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At least 235 records · Page 13
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DOE OSTI2026

Vibrational Spin-Orbit Coupling Contributions to Excited State Decay of Ligand-to-Ligand Charge Transfer States

Controlling excited state relaxation processes is important in a variety of photochemical and photophysical processes, including the generation of ground and excited state spin polarization for quantum information science applications. Here, we address how specific static distortions – based on vibrational spin-orbit active modes at C2v symmetry determined by group theory – in a series of low-symmetry ligand-to-ligand charge transfer complexes enable direct spin-orbit coupling contributions to T1 → S0 excited state decay. These results are used to address spin-vibronic coupling contributions to T1 → S0 decay in a high-symmetry (tBu2bpy)Pt(S,S) (tBu2bpy = 4,4’-di-tert-butyl-2,2’-bipyridine and S,S = benzene-1,2-dithiolate) ligand-to-ligand charge transfer complex with effective C2v symmetry, where T1 relaxation is both spin- and orbitally forbidden due to the direct spin-orbit coupling matrix element being zero by symmetry. Low-frequency vibrations that involve a pyridine-pyridine twisting motion within the bpy ligand generate large ∂/∂Qi values that will contribute significantly to T1 → S0 relaxation. The work advances ligand design strategies for the generation of tailored T1 → S0 relaxation rates, which can be utilized to optimize the generation of electron spin polarization in radical-elaborated ligand-to-ligand charge transfer complexes.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
NASA NTRS2010

The Roles of Tidal Evolution and Evaporative Mass Loss in the Origin of CoRoT-7 b

CoRoT-7 b is the first confirmed rocky exoplanet, but, with an orbital semimajor axis of 0.0172 au, its origins may be unlike any rocky planet in our Solar System. In this study, we consider the roles of tidal evolution and evaporative mass loss in CoRoT-7 b's history, which together have modified the planet's mass and orbit. If CoRoT-7 b has always been a rocky body, evaporation may have driven off almost half its original mass, but the mass loss may depend sensitively on the extent of tidal decay of its orbit. As tides caused CoRoT-7 b's orbit to decay, they brought the planet closer to its host star, thereby enhancing the mass loss rate. Such a large mass loss also suggests the possibility that CoRoT-7 b began as a gas giant planet and had its original atmosphere completely evaporated. In this case, we find that CoRoT-7 b's original mass probably did not exceed 200 Earth masses (about two-third of a Jupiter mass). Tides raised on the host star by the planet may have significantly reduced the orbital semimajor axis, perhaps causing the planet to migrate through mean-motion resonances with the other planet in the system, CoRoT-7 c. The coupling between tidal evolution and mass loss may be important not only for CoRoT-7 b but also for other close-in exoplanets, and future studies of mass loss and orbital evolution may provide insight into the origin and fate of close-in planets, both rocky and gaseous.

Jackson, Brian↗
NASA NTRS1999

The Starshine Hitchhiker Mission on STS-96

A mirrored, spherical "Starshine" satellite was ejected by NASA into a circular low Earth orbit from a Hitchhiker canister in the cargo bay of Space Shuttle OV-103 Discovery at 07:21 Universal Time on June 5, 1999, near the end of Discovery's STS-96 mission to the International Space Station. Starshine's initial orbital altitude was 218 Nautical Miles (387 km), and its orbital inclination was 51.6 deg. The satellite is expected to orbit Earth until sometime in January 2000, when it will reenter the atmosphere and vaporize. Some 25,030 students in 700 schools around the world participated in the construction of this satellite by polishing 878 small, front-surface aluminum mirrors that stud its outer surface. A small fraction of those students is presently tracking the satellite and measuring its angular position at specific times. The Naval Research Laboratory is combining the students' measurements with Naval Space Command radar tracking data to compute the satellite's orbit on a daily basis. From the rate of decay of the orbit, the students are able to calculate the density of the atmosphere at the satellite's present altitude. The students are also accessing the project's web site to observe ground-based and space-based images of the sun and other indices of solar activity. They are then using these data to make correlations between the intensity of solar storms and fluctuations in the density of the earth's upper atmosphere. The number of students participating in the tracking phase of the project is expected to increase dramatically at the start of the fall school term in the northern hemisphere. At the conclusion of the Starshine mission, the student team will attempt to predict when and where the satellite will re-enter the atmosphere, so they can compete for a cash prize for the best photograph of the satellite's fiery demise.

