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At least 235 records · Page 13
All sourcesNASA NTRSDOE OSTI
NASA NTRS1992

Compressive strength of directionally solidified NiAl-NiAlNb intermetallics at 1200 and 1300 K

Results are presented from measurements of 1200 K and 1300 K compressive properties of two directionally solidified NiAl-NiAlNb compositions (in at. pct): Ni-41.75Al-16.5Nb (eutectic composition) and Ni-47.5Al-8.9Nb-1.3C (Al-rich composition). Results showed that the strength of the eutectic was a factor of 2 greater than that of the Al-rich composition. However, the analysis of the compressive stress-strain data indicated that the deformation mechanism was the same in both materials.

Whittenberger, J. D.↗
NASA NTRS1992

Effect of an applied magnetic field on the performance of a SIS receiver near 300 GHz

A superconductor-insulator-superconductor (SIS) receiver has been successfully constructed and tested for operation at 265 - 280 GHz using 1 micron/sq area Nb-AlO(x)-Nb tunnel junctions fabricated at Stony Brook. The best performance to date is a double sideband (DSB) receiver noise temperature of 129 K at 278 GHz. It is found that suppression of the Josephson pair currents with a magnetic field is essential for good performance and a stable dc bias point. Fields as high as 280 gauss have been used with no degradation of mixing performance. The improvement in the intermediate frequency output stability with progressively increasing magnetic fields is illustrated.

Mallison, W. H.↗
NASA NTRS1992

Quasi-periodic oscillations in the Z source GX 5-1

A detailed study has been conducted of the time variability in the Z source GX 5-1 using Ginga, which observed the source in the horizontal and normal branches (HB, NB). Intensity-dependent HF, quasi-periodic oscillations (QPO) were observed in the HB, in which the source flux varied by a factor of 1.9. The QPO frequency in this portion of the HB ranges from about 13 to 17 Hz; this is lower than previously observed in any Z source. The HF and LF QPO were simultaneously observed in the NB. The strength of both forms of QPO and the strength of the LF noise increase rapidly with increasing photon energy.

Lewin, Walter H. G.↗
NASA NTRS1992

Stability of the ordered orthorhombic phase in Ti-24Al-11Nb

The ordered orthorhombic 'O' phase in the Ti-Al-Nb ordered alloy system emerges either through slow cooling from above 1200 C or through isothermal aging after quenching from that temperature regime. An experimental investigation is presently conducted of the structural relationship between the O and alpha(2) phases, in order to clarify the mechanism of transition between the two. The transition occurs with the formation of a platelike alpha(2) phase within the O matrix, and may be characterized as due to a shape-deformation mechanism associated with diffusion of excess Nb away from the O/alpha(2) interface.

Hsiung, L. M.↗
NASA NTRS1992

Comparison of measured and predicted performance of a SIS waveguide mixer at 345 GHz

The measured gain and noise of a SIS waveguide mixer at 345 GHz have been compared with theoretical values, calculated from the quantum mixer theory using a three port model. As a mixing element, we use a series array of two Nb-Al2O3-Nb SIS junctions. The area of each junction is 0.8 sq microns and the normal state resistance is 52 omega. The embedding impedance of the mixer has been determined from the pumped DC-IV curves of the junction and is compared to results from scale model measurements (105 x). Good agreement was obtained. The measured mixer gain, however, is a factor of 0.45 plus or minus 0.5 lower than the theoretical predicted gain. The measured mixer noise temperature is a factor of 4-5 higher than the calculated one. These discrepancies are independent on pump power and are valid for a broad range of tuning conditions.

Honingh, C. E.↗
NASA NTRS1993

The kinetics of composite particle formation during mechanical alloying

The kinetics of composite particle formation during attritor milling of insoluble binary elemental powders have been examined. The effects of processing conditions (i.e., mill power, temperature, and charge ratio) on these kinetics were studied. Particle size distributions and fractions of elemental and composite particles were determined as functions of milling time and processing conditions. This allowed the deduction of phenomenological rate constants describing the propensity for fracture and welding during processing. For the mill-operating conditions investigated, the number of particles in the mill generally decreased with milling time, indicating a greater tendency for particle welding than fracture. Moreover, a bimodal size distribution is often obtained as a result of preferential welding. Copper and chromium 'alloy' primarily by encapsulation of Cr particles within Cu. This form of alloying also occurs in Cu-Nb alloys processed at low mill power and/or for short milling times. For other conditions, however, Cu-Nb alloys develop a lamellar morphology characteristic of mechanically alloyed two-phase ductile metals. Increasing mill power or charge (ball-to-powder weight) ratio (CR) increases the rate of composite particle formation.

