal evolution characterized by both enhancement and reduction. This transient bidirectional controllability, tunable by adjusting photoexcitation intensity, arises from the interplay between optical quenching and phase-competition-induced enhancement. Our findings, supported by phenomenological time-dependent Ginzburg-Landau theory simulations, not only clarify the relationship between the two CDWs in EuTe 4 , but also highlight the versatility of optical control over order parameters enabled by phase competition.

charge density waves↗
DOE OSTI2019

Co-infiltration of Nickel and Mixed Conducting Gd 0.1 Ce 0.9 O 2-δ and La 0.6 Sr 0.3 Ni 0.15 Cr 0.85 O 3-δ Phases in Ni-YSZ Anodes for Improved Stability and Performance

Liquid-phase infiltration of nickel (Ni) nanoparticles in Ni/yttria-stabilized-zirconia (YSZ) cermet anodes for solid oxide fuel cells can improve anode performance provided that the infiltrated nanoparticles on YSZ connect to form conducting pathways and the Ni nanoparticles do not coarsen significantly. This study explores liquid phase co-infiltration of Ni with mixed conducting oxides, the latter providing microstructural stability and conductive pathways between Ni nanoparticles. Two mixed conducting oxides have been studied: Gd 0.1 Ce 0.9 O 2-δ (GDC), a predominantly ionic conductor, and La 0.6 Sr 0.3 Ni 0.15 Cr 0.85 O 3-δ (LSNC), a predominantly electronic conductor. Experimental results show that both oxides improve the nickel nanoparticle stability and charge transfer kinetics. However, the electrochemical performance of the Ni-GDC-infiltrated electrode is much better than that of the Ni-LSNC-infiltrated electrode. This is attributed to the citrate–nitrate combustion reaction required to form LSNC, which fills the pores of the anode and inhibits gas diffusion, reducing the performance of the Ni-LSNC-infiltrated electrode.

25 ENERGY STORAGE↗