Moore, Gil↗
NASA NTRS1985

The enigma of the Uranian satellites' orbital eccentricities

The eccentricity decay times for the Uranian satellites are calculated using recent observations (Brown et al., 1982) of the diameters and orbital elements of the satellites and assuming reasonable dissipation functions and rigidities for icy satellites. For the outer two satellites, Titania and Oberon, the decay times are found to be very long, whereas the inner three satellites, Miranda, Ariel, and Umbriel, have decay times on the order of 10 to the 7th to 10 to the 8th years and have a near-commensurability in their mean motions that cannot force their eccentricities. There are several possible solutions for the lack of resonant forcing: (1) the reported eccentricities are incorrect, and are very nearly zero, (2) the reported mean motions are incorrect, and an exact commensurability exists, (3) the physical properties assumed for the satellites are grossly in error, and (4) the system is evolving rapidly, perhaps from a previous state of higher eccentricity. A new lower bound of about 17,000 on the dissipation function of Uranus is calculated from the mass of Ariel and its proximity to Uranus.

Squyres, S. W.↗
NASA NTRS1985

Orbital Resonances and Planetary Accretion in the Solar Nebula

Planetesimal orbital evolution in a resisting medium near an accreting protoplanet was studied to explore mechanisms for capture into Trojan and satellite orbits. Various mechanisms for capture into libration were proposed, e.g., increase in Jupiter/Sun mass ratio, change in Jovian orbital radius, and collisions of asteroids with interplanetary dust. Studies include effects of solar nebula gas drag on orbital evolution. In general, the gas deviates from Keplerian motion, causing secular decay of planetesimal orbits, as well as damping eccentricity. The motion of bodies near Jupiter under the effect of a resisting medium was numerically explored. The equations of motion were integrated using the formalism of the planar restricted three body problem, modified to include effects by gas drag and a growing Jupiter.

Weidenschilling, S. J.↗
NASA NTRS1985

Langley Research Center Photogrammetric Measurements of Solar Array Dynamics: Preliminary Results

The NASA Langley Research Center participated in the Solar Array Experiment with two primary objectives: (1) to study the structural and control dynamics of a new class of large, lightweight, low-frequency space structures, and (2) to develop technology for remote video measurement of structural motions. The shuttle orbiter's closed circuit television (CCTV) system was used to provide recorded video images of the solar array from four locations in the payload bay, two on the forward bulkhead and two on the aft bulkhead. White reflective targets were placed on the array to provide discrete points at which to track array motion. A dynamic test consisted of a quiescent period in which orbiter operations were inhibited and crew motion restricted, an excitation period, and a free decay period. The orbiter was placed in free drift while in a gravity gradient orientation and dynamics tests were timed to occur at orbital noon so that the Sun would illuminate one side of the array and Earth albedo the other. The CCTV system was turned on during the quiescent period, approximately 3 minutes prior to excitation. Video from all four CCTV cameras was recorded continuously through the excitation and free-decay periods for a total test record of 8 to 10 minutes.