Aikin, B. J. M.↗
NASA NTRS1993

An experimental study of trace element partitioning between perovskite, hibonite and melt: Equilibrium values

The presence of perovskite (CATiO3) and hibonite (Ca Al12O19) within different regions of Calcium-, Aluminum-rich Inclusions (CAI) and the trace element concentrations of these minerals in each circumstance, constrain models of precursor formation, nebular condensation, the thermal history of inclusions with relict perovskite and hibonite, and the formation of the Wark-Lovering rim. At present mineral/melt partition coefficient data for hibonite are limited to a few elements in simple experimental systems, or to those derived from hibonite-glass pairs in hibonite/glass microspherules. Similarly, there is only limited data on perovskite D that are applicable to meteorite compositions. Apart from the importance of partitioning studies to meteorite research, D values also are invaluable in the development of thermodynamic models, especially when data is available for a large number of elements that have different ionic charge and radii. In addition, study of the effect of rapid cooling on partitioning is crucial to our understanding of meteorite inclusions. To expand our knowledge of mineral/melt D for perovskite and hibonite, a study was instituted where D values are obtained in both equilibrium and dynamic cooling experiments. As an initial phase of this study mineral/melt D was measured for major elements (Ca, Mg, Al, Ti, and Si), 15 rare earth elements (La-Lu) and 8 other elements (Ba, Sr, U, Th, Nb, Zr, Hf, and Ge) in perovskite and hibonite grown under equilibrium conditions, in bulk compositions that are respectively similar to Compact Type A (CTA) CAI and to a hibonite/glass microspherule. Experimental mixes were doped with REE at 20-50x chondritic (ch) abundances, Ba at 50 ppm, Sr, Hf, Nb, and Zr at 100 ppm and, U and Th at 200 ppm. Trace element abundances were measured with the PANURGE ion microprobe. Major element compositions were obtained by electron microprobe analysis.

Kennedy, A. K.↗
NASA NTRS1994

Tropospheric ozone measurements at the equatorial region (1980-1988)

Results from surface ozone measurements at Penang (5.5 deg N, 100 deg E) over 1980-88 period are presented. The study indicates the ozone concentrations undergoing significant diurnal and seasonal variations. The peak concentration are observed at around mid-day (up to 35 nb) but the O3 concentration generally drops to zero level in the early evening and remains unchanged until mid-morning. Monthly-averaged daily 1-h average concentrations are generally small (4-13 nb) and decrease continually from the early part of the year to the end. Frequently, varying local weather conditions seem to influence the O3 concentrations.

Ilyas, Mohammad↗
NASA NTRS1960

Oxidation Behavior of Binary Niobium Alloys

This investigation concludes a study to determine the effects of up to 25 atomic percent of 55 alloying additions on the oxidation characteristics of niobium. The alloys were evaluated by oxidizing in an air atmosphere for 4 hours at 1000 C and 2 hours at 1200 C. Titanium and chromium improved oxidation resistance at both evaluation conditions. Vanadium and aluminum improved oxidation resistance at 1000 C, even though the V scale tended to liquefy and the Al specimens became brittle and the scale powdery. Copper, cobalt, iron, and iridium improved oxidation resistance at 1200 C. Other investigations report tungsten and molybdenum are protective up to about 1000 C, and tantalum at 1100 C. The most important factor influencing the rate of oxidation was the ion size of the alloy additions. Ions slightly smaller than the Nb(5+) ion are soluble in the oxide lattice and tend to lower the compressive stresses in the bulk scale that lead to cracking. The solubility of the alloying addition also depends on the valence to some extent. All of the elements mentioned that improve the oxidation resistance of Nb fit this size criterion with the possible exception of Al, whose extremely small size in large concentrations would probably lead to the formation of a powdery scale. Maintenance of a crack-free bulk scale for as long as possible may contribute to the formation of a dark subscale that ultimately is rate- controlling in the oxidation process. The platinum-group metals, especially Ir, appear to protect by entrapment of the finely dispersed alloying element by the incoming Nb2O5 metal-oxide interface. This inert metallic Ir when alloyed in a sufficient amount with Yb appears to give a ductile phase dispersed in the brittle oxide. This scale would then flow more easily to relieve the large compressive stresses to delay cracking. Complex oxide formation (which both Ti and Zr tend to initiate) and valence effects, which probably change the vacancy concentration in the scale, are masked by the overriding tendency for a porous scale.