Brumfield, M. L.↗
NASA NTRS1960

The Origin of Tektites

Tektites are probably extraterrestrial, rather than the result of heating some terrestrial materials, because they are a chemically homogeneous group with definite peculiarities (high silica, excess of alkaline earths over alkalis, excess of potash over soda, absence of water), and because some of them (the australites) appear to have undergone ablation in flight through the atmosphere. Since comparatively slow heating is required to explain the liquefaction of the tektite material, it is suggested that the tektites arrived along orbits which were nearly parallel to the surface of the earth, and which resulted from the decay of the orbit of a natural satellite. The great meteor procession of February 9, 1913, is an example of such an object. Comparison with the reentry phenomena of the artificial satellite 1957 Beta suggests that the 1913 shower consisted of a single large stone weighing about 400 kilograms, and a few dozen smaller bodies weighing about 40 grams each, formed by ablation from the larger body. It is shown that under the observed conditions considerable liquid flow would be expected in the stone, which would be heated to about 2100 K. Objects falling from such a shower near the perigee point of the orbit would have a considerable distribution along the orbit as a result of slight variations in height or drag coefficient. The distribution in longitude would be made wider by the turning of the earth under the orbit during the time of fall. The ultimate source of the body which produces a tektite shower is probably the moon, which appears, by virtue of its polarization and the phase distribution of the returned light, to contain high-silica materials. It is suggested that the Igast object alleged to have fallen in 1855 is in fact genuine and represents an unmelted portion of the lunar crust.

OKeefe, J. A.↗
NASA NTRS1985

Orbital resonances in the solar nebula - Implications for planetary accretion

The influence of gas drag and gravitational perturbations by a planetary embryo on the orbit of a planetesimal in the solar nebula was examined. Non-Keplerian rotation of the gas causes secular decay of the orbit. If the planetesimal's orbit is exterior to the perturber's, resonant perturbations oppose this drag and can cause it to be trapped in a stable orbit at a commensurability of order j/(j + 1), where j is an integer. Numerical and analytical demonstrations show that resonant trapping occurs for wide ranges of perturbing mass, planetesimal size, and j. Induced eccentricities are large, causing overlap of orbits for bodies in different resonances with j greater than 2. Collisions between planetesimals in different resonances, or between resonant and nonresonant bodies, result in their disruption. Fragments smaller than a critical size can pass through resonances under the influence of drag and be accreted by the embryo. This effect speeds accretion and tends to prevent dynamical isolation of planetary embryos, making gas-rich scenarios for planetary formation more plausible.

Weidenschilling, S. J.↗
NASA NTRS1985

Models of Angular Momentum Input to a Circumterrestrial Swarm from Encounters with Heliocentric Planetesimals

Models of lunar origin in which the Moon accretes in orbit about the Earth from material approaching the Earth from heliocentric orbits must overcome a fundamental problem: the approach orbits of such material would be, in the simplest approximation, equally likely to be prograde or retrograde about the Earth, with the result that accretion of such material adds mass but not angular momentum to circumterrestrial satellites. Satellite orbits would then decay due to the resulting drag, ultimately impacting onto the Earth. One possibility for adding both material and angular momentum to Earth orbit is investigated: imbalance in the delivered angular momentum between pro and retrograde Earth passing orbits which arises from the three body dynamics of planetesimals approaching the Earth from heliocentric space. In order to study angular momentum delivery to circumterrestrial satellites, the near Earth velocities were numerically computed as a function of distance from the Earth for a large array of orbits systematically spanning heliocentric phase space.

Davis, D. R.↗
NASA NTRS2000

Planet Formation and the Characteristics of Extrasolar Planets

An overview of current theories of planetary growth, emphasizing the formation of extrasolar planets, is presented. Models of planet formation are based upon observations of the Solar System, extrasolar planets, and young stars and their environments. Terrestrial planets are believed to grow via pairwise accretion until the spacing of planetary orbits becomes large enough that the configuration is stable for the age of the system. Giant planets begin their growth like terrestrial planets, but if they become massive enough before the protoplanetary disk dissipates, then they are able to accumulate substantial amounts of gas. These models predict that rocky planets should form in orbit about most single stars. It is uncertain whether or not gas giant planet formation is common, because most protoplanetary disks may dissipate before solid planetary cores can grow large enough to gravitationally trap substantial quantities of gas. A potential hazard to planetary systems is radial decay of planetary orbits resulting from interactions with material within the disk. Planets more massive than Earth have the potential to decay the fastest, and may be able to sweep up smaller planets in their path. The implications of the giant planets found in recent radial velocity searches for the abundances of habitable planets are discussed.