Barrett, Charles A.↗
NASA NTRS1999

An Intercomparison of Radiation Codes for Retrieving Upper Tropospheric Humidity in the 6.3-micron Band: A Report from the 1st GVaP Workshop

An intercomparison of radiation codes used in retrieving upper tropospheric humidity (UTH) from observations in the v2 (6.3 microns) water vapor absorption band was performed. This intercomparison is one part of a coordinated effort within the GEWEX Water Vapor Project (GVaP) to assess our ability to monitor the distribution and variations of upper tropospheric moisture from space-borne sensors. A total of 23 different codes, ranging from detailed line-by-line (LBL) models, to coarser resolution narrow-band (NB) models, to highly-parameterized single-band (SB) models participated in the study. Forward calculations were performed using a carefully selected set of temperature and moisture profiles chosen to be representative of a wide range of atmospheric conditions. The LBL model calculations exhibited the greatest consistency with each other, typically agreeing to within 0.5 K in terms of the equivalent blackbody brightness temperature (T(sub b)). The majority of NB and SB models agreed to within +/- 1 K of the LBL models, although a few older models exhibited systematic T(sub b) biases in excess of 2 K. A discussion of the discrepancies between various models, their association with differences in model physics (e.g. continuum absorption), and their implications for UTH retrieval and radiance assimilation is presented.

Soden, B.↗
NASA NTRS1997

Low Noise in a Diffusion-Cooled Hot-Electron Mixer at 2.5 THz

The noise performance of a Nb hot-electron bolometer mixer at 2.5 THz has been investigated. The devices are fabricated from a 12-nm-thick Nb film, and have a 0.30 micrometer x 0.15 micrometer in-plane size, thus exploiting diffusion as the electron cooling mechanism. The rf coupling was provided by a twin-slot planar antenna on an elliptical Si lens. The experimentally measured double sideband noise temperature of the receiver was as low as 2750 +/- 250 K with an estimated mixer noise temperature of approximately equal 900 K. The mixer bandwidth derived from both noise bandwidth and IF impedance measurements was approximately equal 1.4 GHz. These results demonstrate the low-noise operation of the diffusion-cooled bolometer mixer above 2 THz.

Karasik, B. S.↗
NASA NTRS1997

Validity Using Pump-Probe Pulses to Determine the Optical Response of Niobate Crystals

A variety of niobate crystals have found their places in nonlinear optical applications as well as in laser devices. In recent years much attention has been paid to study the ultrafast optical response in a variety of photorefractive crystals such as KTa(1-x)Nb(x)O3 and KNbO3 crystals, glasses, semiconductors and polymers for applications in optical switching, information processing, optical computing, and all-optical device systems. Third-order optical nonlinearity is the most important property for realization of all-optical switching. Therefore experiments have been performed on the third order susceptibility using a variety of techniques such as the third-order harmonic generation, EFISH and degenerate four-wave mixing(DFWM). The latter has been conducted with a variety of pump wavelengths and with nanosecond, picosecond and femtosecond pulses. Niobate crystals, such as potassium niobate KNbO3, potassium tantalate niobate KTN family (KTa(1-x)Nb(x)O3), strontium barium niobate SBN (Sr(x)Ba(1-x)Nb2O6) and potassium-sodium niobate SBN (KNSBN) are attractive due to their photorefractive properties for application in optical storage and processing. The pulsed probe experiments performed on theses materials have suggested two types of time responses. These responses have been associated with an coherent response due to Chi(sup 3), and a long lived component due to excited state population. Recent study of DFWM on KNbO3 and KTN family reveals that the long lived component of those crystals depends on the crystal orientation. A slowly decaying signal is observable when the grating vector K(sub g) is not perpendicular to the C-axis of those photorefractive crystals', otherwise the optical response signal would be only a narrow coherent peak with FWHM equal to the cross-correlation width of the write beam pulses. Based on this understanding, we study the photodynamical process of a variety of niobate crystals using DFWM in a Kg perpindicular to C geometry with a ps-YAG: Nd laser operating at 532nm. However, the discrepancies in numerical estimations of Chi(sup 3) in these materials and other nonlinear optical media have resulted in a number of discussions. In order to better understand the photodynamical process of niobate crystals after an short pulse excitation we analyze the factors governing the coherent signal and present the DFWM spectra of niobate crystals.

Liu, Huimin↗
NASA NTRS2001

Vertical Distribution and Variability of Ozone During July 1999 Over Andenes, Norway

Ozonesonde measurements of the polar atmosphere obtained at Andenes, Norway during July 1999 showed unusual characteristics when compared with mid- or low-latitude ozone profiles. A minimum of two ozonesondes each day were released, one in late afternoon and one in early evening. A very well-defined ledge in the ozone profile corresponding to the tropopause appears to form as a result of transport. The ozone amount increases four to five times, from about 30 nb at the tropopause to 120 nb at a pressure about 10-20 hPa lower. The typical peak ozone value, although at a higher altitude than the ledge, appears at a much lower pressure (approx. 140 hPa) than found in midor low-latitudes (approx. 18-25 hPa), Total column ozone amounts are consistently higher than 300 DU. Analysis of the variation with regard to wind conditions will be discussed.

Schmidlin, F. J.↗
NASA NTRS2003

The Complete Z-diagram of LMC X-2

We present results from four Rossi X-ray Timing Explorer (RXTE) observations of the bright low mass X-ray binary LMC X-2. During these observations, which span a year and include over 160 hrs of data, the source exhibits clear evolution through three branches on its hardness-intensity and color-color diagrams, consistent with the flaring, normal, and horizontal branches (FB, NB, HB) of a Z-source, and remarkably similar to Z-tracks derived for GX 17+2, Sco X-1 and GX 349+2. LMC X-2 was observed in the FB, NB, and HB for roughly 30%, 40%, and 30% respectively of the total time covered. The source traces out the full extent of the Z in approximately 1 day, and the Z-track shows evidence for secular shifts on a timescale in excess of a few days. Although the count rate of LMC X-2 is low compared with the other known 2-sources due to its greater distance, the power density spectra selected by branch show very-low-frequency noise characteristics at least consistent with those from other Z-sources. We thus confirm the identification of LMC X-2 as a Z-source, the first identified outside our Galaxy.

White, Nicholas E.↗
NASA NTRS2003

Microstructure and Mechanical Properties of Extruded Gamma Met PX

A gamma TiAl alloy with a high Nb content is being assessed as a compressor blade material. The microstructure and mechanical properties of extruded Ti-45Al-X(Nb,B,C) (at %) were evaluated in both an as-extruded condition and after a lamellar heat treatment. Tensile behavior of both as-extruded and lamellar heat treated specimens was studied in the temperature range of RT to 926 C. In general, the yield stress and ultimate tensile strength reached relatively high values at room temperature and decreased with increasing deformation temperature. The fatigue strength of both microstructures was characterized at 650 C and compared to a baseline TiAl alloy and to a Ni-base superalloy. Tensile and fatigue specimens were also exposed to 800 C for 200 h in air to evaluate the alloy's environmental resistance. A decrease in ductility was observed at room temperature due to the 800 C exposure but the 650 C fatigue properties were unaffected. Compressive and tensile creep testing between 727 and 1027 C revealed that the creep deformation was reproducible and predictable. Creep strengths reached superalloy-like levels at fast strain rates and lower temperatures but deformation at slower strain rates and/or higher temperature indicated significant weakening for the as-extruded condition. At high temperatures and low stresses, the lamellar microstructure had improved creep properties when compared to the as-extruded material. Microstructural evolution during heat treatment, identification of various phases, and the effect of microstructure on the tensile, fatigue, and creep behaviors is discussed.