Lissauer, Jack J.↗
NASA NTRS1997

On the Diversity of Planetary Systems

Models of planet formation and of the orbital stability of planetary systems are described and used to discuss possible characteristics of undiscovered planetary systems. Modern theories of star and planet formation, which are based upon observations of the Solar System and of young stars and their environments, predict that rocky planets should form in orbit about most single stars. It is uncertain whether or not gas giant planet formation is common, because most protoplanetary disks may dissipate before solid planetary cores can grow large enough to gravitationally trap substantial quantities of gas. A potential hazard to planetary systems is radial decay of planetary orbits resulting from interactions with material within the disk. Planets more massive than Earth have the potential to decay the fastest, and may be able to sweep up smaller planets in their path. The implications of the giant planets found in recent radial velocity searches for the abundances of habitable planets are discussed.

Lissauer, Jack J.↗
NASA NTRS1999

Formation and Detection of Planetary Systems

Modern theories of star and planet formation and of the orbital stability of planetary systems are described and used to discuss possible characteristics of undiscovered planetary systems. The most detailed models of planetary growth are based upon observations of planets and smaller bodies within our own Solar System and of young stars and their environments. Terrestrial planets are believed to grow via pairwise accretion until the spacing of planetary orbits becomes large enough that the configuration is stable for the age of the system. Giant planets begin their growth as do terrestrial planets, but they become massive enough that they are able to accumulate substantial amounts of gas before the protoplanetary disk dissipates. These models predict that rocky planets should form in orbit about most single stars. It is uncertain whether or not gas giant planet formation is common, because most protoplanetary disks may dissipate before solid planetary cores can grow large enough to gravitationally trap substantial quantities of gas. A potential hazard to planetary systems is radial decay of planetary orbits resulting from interactions with material within the disk. Planets more massive than Earth have the potential to decay the fastest, and may be able to sweep up smaller planets in their path. The implications of the giant planets found in recent radial velocity searches for the abundances of habitable planets are discussed, and the methods that are being used and planned for detecting and characterizing extrasolar planets are reviewed.

Lissauer, Jack J.↗
NASA NTRS2002

Planet Formation

Modern theories of star and planet formation and of the orbital stability of planetary systems are described and used to discuss possible characteristics of undiscovered planetary systems. The most detailed models of planetary growth are based upon observations of planets and smaller bodies within our own Solar System and of young stars and their environments. Terrestrial planets are believed to grow via pairwise accretion until the spacing of planetary orbits becomes large enough that the configuration is stable for the age of the system. Giant planets begin their growth as do terrestrial planets, but they become massive enough that they are able to accumulate substantial amounts of gas before the protoplanetary disk dissipates. These models predict that rocky planets should form in orbit about most single stars. It is uncertain whether or not gas giant planet formation is common, because most protoplanetary disks may dissipate before solid planetary cores can grow large enough to gravitationally trap substantial quantities of gas. A potential hazard to planetary systems is radial decay of planetary orbits resulting from interactions with material within the disk. Planets more massive than Earth have the potential to decay the fastest, and may be able to sweep up smaller planets in their path. The implications of the giant planets found in recent radial velocity searches for the abundances of habitable planets are discussed, and the methods that are being used and planned for detecting and characterizing extrasolar planets are reviewed.