Draper, S. L.↗
NASA NTRS2003

Microstructure and Mechanical Properties of Extruded Gamma Microstructure Met PX

A gamma TiAl alloy with a high Nb content is being assessed as a compressor blade material. The microstructure and mechanical properties of extruded Ti-45Al-X(Nb,B,C) (at.%) were evaluated in both an as-extruded condition and after a lamellar heat treatment. Tensile behavior of both as-extruded and lamellar heat treated specimens was studied in the temperature range of RT to 926 C. In general, the yield stress and ultimate tensile strength reached relatively high values at room temperature and decreased with increasing deformation temperature. The fatigue strength of both microstructures was characterized at 650 C and compared to a baseline TiAl alloy and to a Ni-base superalloy. Tensile and fatigue specimens were also exposed to 800 C for 200 h in air to evaluate the alloy's environmental resistance. A decrease in ductility was observed at room temperature due to the 800 C. exposure but the 650 C fatigue properties were unaffected. Compressive and tensile creep testing between 727 and 1027 C revealed that the creep deformation was reproducible and predictable. Creep strengths reached superalloy-like levels at fast strain rates and lower temperatures but deformation at slower strain rates and/or higher temperature indicated significant weakening for the as-extruded condition. At high temperatures and low stresses, the lamellar microstructure had improved creep properties when compared to the as-extruded material. Microstructural evolution during heat treatment, identification of various phases, and the effect of microstructure on the tensile, fatigue, and creep behaviors is discussed.

Draper, S. L.↗
NASA NTRS2005

Energetics of Oxygen Interstitials in Cr and V

Dissolved oxygen in group IIIA-VA (Nb, Ti, Zr, Y) based alloys is a fundamental problem, affecting both mechanical properties and oxidation resistance, yet details of the phenomenon are poorly understood. In these alloys, oxygen is more stable dissolved in the metal than as an oxide-compound. In contrast, alloys based on Ni, Fe, Al and Cr exhibit almost no oxygen solubility. To improve the performance of Nb and Ti based alloys it is necessary to understand the differences in oxygen solubility between these two groups of metals. As a first step we considered the energetics of interstitial oxygen in alpha-V and alpha-Cr. Both of these metals have a BCC structure, yet the oxygen solubility in V is much higher than that in Cr. We obtain total energies, densities of states and population analyses using the CASTEP plane-wave pseudopotential density functional computer code. The differences in the energetics and electronic structures of the two materials, particularly the partial densities of states associated with the interstitial oxygen, are discussed.

Good, Brian S.↗
NASA NTRS2004

Effects of Initial Powder Size on the Mechanical Properties and Microstructure of As-Extruded GRCop-84

GRCop-84 was developed to meet the mechanical and thermal property requirements for advanced regeneratively cooled rocket engine main combustion chamber liners. It is a ternary Cu- Cr-Nb alloy having approximately 8 at% Cr and 4 at% Nb. The chromium and niobium constituents combine to form 14 vol% Cr2Nb, the strengthening phase. The alloy is made by producing GRCop-84 powder through gas atomization and consolidating the powder using extrusion, hot isostatic pressing (HIP) or vacuum plasma spraying (VPS). GRCop-84 has been selected by Rocketdyne, Ratt & Wlutney and Aerojet for use in their next generation of rocket engines. GRCop-84 demonstrates favorable mechanical and thermal properties at elevated temperatures. Compared to NARloy-Z, the currently used inaterial in the Space Shuttle, GRCop-84 has approximately twice the yield strength, 10-1000 times the creep life, and 1.5-2.5 times the low cycle fatigue life. The thermal expansion of GRCop-84 is 7515% less than NARloy-Z which minimizes thermally induced stresses. The thermal conductivity of the two alloys is comparable at low temperature but NARloy-Z has a 20-50 W/mK thermal conductivity advantage at typical rocket engine hot wall temperatures. GRCop-84 is also much more microstructurally stable than NARloy-Z which translates into better long term stability of mechanical properties. Previous research into metal alloys fabricated by means of powder metallurgy (PM), has demonstrated that initial powder size can affect the microstructural development and mechanical properties of such materials. Grain size, strength, ductility, size of second phases, etc., have all been shown to vary with starting powder size in PM-alloys. This work focuses on characterizing the effect of varying starting powder size on the microstructural evolution and mechanical properties of as- extruded GRCop-84. Tensile tests and constant load creep tests were performed on extrusions of four powder meshes: +140 mesh (great3er than l05 micron powder size), -140 mesh (less than or equal to 105 microns), -140 plus or minus 270 (53 - 105 microns), and - 270 mesh (less than or equal to 53 microns). Samples were tested in tension at room temperature and at 500 C (932 F). Creep tests were performed under vacuum at 500 C using a stress of 111 MPa (16.1 ksi). The fracture surfaces of selected samples from both tests were studied using a Scanning Electron Microscope (SEM). The as-extruded materials were also studied, using both optical microscopy and SEM analysis, to characterize changes within the microstructure.

Okoro, Chika L.↗