Lissauer, Jack J.↗
NASA NTRS2005

Planet Formation - Overview

Modern theories of star and planet formation are based upon observations of planets and smaller bodies within our own Solar System, exoplanets &round normal stars and of young stars and their environments. Terrestrial planets are believed to grow via pairwise accretion until the spacing of planetary orbits becomes large enough that the configuration is stable for the age of the system. Giant planets begin their growth as do terrestrial planets, but they become massive enough that they are able to accumulate substantial amounts of gas before the protoplanetary disk dissipates. These models predict that rocky planets should form in orbit about most single stars. It is uncertain whether or not gas giant planet formation is common, because most protoplanetary disks may dissipate before solid planetary cores can grow large enough to gravitationally trap substantial quantities of gas. A potential hazard to planetary systems is radial decay of planetary orbits resulting from interactions with material within the disk. Planets more massive than Earth have the potential to decay the fastest, and may be able to sweep up smaller planets in their path.

Lissauer, Jack J.↗
NASA NTRS1997

The Birth of Planetary Systems

Models of planet formation and of the orbital stability of planetary systems are described and used to discuss possible characteristics of undiscovered planetary systems. Modern theories of star and planet formation, which are based upon observations of the Solar System and of young stars and their environments, predict that rocky planets should form in orbit about most single stars. It is uncertain whether or not gas giant planet formation is common, because most protoplanetary disks may dissipate before solid planetary cores can grow large- enough to gravitationally trap substantial quantities of gas. Another potential hazard to planetary systems is radial decay of planetary orbits resulting from interactions with material within the disk. Planets more massive than Earth have the potential to decay the fastest, and may be able to sweep up smaller planets in their path. The implications of the giant planets found in recent radial velocity searches for the abundances of habitable planets are discussed.

Lissauer, Jack J.↗
NASA NTRS1995

Hydrodynamics of coalescing binary neutron stars: Ellipsoidal treatment

We employ an approximate treatment of dissipative hydrodynamics in three dimensions to study the coalescence of binary neutron stars driven by the emission of gravitational waves. The stars are modeled as compressible ellipsoids obeying a polytropic equation of state; all internal fluid velocities are assumed to be linear functions of the coordinates. The hydrodynamics equations then reduce to a set of coupled ordinary differential equations for the evolution of the principal axes of the ellipsoids, the internal velocity parameters, and the binary orbital parameters. Gravitational radiation reaction and viscous dissipation are both incorporated. We set up exact initial binary equilibrium configurations and follow the transition from the quasi-static, secular decay of the orbit at large separation to the rapid dynamical evolution of the configurations just prior to contact. A hydrodynamical instability resulting from tidal interactions significantly accelerates the coalescence at small separation, leading to appreciable radial infall velocity and tidal lag angles near contact. This behavior is reflected in the gravitational waveforms and may be observable by gravitational wave detectors under construction. In cases where the neutron stars have spins which are not aligned with the orbital angular momentum, the spin-induced quadrupole moment can lead to precession of the orbital plane and therefore modulation of the gravitational wave amplitude even at large orbital radius. However, the amplitude of the modulation is small for typical neutron star binaries with spins much smaller than the orbital angular momentum.

Lai, Dong↗
NASA NTRS1984

The evolution of highly compact binary stellar systems in globular clusters

A highly compact binary represents a system which is composed of a collapsed object (degenerate dwarf, neutron star, or black hole) in orbit with a low-mass (equal to or less than 0.5 solar mass) secondary star. Matter may be transferred from the secondary to the collapsed star due to the decay of the orbit resulting from the emission of gravitational radiation. The present investigation has the objective to study quantitatively the evolution of highly compact binaries in globular cluster cores, subject to the interplay of gravitational radiation and collisions with field stars. The investigation is exploratory in nature. The numerical methods employed are based on the techniques developed by Rappaport et al. (1982). It is found that occasional close encounters with field stars strongly dominate the evolution of highly compact binaries in dense globular cluster cores. Attention is given to the applicability of the findings to observations of X-ray sources and cataclysmic variables.

Krolik, J. H.↗